The organometallic chemistry of the transition metals:
Gespeichert in:
1. Verfasser: | |
---|---|
Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Hoboken, N.J.
Wiley
2014
|
Ausgabe: | 6. ed. |
Schlagworte: | |
Online-Zugang: | Klappentext Inhaltsverzeichnis |
Beschreibung: | XVI, 504 S. Ill., graph. Darst. |
ISBN: | 9781118138076 |
Internformat
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100 | 1 | |a Crabtree, Robert H. |d 1948- |e Verfasser |0 (DE-588)139871314 |4 aut | |
245 | 1 | 0 | |a The organometallic chemistry of the transition metals |c Robert H. Crabtree |
250 | |a 6. ed. | ||
264 | 1 | |a Hoboken, N.J. |b Wiley |c 2014 | |
300 | |a XVI, 504 S. |b Ill., graph. Darst. | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
650 | 7 | |a Organometaalcomplexen |2 gtt | |
650 | 7 | |a Overgangsmetaalcomplexen |2 gtt | |
650 | 4 | |a Organometallic chemistry | |
650 | 4 | |a Organotransition metal compounds | |
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Datensatz im Suchindex
_version_ | 1804151868559982592 |
---|---|
adam_text | CONTENTS
Preface
Xl
List of Abbreviations
···
XIII
1
Introduction
1
1.1
Why Study Organometallic Chemistry?,
1
1.2
Coordination Chemistry,
3
1.3
Werner Complexes,
4
1.4
The Trans Effect,
9
1.5
Soft versus Hard Ligands,
10
1.6
The Crystal Field,
11
1.7
The Ligand Field,
19
1.8
The sd Model and Hypervaiency,
21
1.9
Back Bonding,
23
1.10
Electroneutrality,
27
1.11
Types of Ligand,
29
References,
37
Problems,
38
2
Making Sense of Organometallic Complexes
40
2.1
The IS-Electron Rule,
40
2.2
Limitations of the lS-Electron Rule,
48
2.3
Electron Counting in Reactions,
50
2.4
Oxidation State,
51
ví
CONTENTS
2.5
Coordination Number and Geometry,
57
2.6
Effects of Complexation,
60
2.7
Differences between Metals,
63
References,
66
Problems,
67
3
Alkyls and Hydrides
69
3.1
Alkyls and Aryls,
69
3.2
Other
σ
-Bonded
Ligands,
84
3.3
Metal Hydrides,
86
3.4
Sigma Complexes,
89
3.5
Bond Strengths,
92
References,
95
Problems,
96
4
Carbonyls, Phosphines, and Substitution
98
4.1
Metal Carbonyls,
98
4.2
Phosphines,
109
4.3
N-Heterocyclic Carbenes (NHCs),
113
4.4
Dissociative Substitution,
115
4.5
Associative Substitution,
120
4.6
Redox
Effects and Interchange Substitution,
122
4.7
Photochemical Substitution,
124
4.8
Counterions and Solvents in Substitution,
127
References,
129
Problems,
131
5
Pi-Complexes
134
5.1
Alkene and Alkyne Complexes,
134
5.2
Allyls,
140
5.3 Diene
Complexes,
144
5.4
Cyclopentadienyl Complexes,
147
5.5
Arenes
and Other Alicyclic Ligands,
154
5.6
Isolobal Replacement and Metalacycles,
158
5.7
Stability of Polyene and Polyenyl Complexes,
159
References,
160
Problems,
161
6
Oxidative Addition and Reductive Elimination
163
6.1
Introduction,
163
6.2
Concerted Additions,
166
CONTENTS
vii
6.3 SN2
Pathways,
168
6.4
Radical Mechanisms,
170
6.5
Ionic Mechanisms,
172
6.6
Reductive Elimination,
173
6.7
σ
-Bond
Metathesis,
179
6.8
Oxidative Coupling and Reductive Fragmentation,
180
References,
182
Problems,
182
7
Insertion and Elimination
185
7.1
Introduction,
185
72
CO Insertion,
187
7.3
Alkene Insertion,
192
7.4
Outer Sphere Insertions,
197
75
α, β,
%
and
б
Elimination,
198
References,
201
Problems,
201
8
Addition and Abstraction
204
8.1
Introduction,
204
8.2
Nucleophilic Addition to CO,
207
8.3
Nucleophilic Addition to Polyenes and Polyenyls,
208
8.4
Nucleophilic Abstraction in Hydrides, Alkyls, and
Acyls,
215
8.5
Electrophilic Addition and Abstraction,
216
8.6
Single-Electron Transfer and Radical Reactions,
219
References,
221
Problems,
222
9
Homogeneous Catalysis
224
9.1
Catalytic Cycles,
224
9.2
Alkene Isomerization,
231
9.3
Hydrogénation,
233
9.4
Alkene Hydroformylation,
242
9.5
Alkene Hydrocyanation,
245
9.6
Alkene Hydrosilylation and Hydroboration,
246
9.7
Coupling Reactions,
248
9.8
Organometallic Oxidation Catalysis,
250
9.9
Surface, Supported, and Cooperative Catalysis,
251
References,
253
Problems,
256
viii CONTENTS
10
Physical Methods
259
10.1
Isolation,
259
10.2
Ή
NMR Spectroscopy,
260
10.3
13C NMR Spectroscopy,
264
10.4
3lP NMR Spectroscopy,
266
10.5
Dynamic NMR,
268
10.6
Spin Saturation Transfer,
271
10.7
Τχ
and the Nuclear Overhauser Effect,
272
10.8
IR
Spectroscopy,
276
10.9
Crystallography,
279
10.10
Electrochemistry and EPR,
281
10.11
Computation,
283
10.12
Other Methods,
285
References,
287
Problems,
288
11
M-L Multiple Bonds
290
11.1
Carbenes,
290
11.2
Carbynes,
302
11.3
Bridging Carbenes and Carbynes,
305
11.4
N-Heterocyclic Carbenes,
306
11.5
Multiple Bonds to
Heteroatoms,
310
References,
313
Problems,
315
12
Applications
317
12.1
Alkene Metathesis,
317
12.2
Dimerization, Oligomerization, and Polymerization of
Alkenes,
324
12.3
Activation of CO and CO2,
332
12.4
C
-Н
Activation,
336
12.5
Green Chemistry,
343
12.6
Energy Chemistry,
344
References,
347
Problems,
349
13
Clusters, Nanoparticles, Materials, and Surfaces
353
13.1
Cluster Structures,
354
13.2
The Isolobal Analogy,
364
133
Nanoparticles,
368
CONTENTS ix
13.4 Organometallic Materials, 371
References,
379
Problems, 381
14
Organic
Applications 383
14.1
Carbon-Carbon Coupling,
384
14.2
Metathesis,
391
14.3 Cyclopropanation and
C
-Н
Insertion,
393
14.4
Hydrogénation,
394
14.5 Carbonylation, 396
14.6
Oxidation,
399
14.7
С-Н
Activation,
401
14.8
Click Chemistry,
405
References,
406
Problems,
408
15
Paramagnetic and High Oxidation-State Complexes
411
15.1
Magnetism and Spin States,
413
15.2
Polyalkyls and Polyhydrides,
420
15.3
Cyclopentadienyl Complexes,
425
15.4
/-Block Complexes,
426
References,
433
Problems,
435
16
Bioorganometallic Chemistry
436
16.1
Introduction,
437
16.2
Coenzyme B!2,
442
16.3
Nitrogen Fixation,
449
16.4
Nickel Enzymes,
457
16.5
Biomedical
and Biocatalytic Applications,
463
References,
465
Problems,
467
Appendix A: Useful Texts on Allied Topics
469
Appendix B: Major Reaction Types and Hints on
Problem Solving
472
Solutions to Problems
475
Index
493
New edition highlights organic synthesis applications,
nanoparticle science, and green chemistry
The Sixth Edition of this bestselling and internationally acclaimed text continues to
instill in students and researchers an understanding of the nature of organometallic
compounds as well as their preparation and use in organic synthesis. Readers not
only master the fundamentals of the field, but also its current applications in industry
and research.
Each chapter of this edition of The Organometallic Chemistry of the Transition
Metals has been thoroughly revised, updated, and expanded. Readers will discover
the latest research findings as well as new and emerging applications. In addition,
there are plenty of new examples incorporating the latest discoveries in the field.
This Sixth Edition also offers:
•
Increased focus on organic synthesis applications, nanoparticle science, and green
chemistry
•
Expanded discussions on supramolecular chemistry, N-heterocyclic carbenes,
coupling reactions, and organometallic materials
•
New sections dedicated to green chemistry, multifunctional ligands, and oxidation
catalysis
•
New applications in organic synthesis and bioorganometallic chemistry
Chapters conclude with a set of problems, enabling readers to apply their newfound
knowledge and assess their grasp of the material as they progress through the text.
Solutions to the problems are available at the end of the text, where readers will also
find a list of useful texts on allied topics and a list of major reaction types.
The Organometallic Chemistry of the Transition Metals is recommended for advanced
undergraduate and graduate students as well as chemistry professionals in organic
chemistry, organometallic chemistry, and inorganic chemistry. All readers will gain new
insights into organometallic compounds as well as a variety of new synthetic tools to
advance their research.
ROBERT H. CRABTREE, PhD, is Professor in the Department of Chemistry
at Yale University. Among his many honors and accolades, he is a Fellow
of the American Academy of Arts
&
Sciences and the American Chemical
Society. Dr. Crabtree has served on the editorial boards of Chemical Reviews
and Organometallics.
www.wiley.com/chemistry
Wi
Also available
as an e-book
ISBN
978-1-118-13807-6
90000
|
any_adam_object | 1 |
author | Crabtree, Robert H. 1948- |
author_GND | (DE-588)139871314 |
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dewey-search | 547/.056 |
dewey-sort | 3547 256 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie Chemie |
edition | 6. ed. |
format | Book |
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spelling | Crabtree, Robert H. 1948- Verfasser (DE-588)139871314 aut The organometallic chemistry of the transition metals Robert H. Crabtree 6. ed. Hoboken, N.J. Wiley 2014 XVI, 504 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Organometaalcomplexen gtt Overgangsmetaalcomplexen gtt Organometallic chemistry Organotransition metal compounds Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 s Übergangsmetallorganische Verbindungen (DE-588)4417301-5 s 1\p DE-604 DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027084823&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Klappentext Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027084823&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
spellingShingle | Crabtree, Robert H. 1948- The organometallic chemistry of the transition metals Organometaalcomplexen gtt Overgangsmetaalcomplexen gtt Organometallic chemistry Organotransition metal compounds Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
subject_GND | (DE-588)4417301-5 (DE-588)4131837-7 |
title | The organometallic chemistry of the transition metals |
title_auth | The organometallic chemistry of the transition metals |
title_exact_search | The organometallic chemistry of the transition metals |
title_full | The organometallic chemistry of the transition metals Robert H. Crabtree |
title_fullStr | The organometallic chemistry of the transition metals Robert H. Crabtree |
title_full_unstemmed | The organometallic chemistry of the transition metals Robert H. Crabtree |
title_short | The organometallic chemistry of the transition metals |
title_sort | the organometallic chemistry of the transition metals |
topic | Organometaalcomplexen gtt Overgangsmetaalcomplexen gtt Organometallic chemistry Organotransition metal compounds Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
topic_facet | Organometaalcomplexen Overgangsmetaalcomplexen Organometallic chemistry Organotransition metal compounds Übergangsmetallorganische Verbindungen Übergangsmetallkomplexe |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027084823&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027084823&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT crabtreeroberth theorganometallicchemistryofthetransitionmetals |