Verfügbarkeit: Introduction to polymer science and chemistry

Introduction to polymer science and chemistry: a problem-solving approach

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Bibliographische Detailangaben
1. Verfasser:	Chanda, Manas 1940- (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Boca Raton, Fla. [u.a.] CRC Press 2013
Ausgabe:	2. ed.
Schlagworte:	Polymerization Polymerization > Problems, exercises, etc Polymers Polymers > Problems, exercises, etc Polymerisation Polymere
Online-Zugang:	Inhaltsverzeichnis Klappentext
Beschreibung:	Includes bibliographical references and index
Beschreibung:	XXI, 748 S. Ill., graph. Darst.
ISBN:	9781466553842

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MARC


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Datensatz im Suchindex

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adam_text	Contents Preface xvii Author xxi 1 Introductory Concepts 1 1.1 Basic Definitions .................................. 1 1.1.1 Polymer ................................... 1 1.1.2 Monomer .................................. 2 1.1.3 Molecular Weight and Molar Mass ..................... 3 1.1.4 End Groups ................................. 3 1.1.5 Degree of Polymerization ......................... 4 1.1.6 Copolymers ................................. 4 1.2 Polymerization and Functionality .......................... 5 1.3 Polymerization Processes .............................. 7 1.3.1 Addition or Chain Polymerization ..................... 7 1.3.2 Step Polymerization ............................ 11 1.3.3 Supramolecular Polymerization ...................... 13 1.4 Molecular Architecture ............................... 18 1.5 Classification of Polymers ............................. 22 1.5.1 Thermoplastics and Thermosets ...................... 22 1.6 Plastics, Fibers, and Elastomers ........................... 26 1.7 Polymer Nomenclature ............................... 29 References ......................................... 31 Exercises .......................................... 31 2 Chain Dimensions, Structures, and Transitional Phenomena 35 2.1 Introduction ..................................... 35 2.2 Polymer Chains: Structures and Dimensions ................... 35 2.2.1 Conformational Changes .......................... 35 2.2.1.1 Polyethylene ........................... 38 2.2.1.2 Polyisobutylene ......................... 39 2.2.1.3 Polypropylene .......................... 40 2.2.2 Polymer Conformations in Crystals .................... 40 2.2.3 Polymer Size in the Amorphous State ................... 42 2.2.3.1 Freely Jointed Chains ...................... 43 2.2.3.2 Real Polymer Chains ...................... 44 vii Conic· fits VJJJ 2.3 Constitutional and Configurational Isomerism ................... 47 2.3.1 Constitutional Isomerism .......................... ** 2.3.2 Configurational Isomerism ......................... 50 2.3.2.1 Geometrical Isomerism ..................... S(i 2.3.2.2 Stereoisomcrism ......................... $0 2.4 Crystallinity in Polymers .............................. s7 2.4.1 Structure of Bulk Polymers ......................... 59 2.4.1.1 Spherulites ............................ 59 2.5 Thermal Transitions in Polymers .......................... 61 2.5.1 7І and7^ .................................. 6I 2.5.2 First-and Second-Order Transitions .................... f>3 2.6 Regions of Viscoclastic Behavior .......................... f)^ 2.7 Factors Affecting TK ................................. 66 2.8 Factors Affecting Tm ................................ (}H 2.9 Relation Between Tm and Г^ ............................ M 2.10 Theoretical Treatment of Glass Transition ..................... 6° 2.10.1 Quantitative Effects of Factors on TH .................... 74 2.11 Chain Movements in Amorphous State ....................... KO 2.11.1 The Reptation Model ............................ HI 2.12 Thermodynamics of Rubber Elasticity ....................... КЗ 2.12.1 Stress-Strain Behavior of Crosslinkcd Elastomers ............. H5 2.12.2 Nonideal Networks ............................. 91 2.12.2.1 Network Defects ......................... >1 2.12.2.2 Elastically Active Chain Sections ................ 91 References ......................................... 93 Exercises .......................................... 94 3 Polymers in Solution 101 3.1 Introduction ..................................... 101 3.2 Thermodynamics of Liquid Mixtures ........................ 101 3.2.1 Low-Molecular-Weight Mixtures: van Laar Model ............ 104 3.2.2 Polymer-Solvent Mixtures: Flory-Huggins Model ............ 107 3.2.2.1 Flory-Huggins Expressions for Thermodynamic Functions . . Ill 3.2.2.2 Colligative Properties and Interaction Parameter^ ....... 113 3.2.2.3 Virial Coefficients ........................ 117 3.2.2.4 Modification of Flory-Huggins Theory ............. 119 3.2.2.5 Flory-Krigbaum Theory ..................... 121 3.2.2.6 Excluded Volume Theory .................... 122 3.3 Phase Equilibria in Poor Solvents .......................... 126 3.3.1 Upper and Lower Critical Solution Temperatures ............. 129 3.4 Solubility Behavior of Polymers .......................... 131 3.5 Swelling of Crosslinked Polymers ........................, 138 3.5.1 Determination of χ from Swelling ..................... 142 3.6 Fractional Properties of Polymer Molecules in Dilute Solution ........................... 143 3.6.1 Viscosity of Dilute Polymer Solutions ................... 145 3.6.1.1 Determination of Polymer Molecular Dimensions from Viscosity 148 References ........................ 151 Contents ¡χ Exercises .......................................... 152 4 Polymer Molecular Weights 159 4.1 Introduction ..................................... 159 4.2 Molecular Weight Averages ............................. 159 4.2.1 Arithmetic Mean .............................. 159 4.2.2 Number-Average Molecular Weight .................... 160 4.2.3 Weight-Average Molecular Weight ..................... 162 4.3 Molecular Weights in Terms of Moments ..................... 163 4.3.1 Ratio of First and Zeroth Moments ..................... 164 4.3.2 Ratios of Higher Moments ......................... 165 4.4 Molecular Weight Determination .......................... 166 4.4.1 End-Group Analysis ............................ 167 4.4.2 Colligativc Property Measurement ..................... 168 4.4.2.1 Ebulliometry (Boiling Point Elevation) ............. 168 4.4.2.2 Cryoscopy (Freezing Point Depression) ............. 169 4.4.2.3 Membrane Osmometry ..................... 169 4.4.2.4 Vapor-Phase Osmometry .................... 176 4.4.3 Light-Scattering Method .......................... 180 4.4.3.1 Rayleigh Ratio .......................... 181 4.4.3.2 Turbidity and Rayleigh Ratio .................. 183 4.4.3.3 Turbidity and Molecular Weight of Polymer .......... 184 4.4.3.4 Dissymmetry of Scattering ................... 188 4.4.3.5 Zimm Plots ........................... 191 4.4.4 Dilute Solution Viscometry ......................... 194 4.4.4.1 Calibration of the Mark-Houwink-Sakurada Equation ..... 196 4.4.4.2 Measurement of Intrinsic Viscosity ............... 197 4.4.5 Gel Permeation Chromatography ..................... 200 4.4.5.1 Data Interpretation and Calibration ............... 202 References ......................................... 208 Exercises .......................................... 208 5 Condensation (Step-Growth) Polymerization 213 5.1 Introduction ..................................... 213 5.2 Rates of Polycondensation Reactions ........................ 214 5.2.1 Irreversible Polycondensation Kinetics .................. 216 5.2.2 Reversible Polycondensation Kinetics ................... 222 5.3 Number-Average Degree of Polymerization .................... 224 5.4 Control of Molecular Weight ............................ 227 5.4.1 Quantitative Effect of Stoichiometric Imbalance .............. 228 5.5 Molecular Weight Distribution (MWD) ...................... 232 5.5.1 Breadth of MWD .............................. 234 5.6 Nonlinear Step Polymerization ........................... 241 5.6.1 Branching .................................. 241 5.6.2 Crosslinking and Gelation ......................... 243 5.6.2.1 Statistical Approach ....................... 246 5.6.2.2 Model for Gelation Process ................... 255 5.6.2.3 Molecular Size Distribution ................... 255 Contents 5.6.2.4 Post-Gel Relations ........................ 258 5.7 Recursive Approach for Average Properties .................... 260 5.7.1 Linear Step-Growth Polymerization .................... 260 5.7.2 Nonlinear Step-Growth Polymerization .................. 264 5.7.2.1 Polymerization of A/ (ƒ > 2).................. 264 5.7.2.2 Polymerization of A/ (ƒ> 2) + B2 ............... 266 5.7.2.3 Polymerization of Σ A/ + ΣΒ; ................. 268 5.7.3 Post-Gel Properties ............................. 271 5.7.3.1 Polymerization of A/ ...................... 272 5.7.3.2 Polymerization of A/ + B2 ................... 276 5.8 Polycondensationof ΑΒ Monomers ........................ 278 5.8.1 Dendritic and Hyperbranchcd Polymers .................. 279 References ......................................... 28 Exercises .......................................... 283 Free Radical Polymerization 289 6.1 Introduction ..................................... 289 6.2 Scheme of Radical Chain Polymerization ..................... 290 6.2.1 Overall Scheme ............................... 290 6.2.2 Chain Initiation ............................... 291 6.2.3 Chain Propagation ............................. 291 6.2.4 Chain Termination ............................. 292 6.2.5 Rate of Polymerization ........................... 293 6.2.6 Overall Extent of Polymerization ..................... 295 6.3 Experimental Determination of Rp . Dilatometry ................. 298 6.4 Methods of Initiation ................................ 300 6.4.1 Thermal Decomposition of Initiators .................... 300 6.4.1.1 Initiator Efficiency ........................ 301 6.4.2 Redox Initiation .............................. 305 6.4.3 Photochemical Initiation .......................... 308 6.4.3.1 Direct Photoinitiation ...................... 308 6.4.3.2 Photosensitization ........................ 309 6.4.3.3 Rate of Photoinitiated Polymerization .............. 310 6.4.4 Initiation by High-Energy Radiations ................... 311 6.4.5 Thermal Initiation in Absence of Initiator ................. 312 6.5 Dead-End Polymerization .............................. 313 6.6 Determination of Absolute Rate Constants ..................... 316 6.6.1 Nonsteady-State Kinetics .......................... 316 6.7 Chain Length and Degree of Polymerization .................... 321 6.7.1 Kinetic Chain Length ........................... 321 6.7.2 Mode of Chain Termination ........................ 323 6.7.3 Average Lifetime of Kinetic Chains .................... 325 6.8 Chain Transfer ................................... 325 6.8.1 Degree of Polymerization ......................... 328 6.8.2 Chain Transfer to Polymer ......................... 334 6.8.3 Allylic Transfer ............................... 335 6.9 Deviations from Ideal Kinetics ...................... 337 6.9.1 Primary Radical Termination ...................... 337 Contents xi 6.9.2 Initiator-Monomer Complex Formation.................. 338 6.9.3 Degradative Initiator Transfer ....................... 339 6.9.4 Autoacceleration .............................. 341 6.10 Inhibition/Retardation of Polymerization ...................... 343 6.10.1 Inhibition/Retardation Kinetics ....................... 345 6.11 Effects of Temperature ............................... 347 6.11.1 Rate of Polymerization ........................... 347 6.11.2 Degree of Polymerization ......................... 350 6.11.3 Polymerization-Depolymerization Equilibrium .............. 351 6.12 Molecular Weight Distribution ........................... 355 6.12.1 Low-Conversion Polymerization ...................... 355 6.12.1.1 Termination by Disproportionation and/or Transfer ....... 356 6.12.1.2 Termination by Coupling .................... 357 6.12.1.3 Termination by Coupling, Disproportionation, and Chain Transfer358 6.12.2 High-Conversion Polymerization ..................... 359 6.13 Polymerization Processes .............................. 359 6.13.1 Emulsion Polymerization .......................... 361 6.13.1.1 Qualitative Picture ........................ 361 6.13.1.2 Kinetics of Emulsion Polymerization .............. 364 6.13.1.3 Other Theories .......................... 371 6.13.2 Photoemulsion Polymerization ....................... 372 6.13.3 Grafting-From Polymerization ...................... 373 6.14 Living Radical Polymerization ........................... 376 References ......................................... 376 Exercises .......................................... 377 7 Chain Copolymerization 383 7.1 Introduction ..................................... 383 7.2 Binary Copolymer Composition-Terminal Model ................ 384 7.2.1 Significance of Monomer Reactivity Ratios ................ 386 7.2.2 Types of Copolymerization ......................... 387 7.2.2.1 Alternating Copolymerization .................. 388 7.2.2.2 Ideal (random) Copolymerization ................ 388 7.2.2.3 Random-Alternating Copolymerization ............. 388 7.2.2.4 Block Copolymerization ..................... 389 7.2.3 Instantaneous Copolymer Composition .................. 389 7.2.4 Integrated Binary Copolymer Equation .................. 392 7.2.5 Evaluation of Monomer Reactivity Ratios ................. 396 7.2.5.1 Plot of r versus Г2 ....................... 396 7.2.5.2 Plot of F versus/i ....................... 397 7.2.5.3 Direct Curve Fitting ....................... 399 7.2.6 The Q-e Scheme ............................. 400 7.2.7 Sequence Length Distribution ....................... 402 7.2.8 Rate of Binary Free-Radical Copolymerization .............. 405 7.3 Multicomponent Copolymerization: Terpolymerization .............. 409 7.4 Deviations from Terminal Model .......................... 413 7.4.1 Penultimate Model ............................. 413 7.4.2 Complex-Participation Model ....................... 414 Contents хи 7.5 Copolymerization and Crosslinking ........................ 415 7.5.1 Vinyl and Divinyl Monomers of Equal Reactivity ............. 415 7.5.2 Vinyl and Divinyl Monomers of Different Reactivities .......... 418 7.5.3 One Group of Divinyl Monomer Having Lower Reactivity ........ 419 7.6 Block and Graft Copolymerization ......................... 420 7.6.1 Block Copolymerization .......................... 421 7.6.1.1 Producing Internal Peroxide Linkages ............. 421 7.6.1.2 Introducing Peroxide End Groups ................ 421 7.6.1.3 Mechanical Cleaving of Polymer Chains ............ 422 7.6.1.4 Controlled Radical Polymerization ............... 423 7.6.2 Graft Copolymerization .......................... 423 7.6.2.1 Chain Transfer Methods ..................... 423 7.6.2.2 Irradiation with Ionizing Radiation ............... 424 References ......................................... 425 Exercises .......................................... 426 8 Ionic Chain Polymerization 429 8.1 Introduction ..................................... 429 8.2 Ionic Polymerizability of Monomers ........................ 430 8.3 Anionie Polymerization ............................... 433 8.3.1 Anionie Initiation .............................. 433 8.3.1.1 Nucleophilic Attack ....................... 433 8.3.1.2 Electron Transfer ........................ 434 8.3.2 Termination Reactions ........................... 436 8.3.2.1 Living Polymerization ...................... 436 8.3.2.2 Termination by Transfer Agents ................. 436 8.3.2.3 Spontaneous Termination .................... 438 8.3.3 Polymerization with Complete Dissociation of Initiator .......... 438 8.3.3.1 Polymerization Kinetics ..................... 439 8.3.3.2 Experimental Methods ...................... 439 8.3.3.3 Average Kinetic Chain Length ................. 441 8.3.3.4 Average Degree of Polymerization ............... 441 8.3.3.5 Distribution of the Degree of Polymerization .......... 443 8.3.3.6 Effects of Reaction Media .................... 447 8.3.3.7 Effect of Excess Counterion ................... 451 8.3.4 Polymerization with Incomplete Dissociation of Initiator ......... 454 8.3.5 Polymerization with Simultaneous Propagation and Termination ..... 455 8.4 Anionie Copolymerization ............................. 457 8.4.1 Reactivity Groups ............................. 458 8.4.2 Block Copolymers ............................. 459 8.4.2.1 Sequential Monomer Addition ................. 460 8.4.2.2 Coupling Reactions ....................... 461 8.5 Cationic Polymerization .............................. 463 8.5.1 Cationic Initiation ............................. 463 8.5.1.1 Protonie Acids .......................... 464 8.5.1.2 Lewis Acids ........................... 464 8.5.2 Propagation of Cationic Chain ....................... 465 8.5.3 Chain Transfer and Termination ............. 466 Contents 8.5.3.1 Chain Transfer to Monomer ................... 466 8.5.3.2 Spontaneous Termination .................... 467 8.5.3.3 Combination with Counterion .................. 467 8.5.3.4 Transfer to Solvents/Reagents .................. 469 8.5.3.5 Chain Transfer to Polymer ................... 470 8.5.4 Kinetics ................................... 471 8.5.4.1 Ions and Ion Pairs ........................ 471 8.5.4.2 Simplified Kinetic Scheme ................... 472 8.5.4.3 Degree of Polymerization .................... 478 8.5.5 Molecular Weight Distribution ....................... 479 8.5.6 Cationic Copolymerization ......................... 482 References ......................................... 482 Exercises .......................................... 483 Coordination Addition Polymerization 487 9.1 Introduction ..................................... 487 9.2 Ziegler-Natta Catalysts ............................... 488 9.2.1 Catalyst Composition ............................ 488 9.2.2 Nature of the Catalyst ........................... 488 9.2.3 Evolution of the Titanium-Aluminum System ............... 489 9.3 Mechanism of Ziegler-Natta Polymerization .................... 490 9.3.1 Mechanism of Stereospecific Placement .................. 490 9.3.2 Bimetallic and Monometallic Mechanisms ................ 491 9.3.2.1 Bimetallic Mechanism ...................... 492 9.3.2.2 Monometallic Mechanism .................... 492 9.4 Kinetics of Ziegler-Natta Polymerization ...................... 495 9.4.1 Typical Shapes of Kinetic Curves ..................... 495 9.4.2 Effect of Catalyst Particle Size ....................... 497 9.4.3 Chain Termination ............................. 498 9.4.4 Kinetic Models ............................... 499 9.4.4.1 Early Models .......................... 499 9.4.4.2 Adsorption Models ....................... 502 9.4.4.3 Average Degree of Polymerization ............... 514 9.5 Supported Metal Oxide Catalysts .......................... 515 9.5.1 Polymerization Mechanism ........................ 515 9.5.1.1 Bound-Ion-Radical Mechanism ................. 516 9.5.1.2 Bound-Ion-Coordination Mechanism .............. 520 9.6 Ziegler-Natta Copolymerization .......................... 521 9.7 Metallocene-Based Ziegler-Natta Catalysts .................... 522 9.7.1 Catalyst Composition ............................ 523 9.7.2 The Active Center ............................. 525 9.7.3 Polymerization Mechanism ........................ 526 9.7.4 Kinetic Models ............................... 526 9.7.4.1 Ewen s Model .......................... 526 9.7.4.2 Chien s Model .......................... 527 9.7.4.3 Molecular Weight and Chain Transfer ............. 530 9.8 Immobilized Metallocene Catalysts ........................ 531 9.9 Oscillating Metallocene Catalysts ......................... 534 Contents xiv References ......................................... Exercises .......................................... 10 Ring-Opening Polymerization 541 10.1 Introduction ..................................... 541 10.2 Polymerization Mechanism and Kinetics ...................... 543 10.2.1 Cyclic Ethers/Epoxides ........................... 544 10.2.1.1 Anionie Polymerization ..................... 544 10.2.1.2 Cationic Polymerization ..................... 548 10.2.2 Lactams ................................... 557 10.2.2.1 Hydrolytic Polymerization ................... 557 10.2.2.2 Anionie Polymerization ..................... 560 10.2.3 Lactones .................................. 563 References ......................................... 564 Exercises .......................................... 565 11 Living/Controlled Radical Polymerization 567 11.1 Introduction ..................................... 567 11.2 Stable Free Radical Polymerization ......................... 571 11.2.1 Monomers ................................. 573 11.2.2 Stable Nitroxide Radicals ......................... 573 11.2.3 Mechanism and Kinetics .......................... 573 11.2.4 Copolymerization .............................. 579 11.2.5 Aqueous Systems .............................. 589 11.3 Atom Transfer Radical Polymerization (ATRP) .................. 593 11.3.1 ATRP Monomers .............................. 596 11.3.2 ATRP Initiators ............................... 599 11.3.3 ATRP Catalysts ............................... 600 11.3.4 ATRPLigands ............................... 601 11.3.5 ATRP Solvents ............................... 601 11.3.6 ATRP Mechanism and Kinetics ...................... 602 11.3.7 Chain-End Functionality .......................... 607 11.3.8 Copolymerization .............................. 609 11.3.8.1 Block Copolymers ........................ 609 11.3.8.2 Graft Copolymers ........................ 618 11.3.8.3 Star and Hyperbranched Polymers ............... 621 11.3.9 Aqueous Systems .............................. 624 11.4 Degenerative Chain Transfer ............................ 625 11.5 Reversible Addition-Fragmentation Chain Transfer ................ 625 11.5.1 Mechanism and Kinetics .......................... 629 11.5.2 Theoretical Molecular Weight ....................... 635 11.5.3 Block Copolymers ........................ 636 11.5.3.1 Sequential Monomer Addition ................. 636 11.5.3.2 Macro-CTA Method ....................... 641 11.5.4 Star (Co)polymers .................... 641 11.5.5 Branched (Co)polymers .............. 644 11.5.6 Surface Modification ............... 644 11.5.7 Combination of RAFT and Other Polymerization Techniques. . . . . . . 645 Contents xv 11.5.8 Transformation of RAFT Polymer End Groups .............. 646 References ......................................... 649 Exercises .......................................... 653 12 Polymer Synthesis by Click Chemistry 661 12.1 Introduction ..................................... 661 12.2 Copper-Catalyzed Azide- Alky ne Cycloaddition.................. 665 12.2.1 Combination of ATRP and CuAAC Reactions ............... 675 12.2.1.1 Macromonomer Synthesis .................... 675 12.2.1.2 End-Functionalization of (Co)polymer Chains ......... 680 12.2.1.3 Cyclization of Linear Polymers ................. 681 12.2.1.4 Moldular Synthesis of Block Copolymers ........... 682 12.2.1.5 Nonlinear Polymer Synthesis .................. 683 12.2.2 Combination of RAFT Polymerization and CuAAC ............ 690 12.3 Strain-Promoted Azide-Alkyne Coupling ..................... 694 12.4 Diels-Alder Click Reactions ............................ 696 12.4.1 Copolymer Synthesis ............................ 697 12.4.2 Thermoresponsive Systems, Dendrons, and Dendrimers ......... 702 12.4.3 Hetero-Diels-Alder (HDA) Cycloaddition ................. 707 12.5 Thiol-Ene Reactions ................................ 710 12.5.1 Mechanisms of Thiol-Ene Reactions .................... 714 12.5.2 Synthesis of Star Polymers and Dendrimers ................ 716 References ......................................... 719 Exercises .......................................... 722 Appendix A Conversion of Units 727 Appendix В Fundamental Constants 729 Index 731 POLYMER SCIENCE Introduction to Polymer Science and Chemistry Problem-Solving Approach SECOND EDITION Industry and academia remain fascinated with the diverse properties and applications of polymers. However, most introductory books on this enormous and important field do not stress practical problem solving or include recent advances, which are critical for the modern polymer scientist-to-be. Updating the popular first edition of the polymer book for the new millennium, Introduction to Polymer Science and Chemistry: A Problem-Solving Approach, Second Edition seamlessly integrates exploration of the fundamentals of polymer science and polymer chemistry. See what s new in the second edition: • Chapter on living/controlled radical polymerization, using a unique problem-solving approach • Chapter on polymer synthesis by click chemistry, using a unique problem-solving approach Relevant and practical work-out problems and case studies Examples of novel methods of synthesis of complex polymer molecules by exciting new techniques • Figures and schematics of the novel synthetic pathways described in the new examples Author Manas Chanda takes an innovative problem-solving approach in which the text presents worked-out problems or questions with answers at every step of the development of a new theory or concept, ensuring a better grasp of the subject and scope for self study. Containing 286 text-embedded solved problems and 277 end-of-chapter home-study problems (fully answered separately in a Solutions Manual), the book provides a comprehensive understanding of the subject. These features and more set this book apart from other currently available polymer chemistry texts.
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spelling	Chanda, Manas 1940- Verfasser (DE-588)136724868 aut Introduction to polymer science and chemistry a problem-solving approach Manas Chanda 2. ed. Boca Raton, Fla. [u.a.] CRC Press 2013 XXI, 748 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Polymerization Polymerization Problems, exercises, etc Polymers Polymers Problems, exercises, etc Polymerisation (DE-588)4046704-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Polymere (DE-588)4046699-1 s DE-604 Polymerisation (DE-588)4046704-1 s Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027431334&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027431334&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext
spellingShingle	Chanda, Manas 1940- Introduction to polymer science and chemistry a problem-solving approach Polymerization Polymerization Problems, exercises, etc Polymers Polymers Problems, exercises, etc Polymerisation (DE-588)4046704-1 gnd Polymere (DE-588)4046699-1 gnd
subject_GND	(DE-588)4046704-1 (DE-588)4046699-1
title	Introduction to polymer science and chemistry a problem-solving approach
title_auth	Introduction to polymer science and chemistry a problem-solving approach
title_exact_search	Introduction to polymer science and chemistry a problem-solving approach
title_full	Introduction to polymer science and chemistry a problem-solving approach Manas Chanda
title_fullStr	Introduction to polymer science and chemistry a problem-solving approach Manas Chanda
title_full_unstemmed	Introduction to polymer science and chemistry a problem-solving approach Manas Chanda
title_short	Introduction to polymer science and chemistry
title_sort	introduction to polymer science and chemistry a problem solving approach
title_sub	a problem-solving approach
topic	Polymerization Polymerization Problems, exercises, etc Polymers Polymers Problems, exercises, etc Polymerisation (DE-588)4046704-1 gnd Polymere (DE-588)4046699-1 gnd
topic_facet	Polymerization Polymerization Problems, exercises, etc Polymers Polymers Problems, exercises, etc Polymerisation Polymere
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027431334&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027431334&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA
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