The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2014
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | 109 S. Ill., graph. Darst. 210 mm x 148 mm, 292 g |
| ISBN: | 9783843917285 3843917280 |
Internformat
MARC
| LEADER | 00000nam a22000008c 4500 | ||
|---|---|---|---|
| 001 | BV042137169 | ||
| 003 | DE-604 | ||
| 005 | 20141120 | ||
| 007 | t | ||
| 008 | 141021s2014 gw ad|| m||| 00||| eng d | ||
| 015 | |a 14,N42 |2 dnb | ||
| 016 | 7 | |a 1059096277 |2 DE-101 | |
| 020 | |a 9783843917285 |c Gb. : EUR 60.00 (DE), EUR 61.70 (AT), sfr 79.00 (freier Pr.) |9 978-3-8439-1728-5 | ||
| 020 | |a 3843917280 |9 3-8439-1728-0 | ||
| 024 | 3 | |a 9783843917285 | |
| 035 | |a (OCoLC)893438845 | ||
| 035 | |a (DE-599)DNB1059096277 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 044 | |a gw |c XA-DE-BY | ||
| 049 | |a DE-91 |a DE-12 | ||
| 082 | 0 | |a 546.6362 |2 22/ger | |
| 084 | |a CHE 376d |2 stub | ||
| 084 | |a CHE 622d |2 stub | ||
| 084 | |a 540 |2 sdnb | ||
| 084 | |a CHE 624d |2 stub | ||
| 100 | 1 | |a Wirth, Andreas S. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts |c Andreas Sebastian Wirth |
| 250 | |a 1. Aufl. | ||
| 263 | |a 201409 | ||
| 264 | 1 | |a München |b Verl. Dr. Hut |c 2014 | |
| 300 | |a 109 S. |b Ill., graph. Darst. |c 210 mm x 148 mm, 292 g | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Anorganische Chemie | |
| 502 | |a Zugl.: München, Techn. Univ., Diss., 2014 | ||
| 650 | 0 | 7 | |a Katalyse |0 (DE-588)4029921-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Palladiumverbindungen |0 (DE-588)4173148-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Kupplungsreaktion |0 (DE-588)4166199-0 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Kupplungsreaktion |0 (DE-588)4166199-0 |D s |
| 689 | 0 | 1 | |a Katalyse |0 (DE-588)4029921-1 |D s |
| 689 | 0 | 2 | |a Palladiumverbindungen |0 (DE-588)4173148-7 |D s |
| 689 | 0 | |5 DE-604 | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |a Wirth, Andreas S. |t The Nature of the Active Palladium-Species in C-C Coupling Reactions with Supported Pd-Catalysts |
| 856 | 4 | 2 | |m X:MVB |q text/html |u http://deposit.dnb.de/cgi-bin/dokserv?id=4788844&prov=M&dok_var=1&dok_ext=htm |3 Inhaltstext |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027577212&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-027577212 | |
Datensatz im Suchindex
| _version_ | 1809770492448473088 |
|---|---|
| adam_text |
TABLE OF CONTENTS
1. INTRODUCTION 1
1.1. PALLADIUM-CATALYZED COUPLING REACTIONS 3
1.1.1. OVERVIEW 4
1.1.2. MECHANISTIC CONSIDERATIONS 8
1.2. LEACHING 11
1.2.1. SIGNIFICANCE OFLEACHING IN C-C CROSS-COUPLING REACTIONS 11
1.2.2. DISTINCTION BETWEEN HOMOGENEOUS AND HETEROGENEOUS REACTION
PATHWAYS. 13
1.2.3. CONSEQUENCES FOR MECHANISTIC STUDIES 16
1.3. MOTIVATION AND AIM OF THE PRESENT WORK 18
2. CHARACTERISTICS AND FEATURES OF THE PALLADIUM CATALYSTS APPLIED 21
2.1. PALLADIUM ON ACTIVATED CARBON 22
2.2. CATALYSTS PREPARED BY CONTROLLED PRECIPITATION OF PALLADIUM ONTO
SILICA 24
3. PALLADIUM NANOPARTICLES AS CATALYSTS FOR THE SUZUKI REACTION 27
3.1. STUDIES IN BIPHASIC REACTION MIXTURES 28
3.2. PD-NANOPARTICLES IN SOLUTION AND SUPPORTED ON SILICA 36
3.3. CONCLUSIONS: THE ACTIVE SPECIES IN THE SUZUKI REACTION .'. 40
4. CONTINUOUS GAS FLOW REACTOR FOR THE HECK COUPLING REACTION 43
4.1. CONSTRUCTION OF THE FIXED BED REACTOR 44
4.2. ADVANTAGES AND CONSTRICTIONS 47
4.2.1. SCOPE OF APPLICATIONS 47
4.2.2. MODIFICATIONS 49
4.2.3. LIMITATIONS 52
HTTP://D-NB.INFO/1059096277
5. THE CONTRIBUTION OF SOLID PALLADIUM SURFACES DURING HECK REACTIONS 55
5.1. WORKING HYPOTHESIS 56
5.2. INFLUENCES OF THE REACTION PARAMETERS ON HECK COUPLING,
DEHALOGENATION AND
LEACHING 58
5.2.1. ROLE OF ADDITIVES 59
5.2.2. ROLE OF THE OXIDATION STATE OF PALLADIUM 60
5.2.3. ROLE OF THE PALLADIUM DISPERSION 61
5.2.4. ROLE OF THE BASE 63
5.2.5. INFLUENCE OF REDUCTIVE ENVIRONMENT 64
5.3. HECK REACTIONS IN THE GASEOUS PHASE 69
5.4. DISCUSSION OF THE REACTION MECHANISM 73
5.5. CONCLUSIONS: THE ACTIVE SPECIES IN THE HECK REACTION 77
6. SUMMARY 79
7. ZUSAMMENFASSUNG 85
8. EXPERIMENTAL SECTION 91
8.1. GENERAL REMARKS 92
8.1.1. CHEMICALS 92
8.1.2. ANALYTIC METHODS 92
8.1.3. APPARATUS 95
8.2. CATALYST PREPARATION 96
8.3. CATALYTIC EXPERIMENTS 98
8.3.1. SUZUKI COUPLING 98
8.3.2. HECK COUPLING 100
9. APPENDIX 101
10. REFERENCES 105 |
| any_adam_object | 1 |
| author | Wirth, Andreas S. |
| author_facet | Wirth, Andreas S. |
| author_role | aut |
| author_sort | Wirth, Andreas S. |
| author_variant | a s w as asw |
| building | Verbundindex |
| bvnumber | BV042137169 |
| classification_tum | CHE 376d CHE 622d CHE 624d |
| ctrlnum | (OCoLC)893438845 (DE-599)DNB1059096277 |
| dewey-full | 546.6362 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546.6362 |
| dewey-search | 546.6362 |
| dewey-sort | 3546.6362 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| edition | 1. Aufl. |
| format | Thesis Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>00000nam a22000008c 4500</leader><controlfield tag="001">BV042137169</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20141120</controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">141021s2014 gw ad|| m||| 00||| eng d</controlfield><datafield tag="015" ind1=" " ind2=" "><subfield code="a">14,N42</subfield><subfield code="2">dnb</subfield></datafield><datafield tag="016" ind1="7" ind2=" "><subfield code="a">1059096277</subfield><subfield code="2">DE-101</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">9783843917285</subfield><subfield code="c">Gb. : EUR 60.00 (DE), EUR 61.70 (AT), sfr 79.00 (freier Pr.)</subfield><subfield code="9">978-3-8439-1728-5</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">3843917280</subfield><subfield code="9">3-8439-1728-0</subfield></datafield><datafield tag="024" ind1="3" ind2=" "><subfield code="a">9783843917285</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)893438845</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DNB1059096277</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="044" ind1=" " ind2=" "><subfield code="a">gw</subfield><subfield code="c">XA-DE-BY</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-91</subfield><subfield code="a">DE-12</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">546.6362</subfield><subfield code="2">22/ger</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 376d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 622d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">540</subfield><subfield code="2">sdnb</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 624d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Wirth, Andreas S.</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts</subfield><subfield code="c">Andreas Sebastian Wirth</subfield></datafield><datafield tag="250" ind1=" " ind2=" "><subfield code="a">1. Aufl.</subfield></datafield><datafield tag="263" ind1=" " ind2=" "><subfield code="a">201409</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">München</subfield><subfield code="b">Verl. Dr. Hut</subfield><subfield code="c">2014</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">109 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield><subfield code="c">210 mm x 148 mm, 292 g</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="490" ind1="0" ind2=" "><subfield code="a">Anorganische Chemie</subfield></datafield><datafield tag="502" ind1=" " ind2=" "><subfield code="a">Zugl.: München, Techn. Univ., Diss., 2014</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Katalyse</subfield><subfield code="0">(DE-588)4029921-1</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Palladiumverbindungen</subfield><subfield code="0">(DE-588)4173148-7</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Kupplungsreaktion</subfield><subfield code="0">(DE-588)4166199-0</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4113937-9</subfield><subfield code="a">Hochschulschrift</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Kupplungsreaktion</subfield><subfield code="0">(DE-588)4166199-0</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Katalyse</subfield><subfield code="0">(DE-588)4029921-1</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="2"><subfield code="a">Palladiumverbindungen</subfield><subfield code="0">(DE-588)4173148-7</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="776" ind1="0" ind2="8"><subfield code="i">Erscheint auch als</subfield><subfield code="n">Online-Ausgabe</subfield><subfield code="a">Wirth, Andreas S.</subfield><subfield code="t">The Nature of the Active Palladium-Species in C-C Coupling Reactions with Supported Pd-Catalysts</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">X:MVB</subfield><subfield code="q">text/html</subfield><subfield code="u">http://deposit.dnb.de/cgi-bin/dokserv?id=4788844&prov=M&dok_var=1&dok_ext=htm</subfield><subfield code="3">Inhaltstext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027577212&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="943" ind1="1" ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-027577212</subfield></datafield></record></collection> |
| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV042137169 |
| illustrated | Illustrated |
| indexdate | 2024-09-10T01:27:16Z |
| institution | BVB |
| isbn | 9783843917285 3843917280 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027577212 |
| oclc_num | 893438845 |
| open_access_boolean | |
| owner | DE-91 DE-BY-TUM DE-12 |
| owner_facet | DE-91 DE-BY-TUM DE-12 |
| physical | 109 S. Ill., graph. Darst. 210 mm x 148 mm, 292 g |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Verl. Dr. Hut |
| record_format | marc |
| series2 | Anorganische Chemie |
| spelling | Wirth, Andreas S. Verfasser aut The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts Andreas Sebastian Wirth 1. Aufl. 201409 München Verl. Dr. Hut 2014 109 S. Ill., graph. Darst. 210 mm x 148 mm, 292 g txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2014 Katalyse (DE-588)4029921-1 gnd rswk-swf Palladiumverbindungen (DE-588)4173148-7 gnd rswk-swf Kupplungsreaktion (DE-588)4166199-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Kupplungsreaktion (DE-588)4166199-0 s Katalyse (DE-588)4029921-1 s Palladiumverbindungen (DE-588)4173148-7 s DE-604 Erscheint auch als Online-Ausgabe Wirth, Andreas S. The Nature of the Active Palladium-Species in C-C Coupling Reactions with Supported Pd-Catalysts X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4788844&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027577212&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wirth, Andreas S. The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts Katalyse (DE-588)4029921-1 gnd Palladiumverbindungen (DE-588)4173148-7 gnd Kupplungsreaktion (DE-588)4166199-0 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4173148-7 (DE-588)4166199-0 (DE-588)4113937-9 |
| title | The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts |
| title_auth | The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts |
| title_exact_search | The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts |
| title_full | The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts Andreas Sebastian Wirth |
| title_fullStr | The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts Andreas Sebastian Wirth |
| title_full_unstemmed | The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts Andreas Sebastian Wirth |
| title_short | The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts |
| title_sort | the nature of the active palladium species in c c coupling reactions with supported pd catalysts |
| topic | Katalyse (DE-588)4029921-1 gnd Palladiumverbindungen (DE-588)4173148-7 gnd Kupplungsreaktion (DE-588)4166199-0 gnd |
| topic_facet | Katalyse Palladiumverbindungen Kupplungsreaktion Hochschulschrift |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4788844&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027577212&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT wirthandreass thenatureoftheactivepalladiumspeciesincccouplingreactionswithsupportedpdcatalysts |