The chemical bond: 1 Fundamental aspects of chemical bonding
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Weinheim
Wiley-VCH
2014
|
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| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XXV, 411 S. Ill., graph. Darst. |
| ISBN: | 9783527333141 9783527664696 |
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| 245 | 1 | 0 | |a The chemical bond |n 1 |p Fundamental aspects of chemical bonding |c ed. by Gernot Frenking and Sason Shaik |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2014 | |
| 300 | |a XXV, 411 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 700 | 1 | |a Frenking, Gernot |d 1946- |0 (DE-588)109379756 |4 edt | |
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|---|---|
| adam_text | CONTENTS
PREFACE XIII
LIST OF CONTRIBUTORS XXIII
1 THE PHYSICAL ORIGIN OF COVALENT BONDING 1
MICHAEL W. SCHMIDT, JOSEPH IVANIC, AND KLAUS RUEDENBERG
1.1 THE QUEST FOR A PHYSICAL MODEL OF COVALENT BONDING 1
1.2 RIGOROUS BASIS FOR CONCEPTUAL REASONING 3
1.2.1 PHYSICAL ORIGIN OF THE GROUND STATE 3
1.2.2 PHYSICAL ORIGIN OF GROUND STATE ENERGY DIFFERENCES 5
1.2.3 RELATION BETWEEN KINETIC AND POTENTIAL ENERGIES 8
1.3 ATOMS IN MOLECULES 10
1.3.1 QUANTITATIVE BONDING ANALYSES REQUIRE QUASI-ATOMS IN A
MOLECULE 10
1.3.2 PRIMARY AND SECONDARY ENERGY CONTRIBUTIONS 10
1.3.3 IDENTIFICATION OF QUASI-ATOMS IN A MOLECULE 11
1.4 THE ONE-ELECTRON BASIS OF COVALENT BINDING: H
2+
13
1.4.1 MOLECULAR WAVE FUNCTION AS A SUPERPOSITION OF QUASI-ATOMIC
ORBITALS 13
1.4.2 MOLECULAR ELECTRON DENSITY AND GRADIENT DENSITY AS SUMS OF
INTRA-ATOMIC AND INTERATOMIC CONTRIBUTIONS 16
1.4.2.1 RESOLUTION OF THE MOLECULAR DENSITY 16
1.4.2.2 RESOLUTION OF THE MOLECULAR GRADIENT DENSITY 17
1.4.3 DEPENDENCE OF DEREALIZATION AND INTERFERENCE ON THE SIZE OF THE
QUASI-ATOMIC ORBITALS 18
1.4.3.1 CHARGE ACCUMULATION AT THE BOND MIDPOINT 19
1.4.3.2 TOTAL CHARGE ACCUMULATION IN THE BOND 19
1.4.3.3 ORIGIN OF THE RELATION BETWEEN INTERFERENCE AND QUASI-ATOMIC
ORBITAL
CONTRACTION/EXPANSION 20
1.4.4 BINDING ENERGY AS A SUM OF TWO INTRA-ATOMIC AND THREE INTERATOMIC
CONTRIBUTIONS 22
1.4.5 QUANTITATIVE CHARACTERISTICS OF THE FIVE ENERGY CONTRIBUTIONS 24
1.4.5.1 INTRA-ATOMIC DEFORMATION ENERGY: E
INLRA
= T
INLRA
+ V
INTRA
24
HTTP://D-NB.INFO/1045580503
VI J
CONTENTS
1.4.5.2
QUASI-CLASSICAL INTERACTION BETWEEN THE ATOMS: V
QC
24
1.4.5.3 POTENTIAL INTERFERENCE ENERGY: V, 25
1.4.5.4 KINETIC INTERFERENCE ENERGY: T, 25
1.4.5.5 INTERFERENCE ENERGIES AND QUASI-ATOMIC ORBITAL CONTRACTION AND
EXPANSION 25
1.4.6 SYNERGISM OF THE BINDING ENERGY CONTRIBUTIONS ALONG THE
DISSOCIATION CURVE 27
1.4.6.1 FIRST COLUMN: ZEROTH ORDER APPROXIMATION TO Y/
A
, I//
B
BY THE LS
A
, LS
B
HYDROGEN ATOM ORBITALS 27
1.4.6.2 SECOND COLUMN: OPTIMAL SPHERICAL APPROXIMATION TO I//
A
, Y/
B
BY THE
SCALED ORBITALS LS
A
*, LS
B
* 29
1.4.6.3
THIRD COLUMN: EXACT QUASI-ATOMIC ORBITALS I//
A
, I//
B
30
1.4.6.4
CONCLUSION 30
1.4.7
ORIGIN OF BONDING AT THE EQUILIBRIUM DISTANCE 30
1.4.7.1 CONTRIBUTIONS TO THE BINDING ENERGY 30
1.4.7.2 ENERGY LOWERING BY ELECTRON SHARING 31
1.4.7.3
ENERGY LOWERING BY QUASI-ATOMIC ORBITAL DEFORMATION 32
1.4.7.4
VARIATIONAL PERSPECTIVE 32
1.4.7.5
GENERAL IMPLICATIONS 33
1.5
THE EFFECT OF ELECTRONIC INTERACTION IN THE COVALENT ELECTRON PAIR
BOND: H
2
34
1.5.1
QUASI-ATOMIC ORBITALS OF THE FORS WAVE FUNCTION 35
1.5.2
FORS WAVE FUNCTION AND DENSITY IN TERMS OF QUASI-ATOMIC
ORBITALS 38
1.5.3 BINDING ENERGY AS A SUM OF TWO INTRA-ATOMIC AND FIVE INTERATOMIC
CONTRIBUTIONS 39
1.5.3.1
OVERALL RESOLUTION 39
1.5.3.2
INTERATOMIC COULOMBIC CONTRIBUTIONS 40
1.5.3.3 INTERATOMIC INTERFERENCE CONTRIBUTIONS 41
1.5.3.4 BINDING ENERGY AS A SUM OF TWO INTRA-ATOMIC AND FIVE INTERATOMIC
CONTRIBUTIONS 42
1.5.4
QUANTITATIVE SYNERGISM OF THE CONTRIBUTIONS TO THE BINDING
ENERGY 42
1.5.4.1 QUANTITATIVE CHARACTERISTICS 42
1.5.4.2 SYNERGISM ALONG THE DISSOCIATION CURVE 43
1.5.5 ORIGIN OF BONDING AT THE EQUILIBRIUM DISTANCE 45
1.5.5.1
THE PRIMARY MECHANISM AS EXHIBITED BY CHOOSING THE FREE-ATOM
ORBITALS AS QUASI-ATOMIC ORBITALS 46
1.5.5.2 EFFECT OF QUASI-ATOMIC ORBITAL CONTRACTION 46
1.5.5.3 EFFECT OF POLARIZATION 47
1.5.5.4 BINDING IN THE ELECTRON PAIR BOND OF H
2
47
1.5.6 ELECTRON CORRELATION CONTRIBUTION TO BONDING IN H
2
48
1.6 COVALENT BONDING IN MOLECULES WITH MORE THAN TWO ELECTRONS: B
2
, C
2
N
2
, 0
2
, AND F
2
51
1.6.1 BASIS OF BINDING ENERGY ANALYSIS 52
CONTENTS I VII
1.6.2 ORIGIN OF BINDING AT THE EQUILIBRIUM GEOMETRY 53
1.6.3 SYNERGISM ALONG THE DISSOCIATION CURVE 57
1.6.4 EFFECT OF DYNAMIC CORRELATION ON COVALENT BINDING 61
1.7 CONCLUSIONS 62
ACKNOWLEDGMENTS 65
REFERENCES 65
2 BRIDGING CULTURES 69
PHILIPPE C. HIBERTY AND SASON SHAIK
2.1 INTRODUCTION 69
2.2 A SHORT HISTORY OF THE MO/VB RIVALRY 69
2.3 MAPPING MO-BASED WAVE FUNCTIONS TO VB WAVE FUNCTIONS 74
2.4 LOCALIZED BOND ORBITALS - A PICTORIAL BRIDGE BETWEEN MO AND VB
WAVE FUNCTIONS 78
2.5 BLOCK-LOCALIZED WAVE FUNCTION METHOD 79
2.6 GENERALIZED VALENCE BOND THEORY: A SIMPLE BRIDGE FROM VB TO
MOS 80
2.7 VB READING OF CASSCF WAVE FUNCTIONS 82
2.8 NATURAL BONDING ORBITALS AND NATURAL RESONANCE THEORY - A DIRECT
BRIDGE BETWEEN MO AND VB 83
2.8.1 NATURAL BONDING ORBITALS 83
2.8.2 NATURAL RESONANCE THEORY 84
2.9 THE MYTHICAL CONFLICT OF HYBRID ORBITALS WITH PHOTOELECTRON
SPECTROSCOPY 85
2.10 CONCLUSION 87
APPENDIX 88
REFERENCES 88
3 THE N BO VIEW OF CHEMICAL BONDING 91
CLARK R. LANDIS AND FRANK WEINHOLD
3.1 INTRODUCTION 91
3.2 NATURAL BOND ORBITAL METHODS 92
3.2.1 NBO ANALYSIS OF FREE ATOMS AND ATOMS IN MOLECULAR
ENVIRONMENTS 97
3.2.2 NBO ANALYSIS OF SIMPLE CHEMICAL BONDS: LIOH AND H
2
0 99
3.2.3 LEWIS-LIKE STRUCTURES OF THE P- AND D-BLOCK ELEMENTS 101
3.2.4 UNRESTRICTED CALCULATIONS AND DIFFERENT LEWIS STRUCTURES FOR
DIFFERENT
SPINS (DLDS) 104
3.3 BEYOND LEWIS-LIKE BONDING: THE DONOR-ACCEPTOR PARADIGM 106
3.3.1 HYPERCONJUGATIVE EFFECTS IN BOND BENDING 110
3.3.2 C
3
H
3
CATION, ANION, AND RADICAL: AROMATICITY, JAHN-TELLER
DISTORTIONS, RESONANCE STRUCTURES, AND 3C/2E BONDING 111
3.3.3 3C/4E HYPERVALENCY 114
3.4 CONCLUSION 117
REFERENCES 118
VIIII
CONTENTS
4 THE EDA PERSPECTIVE OF CHEMICAL BONDING 121
GEMOT FRENKING AND F. MATTHIAS BICKELHAUPT
4.1 INTRODUCTION 121
4.2 BASIC PRINCIPLES OF THE EDA METHOD 125
4.3 THE EDA-NOCV METHOD 126
4.4 CHEMICAL BONDING IN H
2
AND N
2
127
4.5 COMPARISON OF BONDING IN ISOELECTRONIC N
2
, CO AND BF 133
4.6 BONDING IN THE DIATOMIC MOLECULES E
2
OF THE FIRST OCTAL ROW
E = LI-F 135
4.7 BONDING IN THE DIHALOGENS F
2
- I
2
144
4.8 CARBON-ELEMENT BONDING IN CH
3
-X 146
4.9 EDA-NOCV ANALYSIS OF CHEMICAL BONDING IN THE TRANSITION
STATE 148
4.10 SUMMARY AND CONCLUSION 155
ACKNOWLEDGEMENTS 15 6
REFERENCES 156
5 THE VALENCE BOND PERSPECTIVE OF THE CHEMICAL BOND 159
SASON SHAIK, DAVID DANOVICH, WEI WU, AND PHILIPPE C. HIBERTY
5.1 INTRODUCTION 159
5.2 A BRIEF HISTORICAL RECOUNTING OF THE DEVELOPMENT OF THE CHEMICAL
BOND NOTION 160
5.3 THE PAULING-LEWIS VB PERSPECTIVE OF THE ELECTRON-PAIR BOND 162
5.4 A PREAMBLE TO THE MODERN VB PERSPECTIVE OF THE ELECTRON-PAIR
BOND 165
5.5 THEORETICAL CHARACTERIZATION OF BOND TYPES BY VB AND OTHER
METHODS 168
5.5.1 VB CHARACTERIZATION OF BOND TYPES 168
5.5.2 ELF AND AIM CHARACTERIZATION OF BOND TYPES 169
5.5.2.1 ELF CHARACTERIZATION OF BOND TYPES 169
5.5.2.2 AIM CHARACTERIZATION OF BOND TYPES 170
5.6 TRENDS OF BOND TYPES REVEALED BY VB, AIM AND ELF 170
5.6.1 VB AND AIM CONVERGE 170
5.6.2 VB AND ELF CONVERGE 173
5.6.3 CONVERGENCE OF VB, ELF AND AIM 176
5.6.4 THE THREE BONDING FAMILIES 176
5.7 PHYSICAL ORIGINS OF CS BONDING 178
5.7.1 THE ROLE OF ATOMIC SIZE 178
5.7.2 THE ROLE OF PAULI REPULSION PRESSURE 179
5.8 GLOBAL BEHAVIOR OF ELECTRON-PAIR BONDS 181
5.9 ADDITIONAL FACTORS OF CS BONDING 183
5.10 CAN A COVALENT BOND BECOME CS BONDS BY SUBSTITUTION? 184
5.11 EXPERIMENTAL MANIFESTATIONS OF CS BONDING 187
5.11.1 MARKS OF CS BONDING FROM ELECTRON DENSITY MEASUREMENTS 187
5.11.2 MARKS OF CS BONDING IN ATOM TRANSFER REACTIVITY 188
CONTENTS IX
5.11.3 MARKS OF CS BONDING IN THE IONIC CHEMISTRY OF SILICON IN
CONDENSED
PHASES 189
5.12 SCOPE AND TERRITORY OF CS BONDING 190
5.12.1 CONCLUDING REMARKS 191
APPENDIX 192
5.A MODERN VB METHODS 192
5.B THE VIRIAL THEOREM 193
5.C RESONANCE INTERACTION AND KINETIC ENERGY 195
REFERENCES 195
6 THE BLOCK-LOCALIZED WAVEFIINCTION (BLW)
PERSPECTIVE OF CHEMICAL
BONDING 199
YIRONG MO
6.1 INTRODUCTION 199
6.2 METHODOLOGY EVOLUTIONS 202
6.2.1 SIMPLIFYING AB INITIO VB THEORY TO THE BLW METHOD 202
6.2.2 BLW METHOD AT THE DFT LEVEL 204
6.2.3 DECOMPOSING INTERMOLECULAR INTERACTION ENERGIES WITH THE BLW
METHOD 205
6.2.4 PROBING ELECTRON TRANSFER WITH BLW-BASED TWO-STATE MODELS 207
6.3 EXEMPLARY APPLICATIONS 209
6.3.1 BENZENE: EVALUATING THE GEOMETRICAL AND ENERGETIC IMPACTS FROM JT
CONJUGATION 209
6.3.2 BUTADIENE: THE ROTATION BARRIER VERSUS THE CONJUGATION
MAGNITUDE 214
6.3.3 ETHANE: WHAT FORCE(S) GOVERNS THE CONFORMATIONAL PREFERENCE? 217
6.3.4 H
3
B-NH
3
: QUANTIFYING THE ELECTRON TRANSFER EFFECT IN DONOR-ACCEPTOR
COMPLEXES 221
6.4 CONCLUSION 223
6.5 OUTLOOK 225
ACKNOWLEDGEMENTS 225
REFERENCES 225
7 THE CONCEPTUAL DENSITY FUNCTIONAL THEORY PERSPECTIVE OF
BONDING 233
FRANK DE PROFT, PAUL
W. AYERS,
AND
PAUL GEERLINGS
7.1 INTRODUCTION 233
7.2 BASICS OF DFT: THE DENSITY AS A FUNDAMENTAL CARRIER OF INFORMATION
AND HOW TO OBTAIN IT 235
7.3 CONCEPTUAL DFT: A PERTURBATIVE APPROACH TO CHEMICAL REACTIVITY AND
THE PROCESS OF BOND FORMATION 238
7.3.1 BASICS: GLOBAL AND LOCAL RESPONSE FUNCTIONS 238
7.3.1.1 GLOBAL RESPONSE FUNCTIONS 240
7.3.1.2 LOCAL RESPONSE FUNCTIONS 242
7.3.1.3 NONLOCAL RESPONSE FUNCTIONS: THE LINEAR RESPONSE KERNEL 249
X I
CONTENTS
7.3.2 COMBINED USE OF DFT-BASED REACTIVITY INDICES AND PRINCIPLES IN THE
STUDY OF CHEMICAL BONDING 252
7.3.2.1 PRINCIPLE OF ELECTRONEGATIVITY EQUALIZATION 252
7.3.2.2 HARD AND SOFT ACIDS AND BASES PRINCIPLE 256
7.3.2.3 BERLIN S APPROACH IN A CONCEPTUAL DFT CONTEXT: THE NUCLEAR FUKUI
FUNCTION 261
7.4 CONCLUSIONS 264
ACKNOWLEDGMENTS 264
REFERENCES 265
8 THE QTAIM PERSPECTIVE OF CHEMICAL BONDING 271
PAUL LODE ALBERT
POPELIER
8.1 INTRODUCTION 271
8.2 BIRTH OF QTAIM: THE QUANTUM ATOM 274
8.3 THE TOPOLOGICAL ATOM: IS IT ALSO A QUANTUM ATOM? 278
8.4 THE BOND CRITICAL POINT AND THE BOND PATH 284
8.5 ENERGY PARTITIONING REVISITED 295
8.6 CONCLUSION 302
ACKNOWLEDGMENT 303
REFERENCES 303
9 THE EXPERIMENTAL DENSITY PERSPECTIVE OF CHEMICAL BONDING 309
WOLJGANG SCHERER, ANDREAS FISCHER, AND GEORG
EICKERLING
9.1 INTRODUCTION 309
9.2 ASPHERICITY SHIFTS AND THE BREAKDOWN OF THE STANDARD X-RAY
MODEL 311
9.3 PRECISION OF CHARGE DENSITY DISTRIBUTIONS IN EXPERIMENTAL AND
THEORETICAL STUDIES 313
9.4 CORE DENSITY DEFORMATIONS INDUCED BY CHEMICAL BONDING 322
9.5 HOW STRONGLY IS THE STATIC ELECTRON DENSITY DISTRIBUTION BIASED BY
THERMAL MOTION? 325
9.6 RELATIVISTIC EFFECTS ON THE TOPOLOGY OF ELECTRON DENSITY 326
9.7 THE TOPOLOGY OF THE LAPLACIAN AND THE MO PICTURE - TWO SIDES OF THE
SAME COIN? 330
9.8 ELUSIVE CHARGE DENSITY PHENOMENA: NONNUCLEAR ATTRACTORS 333
REFERENCES 339
10 THE ELF PERSPECTIVE OF CHEMICAL BONDING 345
YURI GRIN, ANDREAS SAVIN, AND BERNARD SILVI
10.1 INTRODUCTION 345
10.1.1 CONTEXT 345
10.1.1.1 CHEMICAL STRUCTURE GIVEN BY THE ELECTRONIC STRUCTURE 345
10.1.1.2 MOLECULES AND CRYSTALS ARE OBJECTS IN THREE DIMENSIONS 345
10.1.2 CHOICES 346
10.1.2.1 FIX THE NUCLEI 346
CONTENTS I XI
10.1.2.2 COMPUTE, THEN ANALYZE 34
6
10.1.2.3 CHOOSE REGIONS OF SPACE 346
10.2 DEFINITIONS 347
10.2.1 DEFINITION OF THE ELECTRON LOCALIZATION FUNCTION (ELF) 347
10.2.2 DEFINITION OF AUXILIARY QUANTITIES 348
10.2.2.1 ELF MAXIMA 348
10.2.2.2 SPATIAL REGIONS:/-LOCALIZATION DOMAINS 349
10.2.2.3 BIFURCATION DIAGRAMS 350
10.2.2.4 SPATIAL REGIONS: BASINS 351
10.2.2.5 ELF TERMINOLOGY 351
10.2.2.6 QUANTITIES OBTAINED FOR ELF BASINS 352
10.2.2.7 ELF FROM EXPERIMENTAL DATA 353
10.2.2.8 SIMPLIFIED FORMS OF ELF 354
10.2.3 HINTS FOR INTERPRETATION 354
10.2.3.1 ELF AND MESOMERY 354
10.2.3.2 HOW IMPORTANT IS A MAXIMUM? 354
10.2.3.3 WHEN SEVERAL MAXIMA MERGE INTO A SINGLE ONE 355
10.2.3.4 HIDDEN BONDING 355
10.2.3.5 ELECTRON COUNTING: OXIDATION NUMBERS AND FORMAL CHARGES 356
10.2.4 SENSITIVITY OF ELF TO TECHNICAL DETAILS 356
10.3 SIMPLE EXAMPLES 358
10.3.1 ATOMS AND IONS 358
10.3.1.1 ATOMIC SHELLS AND CORES 358
10.3.1.2 STRUCTURED CORES: TIH
4
, CRH
6
359
10.3.1.3 IONS 359
10.3.1.4 SQUEEZING EFFECTS 359
10.3.2 BONDS AND LONE PAIRS 360
10.3.2.1 BONDS: C2H
6
, DIAMOND 360
10.3.2.2 MULTIPLE BONDS: ALLENE 361
10.3.2.3 LONE PAIRS: NH
3
, H
2
0, ICE 363
10.3.2.4 MULTICENTER BONDS: B
2
H
6
362
10.3.2.5 CYLINDRICAL SYMMETRY EFFECTS: C
2
H
2
, HF 362
10.3.2.6 DEREALIZATION: BUTADIENE, BENZENE 363
10.3.3 MOLECULAR REACTIONS 364
10.3.3.1 PROTON TRANSFER IN MALONALDEHYDE 364
10.3.3.2 ALIPHATIC NUCLEOPHILIC SUBSTITUTION S
N
2 366
10.3.3.3 DIELS ALDER ADDITION 367
10.4 SOLIDS 369
10.4.1 IONIC COMPOUNDS 369
10.4.2 MOLECULAR COMPOUNDS 370
10.4.3 ELEMENTAL METALS 370
10.4.4 INTERMETALLIC COMPOUNDS 372
10.4.4.1 ZINTL-KLEMM CONCEPT AND ELF 372
10.4.4.2 ELF FOR PENULTIMATE SHELLS OF TRANSITION METALS 373
10.4.4.3 CASE OF AL
2
CU 374
XII
| CONTENTS
10.4.4.4 SURPRISES 374
10.5 PERSPECTIVES 375
APPENDIX 376
10.A MATHEMATICAL EXPRESSIONS OF CALCULATED BASIN PROPERTIES 376
10.A.1 BASIN POPULATIONS 376
10.A.2 VARIANCE AND COVARIANCE OF BASIN POPULATIONS 377
10.A.3 PROBABILITY DISTRIBUTIONS 378
10.A.4 BASIN ELECTROSTATIC MOMENTS 378
10.A.5 COMBINING ELF AND AIM APPROACHES 378
10.A.6 POTENTIAL ENERGY CONTRIBUTIONS 379
10.A.7 MISCELLANEOUS 379
REFERENCES 380
11 RELATIVITY AND CHEMICAL BONDING 383
PETER SCHWERDTFEGER
11.1 INTRODUCTION 383
11.2 DIRECT AND INDIRECT RELATIVISTIC EFFECTS AND SPIN-ORBIT COUPLING
387
11.2.1 SCALAR-RELATIVISTIC EFFECTS 387
11.2.2 SPIN-ORBIT EFFECTS 391
11.3 CHEMICAL BONDING AND RELATIVISTIC EFFECTS 393
11.4 CONCLUSIONS 400
ACKNOWLEDGMENTS 400
REFERENCES 400
INDEX 405
|
| any_adam_object | 1 |
| author2 | Frenking, Gernot 1946- |
| author2_role | edt |
| author2_variant | g f gf |
| author_GND | (DE-588)109379756 (DE-588)172371066 |
| author_facet | Frenking, Gernot 1946- |
| building | Verbundindex |
| bvnumber | BV041933936 |
| ctrlnum | (OCoLC)915578489 (DE-599)BVBBV041933936 |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV041933936 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:08:41Z |
| institution | BVB |
| isbn | 9783527333141 9783527664696 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027377153 |
| oclc_num | 915578489 |
| open_access_boolean | |
| owner | DE-384 DE-11 DE-20 DE-29 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-188 |
| owner_facet | DE-384 DE-11 DE-20 DE-29 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-188 |
| physical | XXV, 411 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | The chemical bond 1 Fundamental aspects of chemical bonding ed. by Gernot Frenking and Sason Shaik Weinheim Wiley-VCH 2014 XXV, 411 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemische Bindung (DE-588)4009843-6 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Chemische Bindung (DE-588)4009843-6 s DE-604 Frenking, Gernot 1946- (DE-588)109379756 edt Shaik, Sason S. 1948- Sonstige (DE-588)172371066 oth (DE-604)BV041933926 1 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-66471-9 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-66470-2 Erscheint auch als Online-Ausgabe, PDF 978-3-527-66472-6 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027377153&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | The chemical bond Chemische Bindung (DE-588)4009843-6 gnd |
| subject_GND | (DE-588)4009843-6 (DE-588)4143413-4 |
| title | The chemical bond |
| title_auth | The chemical bond |
| title_exact_search | The chemical bond |
| title_full | The chemical bond 1 Fundamental aspects of chemical bonding ed. by Gernot Frenking and Sason Shaik |
| title_fullStr | The chemical bond 1 Fundamental aspects of chemical bonding ed. by Gernot Frenking and Sason Shaik |
| title_full_unstemmed | The chemical bond 1 Fundamental aspects of chemical bonding ed. by Gernot Frenking and Sason Shaik |
| title_short | The chemical bond |
| title_sort | the chemical bond fundamental aspects of chemical bonding |
| topic | Chemische Bindung (DE-588)4009843-6 gnd |
| topic_facet | Chemische Bindung Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027377153&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV041933926 |
| work_keys_str_mv | AT frenkinggernot thechemicalbond1 AT shaiksasons thechemicalbond1 |