Advanced hydrogel-based chemical microsensors:
Gespeichert in:
1. Verfasser: | |
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Format: | Abschlussarbeit Buch |
Sprache: | English |
Veröffentlicht: |
Dresden
TUDpress
2013
|
Schriftenreihe: | Dresdner Beiträge zur Sensorik
50 |
Schlagworte: | |
Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
Beschreibung: | XXIII, 212 S. Ill., graph. Darst. |
ISBN: | 9783944331300 |
Internformat
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Datensatz im Suchindex
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adam_text |
CONTENTS
LIST OF SYMBOLS XV
LIST OF ABBREVIATIONS XXI
I INTRODUCTION AND THEORY
1 INTRODUCTION 3
1.1 BACKGROUND AND MOTIVATION 3
1.2 HYDROGELS AND THEIR APPLICATIONS 5
1.2.1 DEFINITION, PROPERTIES, AND CLASSIFICATION 5
1.2.2 HYDROGELS FOR SENSOR APPLICATIONS 7
1.3 STATE OF THE ART OF HYDROGEL-BASED SENSORS 9
1.3.1 FUNDAMENTAL PRINCIPLE OF HYDROGEL-BASED SENSORS 9
1.3.2 CONDUCTOMETRIC SENSORS 10
1.3.3 OPTICAL SENSORS 10
1.3.4 RESONANCE FREQUENCY-BASED SENSORS 17
1.3.5 MECHANICAL SENSORS 18
1.3.6 SUMMARY 20
1.4 SCOPE OF THIS WORK 22
2 THEORETICAL FOUNDATIONS 25
2.1 HYDROGEL SWELLING 25
2.1.1 THERMODYNAMICS OF SWELLING EQUILIBRIUM 25
2.1.2 KINETICS OF THE SWELLING PROCESS 32
2.1.3 LINEAR MECHANICAL HYDROGEL MODELS 36
2.2 PIEZORESISTIVE PRESSURE TRANSDUCERS 37
2.2.1 PIEZORESISTIVE EFFECT 37
2.2.2 INFLUENCE OF THE GEOMETRIC PROPERTIES OF THE FLEXURE PLATE ON
SENSITIVITY 39
2.2.3 INFLUENCE OF LOCAL STIFFENING OF THE FLEXURE PLATE 40
II HYBRID HYDROGELS AS SENSOR MATERIAL
3 SENSORS BASED ON POROUS HYDROGELS 45
3.1 POROUS HYDROGELS 45
3.1.1 CLASSIFICATION AND FEATURES 45
3.1.2 PREPARATION METHODS 46
3.1.3 HYDROGEL SYNTHESIS 47
HTTP://D-NB.INFO/1045637599
CONTENTS
3.2 HYDROGEL CHARACTERIZATION 48
3.2.1 FREE-SWELLING MEASUREMENTS 48
3.2.2 ATR-FTIR SPECTROSCOPY 53
3.2.3 SEM MEASUREMENTS 54
3.2.4 MERCURY INTRUSION POROSIMETRY 55
3.3 SENSOR INTEGRATION 57
3.3.1 SENSOR LAYER FABRICATION 57
3.3.2 SENSOR SET-UP 60
3.4 SENSOR CHARACTERIZATION 61
3.4.1 SENSOR CONDITIONING 61
3.4.2 TRANSFER CHARACTERISTICS
V
. 62
3.4.3 TIME-DEPENDENT SENSOR RESPONSE 63
3.5 CONCLUSIONS AND SUMMARY 65
4 SENSORS BASED ON CLAY NANOCOMPOSITE HYDROGELS 67
4.1 PNIPAAM HYDROGEL NETWORKS 67
4.1.1 SENSORIC PROPERTIES 67
4.1.2 CONVENTIONAL GELS 68
4.1.3 STRATEGIES FOR PREPARATION OF MECHANICALLY STABLE HYDROGELS . . 69
4.2 CLAY NANOCOMPOSITE HYDROGELS 69
4.2.1 LAYERED SILICATES 69
4.2.2 SENSOR LAYER FABRICATION 71
4.2.3 STRUCTURAL CHARACTERIZATION 72
4.2.4 MECHANICAL CHARACTERIZATION 74
4.3 SENSOR SET-UP 79
4.4 SENSOR CHARACTERIZATION 80
4.4.1 SENSOR CONDITIONING 80
4.4.2 TEMPERATURE-INDUCED SENSOR RESPONSE 82
4.4.3 SENSOR RESPONSE TO ORGANIC CO-SOLVENTS 85
4.4.4 SENSOR RESPONSE TO MONOVALENT SALT IONS 88
4.5 CONCLUSIONS AND SUMMARY 90
III
HYDROGEL SENSORS
WITH FORCE
COMPENSATION
5 FORCE COMPENSATION METHOD 95
5.1 BASIC CONCEPT OF COMPENSATION 95
5.2 GENERAL SENSOR MODEL FOR DEFLECTION METHOD 97
5.2.1 SENSOR MODEL 97
5.2.2 QUASI-STATIC SENSOR BEHAVIOR 100
5.2.3 RESPONSE TIME 102
5.3 GENERAL SENSOR MODEL FOR COMPENSATION METHOD 103
5.3.1 SYSTEM MODEL 103
5.3.2 STABILITY REQUIREMENTS 107
5.3.3 STEADY-STATE BEHAVIOR 109
CONTENTS
5.3.4 DYNAMIC SYSTEM BEHAVIOR 118
5.4 CONCLUSIONS AND SUMMARY 125
6 CLOSED-LOOP HYDROGEL-BASED SENSOR 127
6.1 SENSOR CONCEPT 127
6.1.1 GENERAL SENSOR PRINCIPLE AND SENSOR STRUCTURE 127
6.1.2 THEORETICAL IMPLICATIONS FOR LIYDROGEL SENSORS IN CLOSED-LOOP
CONFIGURATION 129
6.1.3 DESIGN SPECIFICATIONS 130
6.2 CONSTRUCTION OF THE SENSOR ELEMENT 130
6.2.1 STRUCTURAL SET-UP' 130
6.2.2 FABRICATION OF THE SENSOR ELEMENT COMPONENTS 133
6.2.3 ASSEMBLY AND PACKAGING 141
6.3 SENSOR IN CLOSED-LOOP CONFIGURATION AND ITS COMPONENTS 143
6.3.1 MODEL OF THE SYSTEM STRUCTURE 143
6.3.2 MEASURING UNIT 144
6.3.3 CONTROLLER 146
6.3.4 ACTUATOR 146
6.3.5 HYDROGEL LAYER 147
6.4 SYSTEM IDENTIFICATION AND ANALYSIS 148
6.4.1 IDENTIFICATION OF MODEL COMPONENTS 148
6.4.2 STABILITY ANALYSIS AND PARAMETER ESTIMATION 152
6.5 MEASUREMENT PROCEDURE AND EXPERIMENTAL RESULTS 153
6.5.1 GENERAL MEASUREMENT PROCEDURE 153
6.5.2 REFERENCE PRESSURE ADJUSTMENT 154
6.5.3 SENSOR CONDITIONING 157
6.5.4 PH MEASUREMENT 159
6.5.5 NOISE SUPPRESSION 164
6.5.6 MODEL VALIDATION 164
6.6 CONCLUSIONS AND SUMMARY 165
IV SUMMARY AND FUTURE PROSPECTS
7 SUMMARY 169
7.1 SENSORS BASED ON HYDROGELS WITH IMPROVED MATERIAL PROPERTIES .
169
7.2 HYDROGEL SENSORS WITH FORCE COMPENSATION 171
8 FUTURE PROSPECTS 175
8.1 SENSORS BASED ON HYDROGELS WITH IMPROVED MATERIAL PROPERTIES .
175
8.2 HYDROGEL SENSORS WITH FORCE COMPENSATION 176
V APPENDICES
CONTENTS
A HYDROGEL MATERIAL 181
A.L P(AAM-CO-AA) HYDROGELS 181
A. 1.1 SYNTHESIS 181
A. 1.2 SEM CHARACTERIZATION 183
A.2 NC- AND BIS-PNIPAAM HYDROGELS 184
A.3 PVA/PAA HYDROGELS 184
B SUPPLEMENTARY CALCULATIONS FOR FORCE COMPENSATION 187
B.L APPLICATION OF THE ROUTH CRITERION 187
B.2 CLOSED-LOOP SENSOR WITH TIME-DEPENDENT PARAMETER VARIATIONS 189
B.2.1 PARAMETER RANGE FOR STABILITY AND MINIMUM-PHASE SYSTEM FOR
DRIFT-AFFLICTED SENSORS 189
B.2.2 ISE QUALITY CRITERIA FOR DIFFERENT CONTROLLER TYPES 189
B.3 REDEVELOPMENT OF DENOMINATOR POLYNOMIAL 191
BIBLIOGRAPHY 193 |
any_adam_object | 1 |
author | Schulz, Volker 1982- |
author_GND | (DE-588)1047523833 |
author_facet | Schulz, Volker 1982- |
author_role | aut |
author_sort | Schulz, Volker 1982- |
author_variant | v s vs |
building | Verbundindex |
bvnumber | BV042048594 |
classification_rvk | ZQ 3120 |
ctrlnum | (OCoLC)867868857 (DE-599)DNB1045637599 |
dewey-full | 621.3 681.2 |
dewey-hundreds | 600 - Technology (Applied sciences) |
dewey-ones | 621 - Applied physics 681 - Precision instruments and other devices |
dewey-raw | 621.3 681.2 |
dewey-search | 621.3 681.2 |
dewey-sort | 3621.3 |
dewey-tens | 620 - Engineering and allied operations 680 - Manufacture of products for specific uses |
discipline | Handwerk und Gewerbe / Verschiedene Technologien Elektrotechnik / Elektronik / Nachrichtentechnik Mess-/Steuerungs-/Regelungs-/Automatisierungstechnik / Mechatronik |
format | Thesis Book |
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spelling | Schulz, Volker 1982- Verfasser (DE-588)1047523833 aut Advanced hydrogel-based chemical microsensors Volker Schulz 201401 Dresden TUDpress 2013 XXIII, 212 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Dresdner Beiträge zur Sensorik 50 Zugl.: Dresden, Techn. Univ., Diss., 2013 Mikrosensor (DE-588)4561097-6 gnd rswk-swf Piezowiderstandseffekt (DE-588)4211489-5 gnd rswk-swf Funktionsgel (DE-588)4687871-3 gnd rswk-swf Resistiver Sensor (DE-588)7825997-6 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Funktionsgel (DE-588)4687871-3 s Resistiver Sensor (DE-588)7825997-6 s Piezowiderstandseffekt (DE-588)4211489-5 s Mikrosensor (DE-588)4561097-6 s DE-604 Dresdner Beiträge zur Sensorik 50 (DE-604)BV011109099 50 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4550497&prov=M&dok%5Fvar=1&dok%5Fext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027489733&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Schulz, Volker 1982- Advanced hydrogel-based chemical microsensors Dresdner Beiträge zur Sensorik Mikrosensor (DE-588)4561097-6 gnd Piezowiderstandseffekt (DE-588)4211489-5 gnd Funktionsgel (DE-588)4687871-3 gnd Resistiver Sensor (DE-588)7825997-6 gnd |
subject_GND | (DE-588)4561097-6 (DE-588)4211489-5 (DE-588)4687871-3 (DE-588)7825997-6 (DE-588)4113937-9 |
title | Advanced hydrogel-based chemical microsensors |
title_auth | Advanced hydrogel-based chemical microsensors |
title_exact_search | Advanced hydrogel-based chemical microsensors |
title_full | Advanced hydrogel-based chemical microsensors Volker Schulz |
title_fullStr | Advanced hydrogel-based chemical microsensors Volker Schulz |
title_full_unstemmed | Advanced hydrogel-based chemical microsensors Volker Schulz |
title_short | Advanced hydrogel-based chemical microsensors |
title_sort | advanced hydrogel based chemical microsensors |
topic | Mikrosensor (DE-588)4561097-6 gnd Piezowiderstandseffekt (DE-588)4211489-5 gnd Funktionsgel (DE-588)4687871-3 gnd Resistiver Sensor (DE-588)7825997-6 gnd |
topic_facet | Mikrosensor Piezowiderstandseffekt Funktionsgel Resistiver Sensor Hochschulschrift |
url | http://deposit.dnb.de/cgi-bin/dokserv?id=4550497&prov=M&dok%5Fvar=1&dok%5Fext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027489733&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV011109099 |
work_keys_str_mv | AT schulzvolker advancedhydrogelbasedchemicalmicrosensors |