Molecular catalysts: structure and functional design
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2014
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| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XXXII, 493 S. Ill., graph. Darst. |
| ISBN: | 9783527335213 9783527673278 |
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| 245 | 1 | 0 | |a Molecular catalysts |b structure and functional design |c ed. by Lutz H. Gade ... |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2014 | |
| 300 | |a XXXII, 493 S. |b Ill., graph. Darst. | ||
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CONTENTS
LIST OF CONTRIBUTORS XV
FOREWORD XIX
INTRODUCTION XXIX
PART I A/LECHANISMS OF ELEMENTARY REACTIONS IN CATALYTIC PROCESSES 1
LUTZH.
GADE
1 QUANTUM DYNAMICS OF MOLECULAR ELEMENTARY PROCESSES IN CATALYTIC
TRANSFORMATIONS 5
GUNTER KLATT
AND HORST KOPPEL
1.1 INTRODUCTION 5
1.2 STRUCTURAL AND ENERGETIC ASPECTS 6
1.3 QUANTUM DYNAMICAL CALCULATIONS 12
1.3.1 REACTION PATH ENERGY PROFILES 12
1.3.2 WAVE PACKET PROPAGATION FOR LATE-TRANSITION-METAL COMPLEXES 13
1.3.3 NORM DECAY AND LIFETIMES 15
1.3.4 QUANTUM DYNAMICS OF ETHYLENE INSERTION IN CHROMIUM
COMPLEXES 18
1.4 SUMMARY AND OUTLOOK 21
ACKNOWLEDGMENTS 21
REFERENCES 21
2 ACTIVATION OF SMALL MOLECULES WITH METAL AND METAL OXIDE CLUSTERS IN
INERT GAS MATRIXES 25
HANS-JORG HIMMEL AND OLAFHUBNER
2.1 INTRODUCTION 25
2.2 THE MATRIX ISOLATION TECHNIQUE - ADVANTAGES AND LIMITATIONS 28
2.2.1 THERMAL EVAPORATION VERSUS LASER ABLATION 29
2.2.2 METAL OR CSL SUBSTRATES FOR THE MATRIX 30
2.3 FORMATION AND CHARACTERIZATION OF METAL ATOM DIMERS AND
CLUSTERS 32
2.4 REACTIONS OF ATOM DIMERS OR CLUSTERS 35
HTTP://D-NB.INFO/1047121212
VI |
CONTENTS
2.5
2.6
2.7
3
3.1
3.1.1
3.1.2
3.1.2.1
3.1.2.2
3.2
3.2.1
3.2.2
3.2.3
3.2.4
3.3
3.3.1
3.3.2
3.4
4
4.1
4.2
4.3
4.4
4.5
4.5.1
4.5.2
4.5.3
4.5.4
4.5.5
4.5.6
4.6
4.7
FORMATION AND CHARACTERIZATION OF METAL OXIDES 38
REACTIONS INVOLVING METAL OXIDES 44
CONCLUDING REMARKS 46
ACKNOWLEDGMENTS 47
REFERENCES 47
TOWARD SINGLE-MOLECULE CATALYSIS 53
ARINA RYBINA,
MARCEL WIRTZ,
DOMINIK BROX, ROLAND KRAMER,
GREGORJUNG,
AND
DIRK-PETER HERTEN
INTRODUCTION 53
SINGLE-MOLECULE ENZYMOLOGY 54
SINGLE-MOLECULE STUDIES IN CHEMISTRY 55
SINGLE-MOLECULE STUDIES IN HETEROGENEOUS CATALYSIS 56
SINGLE-MOLECULE CHEMISTRY IN HOMOGENEOUS CATALYSIS 58
PROBES FOR SINGLE-MOLECULE CHEMISTRY 60
FLUORESCENCE PROPERTIES: OVERALL CONSIDERATIONS 61
FLUOROGENIC SUBSTRATES 62
SUBSTRATES FOR REVERSIBLE REACTIONS 62
SUBSTRATES FOR IRREVERSIBLE REACTIONS 63
APPROACHING SINGLE-MOLECULE STUDIES IN HOMOGENEOUS
CATALYSIS 64
FLUOROPHORE-LABELED CU(II) CHELATORS AND SUBSTRATES 64
BODIPY SUBSTRATES FOR PROBING REACTIONS OF DOUBLE BONDS 71
DISCUSSION AND PERSPECTIVES 75
ACKNOWLEDGMENTS 76
REFERENCES 76
INTERMEDIATES AND ELEMENTARY REACTIONS IN GOLD CATALYSIS 81
A. STEPHEN
K. HASHMI
INTRODUCTION 81
THE INITIAL STEP: JT-COORDINATION OF THE SUBSTRATE 81
THE NUCLEOPHILIC ADDITION: VINYLGOLD AND ALKYLGOLD
INTERMEDIATES 82
THE REACTION OF THE ORGANOGOLD INTERMEDIATES WITH
ELECTROPHILES 87
"VINYLIDENE" GOLD(I) INTERMEDIATES 89
SETTING THE STAGE 89
AN UNEXPECTED REGIOSELECTIVITY RAISES QUESTIONS 92
THE MECHANISTIC HYPOTHESIS 95
THE OTHER PATHWAY 97
GOLD ALLENYLIDENES AS ANALOGS OF GOLD VINYLIDENES? 99
DUAL ACTIVATION CATALYSTS 99
PROTONS AND HYDRIDE IN GOLD CATALYSIS 101
FUTURE PERSPECTIVES 102
REFERENCES 102
CONTENTS I VII
5 DIASTEREOSELECTIVITY IN ALKENE METATHESIS 107
BERND F. STRAUB AND
ACHIM HAULIERMANN
5.1 INTRODUCTION 107
5.2 STEREOSELECTIVE ALKENE METATHESIS CATALYSTS 107
5.3 COMBINING CATALYTIC ACTIVITY AND STEREOSELECTIVITY IN RUTHENIUM
CARBENES:
AN ANTAGONISM?
ILL
5.4 STEREOSELECTIVITY IN RING-OPENING METATHESIS POLYMERIZATION
(ROMP) 114
5.5 OUTLOOK 116
5.6 SUMMARY 117
REFERENCES 117
PART II NEW CATALYSTS - NEW AND OLD REACTIONS 119
PETER HOFMANN
6 OXIDATION CATALYSIS WITH HIGH-VALENT NONHEME IRON COMPLEXES 123
PETER COMBO
6.1 INTRODUCTION 123
6.2 BISPIDINE LIGANDS 124
6.3 OXIDATION OF THE FERROUS PRECURSORS 125
6.4 SPIN STATES OF THE FERRYL CATALYSTS 128
6.5 REDOX PROPERTIES OF THE FERRYL OXIDANTS 130
6.6 REACTIVITY OF THE FERRYL COMPOUNDS 132
6.6.1 OLEFINE OXIDATION 132
6.6.2 ALKANE OXIDATION 134
6.6.3 SULFOXIDATION 137
6.6.4 WATER OXIDATION 138
6.6.5 DIOXYGEN AS OXIDANT 139
6.7 CONCLUSION 140
ACKNOWLEDGMENT 141
REFERENCES 141
7 SINGLE-SITE ORGANOCHROMIUM CATALYSTS FOR HIGH MOLECULAR WEIGHT
POLYOLEFINS 147
MARKUS ENDERS
7.1 INTRODUCTION 147
7.2 LIGAND DESIGN 148
7.3 CHROMIUM COMPLEXES OF NON-CP LIGANDS 149
7.3.1 NEUTRAL TRIDENTATE LIGANDS 149
7.3.2 ANIONIC LIGANDS 149
7.4 CHROMIUM COMPLEXES BASED ON CP 150
7.4.1 CP SYSTEMS WITH COVALENTLY BOUND ADDITIONAL DONOR
FUNCTIONS 151
7.5 POLYMERIZATION BEHAVIOR OF DONOR-FUNCTIONALIZED CP CHROMIUM
COMPLEXES DEVELOPED IN HEIDELBERG 151
VIII
CONTENTS
7.5.1 STRUCTURAL FEATURES 151
7.5.2 CATALYST ACTIVATION AND CATALYTIC ACTIVITIES 152
7.5.3 CHAIN TERMINATION AND MOLECULAR WEIGHTS 155
7.6 EN ROUTE TO TUNABLE CATALYSTS 157
7.7 CONCLUSION 158
REFERENCES 159
8 LIGAND DESIGN AND MECHANISTIC STUDIES FOR NI-CATALYZED
HYDROCYANATION AND 2-METHYL-3-BUTENENITRILE ISOMERIZATION BASED
UPON RH-HYDROFORMYLATION RESEARCH
161
PETER HOFMANN AND
MICHAEL E. TAUCHERT
8.1 INTRODUCTION 161
8.2 RECENT ADVANCES IN NI-CATALYZED HYDROCYANATION AND ISOMERIZATION
REACTIONS 164
8.2.1 HYDROCYANATION OF VINYLARENES 165
8.2.2 HYDROCYANATION OF 1,3-DIENES 165
8.2.3 HYDROCYANATION OF TRAWS-3-PENTENENITRILE 166
8.2.4 ISOMERIZATION OF 2-METHYL-3-BUTENENITRILE 167
8.3 RECENT ADVANCES IN NI-CATALYZED HYDROCYANATION AND ISOMERIZATION
REACTIONS EMPLOYING THE TTP-LIGAND FAMILY 168
8.3.1 GENESIS OF THE TTP-LIGAND FAMILY 168
8.3.2 NI-CATALYZED ISOMERIZATION AND HYDROCYANATION WITH TTP-TYPE
PHOSPHONITE LIGANDS 170
8.3.3 NI-CATALYZED HYDROCYANATION INVOLVING TTP-TYPE PHOSPHINE
LIGANDS 171
8.3.4 APPLICATIONS AND MECHANISTIC STUDIES OF TTP-TYPE PHOSPHINE
LIGANDS IN NI-CATALYZED 2M3BN ISOMERIZATION 174
ACKNOWLEDGMENTS 179
REFERENCES 179
9 STRONGLY ELECTRON DONATING TRIDENTATE N-HETEROCYDIC BISCARBENE
LIGANDS FOR RHODIUM AND IRIDIUM CATALYSTS 183
DORIS KUNZ AND EVA JURGENS
9.1 INTRODUCTION 183
9.2 LIGAND SYSTEMS 184
9.3 SYNTHESIS AND REACTIVITY OF THE COMPLEXES 186
9.3.1 SYNTHESIS OF M(I) COMPLEXES 186
9.3.2 SYNTHESIS OF M(III) COMPLEXES 190
9.4 CATALYTIC ACTIVITIES OF THE RH COMPLEXES 194
9.5 CATALYTIC ACTIVITIES OF THE IR COMPLEXES 200
9.6 DISCUSSION 202
9.7 SUMMARY, CONCLUSION, AND OUTLOOK 203
REFERENCES 204
CONTENTS
| IX
10 NHCP LIGANDS
FOR CATALYSIS 207
PETER HOFMANN AND MARCEL BRILL
10.1 INTRODUCTION 207
10.2 RECENT ADVANCES IN CATALYSIS WITH NHCP LIGANDS 208
10.2.1 CROSS-COUPLING CATALYSIS AND RELATED REACTIONS 208
10.2.2 MISCELLANEOUS REACTIONS 214
10.3 RECENT ADVANCES IN ASYMMETRIC CATALYSIS WITH CHIRAL NHCP
LIGANDS 216
10.4 RECENT ADVANCES IN NHCP CHEMISTRY FEATURING BULKY,
ELECTRON-RICH, SMALL-BITE-ANGLE LIGANDS 221
10.4.1 LIGAND SYNTHESIS OF AF-PHOSPHINO- AND AF-PHOSPHINOMETHYL
NHCS 222
10.4.2 AF-PHOSPHINO-NHC TRANSITION-METAL COMPLEXES 224
10.4.3 AF-PHOSPHINOMETHYL-NHC RUTHENIUM ALKYLIDENE COMPLEXES 227
REFERENCES 229
PART III CATALYSTS IN SYNTHESIS 235
GUNTER HELMCHEN
11 IR-CATALYZED ASYMMETRIC ALLYLIC SUBSTITUTION REACTIONS -
FUNDAMENTALS AND APPLICATIONS IN NATURAL PRODUCTS SYNTHESIS 239
GUNTER HELMCHEN
11.1 INTRODUCTION 239
11.2 BACKGROUND ON REACTION MECHANISM 240
11.3 DIBENZOCYCLOOCTATETRAENE (DBCOT) AS ANCILLARY LIGAND 242
11.4 APPLICATIONS IN ORGANIC SYNTHESIS 244
11.4.1 ALLYLIC SUBSTITUTION IN COMBINATION WITH RING CLOSING
METATHESIS 245
11.4.2 DOMINO-HYDROFORMYLATION-CYCLIZATION
(HYDROAMINOMETHYLATION) 247
11.4.3 THE ALLYLIC SUBSTITUTION IN COMBINATION WITH THE SUZUKI-MIYAURA
REACTION 248
11.4.4 REACTIONS OF ENINES DERIVED FROM ALLYLIC SUBSTITUTION PRODUCTS
250
11.5 CONCLUSIONS 250
ACKNOWLEDGMENTS 251
REFERENCES 251
'12 SEQUENTIAL CATALYSIS INVOLVING METAL-CATALYZED CYDOISOMERIZATIONS
AND CYDIZATIONS 255
THOMAS J. J. MULLER
12.1 INTRODUCTION 255
12.2 SEQUENCES INITIATED BY CYDOISOMERIZATIONS 256
12.2.1 SEQUENTIALLY PD-CATALYZED SEQUENCES INITIATED BY
CYDOISOMERIZATIONS 256
X |
CONTENTS
12.2.2 SEQUENTIALLY RH-CATALYZED SEQUENCES INITIATED BY
CYCLOISOMERIZATIONS 259
12.3 SEQUENCES INITIATED BY RING-CLOSING OLEFIN METATHESIS 262
12.3.1 RING-CLOSING METATHESIS-ISOMERIZATION SEQUENCES 263
12.3.2 RING-CLOSING METATHESIS-OXIDATION SEQUENCES 267
12.4 SEQUENCES INITIATED BY ALKYNYLATION AND CARBOPALLADATIVE
INSERTIONS 268
12.5 SEQUENCES INTERCEPTED BY CYCLIZATIONS 271
12.6 CONCLUSION 276
ACKNOWLEDGMENT 276
ABBREVIATIONS 276
REFERENCES 277
13 C-N-COUPLING REACTIONS IN CATALYTIC ONE-POT SYNTHESES USING
MOLECULAR GROUP 4 CATALYSTS 281
LUTZ H. GADE AND
SOLVEIG A. SCHOLL
13.1 INTRODUCTION 281
13.2 GROUP 4 METAL CATALYSTS FOR THE HYDROAMINATION AND
HYDROHYDRAZINATION OF C-C MULTIPLE BONDS AS WELL AS COMPLEX
REACTION SEQUENCES BASED THEREON 281
13.3 CASE HISTORIES 283
13.3.1 HIGHLY ACTIVE TITANIUM CATALYSTS FOR THE HYDROHYDRAZINATION OF
TERMINAL ALKYNES AND AMINOGUANYLATION OF CARBODIIMIDES 286
13.3.2 A ZIRCONIUM-CATALYZED NON-FISCHER-TYPE PATHWAY TO INDOLES 287
REFERENCES 294
14 SEQUENTIAL CATALYSIS FOR THE STEREOSELECTIVE SYNTHESIS OF COMPLEX
POLYKETIDES 299
THOMAS DEBNAR AND DIRK MENCHE
14.1 COMPLEX POLYKETIDES 299
14.2 DOMINO NUCLEOPHILIC ADDITION-TSUJI-TROST REACTION 301
14.2.1 CONCISE SYNTHESIS OF TETRAHYDROPYRANS BY A TANDEM
OXA-MICHAEL - TSUJI
- TROST REACTION 301
14.2.2 CONCISE SYNTHESIS OF ACETAL-PROTECTED L,3-SY-DIOLS BY A TANDEM
HEMIACETAL/TSUJI-TROST REACTION 304
14.2.3 GENERAL CONCEPT AND FURTHER APPLICATIONS FOR DIAMINE AND
AMINOALCOHOL SYNTHESIS 306
14.3 SEQUENTIAL DIYNE CYCLIZATION AND REGIOSELECTIVE OPENING OF
ZIRCONACYCLOPENTADIENES 308
14.4 CONCLUSION AND PERSPECTIVES 311
REFERENCES 312
CONTENTS
| XI
15 MODULAR ASSEMBLY OF CHIRAL CATALYSTS WITH POLYDENTATE
STEREODIRECTING LIGANDS 313
LUTZH.
GADE
15.1 INTRODUCTION 313
15.2 A MODULAR SYNTHESIS OF C
3
- AND C\-CHIRAL
L,L,L-TRIS(OXAZOLYL)ETHANES ("TRISOX") 314
15.2.1 C
3
-CHIRALITY IN POLYMERIZATION CATALYSIS WITH RARE-EARTH
COMPLEXES 316
15.2.2 TRISOX AS A BIDENTATE LIGAND: CHIRAL TRISOXAZOLINES IN COPPER(LL)
LEWIS ACID CATALYSIS AND PALLADIUM-CATALYZED ASYMMETRIC ALLYLIC
SUBSTITUTIONS 318
15.3 THE BOXMI PINCER SYSTEM: A HIGHLY EFFICIENT MODULAR STEREODIRECTING
LIGAND FOR A BROAD RANGE OF CATALYTIC REACTIONS 322
15.4 BIDENTATE N-HETEROCYCLIC CARBENE LIGANDS INCORPORATING OXAZOLINE
UNITS 327
15.5 NEW MODULAR DI- AND TRIDENTATE PHOSPHOLANE LIGANDS 332
15.5.1 CYCLOHYDROAMINATIONS OF Y-ALLENYL SULFONAMIDES WITH MONO-, BIS-,
AND TRISPHOSPHOLANE GOLD(I) CATALYSTS 335
REFERENCES 337
PART IV STRUCTURES AND MECHANISMS IN BIOLOGICAL SYSTEMS 343
ANDRES JASCHKE
16 BEATING AND EMPLOYING X-RAY-LNDUCED RADIATION DAMAGE IN STRUCTURAL
STUDIES OF HEMOPROTEINS 347
LIME SCHLLCHTING
16.1 INTRODUCTION 347
16.2 CYTOCHROME P450 ENZYMES 348
16.2.1 THE REACTION CYCLE OF P450
CALN
AT HIGH STRUCTURAL RESOLUTION 348
16.2.2 CHLOROPEROXIDASE COMPOUND 350
16.3 PHOTOELECTRONS - FRIEND AND FOE 353
16.4 X-RAY FREE-ELECTRON LASERS 354
REFERENCES 355
17 THE CATALYTIC STRATEGY OF P-0 BOND-CLEAVING ENZYMES: COMPARING
ECORV AND MYOSIN 359
FAROOQ AHMAD KIANI AND
STEFAN FISCHER
17.1 INTRODUCTION 359
17.1.1 HOW DO ENZYMES ACHIEVE CATALYSIS? 359
17.1.2 COMPUTATIONAL INVESTIGATION OF ENZYMATIC MECHANISMS 361
17.1.3 ENZYMES THAT CATALYZE REACTIONS INVOLVING PHOSPHATE 362
17.1.4 ENDONUCLEASE ENZYMES 363
17.1.5 NTPASE ENZYMES 363
17.1.6 HYDROLYSIS MECHANISM 363
17.2 RESULTS 367
XII
CONTENTS
17.3 CONCLUSIONS 369
17.4 METHODS 373
REFERENCES 373
18 SELECTIVE HYBRID CATALYSTS BASED ON NUCLEIC ACIDS 377
ANDRES JASCHKE
18.1 INTRODUCTION 377
18.2 HYBRID CATALYSIS 378
18.3 DNA-BASED HYBRID CATALYSIS 378
18.4 ORGANOMETALLIC CHEMISTRY WITH NUCLEIC ACIDS 380
18.5 COMBINATORIAL SELECTIONS OF CATALYSTS FROM NUCLEIC ACID
LIBRARIES 381
18.6 SITE-SPECIFIC INTERNAL FUNCTIONALIZATION OF NUCLEIC ACIDS WITH
TRANSITION-METAL LIGANDS AND OTHER MOIETIES 382
18.7 METALLATION OF DN A-LIGAND CONJUGATES 385
18.8 SITE-SPECIFIC TERMINAL FUNCTIONALIZATION OF NUCLEIC ACIDS WITH
SUBSTRATES 38S
18.9 ALLYLIC AMINATIONS BY DNA-BASED HYBRID CATALYSTS 387
18.10 SUMMARY AND OUTLOOK 389
REFERENCES 390
PART V STUDIES OF IMMOBILIZED CATALYSTS - INTRODUCTION 393
OLIVER TRAPP
AND JOHANNES TROENDLIN
V.L INTRODUCTION 393
V.2 COVALENT IMMOBILIZATION OF CATALYSTS 394
V.3 SUPPORT MATERIALS 395
V.4 EXAMPLES OF IMMOBILIZED CATALYST SYSTEMS 397
19 DENDRIMERS AS PLATFORMS FOR STEREOSELECTIVE CATALYSIS 407
LUTZH.GADE
19.1 INTRODUCTION 407
19.2 FIXATION OF CHIRAL CATALYSTS ON DENDRIMERS AND HYPERBRANCHED
POLYMERS 407
19.3 CASE HISTORIES 408
19.3.1 "DENDRITIC EFFECTS" OBSERVED FOR IMMOBILIZED PYRPHOS-BASED
HYDROGENATION CATALYSTS 409
19.3.2 BINAP-COPPER(I) HYDROSILYLATION WITH FUNCTIONALIZED PPI AND
PAMAM DENDRIMERS AS WELL AS HYPERBRANCHED POLYMERS 414
19.3.3 "CATALYSIS IN A TEA BAG" WITH DENDRIMER-IMMOBILIZED BIS- AND
TRISOXAZOLINE COPPER CATALYSTS 416
19.4 CONCLUSION AND OUTLOOK 419
REFERENCES 420
CONTENTS
| XIII
20 SOLID PHASES AS PROTECTIVE ENVIRONMENTS FOR BIOMIMETIC
CATALYSTS 423
KATJA HEINZE
20.1 INTRODUCTION 423
20.2 SITE ISOLATION EXPERIENCED BY MATRIX-BOUND TRANSITION-METAL
COMPLEXES 424
20.3 IMMOBILIZED STRUCTURAL AND SPECTROSCOPIC ACTIVE SITE
MODELS 428
20.4 ELEMENTARY REACTION STEPS PERFORMED BY SOLID-PHASE SUPPORTED
COMPLEXES 437
20.5 IMMOBILIZED FUNCTIONAL ACTIVE SITE MODELS 437
20.6 FINAL REMARKS 446
ABBREVIATIONS 447
REFERENCES 448
21 HIGH-THROUGHPUT SCREENING OF CATALYSTS AND REACTIONS 453
OLIVER TRAPP
21.1 INTRODUCTION 453
21.2 TECHNICAL REQUIREMENTS FOR ON-COLUMN REACTION
CHROMATOGRAPHY 457
21.2.1 EXPERIMENTAL SETUPS OF ON-COLUMN REACTION CHROMATOGRAPHY 457
21.2.2 PREPARATION OF CAPILLARY REACTORS 459
21.2.3 HIGH-THROUGHPUT APPROACH 459
21.3 DETERMINATION OF KINETIC DATA 460
21.3.1 CLASSICAL REACTION KINETICS FOR ON-COLUMN REACTION
CHROMATOGRAPHIC EXPERIMENTS WITH REACTION AND CONSECUTIVE
SEPARATION
460
21.3.2 EVALUATION OF CONVERSION PROFILES OBTAINED BY ON-COLUMN REACTION
CHROMATOGRAPHY 460
21.4 DETERMINATION OF ACTIVATION PARAMETERS 464
21.5 ON-COLUMN REACTION CHROMATOGRAPHY FOR THE INVESTIGATION OF
CATALYTIC REACTIONS 465
21.5.1 HYDROGENATIONS OVER NOBLE METAL NANOPARTICLES 465
21.5.2 RING-CLOSING METATHESIS 468
21.5.3 GOSTELI-CLAISEN REARRANGEMENT 469
21.5.4 COMBINATORIAL HIGH-THROUGHPUT SCREENING: CATALYST BY THE
METER 473
21.6 OUTLOOK 476
REFERENCES 476
INDEX 479 |
| any_adam_object | 1 |
| author2 | Gade, Lutz H. 1963- |
| author2_role | edt |
| author2_variant | l h g lh lhg |
| author_GND | (DE-588)1019812737 |
| author_facet | Gade, Lutz H. 1963- |
| building | Verbundindex |
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| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.39 |
| dewey-search | 541.39 |
| dewey-sort | 3541.39 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV041934228 |
| illustrated | Illustrated |
| indexdate | 2024-08-03T01:36:07Z |
| institution | BVB |
| isbn | 9783527335213 9783527673278 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027377439 |
| oclc_num | 870543635 |
| open_access_boolean | |
| owner | DE-703 DE-29T DE-11 DE-20 DE-19 DE-BY-UBM |
| owner_facet | DE-703 DE-29T DE-11 DE-20 DE-19 DE-BY-UBM |
| physical | XXXII, 493 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Molecular catalysts structure and functional design ed. by Lutz H. Gade ... Weinheim Wiley-VCH 2014 XXXII, 493 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Katalyse (DE-588)4029921-1 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Katalyse (DE-588)4029921-1 s DE-604 Gade, Lutz H. 1963- (DE-588)1019812737 edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-67329-2 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-67328-5 Erscheint auch als Online-Ausgabe, PDF 978-3-527-67330-8 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4583957&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027377439&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Molecular catalysts structure and functional design Katalyse (DE-588)4029921-1 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4143413-4 |
| title | Molecular catalysts structure and functional design |
| title_auth | Molecular catalysts structure and functional design |
| title_exact_search | Molecular catalysts structure and functional design |
| title_full | Molecular catalysts structure and functional design ed. by Lutz H. Gade ... |
| title_fullStr | Molecular catalysts structure and functional design ed. by Lutz H. Gade ... |
| title_full_unstemmed | Molecular catalysts structure and functional design ed. by Lutz H. Gade ... |
| title_short | Molecular catalysts |
| title_sort | molecular catalysts structure and functional design |
| title_sub | structure and functional design |
| topic | Katalyse (DE-588)4029921-1 gnd |
| topic_facet | Katalyse Aufsatzsammlung |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4583957&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027377439&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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