Introduction to polymer science and chemistry: a problem-solving approach
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Boca Raton, Fla. [u.a.]
CRC Press
2013
|
| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Item Description: | Includes bibliographical references and index |
| Physical Description: | XXI, 748 S. Ill., graph. Darst. |
| ISBN: | 9781466553842 |
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| 100 | 1 | |a Chanda, Manas |d 1940- |e Verfasser |0 (DE-588)136724868 |4 aut | |
| 245 | 1 | 0 | |a Introduction to polymer science and chemistry |b a problem-solving approach |c Manas Chanda |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Boca Raton, Fla. [u.a.] |b CRC Press |c 2013 | |
| 300 | |a XXI, 748 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Polymerization | |
| 650 | 4 | |a Polymerization |v Problems, exercises, etc | |
| 650 | 4 | |a Polymers | |
| 650 | 4 | |a Polymers |v Problems, exercises, etc | |
| 650 | 0 | 7 | |a Polymerisation |0 (DE-588)4046704-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Polymere |0 (DE-588)4046699-1 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Polymere |0 (DE-588)4046699-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Polymerisation |0 (DE-588)4046704-1 |D s |
| 689 | 1 | |5 DE-604 | |
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| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027431334&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |3 Klappentext |
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| adam_text | Contents
Preface
xvii
Author
xxi
1
Introductory Concepts
1
1.1
Basic Definitions
.................................. 1
1.1.1
Polymer
................................... 1
1.1.2
Monomer
.................................. 2
1.1.3
Molecular Weight and Molar Mass
..................... 3
1.1.4
End Groups
................................. 3
1.1.5
Degree of Polymerization
......................... 4
1.1.6
Copolymers
................................. 4
1.2
Polymerization and Functionality
.......................... 5
1.3
Polymerization Processes
.............................. 7
1.3.1
Addition or Chain Polymerization
..................... 7
1.3.2
Step Polymerization
............................ 11
1.3.3
Supramolecular Polymerization
...................... 13
1.4
Molecular Architecture
............................... 18
1.5
Classification of Polymers
............................. 22
1.5.1
Thermoplastics and
Thermosets
...................... 22
1.6
Plastics, Fibers, and Elastomers
........................... 26
1.7
Polymer Nomenclature
............................... 29
References
......................................... 31
Exercises
.......................................... 31
2
Chain Dimensions, Structures, and Transitional Phenomena
35
2.1
Introduction
..................................... 35
2.2
Polymer Chains: Structures and Dimensions
................... 35
2.2.1
Conformational Changes
.......................... 35
2.2.1.1
Polyethylene
........................... 38
2.2.1.2
Polyisobutylene
......................... 39
2.2.1.3
Polypropylene
.......................... 40
2.2.2
Polymer Conformations in Crystals
.................... 40
2.2.3
Polymer Size in the Amorphous State
................... 42
2.2.3.1
Freely Jointed Chains
...................... 43
2.2.3.2
Real Polymer Chains
...................... 44
vii
Conic· fits
VJJJ
2.3
Constitutional and Configurational Isomerism
...................
47
2.3.1
Constitutional Isomerism
.......................... **
2.3.2
Configurational Isomerism
......................... 50
2.3.2.1
Geometrical Isomerism
.....................
S(i
2.3.2.2
Stereoisomcrism
......................... $0
2.4
Crystallinity in Polymers
..............................
s7
2.4.1
Structure of Bulk Polymers
.........................
59
2.4.1.1
Spherulites
............................
59
2.5
Thermal Transitions in Polymers
..........................
61
2.5.1
7І
and7^
..................................
6I
2.5.2
First-and Second-Order Transitions
....................
f>3
2.6
Regions of Viscoclastic Behavior
..........................
f)^
2.7
Factors Affecting TK
.................................
66
2.8
Factors Affecting Tm
................................
(}H
2.9
Relation Between Tm and
Г^
............................
M
2.10
Theoretical Treatment of Glass Transition
..................... 6°
2.10.1
Quantitative Effects of Factors on TH
.................... 74
2.11
Chain Movements in Amorphous State
.......................
KO
2.11.1
The
Reptation
Model
............................
HI
2.12
Thermodynamics of Rubber Elasticity
.......................
КЗ
2.12.1
Stress-Strain Behavior of Crosslinkcd Elastomers
.............
H5
2.12.2 Nonideal
Networks
............................. 91
2.12.2.1
Network Defects
.........................
*>1
2.12.2.2
Elastically Active Chain Sections
................ 91
References
......................................... 93
Exercises
.......................................... 94
3
Polymers in Solution
101
3.1
Introduction
..................................... 101
3.2
Thermodynamics of Liquid Mixtures
........................ 101
3.2.1
Low-Molecular-Weight Mixtures: van
Laar
Model
............ 104
3.2.2
Polymer-Solvent Mixtures: Flory-Huggins Model
............ 107
3.2.2.1
Flory-Huggins Expressions for Thermodynamic Functions
. .
Ill
3.2.2.2
Colligative Properties and Interaction Parameter^
....... 113
3.2.2.3
Virial Coefficients
........................ 117
3.2.2.4
Modification of Flory-Huggins Theory
............. 119
3.2.2.5
Flory-Krigbaum Theory
..................... 121
3.2.2.6
Excluded Volume Theory
.................... 122
3.3
Phase Equilibria in Poor Solvents
.......................... 126
3.3.1
Upper and Lower Critical Solution Temperatures
............. 129
3.4
Solubility Behavior of Polymers
.......................... 131
3.5
Swelling of Crosslinked Polymers
........................, 138
3.5.1
Determination of
χ
from Swelling
..................... 142
3.6
Fractional Properties of Polymer Molecules
in Dilute Solution
........................... 143
3.6.1
Viscosity of Dilute Polymer Solutions
................... 145
3.6.1.1
Determination of Polymer Molecular Dimensions from Viscosity
148
References
........................ 151
Contents
¡χ
Exercises
.......................................... 152
4 Polymer
Molecular
Weights
159
4.1
Introduction
..................................... 159
4.2
Molecular Weight Averages
............................. 159
4.2.1
Arithmetic Mean
.............................. 159
4.2.2
Number-Average Molecular Weight
.................... 160
4.2.3
Weight-Average Molecular Weight
..................... 162
4.3
Molecular Weights in Terms of Moments
..................... 163
4.3.1
Ratio of First and Zeroth Moments
..................... 164
4.3.2
Ratios of Higher Moments
......................... 165
4.4
Molecular Weight Determination
.......................... 166
4.4.1
End-Group Analysis
............................ 167
4.4.2
Colligativc Property Measurement
..................... 168
4.4.2.1
Ebulliometry (Boiling Point Elevation)
............. 168
4.4.2.2
Cryoscopy (Freezing Point Depression)
............. 169
4.4.2.3
Membrane Osmometry
..................... 169
4.4.2.4
Vapor-Phase Osmometry
.................... 176
4.4.3
Light-Scattering Method
.......................... 180
4.4.3.1
Rayleigh Ratio
.......................... 181
4.4.3.2
Turbidity and Rayleigh Ratio
.................. 183
4.4.3.3
Turbidity and Molecular Weight of Polymer
.......... 184
4.4.3.4
Dissymmetry of Scattering
................... 188
4.4.3.5
Zimm Plots
........................... 191
4.4.4
Dilute Solution Viscometry
......................... 194
4.4.4.1
Calibration of the Mark-Houwink-Sakurada Equation
..... 196
4.4.4.2
Measurement of Intrinsic Viscosity
............... 197
4.4.5
Gel Permeation Chromatography
..................... 200
4.4.5.1
Data Interpretation and Calibration
............... 202
References
......................................... 208
Exercises
.......................................... 208
5
Condensation (Step-Growth) Polymerization
213
5.1
Introduction
..................................... 213
5.2
Rates of Polycondensation Reactions
........................ 214
5.2.1
Irreversible Polycondensation Kinetics
.................. 216
5.2.2
Reversible Polycondensation Kinetics
................... 222
5.3
Number-Average Degree of Polymerization
.................... 224
5.4
Control of Molecular Weight
............................ 227
5.4.1
Quantitative Effect of Stoichiometric Imbalance
.............. 228
5.5
Molecular Weight Distribution (MWD)
...................... 232
5.5.1
Breadth of MWD
.............................. 234
5.6
Nonlinear Step Polymerization
........................... 241
5.6.1
Branching
.................................. 241
5.6.2
Crosslinking and Gelation
......................... 243
5.6.2.1
Statistical Approach
....................... 246
5.6.2.2
Model for Gelation Process
................... 255
5.6.2.3
Molecular Size Distribution
................... 255
Contents
5.6.2.4
Post-Gel Relations
........................ 258
5.7
Recursive Approach for Average Properties
.................... 260
5.7.1
Linear Step-Growth Polymerization
.................... 260
5.7.2
Nonlinear Step-Growth Polymerization
.................. 264
5.7.2.1
Polymerization of A/
(ƒ > 2).................. 264
5.7.2.2
Polymerization of A/
(ƒ> 2) +
B2
............... 266
5.7.2.3
Polymerization of
Σ
A/
+
ΣΒ;
.................
268
5.7.3
Post-Gel Properties
............................. 271
5.7.3.1
Polymerization of A/
...................... 272
5.7.3.2
Polymerization of A/
+
B2
................... 276
5.8
Polycondensationof
Α*Β
Monomers
........................ 278
5.8.1
Dendritic and Hyperbranchcd Polymers
.................. 279
References
......................................... 28
Exercises
.......................................... 283
Free Radical Polymerization
289
6.1
Introduction
..................................... 289
6.2
Scheme of Radical Chain Polymerization
..................... 290
6.2.1
Overall Scheme
............................... 290
6.2.2
Chain Initiation
............................... 291
6.2.3
Chain Propagation
............................. 291
6.2.4
Chain Termination
............................. 292
6.2.5
Rate of Polymerization
........................... 293
6.2.6
Overall Extent of Polymerization
..................... 295
6.3
Experimental Determination of Rp . Dilatometry
................. 298
6.4
Methods of Initiation
................................ 300
6.4.1
Thermal Decomposition of Initiators
.................... 300
6.4.1.1
Initiator Efficiency
........................ 301
6.4.2
Redox
Initiation
.............................. 305
6.4.3
Photochemical Initiation
.......................... 308
6.4.3.1
Direct
Photoinitiation
...................... 308
6.4.3.2
Photosensitization
........................ 309
6.4.3.3
Rate of Photoinitiated Polymerization
.............. 310
6.4.4
Initiation by High-Energy Radiations
................... 311
6.4.5
Thermal Initiation in Absence of Initiator
................. 312
6.5
Dead-End Polymerization
.............................. 313
6.6
Determination of Absolute Rate Constants
..................... 316
6.6.1
Nonsteady-State Kinetics
.......................... 316
6.7
Chain Length and Degree of Polymerization
.................... 321
6.7.1
Kinetic Chain Length
........................... 321
6.7.2
Mode of Chain Termination
........................ 323
6.7.3
Average Lifetime of Kinetic Chains
.................... 325
6.8
Chain Transfer
................................... 325
6.8.1
Degree of Polymerization
......................... 328
6.8.2
Chain Transfer to Polymer
......................... 334
6.8.3
Allylic Transfer
............................... 335
6.9
Deviations from Ideal Kinetics
...................... 337
6.9.1
Primary Radical Termination
...................... 337
Contents xi
6.9.2 Initiator-Monomer
Complex
Formation.................. 338
6.9.3
Degradative Initiator Transfer
....................... 339
6.9.4
Autoacceleration
.............................. 341
6.10
Inhibition/Retardation of Polymerization
...................... 343
6.10.1
Inhibition/Retardation Kinetics
....................... 345
6.11
Effects of Temperature
............................... 347
6.11.1
Rate of Polymerization
........................... 347
6.11.2
Degree of Polymerization
......................... 350
6.11.3
Polymerization-Depolymerization Equilibrium
.............. 351
6.12
Molecular Weight Distribution
........................... 355
6.12.1
Low-Conversion Polymerization
...................... 355
6.12.1.1
Termination by Disproportionation and/or Transfer
....... 356
6.12.1.2
Termination by Coupling
.................... 357
6.12.1.3
Termination by Coupling, Disproportionation, and Chain Transfer358
6.12.2
High-Conversion Polymerization
..................... 359
6.13
Polymerization Processes
.............................. 359
6.13.1
Emulsion Polymerization
.......................... 361
6.13.1.1
Qualitative Picture
........................ 361
6.13.1.2
Kinetics of Emulsion Polymerization
.............. 364
6.13.1.3
Other Theories
.......................... 371
6.13.2 Photoemulsion
Polymerization
....................... 372
6.13.3
Grafting-From Polymerization
...................... 373
6.14
Living Radical Polymerization
........................... 376
References
......................................... 376
Exercises
.......................................... 377
7
Chain Copolymerization
383
7.1
Introduction
..................................... 383
7.2
Binary Copolymer Composition-Terminal Model
................ 384
7.2.1
Significance of Monomer Reactivity Ratios
................ 386
7.2.2
Types of Copolymerization
......................... 387
7.2.2.1
Alternating Copolymerization
.................. 388
7.2.2.2
Ideal (random) Copolymerization
................ 388
7.2.2.3
Random-Alternating Copolymerization
............. 388
7.2.2.4
Block Copolymerization
..................... 389
7.2.3
Instantaneous Copolymer Composition
.................. 389
7.2.4
Integrated Binary Copolymer Equation
.................. 392
7.2.5
Evaluation of Monomer Reactivity Ratios
................. 396
7.2.5.1
Plot of r versus
Г2
....................... 396
7.2.5.2
Plot of F versus/i
....................... 397
7.2.5.3
Direct Curve Fitting
....................... 399
7.2.6
The Q-e Scheme
............................. 400
7.2.7
Sequence Length Distribution
....................... 402
7.2.8
Rate of Binary Free-Radical Copolymerization
.............. 405
7.3
Multicomponent Copolymerization: Terpolymerization
.............. 409
7.4
Deviations from Terminal Model
.......................... 413
7.4.1
Penultimate Model
............................. 413
7.4.2
Complex-Participation Model
....................... 414
Contents
хи
7.5 Copolymerization
and Crosslinking
........................ 415
7.5.1
Vinyl and Divinyl Monomers of Equal Reactivity
............. 415
7.5.2
Vinyl and Divinyl Monomers of Different Reactivities
.......... 418
7.5.3
One Group of Divinyl Monomer Having Lower Reactivity
........ 419
7.6
Block and Graft Copolymerization
......................... 420
7.6.1
Block Copolymerization
.......................... 421
7.6.1.1
Producing Internal Peroxide Linkages
............. 421
7.6.1.2
Introducing Peroxide End Groups
................ 421
7.6.1.3
Mechanical Cleaving of Polymer Chains
............ 422
7.6.1.4
Controlled Radical Polymerization
............... 423
7.6.2
Graft Copolymerization
.......................... 423
7.6.2.1
Chain Transfer Methods
..................... 423
7.6.2.2
Irradiation with Ionizing Radiation
............... 424
References
......................................... 425
Exercises
.......................................... 426
8
Ionic Chain Polymerization
429
8.1
Introduction
..................................... 429
8.2
Ionic Polymerizability of Monomers
........................ 430
8.3
Anionie
Polymerization
............................... 433
8.3.1
Anionie
Initiation
.............................. 433
8.3.1.1
Nucleophilic Attack
....................... 433
8.3.1.2
Electron Transfer
........................ 434
8.3.2
Termination Reactions
........................... 436
8.3.2.1
Living Polymerization
...................... 436
8.3.2.2
Termination by Transfer Agents
................. 436
8.3.2.3
Spontaneous Termination
.................... 438
8.3.3
Polymerization with Complete Dissociation of Initiator
.......... 438
8.3.3.1
Polymerization Kinetics
..................... 439
8.3.3.2
Experimental Methods
...................... 439
8.3.3.3
Average Kinetic Chain Length
................. 441
8.3.3.4
Average Degree of Polymerization
............... 441
8.3.3.5
Distribution of the Degree of Polymerization
.......... 443
8.3.3.6
Effects of Reaction Media
.................... 447
8.3.3.7
Effect of Excess
Counterion
................... 451
8.3.4
Polymerization with Incomplete Dissociation of Initiator
......... 454
8.3.5
Polymerization with Simultaneous Propagation and Termination
..... 455
8.4
Anionie
Copolymerization
............................. 457
8.4.1
Reactivity Groups
............................. 458
8.4.2
Block Copolymers
............................. 459
8.4.2.1
Sequential Monomer Addition
................. 460
8.4.2.2
Coupling Reactions
....................... 461
8.5
Cationic Polymerization
.............................. 463
8.5.1
Cationic Initiation
............................. 463
8.5.1.1
Protonie
Acids
.......................... 464
8.5.1.2
Lewis Acids
........................... 464
8.5.2
Propagation of Cationic Chain
....................... 465
8.5.3
Chain Transfer and Termination
............. 466
Contents
8.5.3.1 Chain Transfer
to Monomer
................... 466
8.5.3.2
Spontaneous Termination
.................... 467
8.5.3.3
Combination with
Counterion
.................. 467
8.5.3.4
Transfer to Solvents/Reagents
.................. 469
8.5.3.5
Chain Transfer to Polymer
................... 470
8.5.4
Kinetics
................................... 471
8.5.4.1
Ions and Ion Pairs
........................ 471
8.5.4.2
Simplified Kinetic Scheme
................... 472
8.5.4.3
Degree of Polymerization
.................... 478
8.5.5
Molecular Weight Distribution
....................... 479
8.5.6
Cationic Copolymerization
......................... 482
References
......................................... 482
Exercises
.......................................... 483
Coordination Addition Polymerization
487
9.1
Introduction
..................................... 487
9.2
Ziegler-Natta Catalysts
............................... 488
9.2.1
Catalyst Composition
............................ 488
9.2.2
Nature of the Catalyst
........................... 488
9.2.3
Evolution of the Titanium-Aluminum System
............... 489
9.3
Mechanism of Ziegler-Natta Polymerization
.................... 490
9.3.1
Mechanism of Stereospecific Placement
.................. 490
9.3.2
Bimetallic and Monometallic Mechanisms
................ 491
9.3.2.1
Bimetallic Mechanism
...................... 492
9.3.2.2
Monometallic Mechanism
.................... 492
9.4
Kinetics of Ziegler-Natta Polymerization
...................... 495
9.4.1
Typical Shapes of Kinetic Curves
..................... 495
9.4.2
Effect of Catalyst Particle Size
....................... 497
9.4.3
Chain Termination
............................. 498
9.4.4
Kinetic Models
............................... 499
9.4.4.1
Early Models
.......................... 499
9.4.4.2
Adsorption Models
....................... 502
9.4.4.3
Average Degree of Polymerization
............... 514
9.5
Supported Metal Oxide Catalysts
.......................... 515
9.5.1
Polymerization Mechanism
........................ 515
9.5.1.1
Bound-Ion-Radical Mechanism
................. 516
9.5.1.2
Bound-Ion-Coordination Mechanism
.............. 520
9.6
Ziegler-Natta Copolymerization
.......................... 521
9.7
Metallocene-Based Ziegler-Natta Catalysts
.................... 522
9.7.1
Catalyst Composition
............................ 523
9.7.2
The Active Center
............................. 525
9.7.3
Polymerization Mechanism
........................ 526
9.7.4
Kinetic Models
............................... 526
9.7.4.1
Ewen s Model
.......................... 526
9.7.4.2
Chien s Model
.......................... 527
9.7.4.3
Molecular Weight and Chain Transfer
............. 530
9.8
Immobilized Metallocene Catalysts
........................ 531
9.9
Oscillating Metallocene Catalysts
......................... 534
Contents
xiv
References
.........................................
Exercises
..........................................
10
Ring-Opening Polymerization 541
10.1
Introduction
.....................................
541
10.2
Polymerization Mechanism and Kinetics
...................... 543
10.2.1
Cyclic Ethers/Epoxides
........................... 544
10.2.1.1
Anionie
Polymerization
..................... 544
10.2.1.2
Cationic Polymerization
..................... 548
10.2.2
Lactams
................................... 557
10.2.2.1
Hydrolytic Polymerization
................... 557
10.2.2.2
Anionie
Polymerization
..................... 560
10.2.3
Lactones
.................................. 563
References
......................................... 564
Exercises
.......................................... 565
11
Living/Controlled Radical Polymerization
567
11.1
Introduction
..................................... 567
11.2
Stable Free Radical Polymerization
......................... 571
11.2.1
Monomers
................................. 573
11.2.2
Stable Nitroxide Radicals
......................... 573
11.2.3
Mechanism and Kinetics
.......................... 573
11.2.4
Copolymerization
.............................. 579
11.2.5
Aqueous Systems
.............................. 589
11.3
Atom Transfer Radical Polymerization (ATRP)
.................. 593
11.3.1
ATRP Monomers
.............................. 596
11.3.2
ATRP Initiators
............................... 599
11.3.3
ATRP Catalysts
............................... 600
11.3.4
ATRPLigands
............................... 601
11.3.5
ATRP Solvents
............................... 601
11.3.6
ATRP Mechanism and Kinetics
...................... 602
11.3.7
Chain-End Functionality
.......................... 607
11.3.8
Copolymerization
.............................. 609
11.3.8.1
Block Copolymers
........................ 609
11.3.8.2
Graft Copolymers
........................ 618
11.3.8.3
Star and Hyperbranched Polymers
............... 621
11.3.9
Aqueous Systems
.............................. 624
11.4
Degenerative Chain Transfer
............................ 625
11.5
Reversible Addition-Fragmentation Chain Transfer
................ 625
11.5.1
Mechanism and Kinetics
.......................... 629
11.5.2
Theoretical Molecular Weight
....................... 635
11.5.3
Block Copolymers
........................ 636
11.5.3.1
Sequential Monomer Addition
................. 636
11.5.3.2
Macro-CTA Method
....................... 641
11.5.4
Star (Co)polymers
.................... 641
11.5.5
Branched (Co)polymers
.............. 644
11.5.6
Surface Modification
............... 644
11.5.7
Combination of RAFT and Other Polymerization Techniques.
. . . . . . 645
Contents xv
11.5.8 Transformation
of RAFT
Polymer
End Groups
.............. 646
References
......................................... 649
Exercises
.......................................... 653
12
Polymer Synthesis by Click Chemistry
661
12.1
Introduction
..................................... 661
12.2
Copper-Catalyzed Azide- Alky
ne Cycloaddition..................
665
12.2.1
Combination of ATRP and CuAAC Reactions
............... 675
12.2.1.1
Macromonomer Synthesis
.................... 675
12.2.1.2
End-Functionalization of (Co)polymer Chains
......... 680
12.2.1.3
Cyclization of Linear Polymers
................. 681
12.2.1.4
Moldular Synthesis of Block Copolymers
........... 682
12.2.1.5
Nonlinear Polymer Synthesis
.................. 683
12.2.2
Combination of RAFT Polymerization and CuAAC
............ 690
12.3
Strain-Promoted Azide-Alkyne Coupling
..................... 694
12.4
Diels-Alder Click Reactions
............................ 696
12.4.1
Copolymer Synthesis
............................ 697
12.4.2
Thermoresponsive Systems, Dendrons, and Dendrimers
......... 702
12.4.3
Hetero-Diels-Alder (HDA)
Cycloaddition
................. 707
12.5
Thiol-Ene Reactions
................................ 710
12.5.1
Mechanisms of Thiol-Ene Reactions
.................... 714
12.5.2
Synthesis of Star Polymers and Dendrimers
................ 716
References
......................................... 719
Exercises
.......................................... 722
Appendix A Conversion of Units
727
Appendix
В
Fundamental Constants
729
Index
731
POLYMER SCIENCE
Introduction to
Polymer Science
and Chemistry
Problem-Solving Approach
SECOND EDITION
Industry and
academia
remain fascinated with the diverse properties and applications
of polymers. However, most introductory books on this enormous and important field
do not stress practical problem solving or include recent advances, which are critical
for the modern polymer scientist-to-be. Updating the popular first edition of the polymer
book for the new millennium, Introduction to Polymer Science and Chemistry: A
Problem-Solving Approach, Second Edition seamlessly integrates exploration of the
fundamentals of polymer science and polymer chemistry.
See what s new in the second edition:
•
Chapter on living/controlled radical polymerization, using a unique
problem-solving approach
•
Chapter on polymer synthesis by click chemistry, using a unique
problem-solving approach
Relevant and practical work-out problems and case studies
Examples of novel methods of synthesis of complex polymer molecules
by exciting new techniques
•
Figures and schematics of the novel synthetic pathways described in
the new examples
Author Manas
Chanda
takes an innovative problem-solving approach in which the text
presents worked-out problems or questions with answers at every step of the development
of a new theory or concept, ensuring a better grasp of the subject and scope for
self study. Containing
286
text-embedded solved problems and
277
end-of-chapter
home-study problems (fully answered separately in a Solutions Manual), the book
provides a comprehensive understanding of the subject. These features and more set
this book apart from other currently available polymer chemistry texts.
|
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| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547/.7 |
| dewey-search | 547/.7 |
| dewey-sort | 3547 17 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| edition | 2. ed. |
| format | Book |
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| illustrated | Illustrated |
| indexdate | 2024-07-10T01:10:00Z |
| institution | BVB |
| isbn | 9781466553842 |
| language | English |
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| spelling | Chanda, Manas 1940- Verfasser (DE-588)136724868 aut Introduction to polymer science and chemistry a problem-solving approach Manas Chanda 2. ed. Boca Raton, Fla. [u.a.] CRC Press 2013 XXI, 748 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Polymerization Polymerization Problems, exercises, etc Polymers Polymers Problems, exercises, etc Polymerisation (DE-588)4046704-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Polymere (DE-588)4046699-1 s DE-604 Polymerisation (DE-588)4046704-1 s Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027431334&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027431334&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Chanda, Manas 1940- Introduction to polymer science and chemistry a problem-solving approach Polymerization Polymerization Problems, exercises, etc Polymers Polymers Problems, exercises, etc Polymerisation (DE-588)4046704-1 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4046704-1 (DE-588)4046699-1 |
| title | Introduction to polymer science and chemistry a problem-solving approach |
| title_auth | Introduction to polymer science and chemistry a problem-solving approach |
| title_exact_search | Introduction to polymer science and chemistry a problem-solving approach |
| title_full | Introduction to polymer science and chemistry a problem-solving approach Manas Chanda |
| title_fullStr | Introduction to polymer science and chemistry a problem-solving approach Manas Chanda |
| title_full_unstemmed | Introduction to polymer science and chemistry a problem-solving approach Manas Chanda |
| title_short | Introduction to polymer science and chemistry |
| title_sort | introduction to polymer science and chemistry a problem solving approach |
| title_sub | a problem-solving approach |
| topic | Polymerization Polymerization Problems, exercises, etc Polymers Polymers Problems, exercises, etc Polymerisation (DE-588)4046704-1 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Polymerization Polymerization Problems, exercises, etc Polymers Polymers Problems, exercises, etc Polymerisation Polymere |
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