Discovering the future of molecular sciences:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
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Weinheim
Wiley-VCH
2014
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| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XXIV, 409 S. Ill., graph. Darst. |
| ISBN: | 3527335447 9783527335442 9783527673223 |
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| 245 | 1 | 0 | |a Discovering the future of molecular sciences |c ed. by Bruno Pignataro |
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Datensatz im Suchindex
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CONTENTS
PREFACE XIII
LIST OF CONTRIBUTORS XXI
PART I ADVANCED METHODOLOGIES 1
1 SUPRAMOLECULAR RECEPTORS FOR THE RECOGNITION OF BIOANALYTES 3
D. AMILAN JOSE, AMRITA GHOSH, AND ALEXANDER SCHILLER
1.1 INTRODUCTION 3
1.2 BIOANALYTES 4
1.3 METAL COMPLEXES AS RECEPTORS FOR BIOLOGICAL PHOSPHATES 6
1.3.1 FLUORESCENT ZN(II) BASED METAL COMPLEXES AND THEIR APPLICATIONS IN
LIVE CELL IMAGING 7
1.3.2 CHROMOGENIC ZN(II)-BASED METAL RECEPTORS AND THEIR APPLICATIONS IN
BIOLOGICAL CELL STAINING 9
1.4 FUNCTIONALIZED VESICLES FOR THE RECOGNITION OF BIOANALYTES 14
1.4.1 POLYDIACETYLENE BASED CHROMATIC VESICLES 15
1.4.1.1 PDA BASED RECEPTORS FOR BIOLOGICAL PHOSPHATE 15
1.4.1.2 PDA BASED RECEPTORS FOR LIPOPOLYSACCHARIDE 20
1.4.1.3 PDA BASED RECEPTORS FOR OLIGONUCLEOTIDES AND NUCLEIC ACIDS 21
1.5 BORONIC ACID RECEPTORS FOR DIOL-CONTAINING BIOANALYTES 23
1.6 CONCLUSION AND OUTLOOK 25
ACKNOWLEDGMENT 26
REFERENCES 26
2 METHODS OF DNA RECOGNITION 31
OLALLA VAZQUEZ
2.1 INTRODUCTION 31
2.2 HISTORICAL OUTLINE: THE CENTRAL DOGMA 32
2.3 INTERMOLECULAR INTERACTION BETWEEN THE TRANSCRIPTION FACTORS AND THE
DNA 33
2.3.1 THE STRUCTURE OF DNA AND ITS ROLE IN THE RECOGNITION 34
2.3.2 DNA BINDING DOMAINS OF THE TF 36
HTTP://D-NB.INFO/1045580589
VI I
CONTENTS
2.3.3 GENERAL ASPECTS OF THE INTERMOLECULAR INTERACTIONS BETWEEN THE TFS
AND THE DNA 40
2.4 MINIATURE VERSIONS OF TRANSCRIPTION FACTORS 42
2.4.1 SYNTHETIC MODIFICATION OF BZIP TRANSCRIPTION FACTORS 43
2.4.2 RESIDUE GRAFTING 44
2.4.3 CONJUGATION IN ORDER TO DEVELOP DNA BINDING PEPTIDES 45
2.5 INTERMOLECULAR INTERACTION BETWEEN SMALL MOLECULES AND THE
DNA 46
2.5.1 GENERAL CONCEPTS 46
2.5.2 METALLO-DNA BINDERS: FROM CISPLATIN TO RH METALLO-INSERTORS 50
2.5.3 POLYPYRROLES AND BIS(BENZAMIDINE) MINOR GROOVE BINDERS AND THEIR
USE AS SPECIFIC DSDNA SENSORS 53
2.6 OUDOOK 56
ACKNOWLEDGMENTS 56
REFERENCES 56
3 STRUCTURAL ANALYSIS OF COMPLEX MOLECULAR SYSTEMS BY HIGH-RESOLUTION
AND TANDEM MASS SPECTROMETRY 63
YURY O. TSYBIN
3.1 DISSECTING MOLECULAR COMPLEXITY WITH MASS SPECTROMETRY 63
3.2 ADVANCES IN FOURIER TRANSFORM MASS SPECTROMETRY 67
3.3 ADVANCES IN MASS ANALYZERS FOR FT-ICR MS 70
3.4 ADVANCES IN MASS ANALYZERS FOR ORBITRAP FTMS 72
3.5 APPLICATIONS OF HIGH-RESOLUTION MASS SPECTROMETRY 73
3.6 ADVANCES IN TANDEM MASS SPECTROMETRY 78
3.7 OUTLOOK: QUO VADIS FTMS? 81
3.8 SUMMARY AND FUTURE ISSUES 86
ACKNOWLEDGMENTS 88
REFERENCES
88
4 COHERENT ELECTRONIC ENERGY TRANSFER IN BIOLOGICAL AND ARTIFICIAL
MULTICHROMOPHORIC SYSTEMS 91
ELISABETTA COLLINI
4.1 INTRODUCTION TO ELECTRONIC ENERGY TRANSFER IN COMPLEX SYSTEMS 91
4.2 THE MEANING OF ELECTRONIC COHERENCE IN ENERGY TRANSFER 94
4.3 ENERGY MIGRATION IN TERMS OF OCCUPATION PROBABILITY: A UNIFIED
APPROACH 96
4.4 EXPERIMENTAL DETECTION OF QUANTUM COHERENCE 100
4.5 ELECTRONIC COHERENCE MEASURED BY TWO-DIMENSIONAL PHOTON
ECHO 104
4.6 FUTURE PERSPECTIVES AND CONCLUSIVE REMARKS 110
ACKNOWLEDGMENTS 111
REFERENCES 111
CONTENTS
I VII
5 ULTRAFAST STUDIES OF CARRIER DYNAMICS IN QUANTUM DOTS FOR NEXT
GENERATION PHOTOVOLTAICS 115
DANIELLE BUCKLEY
5.1 INTRODUCTION 115
5.2 THEORETICAL LIMITS 116
5.3 BULK SEMICONDUCTORS 117
5.4 SEMICONDUCTOR QUANTUM DOTS 118
5.4.1 LEAD CHALCOGENIDES 120
5.5 CARRIER DYNAMICS 121
5.5.1 CARRIER MULTIPLICATION 121
5.5.2 RELAXATION 121
5.6 ULTRAFAST TECHNIQUES 124
5.6.1 PUMP-PROBE 124
5.6.2 PHOTOLUMINESCENCE 126
5.6.3 RELAXATION TIMES 126
5.7 QUANTUM EFFICIENCY 126
5.7.1 QUANTUM YIELD ARGUMENTS 128
5.7.2 EXPERIMENTAL CONSIDERATIONS 129
5.8 LIGAND EXCHANGE AND FILM STUDIES 130
5.9 CONCLUSIONS 133
ACKNOWLEDGMENTS 133
REFERENCES 133
6 MICRO FLOW CHEMISTRY: NEW POSSIBILITIES FOR SYNTHETIC
CHEMISTS 137
TIMOTHY NOEL
6.1 INTRODUCTION 137
6.2 CHARACTERISTICS OF MICRO FLOW - BASIC ENGINEERING PRINCIPLES 138
6.2.1 MASS TRANSFER - THE IMPORTANCE OF EFFICIENT MIXING 138
6.2.2 HEAT TRANSFER-THE IMPORTANCE OF EFFICIENT HEAT MANAGEMENT 140
6.2.3 MULTIPHASE FLOW 142
6.3 UNUSUAL REACTION CONDITIONS ENABLED BY MICROREACTOR
TECHNOLOGY 144
6.3.1 HIGH-TEMPERATURE AND HIGH-PRESSURE PROCESSING 144
6.3.2 USE OF HAZARDOUS INTERMEDIATES-AVOIDING TROUBLE 145
6.3.3 PHOTOCHEMISTRY 147
6.4 THE USE OF IMMOBILIZED REAGENTS, SCAVENGERS, AND CATALYSTS 149
6.5 MULTISTEP SYNTHESIS IN FLOW 152
6.6 AVOIDING MICROREACTOR CLOGGING 154
6.7 REACTION SCREENING AND OPTIMIZATION PROTOCOLS IN
MICROREACTORS 157
6.8 SCALE-UP ISSUES - FROM LABORATORY SCALE TO PRODUCTION SCALE 157
6.9 OUTLOOK 160
REFERENCES 161
VIII
CONTENTS
7 UNDERSTANDING TRENDS IN REACTION BARRIERS 165
ISRAEL FERNANDEZ LDPEZ
7.1 INTRODUCTION 165
7.2 ACTIVATION STRAIN MODEL AND ENERGY DECOMPOSITION ANALYSIS 166
7.2.1 ACTIVATION STRAIN MODEL 166
7.2.2 ENERGY DECOMPOSITION ANALYSIS 167
7.3 PERICYCLIC REACTIONS 168
7.3.1 DOUBLE GROUP TRANSFER REACTIONS 168
7.3.2 ALDER-ENE REACTIONS 173
7.3.3 1,3-DIPOLAR CYCLOADDITION REACTIONS 174
7.3.4 DIELS-ALDER REACTIONS 178
7.4 NUCLEOPHILIC SUBSTITUTIONS AND ADDITIONS 179
7.4.1 S
N
2 REACTIONS 179
7.4.2 NUCLEOPHILIC ADDITIONS TO ARYNES 180
7.5 UNIMOLECULAR PROCESSES 181
7.6 CONCLUDING REMARKS 183
ACKNOWLEDGMENTS 184
REFERENCES 184
PART II MATERIALS, NANOSCIENCE, AND NANOTECHNOLOGIES 189
8 MOLECULAR METAL OXIDES: TOWARD A DIRECTED AND FUNCTIONAL
FUTURE 191
HARALAMPOS N. MIRAS
8.1 INTRODUCTION 191
8.2 NEW TECHNOLOGIES AND ANALYTICAL TECHNIQUES 192
8.3 NEW SYNTHETIC APPROACHES 196
8.3.1 THE BUILDING BLOCK APPROACH 197
8.3.2 GENERATION OF NOVEL BUILDING BLOCK LIBRARIES 198
8.3.2.1 SHRINK-WRAPPING EFFECT 199
8.3.2.2 HYDROTHERMAL AND IONIC THERMAL SYNTHESIS 200
8.3.2.3 NOVEL TEMPLATES: X0
3
AND X0
6
-TEMPLATED POMS 200
8.3.3 POM-BASED NETWORKS 201
8.4 CONTINUOUS FLOW SYSTEMS AND NETWORKED REACTIONS 203
8.5 3D PRINTING TECHNOLOGY 205
8.6 EMERGENT PROPERTIES AND NOVEL PHENOMENA 206
8.6.1 POROUS KEPLERATE NANOCAPSULES - CHEMICAL ADAPTABILITY 207
8.6.2 TRANSFORMATION OF POM STRUCTURES AT INTERFACES - MOLECULAR TUBES
AND INORGANIC CELLS 208
8.6.3 CONTROLLED POM-BASED OSCILLATIONS 210
8.7 CONCLUSIONS AND PERSPECTIVES 212
REFERENCES 212
CONTENTS
I IX
9 MOLECULAR METAL OXIDES FOR ENERGY CONVERSION AND ENERGY
STORAGE 217
ANDREY SELIVERSTOV, JOHANNES FORSTER,
JOHANNES TUCKER, KATHARINA
KASTNER, AND CARSTEN STREB
9.1 INTRODUCTION TO MOLECULAR METAL OXIDE CHEMISTRY 217
9.1.1 POLYOXOMETALATES - MOLECULAR METAL OXIDE CLUSTERS 217
9.1.2 PRINCIPLES OF POLYOXOMETALATE REDOX CHEMISTRY 219
9.1.3 PRINCIPLES OF POLYOXOMETALATE PHOTOCHEMISTRY 219
9.1.4 POMS FOR ENERGY APPLICATIONS 221
9.2 POM PHOTOCATALYSIS 221
9.2.1 THE ROOTS OF POM-PHOTOCATALYSIS USING UV-LIGHT 221
9.2.2 SUNLIGHT-DRIVEN POM PHOTOCATALYSTS 222
9.2.2.1 STRUCTURALLY ADAPTIVE SYSTEMS FOR SUNLIGHT CONVERSION 222
9.2.2.2 OPTIMIZED SUNLIGHT HARVESTING BY METAL SUBSTITUTION 223
9.2.2.3 VISIBLE-LIGHT PHOTOCATALYSIS - INSPIRATION FROM THE SOLID-STATE
WORLD 224
9.2.3 FUTURE DEVELOPMENT PERSPECTIVES FOR POM PHOTOCATALYSTS 225
9.3 ENERGY CONVERSION 225
9.3.1 WATER SPLITTING 225
9.3.2 WATER OXIDATION BY MOLECULAR CATALYSTS 226
9.3.2.1 WATER OXIDATION BY RU- AND CO-POLYOXOMETALATES 226
9.3.2.2 POLYOXONIOBATE WATER SPLITTING 227
9.3.2.3 WATER OXIDATION BY DAWSON ANIONS IN IONIC LIQUIDS 227
9.3.2.4 ON THE STABILITY OF MOLECULAR POM-WOCS 228
9.3.3 PHOTOREDUCTIVE H
2
-GENERATION 229
9.3.4 PHOTOREDUCTIVE C0
2
-ACTIVATION 229
9.4 PROMISING DEVELOPMENTS FOR POMS IN ENERGY CONVERSION AND
STORAGE 231
9.4.1 IONIC LIQUIDS FOR CATALYSIS AND ENERGY STORAGE 231
9.4.1.1 POLYOXOMETALATE IONIC LIQUIDS (POM-ILS) 231
9.4.1.2 OUTLOOK: FUTURE APPLICATIONS OF POM-ILS 233
9.4.2 POM-BASED PHOTOVOLTAICS 234
9.4.3 POM-BASED MOLECULAR CLUSTER BATTERIES 234
9.5 SUMMARY 235
REFERENCES 235
10 THE NEXT GENERATION OF SILYLENE LIGANDS FOR BETTER CATALYSTS 243
SHIGEYOSHI
INOUE
10.1 GENERAL INTRODUCTION 243
10.1.1 SILYLENES 243
10.1.2 BISSILYLENES 244
10.1.3 SILYLENE TRANSITION METAL COMPLEXES 245
10.2 SYNTHESIS AND CATALYTIC APPLICATIONS OF SILYLENE TRANSITION METAL
COMPLEXES 246
10.2.1 BIS(SILYLENE)TITANIUM COMPLEXES 246
X
CONTENTS
10.2.2 BIS(SILYLENE)NICKEL COMPLEX 248
10.2.3 PINCER-TYPE BIS(SILYLENE) COMPLEXES (PD, IR, RH) 254
10.2.4 BIS(SILYLENYL)-SUBSTITUTED FERROCENE COBALT COMPLEX 260
10.2.5 SILYLENE IRON COMPLEXES 263
10.3 CONCLUSION AND OUTLOOK 267
REFERENCES 268
11 HALIDE EXCHANGE REACTIONS MEDIATED BY TRANSITION METALS 275
ALICIA CASITAS MONTERO
11.1 INTRODUCTION 275
11.2 NICKEL-BASED METHODOLOGIES FOR HALIDE EXCHANGES 278
11.3 RECENT ADVANCES IN PALLADIUM-CATALYZED ARYL HALIDE EXCHANGE
REACTIONS 280
11.4 THE VERSATILITY OF COPPER-CATALYZED ARYL HALIDE EXCHANGE
REACTIONS 284
11.5 CONCLUSIONS AND PERSPECTIVES 290
REFERENCES 292
12 NANOPARTIDE ASSEMBLIES FROM MOLECULAR MEDIATOR 295
MARIE-ALEXANDRA NEOUZE
12.1 INTRODUCTION 295
12.2 ASSEMBLY OR SELF-ASSEMBLY 296
12.3 NANOPARTICLES AND THEIR PROTECTION AGAINST AGGREGATION OR
AGGLOMERATION 297
12.3.1 FINITE-SIZE OBJECTS 297
12.3.2 PROTECTION AGAINST AGGREGATION 298
12.4 NANOPARTIDE ASSEMBLIES SYNTHESIS METHODS 298
12.4.1 INTERLIGAND BONDING 299
12.4.1.1 NONCOVALENT LINKER INTERACTIONS AND SELF-ASSEMBLY 299
12.4.1.2 COVALENT MOLECULAR MEDIATORS 303
12.4.1.3 NONCOVALENT VERSUS COVALENT INTERACTION 305
12.4.2 TEMPLATE ASSISTED SYNTHESIS 306
12.4.3 DEPOSITION OF 2D NANOPARTIDE ASSEMBLIES: MONOLAYERS, MULTILAYERS,
OR FILMS 307
12.4.3.1 LAYER-BY-LAYER DEPOSITION 308
12.4.3.2 LANGMUIR-BLODGETT DEPOSITION 310
12.4.3.3 EVAPORATION INDUCED ASSEMBLY 311
12.4.3.4 BUBBLE DEPOSITION 313
12.4.4 PRESSURE-DRIVEN ASSEMBLY 314
12.5 APPLICATIONS OF NANOPARTIDE ASSEMBLIES 314
12.5.1 PLASMONICS 314
12.5.1.1 PLASMONIC NANOSTRUCTURES 316
12.5.1.2 SENSORIC 317
12.5.1.3 SIGNAL AMPLIFICATION/SURFACE-ENHANCED RAMAN SCATTERING 318
12.5.2 INTERACTING SUPER-SPINS/MAGNETIC MATERIALS 319
CONTENTS
I XI
12.5.3 METAMATERIALS 321
12.5.4 CATALYSIS/ELECTROCATALYSIS 322
12.5.5 WATER TREATMENT/PHOTODEGRADATION 322
12.6 CONCLUSION 323
REFERENCES 324
13 POROUS MOLECULAR SOLIDS 329
SHAN
JIANG, ABBIE TREWIN, AND ANDREW I. COOPER
13.1 INTRODUCTION 329
13.2 POROUS ORGANIC MOLECULAR CRYSTALS 330
13.2.1 POROUS ORGANIC MOLECULES 330
13.2.2 POROUS ORGANIC CAGES 331
13.2.3 SIMULATION OF POROUS ORGANIC MOLECULAR CRYSTALS 336
13.2.4 APPLICATIONS FOR POROUS MOLECULAR CRYSTALS 338
13.3 POROUS AMORPHOUS MOLECULAR MATERIALS 338
13.3.1 SYNTHESIS OF POROUS AMORPHOUS MOLECULAR MATERIALS 339
13.3.1.1 SYNTHESIS OF AMORPHOUS CAGE MATERIALS BY SCRAMBLING REACTIONS
AND
FREEZE-DRYING 340
13.3.2 SIMULATION OF POROUS AMORPHOUS MOLECULAR MATERIALS 342
13.4 SUMMARY 344
REFERENCES 344
14 ELECTROCHEMICAL MOTORS 349
GABRIEL LOGET AND ALEXANDER KUHN
14.1 INSPIRATION FROM BIOMOTORS 349
14.2 CHEMICAL MOTORS 350
14.3 EXTERNALLY POWERED MOTION 353
14.4 ASYMMETRY FOR A CONTROLLED MOTION 355
14.5 BIPOLAR ELECTROCHEMISTRY 356
14.6 ASYMMETRIC MOTORS SYNTHETIZED BY BIPOLAR ELECTROCHEMISTRY 358
14.7 DIRECT USE OF BIPOLAR ELECTROCHEMISTRY FOR MOTION
GENERATION 363
14.8 CONCLUSION AND PERSPECTIVES 372
REFERENCES 373
15 AZOBENZENE IN MOLECULAR AND SUPRAMOLECULAR DEVICES AND
MACHINES 379
MASSIMO BARONCINI AND GIACOMO BERGAMINI
15.1 INTRODUCTION 379
15.2 DENDRIMERS 380
15.2.1 AZOBENZENE AT THE PERIPHERY 380
15.2.2 AZOBENZENE AT THE CORE 384
15.3 MOLECULAR DEVICES AND MACHINES 387
15.3.1 SWITCHING ROTAXANE CHARACTER WITH LIGHT 388
XII | CONTENTS
15.3.2 LIGHT-CONTROLLED UNIDIRECTIONAL TRANSIT OF A MOLECULAR AXLE
THROUGH A
MACROCYCLE 391
15.4 CONCLUSION 395
REFERENCES 39 5
INDEX 399 |
| any_adam_object | 1 |
| author2 | Pignataro, Bruno 1972- |
| author2_role | edt |
| author2_variant | b p bp |
| author_GND | (DE-588)135576520 |
| author_facet | Pignataro, Bruno 1972- |
| building | Verbundindex |
| bvnumber | BV041934258 |
| classification_rvk | VC 5000 |
| ctrlnum | (OCoLC)867166013 (DE-599)DNB1045580589 |
| dewey-full | 540.94 572.094 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 540 - Chemistry and allied sciences 572 - Biochemistry |
| dewey-raw | 540.94 572.094 |
| dewey-search | 540.94 572.094 |
| dewey-sort | 3540.94 |
| dewey-tens | 540 - Chemistry and allied sciences 570 - Biology |
| discipline | Chemie / Pharmazie Biologie |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| geographic | Europa (DE-588)4015701-5 gnd |
| geographic_facet | Europa |
| id | DE-604.BV041934258 |
| illustrated | Illustrated |
| indexdate | 2024-09-10T01:18:31Z |
| institution | BVB |
| isbn | 3527335447 9783527335442 9783527673223 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027377469 |
| oclc_num | 867166013 |
| open_access_boolean | |
| owner | DE-703 DE-11 |
| owner_facet | DE-703 DE-11 |
| physical | XXIV, 409 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Discovering the future of molecular sciences ed. by Bruno Pignataro 201406 Weinheim Wiley-VCH 2014 XXIV, 409 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemie (DE-588)4009816-3 gnd rswk-swf Biochemie (DE-588)4006777-4 gnd rswk-swf Europa (DE-588)4015701-5 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Europa (DE-588)4015701-5 g Chemie (DE-588)4009816-3 s Biochemie (DE-588)4006777-4 s DE-604 Pignataro, Bruno 1972- (DE-588)135576520 edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-67324-7 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-67323-0 Erscheint auch als Online-Ausgabe, PDF 978-3-527-67325-4 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4548265&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027377469&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Discovering the future of molecular sciences Chemie (DE-588)4009816-3 gnd Biochemie (DE-588)4006777-4 gnd |
| subject_GND | (DE-588)4009816-3 (DE-588)4006777-4 (DE-588)4015701-5 (DE-588)4143413-4 |
| title | Discovering the future of molecular sciences |
| title_auth | Discovering the future of molecular sciences |
| title_exact_search | Discovering the future of molecular sciences |
| title_full | Discovering the future of molecular sciences ed. by Bruno Pignataro |
| title_fullStr | Discovering the future of molecular sciences ed. by Bruno Pignataro |
| title_full_unstemmed | Discovering the future of molecular sciences ed. by Bruno Pignataro |
| title_short | Discovering the future of molecular sciences |
| title_sort | discovering the future of molecular sciences |
| topic | Chemie (DE-588)4009816-3 gnd Biochemie (DE-588)4006777-4 gnd |
| topic_facet | Chemie Biochemie Europa Aufsatzsammlung |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4548265&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027377469&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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