Graphene: a new paradigm in condensed matter and device physics
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Oxford
Oxford University Press
2014
|
| Ausgabe: | 1. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | Literaturverz. S. [275] - 295 |
| Beschreibung: | XII, 305 S. Ill., graph. Darst. |
| ISBN: | 9780198783831 9780199645862 |
Internformat
MARC
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| 020 | |a 9780198783831 |c paperback |9 978-0-19-878383-1 | ||
| 020 | |a 9780199645862 |9 978-0-19-964586-2 | ||
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| 100 | 1 | |a Wolf, E. L. |d 1936- |e Verfasser |0 (DE-588)129512176 |4 aut | |
| 245 | 1 | 0 | |a Graphene |b a new paradigm in condensed matter and device physics |c E. L. Wolf |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Oxford |b Oxford University Press |c 2014 | |
| 300 | |a XII, 305 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Literaturverz. S. [275] - 295 | ||
| 650 | 4 | |a Graphene |a Properties | |
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| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026904143&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |3 Klappentext |
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Datensatz im Suchindex
| _version_ | 1810988397841350656 |
|---|---|
| adam_text |
Contents
1
Introduction
1
1.1
"Crystals" one atom thick: a new paradigm
1
1.2
Roles of symmetry and topology
7
1.2.1
Linear bands, "massless Dirac" particles
7
1.2.2
"Pseudo-spins" from dual sublattices and
helicity
11
1.3
Analogies to relativiatic physics backed by experiment
14
1.4
Possibility of carbon ring electronics
17
1.5
Nobel Prize in Physics in
2010
to Andre K. Geim
and
Konstantin
S.
Novoselov
17
1.6
Perspective, scope and organization
18
2
Physics in two dimensions (2D)
20
2.1
Introduction
20
2.2
2D electrons on liquid helium and in semiconductors
21
2.3
The quantum Hall effect, unique to 2D
24
2.3.1
Hall effect at low magnetic field
25
2.3.2
High field effects
27
2.3.3 von Klitzing's
discovery of the quantized Hall effect
28
2.4
Formal theorems on 2D long-range order
32
2.4.1
Absolute vs. relative thermal motions in 2D
32
2.4.2
The Hohenberg-Landau-Mermin-Peierls-Wagner Theorem
38
2.4.3
2D vs. 2D embedded in
3D 39
2.4.4
Soft membrane, crumpling instability
40
2.5
Predictions against growth of 2D crystals
44
2.6
"Artificial" methods for creating 2D crystals
45
2.7
Elastic behavior of thin plates and ribbons
45
2.7.1
Strain Nomenclature and Energies
47
2.7.2
Curvature and Gaussian curvature
49
2.7.3
Isometric distortions of a soft
inextensible
membrane
50
2.7.4
Vibrations and waves on elastic sheets and ribbons of graphene
51
2.7.5
An excursion into one dimension
55
3
Carbon in atomic, molecular and crystalline
(3D
and 2D)
forms
57
3.1
Atomic carbon C: (ls)2(2s)2(2p)2
57
3.1.1.
Wavefunctions for principal quantum numbers
η
= 1
and
η
— 1 58
3.1.2
Linear combinations of
η
= 2
wavefunctions
60
χ
Contents
3.1.3
Two-electron states as relevant to covalent bonding
3.1.4 Pauli
principle and filled states of the carbon atom
(»1
3.2
Molecular carbon: CH4,
C6H6, C6o (t'|
3.2.1
Covalent bonding in simple molecules
63
3.2.2
Methane CH4
:
tetrahedral bonding
<"
3.2.3
Benzene C6H6
:
sp2 and
η
bonding (is
3.2.4
Fullerene
C60 81
3.2.5
Graphane and Fluorographene s-
3.3
Crystals: diamond and graphite
83
3.3.1
Mined graphite
83
3.3.2
Synthetic "Kish" graphite
83
3.3.3
Synthetic HOPG: Highly Oriented Pyrolytic Graphite
84
4
Electron bands of graphene s(l
4.1
Semimetal vs. conductor of relativistic electrons
86
4.2
Linear bands of Wallace and the anomalous neutral point
ί)()
4.2.1
Pseudo-spin wavefunction '((l
4.3
L. Pauling: graphene lattice with
"1/3
double-bond character" i)2
4.4
McClure: diamagnetism and zero-energy Landau level
92
4.5
Fermi level manipulation by chemical doping i)3
4.6
Bilayer graphene
"■'·
5
Sources and forms of graphene "s
5.1
Graphene single-crystals, flakes and cloths !>s
5.1.1
Micro-mechanically cleaved graphite !»s
5.1.2
Chemically and liquid-exfoliated graphite flakes
IDI
5.2
Epitaxially and catalytically grown crystal layers IDs
5.2.1
Epitaxial growth on SiC: Si face vs.
С
face
I Oí)
5.2.2
Catalytic growth on
Ni
or Cu, with
transfer
112
5.2.3
Large area roll-to-roll production of graphene
1 1
I
5.2.4
Grain structure of CVD graphene films
115
5.2.5
Hybrid boron-carbon-nitrogen BCN films
118
5.2.6
Atomic layer deposition
120
5.3
Graphene nanoribbons 1
2
1
5.3.1
Zigzag and armchair terminations
122
5.3.2
Energy gap at small ribbon width, transistor dynamic range
123
5.3.3
Chemical synthesis of perfect armchair nanoribbons
125
6
Experimental probes of graphene
128
6.1
Transport, angle-resolved photoemission spectroscopy
128
6.2
Optical, Raman effect, thermal conductivity
129
6.3
Scanning tunneling spectroscopy and potentiometry
132
6.4
Capacitance spectroscopy
!;>;;
6.5
Inverse compressibility with scanning single
electron transistor (SSET) |;;(,
Contents
xi
139
139
141
s
146
150
158
164
169
176
178
7
Mechanical and physical properties of graphene
7.1
Experimental aspects of 2D graphene crystals
7.1.1
Classical (extrinsic) origin of ripples and wrinkles
in monolayer graphene
7.1.2
Stability of graphene in supported samples up to
30
inches
7.1.3
Phonon dispersion in graphene
7.1.4
Experimental evidence of nanoscale roughness
7.1.5
Electrical conductivity of graphene in experiment
7.2
Theoretical approaches to "intrinsic corrugations"
7.3
Impermeable even to helium
7.4
Nanoelectromechanical resonators
7.5
Metal-insulator Mott-Anderson transition in
ultrapure
screened graphene
179
7.6
Absence of "intrinsic ripples" and "minimum conductivity"
in graphene
183
8
Anomalous properties of graphene
185
8.1
Sublimation of graphite and "melting" of graphene
185
8.2
Electron and hole puddles, electrostatic doping and the
"minimum conductivity"
191
8.3
Giant non-locality in transport
193
8.4
Anomalous integer and fractional quantum Hall effects
197
8.5
Absence of backscattering, carrier mobility
199
8.6
Proposed nematic phase transition in bilayer graphene
202
8.7
Klein tunneling, Dirac equation
204
8.8
Superconducting proximity effect, graphene
Josephson
junction
213
8.Í)
Quasi-Rydberg impurity states;
Zitterbewegung 219
9
Applications of graphene
223
9.1
Transistor-like devices
224
9.1.1
High-frequency
FET
transistors
225
9.1.2
Vertically configured graphene tunneling
FET
devices
231
9.1.3
The graphene Barristor, a solid state
triode
device
237
9.2
Phototransistors,
optical detectors and modulators
237
9.3
Wide area conductors, interconnects, solar cells, Li-ion
batteries and hydrogen storage
244
9.3.1
Interconnects
248
9.3.2
Hydrogen storage, supercapacitors
249
9.4 Spintronic
applications of graphene
251
9.5
Sensors of single molecules, "electronic nose"
254
9.6
Metrology, resistance standard
255
9.7
Memory elements
255
9.8
Prospects for graphene in new digital electronics beyond
CMOS
257
9.8.1
Optimizing silicon
FET
switches
257
xii Contents
9.8.2
Potentially
manufacturable
graphene
FET
devices
'ПУЛ
9.8.3
Tunneling
FET
devices
2í¡ I
9.8.4
Manufacturable graphene
tunneling
FET
devices
2fHi
10
Summary and assessment
270
References
275
Author Index
U!H¡
Subject Index
301
This book is an introduction to the science and possible applications of graphene,
the first one-atom-thick crystalline form of matter. Discovered in
2004
by (now) Nobelists
Geim and Novoselov, the single layer of graphite, a hexagonal network of carbon atoms,
has astonishing electrical and mechanical properties. It supports the highest electrical current
density of any material, far exceeding metals copper and silver. Its absolute minimum
thickness,
0.34
nanometers, provides an inherent advantage in possible forms
of digital electronics past the era of Moore's Law.
Applications of graphene come in classes that range from additives to composite
materials to field effect transistor elements capable of extremely high frequency operation.
The classes of applications correlate with differing methods of fabrication, from inexpensive
chemical exfoliations of graphite, to chemical vapour deposition on catalytic substrates as copper
and nickel, at temperatures around I 300K. The book reviews potential applications within existing
electronics, to include interconnect wires, flash-memory elements, and high frequency field
effect transistors. The chance to supplant the dominant complementary metal-oxide
semiconductor (CMOS) family of silicon logic devices is assessed.
E. L, Wolf is a Professor of Physics at the Polytechnic Institute of New York University.
ALSO PUBLISHED BY
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Cover ¡mage:
©
Fotoi
ISBN
978-0-19-964586-2
UNIVERSITY PRESS
www.oup.com
780199
645862 |
| any_adam_object | 1 |
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| author_variant | e l w el elw |
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| ctrlnum | (OCoLC)867152635 (DE-599)GBV768687519 |
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| indexdate | 2024-09-23T12:05:22Z |
| institution | BVB |
| isbn | 9780198783831 9780199645862 |
| language | English |
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| publishDate | 2014 |
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| publisher | Oxford University Press |
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| spelling | Wolf, E. L. 1936- Verfasser (DE-588)129512176 aut Graphene a new paradigm in condensed matter and device physics E. L. Wolf 1. ed. Oxford Oxford University Press 2014 XII, 305 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturverz. S. [275] - 295 Graphene Properties Graphen (DE-588)7591667-8 gnd rswk-swf Graphen (DE-588)7591667-8 s DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026904143&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026904143&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Wolf, E. L. 1936- Graphene a new paradigm in condensed matter and device physics Graphene Properties Graphen (DE-588)7591667-8 gnd |
| subject_GND | (DE-588)7591667-8 |
| title | Graphene a new paradigm in condensed matter and device physics |
| title_auth | Graphene a new paradigm in condensed matter and device physics |
| title_exact_search | Graphene a new paradigm in condensed matter and device physics |
| title_full | Graphene a new paradigm in condensed matter and device physics E. L. Wolf |
| title_fullStr | Graphene a new paradigm in condensed matter and device physics E. L. Wolf |
| title_full_unstemmed | Graphene a new paradigm in condensed matter and device physics E. L. Wolf |
| title_short | Graphene |
| title_sort | graphene a new paradigm in condensed matter and device physics |
| title_sub | a new paradigm in condensed matter and device physics |
| topic | Graphene Properties Graphen (DE-588)7591667-8 gnd |
| topic_facet | Graphene Properties Graphen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026904143&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026904143&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
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