Variations on N-heterocyclic carbene ligands: new triazolylidene and tetrazolylidene compounds
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2013
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 119 S. graph. Darst. |
| ISBN: | 9783843913447 |
Internformat
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| 245 | 1 | 0 | |a Variations on N-heterocyclic carbene ligands |b new triazolylidene and tetrazolylidene compounds |c Lars-Arne Johann Asmus Schaper |
| 250 | |a 1. Aufl. | ||
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Datensatz im Suchindex
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| adam_text | TABLE OF CONTENTS
DANKSAGUNG 9
DEUTSCHES ABSTRACT 11
ENGLISH ABSTRACT 13
TABLE OF CONTENTS 15
LIST OF ABBREVIATIONS 19
1 BROADER CONTEXT 21
1.1 GLOBAL CHALLENGES * ORGANOMETALLIC SOLUTIONS 21
1.1.1 ATOM-ECONOMIC PROCESSES 21
1.1.2 LIGHT INDUCED APPLICATIONS 23
1.2 THE IDEAL CATALYST 25
1.3 REFERENCES FOR CHAPTER 1 26
2 INTRODUCTION TO JV-HETEROCYCLIC CARBENE CHEMISTRY 31
2.1 GENERAL REMARKS 31
2.2 SYNTHETIC ACCESS ROUTES 31
2.2.1 SYNTHESIS OF NHC PRECURSORS 32
2.2.2 SYNTHESIS OF FREE STABLE NHCS 34
2.2.3 SYNTHESIS OF NHC METAL COMPLEXES 37
2.3 RING AND SUBSTITUENT MODIFICATIONS 42
2.3.1 RING MODIFICATIONS 42
2.3.2 SUBSTITUENT MODIFICATIONS 45
2.3.3 ABNORMAL NHC LIGANDS 46
2.4 LIGAND CHARACTERISTICS 49
2.4.1 ELECTRONIC CHARACTERISTICS 49
2.4.2 STERIC CHARACTERISTICS 55
15
HTTP://D-NB.INFO/1045970190
2.5 CONCLUSION 56
2.6 REFERENCES FOR CHAPTER 2 57
3 OBJECTIVE 65
4 RESULTS - PUBLICATION SUMMARIES 67
4.1 N-HETEROCYCLIC CARBENES VIA ABSTRACTION OF AMMONIA: NORMAL
CARBENES WITH
ABNORMAL CHARACTER 67
4.2 EXPLORING THE SCOPE OF A NOVEL LIGAND CLASS: SYNTHESIS AND CATALYTIC
EXAMINATION
OF METAL COMPLEXES WITH NORMAL 1,2,3-TRIAZOLYLIDENE LIGANDS 69
4.3 GOLD(I) COMPLEXES WITH NORMAL 1,2,3-TRIAZOLYLIDENE LIGANDS:
SYNTHESIS AND
CATALYTIC PROPERTIES 71
4.4 SYNTHESIS AND COMPARISON OF TRANSITION METAL COMPLEXES OF ABNORMAL
AND
NORMAL TETRAZOLYLIDENES: A NEGLECTED LIGAND SPECIES 73
4.5 SYNTHESIS AND CHARACTERISATION OF CHELATED CATIONIC
RE(I)(CO)JBIS(NHC)(WCA)
COMPLEXES 75
4.6 EARLY TRANSITION AND RARE EARTH METAL COMPLEXES WITH N-HETEROCYCLIC
CARBENES.. 77
4.7 GROUP 7 TRANSITION METAL COMPLEXES WITH ^/-HETEROCYCLIC CARBENES 79
4.8 SYNTHESIS AND APPLICATION OF WATER SOLUBLE NHC TRANSITION METAL
COMPLEXES 81
4.9 REFERENCES 83
4.10 REPRINT PERMISSIONS .- 86
4.10.1 ALL ACS PUBLICATIONS 86
4.10.2 ALL RSC PUBLICATIONS 88
4.10.3 ANGEWANDTE CHEMIE INTERNATIONAL EDITION PERMISSION 89
4.10.4 JOURNAL OF ORGANOMETALLIC CHEMISTRY PERMISSION 93
5 BIBLIOGRAPHIC DETAILS FOR COMPLETE PUBLICATIONS 97
5.1 N-HETEROCYCLIC CARBENES VIA ABSTRACTION OF AMMONIA: NORMAL
CARBENES WITH
ABNORMAL CHARACTER 97
5.2 EXPLORING THE SCOPE OF A NOVEL LIGAND CLASS: SYNTHESIS AND CATALYTIC
EXAMINATION
OF METAL COMPLEXES WITH NORMAL 1,2,3-TRIAZOLYLIDENE LIGANDS 98
16
5.3 GOLD(I) COMPLEXES WITH NORMAL 1,2,3-TRIAZOLYLIDENE LIGANDS:
SYNTHESIS AND
CATALYTIC PROPERTIES 99
5.4 SYNTHESIS AND COMPARISON OF TRANSITION METAL COMPLEXES OF ABNORMAL
AND
NORMAL TETRAZOLYLIDENES: A NEGLECTED LIGAND SPECIES 100
5.5 SYNTHESIS AND CHARACTERISATION OF CHELATED CATIONIC
RE(I)(CO)3BIS(NHC)(WCA)
COMPLEXES 101
5.6 EARLY TRANSITION AND RARE EARTH METAL COMPLEXES WITH N-HETEROCYCLIC
CARBENES 102
5.7 GROUP 7 TRANSITION METAL COMPLEXES WITH //-HETEROCYCLIC CARBENES 103
5.8 SYNTHESIS AND APPLICATION OF WATER SOLUBLE NHC TRANSITION METAL
COMPLEXES.... 104
5.9 SIDE PROJECT: CATALYTIC HYDROGENATION OF LEVULINIC ACID IN AQUEOUS
PHASE 105
6 SUMMARY 107
6.1 DEUTSCHE ZUSAMMENFASSUNG 107
6.2 ENGLISH SUMMARY 111
6.3 LIST OF PUBLICATIONS 115
6.3.1 JOURNAL OR BOOK CHAPTER CONTRIBUTIONS 115
6.3.2 TALKS 117
6.3.3 POSTER PRESENTATIONS 117
6.4 CURRICULUM VITAE 118
17
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| discipline | Chemie |
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| spelling | Schaper, Lars-Arne Verfasser aut Variations on N-heterocyclic carbene ligands new triazolylidene and tetrazolylidene compounds Lars-Arne Johann Asmus Schaper 1. Aufl. München Verl. Dr. Hut 2013 119 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2013 Koordinationslehre (DE-588)4133952-6 gnd rswk-swf Heterocyclische Carbene -N (DE-588)7652572-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Heterocyclische Carbene -N (DE-588)7652572-7 s Koordinationslehre (DE-588)4133952-6 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027068886&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Schaper, Lars-Arne Variations on N-heterocyclic carbene ligands new triazolylidene and tetrazolylidene compounds Koordinationslehre (DE-588)4133952-6 gnd Heterocyclische Carbene -N (DE-588)7652572-7 gnd |
| subject_GND | (DE-588)4133952-6 (DE-588)7652572-7 (DE-588)4113937-9 |
| title | Variations on N-heterocyclic carbene ligands new triazolylidene and tetrazolylidene compounds |
| title_auth | Variations on N-heterocyclic carbene ligands new triazolylidene and tetrazolylidene compounds |
| title_exact_search | Variations on N-heterocyclic carbene ligands new triazolylidene and tetrazolylidene compounds |
| title_full | Variations on N-heterocyclic carbene ligands new triazolylidene and tetrazolylidene compounds Lars-Arne Johann Asmus Schaper |
| title_fullStr | Variations on N-heterocyclic carbene ligands new triazolylidene and tetrazolylidene compounds Lars-Arne Johann Asmus Schaper |
| title_full_unstemmed | Variations on N-heterocyclic carbene ligands new triazolylidene and tetrazolylidene compounds Lars-Arne Johann Asmus Schaper |
| title_short | Variations on N-heterocyclic carbene ligands |
| title_sort | variations on n heterocyclic carbene ligands new triazolylidene and tetrazolylidene compounds |
| title_sub | new triazolylidene and tetrazolylidene compounds |
| topic | Koordinationslehre (DE-588)4133952-6 gnd Heterocyclische Carbene -N (DE-588)7652572-7 gnd |
| topic_facet | Koordinationslehre Heterocyclische Carbene -N Hochschulschrift |
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