Verfügbarkeit: The effect of long term thermal exposure on plastics and elastomers

The effect of long term thermal exposure on plastics and elastomers:

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Bibliographische Detailangaben
1. Verfasser:	McKeen, Laurence W. (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Amsterdam [u.a.] Elsevier 2014
Schriftenreihe:	PDL handbook series
Schlagworte:	Plastics / Effect of high temperatures on Elastomers / Effect of high temperatures on Technology Elastomer Polymere Kunststoff Thermoanalyse Hitzebeständigkeit
Online-Zugang:	Inhaltsverzeichnis Klappentext
Beschreibung:	IX, 280 S.
ISBN:	0323221084 9780323221085

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adam_text	A Volume in the Plastics Design Library Series The Effect of Long Term Thermal Exposure on Plastics and Elastomers Laurence W. McKeen This reference guide brings together a wide range of essential data on the effect of long-term thermal exposure on plastics and elastomers, enabling engineers to make optimal material choices and design decisions. The data is supported by explanations of how to make use of the data in real-world engineering contexts. High heat environments are common in automotive, oil and gas, household appliances, coatings, space and aeronautics, and many more end uses. As a result, thermal stability data are critically important to engineers designing parts particularly that replace metals, work that is common today as they look for ways to reduce weight. The data tables in this book enable engineers and scientists to select the right materials for a given product or application across a wide range of sectors. Several polymer classes are covered, including polyolefins, polyamides, polyesters, elastomers, fluoropolymers, biodegradable plastics, and more, saving readers the need to contact suppliers. The book also includes introductory sections to provide background on plastic/polymer chemistry and formulation and plastic testing methods, providing the knowledge required to make best use of the data. ABOUT THE AUTHOR Laurence W. McKeen has a PhD. in Chemistry from the University of Wisconsin and has worked for Dufbnt Fluoroproducts since 1978. Currently he is a Senior Research Associate Chemist responsible for new product development including application technology and product optimization for particular end uses, and product testing. RELATED TITLES The Effect afSteriliwtion on Plastics and Elastomers, 3e, McKeen, 2012. ISBN: 9781455725984 Film Properties of Plastics and Elastomers, 3e, McKeen, 2012. ISBN: 9781455725519 The Effect of Creep and Other Tone Related Factors on Plastics and Elastomers, 2e, McKeen, 2009. ISBN: 9780815515852 Handbook of Biopolymers and Biodegradable Plastics, Ebnesajjad, 2012. ISBN: 9781455728343 Contents^ Preface .........................................................................................................................................................................ix 1 Introduction to Plastics and Polymers .........................................................................................................1 1.1 Polymerization .........................................................................................................................................1 1.1.1 Addition Polymerization ...............................................................................................................1 1.1.2 Condensation Polymerization .......................................................................................................2 1.2 Copolymers ..............................................................................................................................................2 1.3 Linear, Branched, and Crosslinked Polymers ........................................................................................3 1.4 Polarity ....................................................................................................................................................3 1.5 Unsaturation ............................................................................................................................................4 1.6 Steric Hindrance ......................................................................................................................................5 1.7 Isomers ....................................................................................................................................................5 1.7.1 Structural Isomers .........................................................................................................................6 1.7.2 Geometric Isomers ........................................................................................................................6 1.7.3 Stereoisomers — Syndiotactic, Isotactic, Atactic ...........................................................................6 1.8 Inter- and Intramolecular Attractions in Polymers .................................................................................7 1.8.1 Hydrogen Bonding ........................................................................................................................7 1.8.2 Van der Waals Forces ...................................................................................................................8 1.8.3 Chain Entanglement ......................................................................................................................8 1.9 General Classifications ............................................................................................................................8 1.9.1 Molecular Weight ..........................................................................................................................8 1.9.2 Thermosets Versus Thermoplastics ..............................................................................................9 1.9.3 Crystalline Versus Amorphous ...................................................................................................10 1.10 Plastic Compositions .............................................................................................................................10 1.10.1 Fillers, Reinforcement, Composites ........................................................................................11 1.10.2 Combustion Modifiers, Fire, Flame Retardants, and Smoke Suppressants ...........................12 1.10.3 Release Agents ........................................................................................................................12 1.10.4 Slip Additives/Internal Lubricants ..........................................................................................13 1.10.5 Antiblock Additives ................................................................................................................14 1.10.6 Catalysts ..................................................................................................................................14 1.10.7 Impact Modifiers and Tougheners ..........................................................................................14 1.10.8 UV/Radiation Stabilizers ........................................................................................................14 1.10.9 Optical Brighteners .................................................................................................................14 1.10.10 Plasticizers ...............................................................................................................................15 1.10.11 Pigments, Extenders, Dyes, Mica ...........................................................................................15 1.10.12 Coupling Agents ......................................................................................................................15 1.10.13 Thermal Stabilizers .................................................................................................................15 1.10.14 Antistats ...................................................................................................................................16 vj Contents 1.11 Summary ................................................................................................................................................16 References .......................................................................................................................................................16 2 Introduction to the Effect of Heat Aging on Plastics ...............................................................................17 2.1 Physical Processes of Heating on Plastic Materials ...............................................................................17 2.2 Thermal Degradation Chemistry .............................................................................................................17 2.3 Mechanisms of Thermal Stabilization ....................................................................................................17 2.3.1 Phenolic Antioxidants ...................................................................................................................17 2.3.2 Secondary Antioxidants — Phosphites and Phosphonites .............................................................18 2.3.3 Secondary Antioxidants — Thioethers ...........................................................................................20 2.3.4 Metal Deactivators ........................................................................................................................20 2.3.5 Optical Brighteners .......................................................................................................................20 2.3.6 Acid Scavengers ............................................................................................................................22 2.4 Thermal/Heat Aging Testing ..................................................................................................................23 2.4.1 Oven Aging Tests ..........................................................................................................................23 2.4.2 Thermal Analysis ..........................................................................................................................24 2.5 Creep — Aging Under Stress ....................................................................................................................31 2.5.1 Categories, Stages, or Regions of Creep ......................................................................................33 2.5.2 Measures of Creep ........................................................................................................................34 References .......................................................................................................................................................42 3 Introduction to the Physical, Mechanical, and Thermal Properties of Plastics and Elastomers ____43 3.1 Appearance Properties .............................................................................................................................43 3.1.1 Color ..............................................................................................................................................43 3.1.2 Gloss Measurement .......................................................................................................................45 3.1.3 Haze Measurement ........................................................................................................................46 3.1.4 Yellowness Index ..........................................................................................................................46 3.2 Mechanical Testing of Plastics ...............................................................................................................47 3.2.1 Tensile Properties ..........................................................................................................................47 3.2.2 Rigidity of Plastics Materials ........................................................................................................53 3.2.3 Shear Properties .............................................................................................................................53 3.2.4 Flexural Properties ........................................................................................................................56 3.2.5 Puncture and Impact Properties ....................................................................................................56 3.2.6 Tear Properties ..............................................................................................................................60 3.2.7 Toughness ......................................................................................................................................61 3.3 Thermal Property Testing of Plastics .....................................................................................................63 3.3.1 Melt Flow Index ............................................................................................................................63 3.3.2 Heat Deflection Temperature ........................................................................................................63 3.3.3 Vicat Softening Temperature ........................................................................................................65 3.3.4 Melting Point, Tm ..........................................................................................................................65 3.3.5 Glass Transition Temperature, Tg .................................................................................................66 References .......................................................................................................................................................71 4 Styrenie Plastics __........................___________.............________...____.___..............._____________.73 4.1 Acrylonitrile—Butadiene— Styrene Copolymer ......................................................................................73 4.2 Polystyrene ..............................................................................................................................................73 Contents vii 4.3 Styrene— Acrylonitrile Copolymer ..........................................................................................................77 4.4 Acrylonitrile— Styrene Acrylate ..............................................................................................................80 4.5 Styrene— Butadiene Copolymer ..............................................................................................................82 4.6 Styrenie Blends/Alloys............................................................................................................................ 83 References .......................................................................................................................................................84 5 Polyesters .......................................................................................................................................................85 5.1 Liquid Crystalline Polymers ...................................................................................................................85 5.2 Polybutylene Terephthalate .....................................................................................................................86 5.3 Polycarbonate ..........................................................................................................................................93 5.4 Polyethylene Terephthalate .....................................................................................................................97 5.5 Polyethylene Naphthalate and Polybutylene Naphthalate ......................................................................99 5.6 Isophorone Bisphenol Based PCs .........................................................................................................100 5.7 Copolyesters ..........................................................................................................................................102 References .....................................................................................................................................................114 6 Polyimides ....................................................................................................................................................117 6.1 Polyamide— Imide .................................................................................................................................117 6.2 Polyetherimide .......................................................................................................................................117 6.3 Polyimide ...............................................................................................................................................125 References .....................................................................................................................................................137 7 Polyamides (Nylons) ______________________________________________________________139 7.1 Amorphous Polyamide (Polyamide Copolymers)..............................................................................139 7.2 Polyamide 6 (Nylon 6)........................................................................................................................141 7.3 Polyamide 11 (Nylon 11)....................................................................................................................142 7.4 Polyamide 12 (Nylon 12)....................................................................................................................142 7.5 Polyamide 46 (Nylon 46)....................................................................................................................145 7.6 Polyamide 66 (Nylon 66)....................................................................................................................145 7.7 Polyamide 612 (Nylon 612)................................................................................................................158 7.8 Polyamide 666 (Nylon 666 or 66/6)...................................................................................................159 7.9 Polyarylamide ......................................................................................................................................159 7.10 Polyphthalamide/High-Performance Polyamide.................................................................................161 7.11 Polyamide Alloys ................................................................................................................................168 References .....................................................................................................................................................169 8 Polyolefins, Polyvinyls, and Acrylics --------------------------------------------------------------------------171 8.1 Polyolefins .............................................................................................................................................171 8.1Л Polyethylene ................................................................................................................................171 8.1.2 Polypropylene ..............................................................................................................................172 8.2 Benzocyclobutene Polymer ...................................................................................................................175 8.3 Polyacrylics ...........................................................................................................................................177 8.4 Polyvinylchloride................................................................................................................................177 8.5 Ethylene- Vinyl Acetate Copolymer ....................................................................................................179 References .....................................................................................................................................................182 viii Contents 9 Fluoropolymers ...........................................................................................................................................183 9.1 Polytetrafluoroethylene .........................................................................................................................183 9.2 Fluorinated Ethylene-Propylene (FEP)...............................................................................................185 9.3 Perfluoroalkoxy (PFA) ..........................................................................................................................189 9.4 Polyvinyl Fluoride .................................................................................................................................191 9.5 Polychlorotrifluoroethylene ...................................................................................................................193 9.6 Polyvinylidene Fluoride ........................................................................................................................198 9.7 Ethylene— Tetrafluoroethylene Copolymer ...........................................................................................198 9.8 Ethylene— Chlorotrifluoroethylene Copolymer ....................................................................................200 References .....................................................................................................................................................207 10 High-Temperature/High-Performance Polymers ..................................................................................209 10.1 Polyaryletherketone ...........................................................................................................................209 10.2 Polyphenylene Sulfide .......................................................................................................................210 10.3 Polysulfone ........................................................................................................................................215 10.4 Polyphenylsulfone .............................................................................................................................221 10.5 Polyethersulfone ................................................................................................................................221 10.6 Parylene (Poly(p-xylylene)) ..............................................................................................................224 10.7 Polyoxymethylene (POM or Acetal Homopolymer)/Polyoxymethylene Copolymer (POM-Co or Acetal Copolymer) ......................................................................................................227 10.8 Polyphenylene Oxide (PPO or PPE) .................................................................................................237 References ...................................................................................................................................................238 11 Elastomers and Rubbers ____________________________________________________________239 . 1 Thermoplastic Polyurethane Elastomers ...........................................................................................239 .2 Olefinic Thermoplastic Elastomers ...................................................................................................242 .3 Thermoplastic Copolyester Elastomers ............................................................................................243 .4 Bromobutyl Rubber ...........................................................................................................................244 .5 Chlorobutyl Rubber (Polychloroprene) ............................................................................................244 .6 Ethylene-Propylene Rubbers (EPM, EPDM) ..................................................................................245 .7 Fluoroelastomers ...............................................................................................................................246 .8 Natural Rubber ..................................................................................................................................250 11.9 Acrylonitrile—Butadiene Copolymer ................................................................................................259 References ...................................................................................................................................................271 Index ..........................................................................................................................................................................273
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spelling	McKeen, Laurence W. Verfasser (DE-588)1030069247 aut The effect of long term thermal exposure on plastics and elastomers by Laurence W. McKeen Amsterdam [u.a.] Elsevier 2014 IX, 280 S. txt rdacontent n rdamedia nc rdacarrier PDL handbook series Plastics / Effect of high temperatures on Elastomers / Effect of high temperatures on Technology ukslc Elastomer (DE-588)4014162-7 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Thermoanalyse (DE-588)4135675-5 gnd rswk-swf Hitzebeständigkeit (DE-588)4160053-8 gnd rswk-swf Polymere (DE-588)4046699-1 s Thermoanalyse (DE-588)4135675-5 s DE-604 Elastomer (DE-588)4014162-7 s Kunststoff (DE-588)4033676-1 s Hitzebeständigkeit (DE-588)4160053-8 s Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027156175&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027156175&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext
spellingShingle	McKeen, Laurence W. The effect of long term thermal exposure on plastics and elastomers Plastics / Effect of high temperatures on Elastomers / Effect of high temperatures on Technology ukslc Elastomer (DE-588)4014162-7 gnd Polymere (DE-588)4046699-1 gnd Kunststoff (DE-588)4033676-1 gnd Thermoanalyse (DE-588)4135675-5 gnd Hitzebeständigkeit (DE-588)4160053-8 gnd
subject_GND	(DE-588)4014162-7 (DE-588)4046699-1 (DE-588)4033676-1 (DE-588)4135675-5 (DE-588)4160053-8
title	The effect of long term thermal exposure on plastics and elastomers
title_auth	The effect of long term thermal exposure on plastics and elastomers
title_exact_search	The effect of long term thermal exposure on plastics and elastomers
title_full	The effect of long term thermal exposure on plastics and elastomers by Laurence W. McKeen
title_fullStr	The effect of long term thermal exposure on plastics and elastomers by Laurence W. McKeen
title_full_unstemmed	The effect of long term thermal exposure on plastics and elastomers by Laurence W. McKeen
title_short	The effect of long term thermal exposure on plastics and elastomers
title_sort	the effect of long term thermal exposure on plastics and elastomers
topic	Plastics / Effect of high temperatures on Elastomers / Effect of high temperatures on Technology ukslc Elastomer (DE-588)4014162-7 gnd Polymere (DE-588)4046699-1 gnd Kunststoff (DE-588)4033676-1 gnd Thermoanalyse (DE-588)4135675-5 gnd Hitzebeständigkeit (DE-588)4160053-8 gnd
topic_facet	Plastics / Effect of high temperatures on Elastomers / Effect of high temperatures on Technology Elastomer Polymere Kunststoff Thermoanalyse Hitzebeständigkeit
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027156175&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027156175&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT mckeenlaurencew theeffectoflongtermthermalexposureonplasticsandelastomers

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