Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes: New Developments and Mechanistic Studies
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cham [u.a.]
Springer
2014
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| Schriftenreihe: | Springer Theses
|
| Schlagworte: | |
| Online-Zugang: | UBT01 Volltext Inhaltsverzeichnis Abstract |
| Beschreibung: | 1 Online-Ressource |
| ISBN: | 9783319067070 |
| DOI: | 10.1007/978-3-319-06707-0 |
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Datensatz im Suchindex
| _version_ | 1804152289050492928 |
|---|---|
| adam_text | GOLD-CATALYZED CYCLOISOMERIZATION REACTIONS THROUGH ACTIVATION OF
ALKYNES
/ SIMONNEAU, ANTOINE
: 2014
TABLE OF CONTENTS / INHALTSVERZEICHNIS
FROM THE CONTENTS: GENERAL INTRODUCTION GOLD, A POWERFUL TOOL FOR THE
ACTIVATION OF C-C MULTIPLE BONDS
GOLD AND PLATINUM-CATALYZED REACTIONS OF ENYNES
NEW ADVANCES IN THE GOLD-CATALYZED CYCLOISOMERIZATION REACTIONS OF
ENYNES: 1,5-HYDRIDE SHIFTS AND ACCESS TO KETOMACROLACTONES
DIESES SCHRIFTSTUECK WURDE MASCHINELL ERZEUGT.
GOLD-CATALYZED CYCLOISOMERIZATION REACTIONS THROUGH ACTIVATION OF
ALKYNES
/ SIMONNEAU, ANTOINE
: 2014
ABSTRACT / INHALTSTEXT
ANTOINE SIMONNEAU S THESIS HIGHLIGHTS THE DEVELOPMENT OF NEW
CYCLOISOMERIZATION REACTIONS THROUGH THE ACTIVATION OF ALKYNES WITH GOLD
COMPLEXES. FIRST SIMONNEAU DESCRIBES 1,6-ENYNES AND THEIR DIRECT
CONVERSION INTO ALLENES THROUGH 1,5-HYDRIDE OR ESTER MIGRATION
PROCESSES.THE AUTHOR AND HIS TEAM USED APPROPRIATE PROPARGYLIC
FUNCTIONAL GROUPS TO ACHIEVE THIS CONVERSION. THIS STUDY SHOWS THAT
O-TETHERED 1,6-ENYNES CARRYING A STRAINED CYCLOALKANE AT THE PROPARGYLIC
POSITION COULD UNDERGO A CYCLOPROPANATION/RING EXPANSION CASCADE
REACTION.THE AUTHOR EMPLOYED THIS REARRANGEMENT AS THE STARTING POINT IN
THE DESIGN OF A NEW MACROCYCLE SYNTHESIS. THE NEXT PART OF THE THESIS
FOCUSES ON THE CYCLOISOMERIZATION OF DIYNES INVOLVING AS THE FIRST STEP
OF THE PROCESS THE REARRANGEMENT OF ONE ALKYNE PARTNER INTO AN ALLENE
THANKS TO A GOLD-CATALYZED 1,3-SHIFT OF A PROPARGYLIC ESTER. THE THESIS
DISCLOSES A NEW CYCLOISOMERIZATION PATTERN FEATURING A 1,5-CARBONYL
TRANSFER, GIVING RISE TO UNPRECEDENTED CROSS-CONJUGATED DIKETONES. IN
THE FINAL PART OF THE RESEARCH, SIMMONEAU INVESTIGATES THE
GOLD-CATALYZED CYCLOISOMERIZATION MECHANISM OF 1,6-ENYNES AND QUESTIONS
THE INTERMEDIACY OF GOLD ACETYLIDES. BY THE MEANS OF NMR AND MASS
SPECTROMETRY ANALYSIS, THEORETICAL TREATMENT AND SOLUTION EXPERIMENTS,
IT WAS POSSIBLE TO RULE OUT THE INVOLVEMENT OF THESE SPECIES IN THE
CATALYTIC CYCLE. THIS THESIS HAS LED TO A NUMBER OF PUBLICATIONS IN
HIGH-IMPACT JOURNALS
DIESES SCHRIFTSTUECK WURDE MASCHINELL ERZEUGT.
|
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| spelling | Simonneau, Antoine Verfasser aut Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes New Developments and Mechanistic Studies Antoine Simonneau Cham [u.a.] Springer 2014 1 Online-Ressource txt rdacontent c rdamedia cr rdacarrier Springer Theses Zugl.: Paris, Université Pierre et Marie Curie, Diss. Chemie Chemistry, Organic Chemical engineering Catalysis Chemistry (DE-588)4113937-9 Hochschulschrift gnd-content Erscheint auch als Druckausgabe 978-3-319-06706-3 https://doi.org/10.1007/978-3-319-06707-0 Verlag Volltext Springer Fremddatenuebernahme application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027364041&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Springer Fremddatenuebernahme application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027364041&sequence=000003&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Abstract |
| spellingShingle | Simonneau, Antoine Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes New Developments and Mechanistic Studies Chemie Chemistry, Organic Chemical engineering Catalysis Chemistry |
| subject_GND | (DE-588)4113937-9 |
| title | Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes New Developments and Mechanistic Studies |
| title_auth | Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes New Developments and Mechanistic Studies |
| title_exact_search | Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes New Developments and Mechanistic Studies |
| title_full | Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes New Developments and Mechanistic Studies Antoine Simonneau |
| title_fullStr | Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes New Developments and Mechanistic Studies Antoine Simonneau |
| title_full_unstemmed | Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes New Developments and Mechanistic Studies Antoine Simonneau |
| title_short | Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes |
| title_sort | gold catalyzed cycloisomerization reactions through activation of alkynes new developments and mechanistic studies |
| title_sub | New Developments and Mechanistic Studies |
| topic | Chemie Chemistry, Organic Chemical engineering Catalysis Chemistry |
| topic_facet | Chemie Chemistry, Organic Chemical engineering Catalysis Chemistry Hochschulschrift |
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