Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online-Zugang: | kostenfrei Inhaltsverzeichnis |
| Beschreibung: | Zsfassung in dt. und engl. Sprache |
| Beschreibung: | 181 S. graph. Darst. |
Internformat
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| 246 | 1 | 3 | |a Photoinduzierte Ladungstransferprozesse in Redox-Kaskaden basierend auf Triarylamin-Donoren und dem perchlorierten Triphenylmethyl-Radikal-Akzeptor |
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Datensatz im Suchindex
| _version_ | 1804151866778451968 |
|---|---|
| adam_text | TABLE OF CONTENTS
1 INTRODUCTION 1
2 THEORY 3
2.1
MARCUS-THEORY 3
2.2 JORTNER-
THEORY 7
3 STATE
OF THE ART 9
3.1 GENERAL ASPECTS 9
*
3.2 ARTIFICIAL SYSTEMS FOR THE STUDY OF CHARGE-TRANSFER PROCESSES 10
3.3 THE PERCHLORINATED TRIPHENYLMETHYL (PCTM) RADICAL ACCEPTOR.: 15
3.3.1 PERCHJORINATED TRIPHENYLMETHYL RADICALS - SYNTHESIS, STRUCTURE &
REACTIVITY 15
3.3.2 PERCHLORINATED BI- AND POLYRADICALS 19
3.3.3 DYADS BASED ON THE PCTM RADICAL ACCEPTOR 31
3.4 1,2,3-TRIAZOLES AS VERSATILE LINKERS 37
4 PROJECT AIM 39
4.1 SYNTHESIS AND INVESTIGATION OF REDOX CASCADES 39
4.2 SYNTHESIS OF DONOR-ACCEPTOR SUBSTITUTED DIKETOPYRROLOPYRROLES 42
5 RESULTS
AND DISCUSSION 44
5.1 SYNTHESIS 44
5.1.1 SYNTHESIS OF CASCADES WITH TRIAZOLE BRIDGES 44
5.1.2 SYNTHESIS OF CASCADES WITH A SATURATED SPACER 55
5.1.3 SYNTHESIS OF DIKETOPYRROLOPYRROLES (DPPS) 61
5.1.4 ANALYTICAL METHODS 64
5.2 ABSORPTION SPECTROSCOPY 69
5.3 EMISSION SPECTROSCOPY 73
5.3 CYCLIC
VOLTAMMETRY 78
5.4 SPECTROELECTROCHEMISTRY AND CHEMICAL OXIDATION 82
5.5 TRANSIENT ABSORPTION SPECTROSCOPY 88
5.5.1 NS-TRANSIENT ABSORPTION SPECTROSCOPY 88
HTTP://D-NB.INFO/1048730239
5.5.2 FS-TRANSIENT ABSORPTION SPECTROSCOPY 93
5.6 ELECTRON SPIN
RESONANCE SPECTROSCOPY 104
6 SUMMARY 106
7 EXPERIMENTAL SECTION 108
7.1 ANALYTICAL
METHODS 108
7.2 SYNTHESIS 115
7.2.1 GENERAL
EXPERIMENTAL PROCEDURES 115
7.2.2 REDOX CASCADES WITH TRIAZOLE-SPACER UNITS 117
7.2.3 REDOX CASCADES WITH SATURATED SPACER UNITS 139
7.2.4 PRECURSORS AND
REFERENCE COMPOUNDS 149
7.2.5 SYNTHESIS OF DIKETOPYRROLOPYRROLES 157
8 LITERATURE 161
9 TABLE OF FORMULAS 172
10 ZUSAMMENFASSUNG 177
APPENDIX 179
TIME DECAY CURVES
(EMISSION SPECTROSCOPY) 179
TIME DECAY CURVES
(NS-TRANSIENT ABSORPTION SPECTROSCOPY) 180
|
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| discipline | Chemie / Pharmazie |
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| spelling | Dürrbeck, Nina Verfasser (DE-588)1047359324 aut Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor von Nina Dürrbeck Photoinduzierte Ladungstransferprozesse in Redox-Kaskaden basierend auf Triarylamin-Donoren und dem perchlorierten Triphenylmethyl-Radikal-Akzeptor 2013 181 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Zsfassung in dt. und engl. Sprache Würzburg, Univ., Diss., 2013 Donator Chemie (DE-588)4255817-7 gnd rswk-swf Akzeptor Chemie (DE-588)4327806-1 gnd rswk-swf Ladungstransfer (DE-588)4307016-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Akzeptor Chemie (DE-588)4327806-1 s Donator Chemie (DE-588)4255817-7 s Ladungstransfer (DE-588)4307016-4 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:20-opus-90078 https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-90078 Resolving-System kostenfrei Volltext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027083691&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Dürrbeck, Nina Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor Donator Chemie (DE-588)4255817-7 gnd Akzeptor Chemie (DE-588)4327806-1 gnd Ladungstransfer (DE-588)4307016-4 gnd |
| subject_GND | (DE-588)4255817-7 (DE-588)4327806-1 (DE-588)4307016-4 (DE-588)4113937-9 |
| title | Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor |
| title_alt | Photoinduzierte Ladungstransferprozesse in Redox-Kaskaden basierend auf Triarylamin-Donoren und dem perchlorierten Triphenylmethyl-Radikal-Akzeptor |
| title_auth | Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor |
| title_exact_search | Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor |
| title_full | Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor von Nina Dürrbeck |
| title_fullStr | Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor von Nina Dürrbeck |
| title_full_unstemmed | Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor von Nina Dürrbeck |
| title_short | Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor |
| title_sort | photoinduced charge transfer processes in redox cascades based on triarylamine donors and the perchlorinated triphenylmethyl radical acceptor |
| topic | Donator Chemie (DE-588)4255817-7 gnd Akzeptor Chemie (DE-588)4327806-1 gnd Ladungstransfer (DE-588)4307016-4 gnd |
| topic_facet | Donator Chemie Akzeptor Chemie Ladungstransfer Hochschulschrift |
| url | https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-90078 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027083691&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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