Water at interfaces: a molecular approach
"The behavior of water at interfaces and surfaces is still poorly understood at the molecular scale. This book is written for the practicing scientist and engineer who want a fundamental understanding of what water does at surfaces and interfaces. It covers a host of examples to convey general...
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton, FL
CRC Press Taylor & Francis
2014
|
| Schlagworte: | |
| Online-Zugang: | Cover image Inhaltsverzeichnis Klappentext |
| Zusammenfassung: | "The behavior of water at interfaces and surfaces is still poorly understood at the molecular scale. This book is written for the practicing scientist and engineer who want a fundamental understanding of what water does at surfaces and interfaces. It covers a host of examples to convey general principles, including the hydrophobicity and hydrophilicity of materials, the special structure of interfacial water for biological and electrochemical processes, the role of water at biosurfaces (DNA, proteins, and membranes), friction and adhesion, marine aerosols, ice formation, wetting-dewetting, and filtration".. |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | XIV, 243 S. |
| ISBN: | 9781439861042 |
Internformat
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| 264 | 1 | |a Boca Raton, FL |b CRC Press Taylor & Francis |c 2014 | |
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| 500 | |a Includes bibliographical references and index | ||
| 520 | |a "The behavior of water at interfaces and surfaces is still poorly understood at the molecular scale. This book is written for the practicing scientist and engineer who want a fundamental understanding of what water does at surfaces and interfaces. It covers a host of examples to convey general principles, including the hydrophobicity and hydrophilicity of materials, the special structure of interfacial water for biological and electrochemical processes, the role of water at biosurfaces (DNA, proteins, and membranes), friction and adhesion, marine aerosols, ice formation, wetting-dewetting, and filtration".. | ||
| 650 | 7 | |a SCIENCE / Chemistry / Physical & Theoretical |2 bisacsh | |
| 650 | 4 | |a Chemie | |
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| 650 | 4 | |a Molelar structure | |
| 650 | 4 | |a Biological interfaces | |
| 650 | 4 | |a Water chemistry | |
| 650 | 4 | |a SCIENCE / Chemistry / Physical & Theoretical | |
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Datensatz im Suchindex
| _version_ | 1804152199047020544 |
|---|---|
| adam_text | Contents
μ
Preface
..................................................................ix
Abbreviations and Symbols
................................................xi
Chapter
1
An Introduction to Water
........................................1
1
.1
Where Does Water Come From?
...........................2
1.2
Molecular Structure of Isolated Water Molecules
.............4
1.2.1
A Nonlinear Polar Molecule
.......................4
1.2.2
Electronic Structure
...............................6
L2.3 Vibrational Structure
.............................13
1
.3
Hydrogen Bonding Off: van
der Waals
Interactions
..........17
1.4
Hydrogen Bonding On: Condensed Water
..................21
1
A.
1
Water Clusters
..................................21
L4.2 Solid Water
.....................................26
1.4.3
Liquid Water
....................................39
1.4.4
Computer Water
.................................43
1.5
Elixir of Life
............................................48
1.6
Summary
...............................................50
Chapter
2
Interfaces of Condensed Pure Water
.............................59
2.1
Liquid Water
............................................59
2.1.1
Vapor/Liquid Interfaces
..........................60
2.1.2
Water/Oil Interfaces
.............................69
2.2
Solid Water
.............................................72
2.2.1
Solid/Vacuum Interfaces
.........................72
2.2.2
Solid/Liquid/Vapor Interfaces
.....................75
2.3
Summary
...............................................82
Chapter
3
Water on Ideal Solid Surfaces
..................................87
3.1
Single Water Molecules and Clusters
......................87
3.1.1
Single Water Molecules on Metallic Surfaces
.......87
3.1.2
Small Clusters on Surfaces
.......................96
3.2
Substrate-Induced Structuring of Mono- and Bilayers
........99
3.2.1
Interfacial
Registry
..............................99
3.2.2
Inorganic Surfaces with Hexagonal Symmetry
.....100
3.2.3
Surfaces with Non-Hexagonal Symmetry
.........117
3.3
Substrate-Induced Structuring of Water Multilayers
........123
3.3.1
Unpolarized Substrates
..........................123
3.3.2
Polarized Substrates: Electrofreezing
.............124
3.4
Confined Water
.........................................126
3.4.1
2D Confinement
...............................126
3.4.2
ID Confinement
................................131
3.4.3
Electrochemical Nanopatteming
.................134
VII
•
m
·
VIII
Contents
3.5
When Ions Come on the Scene
...........................135
3.5.1
Ion
Hydration..................................135
3.5.2
Electrical Double Layer
.........................141
3.5.3
Dissolution of an Ionic Surface
..................143
3.6
Summary
..............................................145
Chapter
4 Hydrophobie
ity and Hydrophilicity
............................155
4.1
Wetting and Contact Angle
..............................155
4.2
Hydrophobicity at Different Length Scales
................156
4.2.1
Clathrate Hydrates
..............................157
4.2.2
Extended Surfaces
..............................158
4.2.3
Superhydrophobicity
...........................163
4.3
Amphiphilicity
.........................................170
4.3.1
Janus Particles
.................................170
4.3.2
Janus Surfaces
.................................171
4.3.3
Tunable Wetting
................................176
4.4
The Role of Dipoles
....................................179
4.5
Summary
..............................................182
Chapter
5
Water on Real Solid Surfaces
.................................189
5.1
Water Purification
......................................189
5.2
Water Splitting
.........................................194
5.3
Atmospheric Agents
....................................196
5.4
Capillary Adhesion
.....................................200
5.5
Water Desorption in Vacuum Systems
....................202
5.6
Summary
..............................................204
Chapter
6
Water/Biomolecule
Interfaces
.................................209
6.1
Is Water
a
Biomolecule?
................................209
6.2
Proteins
...............................................211
6.2.1
Water-
Peptide
Interactions
......................211
6.2.2 Hydrophobie
Forces and
Hydration..............213
6.2.3
Antifreeze and Ice Nucleating Proteins
...........217
6.3
Nucleic Acids and
DNA.................................220
6.4
Biological Membranes
..................................222
6.4.1
Water/Phospholipid Interfaces
...................222
6.4.2
Water Channels: Aquaporins
....................225
6.5
Summary
..............................................226
Appendix A Buoyancy and Surface Tension
...............................231
Appendix
В
Capillary Forces
............................................233
Appendix
С
Marangoni-Bénard
Patterns
.................................235
Index
..................................................................237
Chemistry
Water, with its simple molecular structure, reveals a complex nature upon
interaction with other molecules and surfaces. Water at Interfaces: A Molecular
Approach provides a broad, multidisciplinary introduction to water at interfaces,
focusing on its molecular characteristics. The book considers interfaces at
different length scales from single water molecules to involvement of large
numbers of water molecules, and from one-dimensional to three-dimensional
interfaces. It begins with individual water molecules, describing their basic
properties and the fundamental concepts that form the basis of this book.
The text explores the main interfaces involving pure and ion-free condensed
(liquid and solid) water, including water vapor/liquid water, liquid/oil, and
liquid/solid interfaces. It examines water molecules on ideal surfaces
—
well-
ordered (crystalline) and defect-free
—
covering topics such as electronic
structure using frontier
orbitais
and substrate-induced structuring. The book
discusses the affinity of water to surfaces, hydrophobicity and hydrophilicity,
emphasizing two extreme cases of affinity. It then addresses real solid
surfaces where water/solid interfaces play a key role in actual working
conditions, examining water purification, photocatalytic activity, corrosion
and degradation, and atmospheric agents.
The final chapter deals with the interaction of water with the heterogeneous and
complex surfaces of biomolecules, which can both influence the structure of
the surrounding water and be modulated by the surrounding liquid. The author
discusses simple to more complex biomolecules from peptides to proteins,
nucleic acids, and membranes.
|
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| spelling | Fraxedas, Jordi Verfasser aut Water at interfaces a molecular approach Jordi Fraxedas Boca Raton, FL CRC Press Taylor & Francis 2014 XIV, 243 S. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index "The behavior of water at interfaces and surfaces is still poorly understood at the molecular scale. This book is written for the practicing scientist and engineer who want a fundamental understanding of what water does at surfaces and interfaces. It covers a host of examples to convey general principles, including the hydrophobicity and hydrophilicity of materials, the special structure of interfacial water for biological and electrochemical processes, the role of water at biosurfaces (DNA, proteins, and membranes), friction and adhesion, marine aerosols, ice formation, wetting-dewetting, and filtration".. SCIENCE / Chemistry / Physical & Theoretical bisacsh Chemie Water Analysis Molelar structure Biological interfaces Water chemistry SCIENCE / Chemistry / Physical & Theoretical Festkörperoberfläche (DE-588)4127823-9 gnd rswk-swf Molekülstruktur (DE-588)4170383-2 gnd rswk-swf Wasser (DE-588)4064689-0 gnd rswk-swf Wasser (DE-588)4064689-0 s Festkörperoberfläche (DE-588)4127823-9 s Molekülstruktur (DE-588)4170383-2 s DE-604 http://images.tandf.co.uk/common/jackets/websmall/978143986/9781439861042.jpg Cover image Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027296503&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027296503&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Fraxedas, Jordi Water at interfaces a molecular approach SCIENCE / Chemistry / Physical & Theoretical bisacsh Chemie Water Analysis Molelar structure Biological interfaces Water chemistry SCIENCE / Chemistry / Physical & Theoretical Festkörperoberfläche (DE-588)4127823-9 gnd Molekülstruktur (DE-588)4170383-2 gnd Wasser (DE-588)4064689-0 gnd |
| subject_GND | (DE-588)4127823-9 (DE-588)4170383-2 (DE-588)4064689-0 |
| title | Water at interfaces a molecular approach |
| title_auth | Water at interfaces a molecular approach |
| title_exact_search | Water at interfaces a molecular approach |
| title_full | Water at interfaces a molecular approach Jordi Fraxedas |
| title_fullStr | Water at interfaces a molecular approach Jordi Fraxedas |
| title_full_unstemmed | Water at interfaces a molecular approach Jordi Fraxedas |
| title_short | Water at interfaces |
| title_sort | water at interfaces a molecular approach |
| title_sub | a molecular approach |
| topic | SCIENCE / Chemistry / Physical & Theoretical bisacsh Chemie Water Analysis Molelar structure Biological interfaces Water chemistry SCIENCE / Chemistry / Physical & Theoretical Festkörperoberfläche (DE-588)4127823-9 gnd Molekülstruktur (DE-588)4170383-2 gnd Wasser (DE-588)4064689-0 gnd |
| topic_facet | SCIENCE / Chemistry / Physical & Theoretical Chemie Water Analysis Molelar structure Biological interfaces Water chemistry Festkörperoberfläche Molekülstruktur Wasser |
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