Flows and chemical reactions in homogeneous mixtures:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
London
ISTE [u.a.]
2013
|
| Ausgabe: | 1. publ. |
| Schriftenreihe: | Fluid mechanics series
|
| Schlagworte: | |
| Online-Zugang: | Klappentext Inhaltsverzeichnis |
| Beschreibung: | XXIV, 223 S. graph. Darst. |
| ISBN: | 1848216335 9781848216334 |
Internformat
MARC
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| 245 | 1 | 0 | |a Flows and chemical reactions in homogeneous mixtures |c Roger Prud'homme |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a London |b ISTE [u.a.] |c 2013 | |
| 300 | |a XXIV, 223 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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Datensatz im Suchindex
| _version_ | 1804152081707171840 |
|---|---|
| adam_text | Table
of
Contents
Symbols
.................................................. ix
Preface
................................................... xxiii
Chapter
1.
Flows in Nozzles
................................... 1
1.1.
Sound propagation in the presence of chemical reactions
.......... 1
1.1.1.
Thermodynamic considerations
......................... 2
1.1.2.
Sound propagation in a mono-reactive medium
.............. 7
1.1.3.
Sound propagation in a multi-reactive medium
.............. 12
1.2.
Relaxed flows in nozzles
................................ 26
1.2.1.
Calculation of a continuous flow with a recombination-dissociation
reaction in
a de
Laval nozzle
............................... 27
1.2.2.
Asymptotic study of the transonic zone of a continuous mono-
dimensional flow in
a de
Laval nozzle
......................... 31
1.3.
Flows in thermal and chemical non-equilibrium
................ 35
1.3.1.
Balance equations and closure relations in the presence of thermal and
chemical non-equilibria
................................... 35
1.3.2.
Application
....................................... 37
1.4.
Conclusion about flows in nozzles
.......................... 45
Chapter
2.
Chemical Reactors
................................. 47
2.1.
Ideal reactors, real reactors, balance equations
................. 48
2.1.1.
Ideal chemical reactors
............................... 48
2.1.2.
Balance equations for chemical reactors
................... 50
2.2.
Perfectly mixed homogeneous chemical reactors
.............. 55
2.2.1.
Equations for a perfectly stirred homogeneous chemical reactor.
. 55
2.2.2.
Steady regimes in perfectly stirred homogeneous chemical reactors
59
vi
Flows and Chemical Reactions in Homogeneous Mixtures
2.2.3.
Stability of operating points in the perfectly stirred homogeneous
chemical reactor
........................................ 61
2.3.
Tubular reactor
....................................... 67
2.3.1.
Plug flow reactor
................................... 68
2.3.2.
Reactor with axial mixing
............................. 70
2.3.3.
Reactor with radial mixing
............................ 73
2.4.
Residence time distribution
............................... 74
2.4.1.
Balance equations
................................... 74
2.4.2.
Perfectly stirred homogeneous reactors in a steady regime
...... 76
2.4.3.
Plug flow reactors
.................................. 76
2.4.4.
Poiseuille flow
..................................... 76
2.4.5.
Real reactors
...................................... 78
Chapter
3.
Laminar and Turbulent Flames
....................... 79
3.1.
Laminar premixed combustion
............................ 79
3.1.1.
Rankine-Hugoniot theory
............................. 80
3.1.2.
Velocity and structure of the plane adiabatic laminar and steady
premixed flame
......................................... 87
3.1.3.
Other examples of a steady laminar premixed flame
.......... 91
3.2.
Laminar non-premixed combustion
......................... 95
3.2.1.
Burke-Schumann problem
............................ 95
3.2.2.
Other examples of diffusion flames
...................... 98
3.3.
Turbulent combustion
................................... 104
3.3.1.
Averaged balance equation for turbulent combustion
.......... 105
3.3.2.
Premixed turbulent combustion regimes
................... 107
3.3.3.
Non-premixed turbulent combustion regimes
............... 110
3.3.4.
Models of turbulent combustion
........................ 112
3.3.5.
LESs in combustion
................................. 119
3.3.6.
Triple flames
...................................... 121
Appendices
............................................... 125
Appendix
1.
Dimensionless Numbers, Similarity
................... 127
Al.l. Fundamentals of dimensional analysis:
П.
groups
............. 128
A
1.1.1.
Basic considerations
............................... 128
Al.
1.2.
Vaschy-Buckingham theorem
(1890)
or
Π
theorem
......... 129
Al
.1.3.
Practical advantage to dimensional analysis
............... 130
A
1.1.4.
Example of application: head loss in a cylindrical pipe
....... 130
Al.
2.
Similarity
.......................................... 132
Al.
2.1.
Definition
....................................... 132
Al.
2.2.
Application: condition of similarity in a soft balloon placed in a
current of air with a given velocity
.................. . 133
Table
of
Contents
vii
Al
.3.
Analytical searching for solutions to a heat transfer problem (self-similar
solution)
............................................... 135
A
1.4.
Some dimensionless numbers
............................ 137
Appendix
2.
Thermodynamic Functions
.......................... 141
A2.1. General points
....................................... 141
A2.2. Translational motion
.................................. 142
A2.3. Internal motions
..................................... 143
A2.3.1. Monatomic species
................................ 143
A2.3.2. Diatomic species
.................................. 145
A.
2.3.3.
Linear polyatomic species
........................... 146
A2.3.4. Nonlinear polyatomic species
......................... 147
Appendix
3.
Concepts of Turbulence
............................ 149
A3.1. Experimental demonstration
............................. 151
A3.1.1.
Reynolds experiment
.............................. 151
A3.1.2.
Viscous flow over a smooth plane plate
.................. 152
A3.1.3.
Effect of roughness of the plate
........................ 153
A3.1.4.
Effect of turbulence on chemical reactivity
............... 153
A3.2.
Apparition and damping of turbulence
...................... 154
A3.2.1. Instability between two superposed fluids
................ 154
A3.2.2.
Instability of a fluid between two rotating cylinders
......... 158
A3.2.3.
Instability of apremixed flame
........................ 165
A3.2.4.
Damping of turbulence
.............................. 169
A3.3. Classic turbulence (RANS model)
......................... 170
A3.3.1. Turbulent transfer and chemical kinetics coefficients
........ 170
A3.3.2.
Remarks about averages and scales
..................... 176
A3.3.3.
k
— ε
models (closure for transfer terms)
................ 178
A3.3.4.
Spectral analysis and Kolmogorov s theory
............... 181
A3.4.
Ideas about large eddy simulation
......................... 185
A3.4.1.
Filtering
........................................ 187
A3,.4.2.
Filtered balance equations for a non-reactive incompressible fluid
189
A3.4.3. Closure relations for the filtered balance equations
.......... 190
A3.5. Conclusion
......................................... 193
Appendix
4.
Thermodynamic functions for a mixture in disequilibrium.
195
A4.1.
Thermodynamics
..................................... 195
A4.2. Chemistry
.......................................... 197
A4.3. Vibration
..........................................
197
viii
Flows and Chemical Reactions in Homogeneous Mixtures
Appendix
5.
Notion of bifurcation
..............................
I
W
Appendix
6.
Confined flame
................................... 201
Appendix
7.
Limits of Validity of the First-order Kxpansions for
Diffusion Flames
........................................... 203
A7.1. Burke Schumann flame
................................ 201
A7.
2.
Juxtaposed
oxidi/er/ťuel
flows from rectangular burners
......... 204
Bibliography
.............................................. 207
Index
.................................................... 21
l)
Flows with chemical reactions can occur in various fields such as
combustion, process engineering, aeronautics, the atmospheric
environment and aquatics.
The examples of application chosen in this book mainly concern
homogeneous reactive mixtures that can occur in propellers within the
fields of process engineering and combustion:
-
propagation of sound and monodimensional flows in nozzles, which
may include disequilibria of the internal modes of the energy of
molecules;
-
ideal chemical reactors, stabilization of their steady operation points
in the homogeneous case of a perfect mixture and classical
instruments of experimental and theoretical analysis such as
population balances, and the distribution of residence and passage
times;
-
laminar and turbulent flames, separating those which are premixed
from those which are not and which do not exhibit the same
mechanisms, but which also occur in the case of triple flames.
Flows and Chemical Reactions in Homogeneous Mixtures provides
information on dimensional analysis, statistical thermodynamics with
coupling between internal modes and chemical reactions, the apparition
and damping of fluid turbulence as well as its statistical processing,
bifurcations, flames in a confined medium and diffusion.
Roger
Prud homme
has been Emeritus Research Director at
CNRS,
in
France, since
2004.
His most recent research topics have included
flames {premixed flame modeling and their behavior in microgravity),
two phase flows (droplet combustion with condensation of the
products, sound propagation in suspensions, vortex, chock wave
structure) and the modeling of fluid interfaces. He has published
5
books,
7
contributions to volumes and
50
publications in international
journals.
|
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| bvnumber | BV041772443 |
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| ctrlnum | (OCoLC)886657470 (DE-599)BVBBV041772443 |
| discipline | Chemie / Pharmazie |
| edition | 1. publ. |
| format | Book |
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| id | DE-604.BV041772443 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:05:03Z |
| institution | BVB |
| isbn | 1848216335 9781848216334 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027218408 |
| oclc_num | 886657470 |
| open_access_boolean | |
| owner | DE-703 |
| owner_facet | DE-703 |
| physical | XXIV, 223 S. graph. Darst. |
| publishDate | 2013 |
| publishDateSearch | 2013 |
| publishDateSort | 2013 |
| publisher | ISTE [u.a.] |
| record_format | marc |
| series2 | Fluid mechanics series |
| spelling | Prud'homme, Roger Verfasser aut Flows and chemical reactions in homogeneous mixtures Roger Prud'homme 1. publ. London ISTE [u.a.] 2013 XXIV, 223 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Fluid mechanics series Turbulenz (DE-588)4061232-6 gnd rswk-swf Reagierende Strömung (DE-588)4137697-3 gnd rswk-swf Mischphase (DE-588)4131537-6 gnd rswk-swf Strömungsmechanik (DE-588)4077970-1 gnd rswk-swf Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf Mischphase (DE-588)4131537-6 s Strömungsmechanik (DE-588)4077970-1 s Turbulenz (DE-588)4061232-6 s DE-604 Chemische Reaktion (DE-588)4009853-9 s Reagierende Strömung (DE-588)4137697-3 s 1\p DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027218408&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Klappentext Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027218408&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Prud'homme, Roger Flows and chemical reactions in homogeneous mixtures Turbulenz (DE-588)4061232-6 gnd Reagierende Strömung (DE-588)4137697-3 gnd Mischphase (DE-588)4131537-6 gnd Strömungsmechanik (DE-588)4077970-1 gnd Chemische Reaktion (DE-588)4009853-9 gnd |
| subject_GND | (DE-588)4061232-6 (DE-588)4137697-3 (DE-588)4131537-6 (DE-588)4077970-1 (DE-588)4009853-9 |
| title | Flows and chemical reactions in homogeneous mixtures |
| title_auth | Flows and chemical reactions in homogeneous mixtures |
| title_exact_search | Flows and chemical reactions in homogeneous mixtures |
| title_full | Flows and chemical reactions in homogeneous mixtures Roger Prud'homme |
| title_fullStr | Flows and chemical reactions in homogeneous mixtures Roger Prud'homme |
| title_full_unstemmed | Flows and chemical reactions in homogeneous mixtures Roger Prud'homme |
| title_short | Flows and chemical reactions in homogeneous mixtures |
| title_sort | flows and chemical reactions in homogeneous mixtures |
| topic | Turbulenz (DE-588)4061232-6 gnd Reagierende Strömung (DE-588)4137697-3 gnd Mischphase (DE-588)4131537-6 gnd Strömungsmechanik (DE-588)4077970-1 gnd Chemische Reaktion (DE-588)4009853-9 gnd |
| topic_facet | Turbulenz Reagierende Strömung Mischphase Strömungsmechanik Chemische Reaktion |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027218408&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027218408&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT prudhommeroger flowsandchemicalreactionsinhomogeneousmixtures |