Lithium batteries and other electrochemical storage systems:
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| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London [u.a.]
ISTE [u.a.]
2013
|
| Series: | Electrical engineering series
|
| Subjects: | |
| Online Access: | Klappentext Inhaltsverzeichnis |
| Physical Description: | XVIII, 354 S. Ill., graph. Darst. |
| ISBN: | 9781848214965 |
Staff View
MARC
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| 100 | 1 | |a Glaize, Christian |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Lithium batteries and other electrochemical storage systems |c Christian Glaize ; Sylvie Geniès |
| 264 | 1 | |a London [u.a.] |b ISTE [u.a.] |c 2013 | |
| 300 | |a XVIII, 354 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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Record in the Search Index
| _version_ | 1804151548697116672 |
|---|---|
| adam_text | Table
of
Contents
Preface
........................................ xiä
Acknowledgements
................................ xv
Introduction
..................................... xvii
Part l. Storage Requirements Characteristics of
Secondary Batteries Examples of use
................ 1
Chapter
1.
Breakdown of Storage Requirements
............ 3
1.1.
Introduction
................................. 3
1.2.
Domains of application for energy storage
............. 3
1.2.1.
Starter batteries
............................ 4
1.2.2.
Traction batteries
........................... 6
1.2.3.
Stationary batteries
.......................... 10
1.2.4.
Batteries for mobile or nomadic devices
............ 17
1.3.
Review of storage requirements and appropriate
technologies
................................... 18
1.4.
Conclusion
................................. 19
Chapter
2.
Definitions and Measuring Methods
............. 21
2.1.
Introduction
................................. 21
2.2.
Terminology
................................ 21
2.2.1.
Accumulator
.............................. 22
2.2.2.
Element, elementary cell, electrolyte
.............. 22
2.2.3.
Electrode, half-element, half-cell
................. 23
vi
Lithium
Batteries
2.2.4.
Oxidation, reduction, anode, cathode
.............. 24
2.2.5.
Active material
............................ 25
2.2.6.
Voltage
................................. 25
2.2.7.
Battery of accumulators, modules, packs, BMS
........ 26
2.3.
Definitions of the characteristics
.................... 27
2.3.1.
Nominal voltage
........................... 27
2.3.2.
Voltage undercurrent
........................ 27
2.3.3.
Capacities
................................ 30
2.4.
States of the battery
............................ 40
2.4.1.
Depth of discharge
.......................... 40
2.4.2.
State of charge
............................. 41
2.4.3.
State of energy
............................ 41
2.4.4.
State of health
............................. 41
2.4.5.
State of function
........................... 45
2.4.6.
Theoretical gravimetric capacity
................. 45
2.4.7.
Practical gravimetric capacity
................... 46
2.4.8.
Volumetric capacity
......................... 46
2.4.9.
Specific capacity
........................... 46
2.4.10.
Direct-current internal resistance and short-circuit
current
...................................... 47
2.4.11.
AC internal resistance
....................... 48
2
A.M. Impedance, impedancemetry, impedance
spectroscopy
.................................. 49
2.4.13.
Stored energy and deliverable energy
............. 62
2.4.14.
Gravimetric energy density
.................... 63
2.4.15.
Volumetric energy density
.................... 64
2.4.16.
Specific energy
........................... 64
2.4.17.
Gravimetric power and volumetric power
........... 65
2.5.
Faradaic efficiency
............................ 66
2.6.
Self-discharge
............................... 67
2.7.
Acceptance current
............................ 68
2.8.
Conclusion
................................. 69
2.9.
Appendix
1:
Nerast s law
........................ 69
2.9.1.
Redox
potential of an electrode
.................. 69
2.9.2.
Electromotive force of an electrochemical cell
........ 70
2.9.3.
Nernst s law
.............................. 71
2.9.4.
Activity of the species
........................ 73
2.9.5.
Example of the application of Nernst s law to a lithium
secondary battery using the insertion mechanism
.......... 74
2.10.
Appendix
2:
Double layer
...................... 78
2.11.
Appendix
3:
Warburg impedance
................. 79
2.12.
Solutions to the exercises in Chapter
2.............. 82
Table
of
Contents
vii
Chapter
3.
Practical Examples Using Electrochemical Storage
... 89
3.1.
introduction
................................. 89
3.1.1.
Starter currents for internal combustion engines
in cars
...................................... 89
3.1.2.
Power required by a telecommunications transceiver
in an isolated site
............................... 94
3.1.3.
House in an isolated site
...................... 98
3.1.4.
Currents in an operational electric car battery
......... 101
3.1.5.
Currents during the phase of recharging of batteries
in electric cars
................................. 104
3.1.6.
Autonomous urban lighting
.................... 107
3.2.
Conclusion
................................. 109
3.3.
Solution to the exercises in Chapter
3............... 110
Part
2.
Lithium Batteries
.......................... 115
Chapter
4.
Introduction to Lithium Batteries
............... 117
4.1.
History of lithium batteries
....................... 117
4.2.
Categories of lithium batteries
..................... 121
4.3.
The different operational mechanisms for lithium
batteries
...................................... 122
4.3.1.
Intercalation (or insertion) materials
............... 122
4.3.2.
Alloys
.................................. 123
4.3.3.
Direction conversion materials
.................. 128
4.3.4.
Differences of voltage profiles between intercalation
materials, alloys and conversion materials
............... 129
4.3.5.
Properties of the electrode materials
............... 130
4.4.
Appendices
................................. 131
4.4.1.
Appendix
1:
Examples of
redox
couples
............ 131
4.4.2.
Appendix
2:
Dendrites
....................... 131
4.4.3.
Appendix
3:
Transition metals
.................. 132
Chapter
5.
The Basic Elements in Lithium-ion Batteries:
Electrodes, Electrolytes and Collectors
................... 135
5.1.
Introduction
................................. 135
5.2.
Operation of lithium-ion technology
................. 136
5.3.
Positive electrodes
............................. 138
5.3.1.
Lithiated transition metal oxides
................. 138
5.3.2.
Manganese oxide
........................... 142
5.3.3.
Lithiated iron oxyphosphate
.................... 143
viii Lithium
Batteries
5.3.4.
Crystalline
structures
........................ 145
5.3.5.
Mass capacities
............................ 146
5.4.
Negative electrodes
............................ 146
5.4.1.
Carbonaceous materials
....................... 146
5.4.2.
Other carbonaceous materials
................... 150
5.4.3.
Lithium titanate oxide
........................ 152
5.4.4.
Electrochemical potentials
..................... 156
5.4.5.
Mass capacities
............................ 156
5.5.
Electrolyte
.................................. 158
5.5.1.
Liquid electrolyte
........................... 158
5.5.2.
Polymer electrolyte
.......................... 160
5.6.
Current collectors
............................. 161
5.7.
Conclusion
................................. 162
5.8.
Solution to exercises in Chapter
5................... 162
Chapter
6.
Usual Lithium-ion Batteries
................... 167
6.1.
Principle of operation of conventional assemblies
of electrodes
................................... 167
6.1.1.
Principle of operation of a C-LiMO2 element
......... 168
6.1.2.
Principle of operation of
a C-LÌC0O2
element
......... 168
6.1.3.
Principle of operation of a C-LiFePCU element
........ 171
6.1.4.
Principle of operation of a Li^isOh-LiM^CU
element
..................................... 173
6.1.5.
Principle of operation of a LuTisO^-LiFePC^
element
..................................... 176
6.2.
Major characteristics
........................... 177
6.2.1.
Voltage of an element
........................ 178
6.2.2.
Usage for energy or power
.................. 179
6.2.3.
Window of voltage explored
.................... 181
6.2.4.
Charge
.................................. 183
6.2.5.
Safety management in cells
.................... 187
6.2.6.
Internal failures
............................ 188
6.2.7.
Operating temperatures
....................... 189
6.2.8.
Self-discharge
............................. 189
6.2.9.
Memory effect
............................. 190
6.2.10.
Commercially available capacities
............... 190
6.2.11.
Dependency of the capacity on the discharge
current and the temperature.
Peukerť s
law
............... 190
6.2.12.
Gauges
................................. 192
6.2.13.
Practical gravimetric energy density
.............. 198
6.2.14.
Practical volumetric energy density
.............. 202
Table
of
Contents ix
6.2.15.
Plot of the gravimetric energy densities as a function
of the volumetric energy densities
.................... 203
6.2.16.
Gravimetric and volumetric power densities
......... 204
6.2.17.
Faradaic efficiency of a charge discharge cycle
....... 206
6.2.18.
Energy efficiency of a charge/discharge cycle
........ 207
6.2.19.
Average cycling lifetime
..................... 210
6.2.20.
Calendar lifetime
.......................... 210
6.2.21.
Degradation phenomena
...................... 214
6.2.22.
Operational safety
.......................... 217
6.2.23.
Transport and storage of lithium batteries
........... 219
6.2.24.
Packaging
............................... 221
6.2.25.
Manufacturing procedures
.................... 222
6.2.26.
Energy cost throughout lifecycle
................ 226
6.2.27.
Purchasing cost
........................... 228
6.2.28.
Manufacturers and suppliers/integrators
............ 228
6.2.29.
Main outlets
............................. 229
6.2.30.
Recycling options
.......................... 230
6.3.
Solution to exercises from Chapter
6................. 230
Chapter
7.
Present and Future Developments Regarding
Lithium-ion Batteries
............................... 235
7.1.
Improvement of the operation and safety of current
technologies
................................... 236
7.1.1.
Developments of advanced BMSs (Battery
Management Systems)
............................ 236
7.1.2.
Development of high-performance management
systems
..................................... 238
7.1.3.
Synthesis of new solvents
..................... 239
7.1.4.
Introduction of
redox
shuttle molecules to prevent
over-charging
................................. 240
7.2.
Improvement of the intrinsic performances
(energy, power)
................................. 244
7.2.1.
Synthesis of new materials
..................... 244
7.3.
New formats of batteries
......................... 252
7.3.1.
Development of specific architectures: bipolar
........ 252
7.3.2.
Development of thin and soft batteries
............. 253
7.3.3.
Development of micro-batteries
.................. 254
7.4.
Conclusion
................................. 255
Chapter
8.
Lithium-Metal Polymer Batteries
257
8.1.
Principle of operation
........................... 258
8.1.1.
Positive electrode
........................... 259
χ
Lithium
Batteries
8.1.2.
Negative electrode
.......................... 260
8.1.3.
Electrolyte
............................... 260
8.2.
Manufacturing process
.......................... 260
8.3.
Main characteristics
............................ 261
8.3.1.
Operating voltage
........................... 261
8.3.2.
Capacity
................................. 261
8.3.3.
Practical gravimetric energy density
............... 261
8.3.4.
Practical volumetric energy density
............... 262
8.3.5.
Power
.................................. 262
8.3.6.
Operating temperature
........................ 262
8.3.7.
Self-discharge
............................. 262
8.3.8.
Average cycling lifetime
...................... 262
8.3.9.
Recyclability
.............................. 262
Chapter
9.
Lithium-Sulfur Batteries
..................... 263
9.1.
Introduction
................................. 263
9.2.
The element Sulfur
............................ 264
9.3.
Principle of operation
........................... 264
9.4.
Discharge curve
.............................. 269
9.5.
Advantages to Li-S
............................ 270
9.6.
Limitations and disadvantages of a Li-S battery
.......... 271
9.6.1.
Positive electrode
........................... 271
9.6.2.
Electrolyte
............................... 278
9.6.3.
Negative electrode
.......................... 283
9.7.
Conclusion
................................. 285
Chapter
10.
Lithium-Air Batteries
...................... 287
10.1.
Introduction
................................ 287
10.2.
Operational principle
.......................... 289
10.2.1.
Aqueous Li O2
............................ 290
10.2.2.
Organic Li-Cb
............................ 292
10.3.
Electrolytes
................................ 295
10.4.
Main limitations
............................. 297
10.4.1.
General limitations
......................... 298
10.5.
Main actors
..............................
304
10.6.
Conclusion
................................ 306
10.7.
Appendix: calculation of theoretical gravimetric
energy densities
.............................. 307
Table
of
Contents
xi
Chapter
11.
Lithium Resources
........................ 309
11.1.
State
of the art in terms of availability of lithium
resources
..................................... 310
11.2.
Comparison of resources with the needs
of the electrical industry
............................ 312
11.3.
State of the art of extraction techniques and known
production reserves
............................... 315
11.4.
Nature and geological origin of all potential lithium
resources
..................................... 318
11.5.
Global geographic distribution of raw lithium resources
.... 320
11.6.
Evolution of the cost of lithium
.................... 323
11.7.
Summary
.................................. 325
Part
3.
Other Types of Batteries
.................... 327
Chapter
12.
Other Types of Batteries
.................... 329
12.1.
Introduction
................................ 329
12.2.
Sodium-Sulfur technology
...................... 330
12.2.1.
Operational principle
........................ 330
12.2.2.
Main characteristics
........................ 333
12.3.
Nickel chloride batteries
........................ 335
12.3.1.
Operational principle
........................ 336
12.3.2.
Main characteristics
........................ 338
12.3.3.
Availability
.............................. 339
12.4.
Conclusions about high-temperature batteries
.......... 340
12.5.
Redox
flow systems
........................... 340
12.5.1.
Vanadium
redox
battery
...................... 343
12.5.2.
Operational principle
........................ 343
12.5.3.
Main characteristics
........................ 345
12.5.4.
Availability
.............................. 347
12.5.5.
Other
redox
flow battery technologies
............. 349
12.5.6.
Conclusion about
redox
flow batteries
............. 350
Conclusion
...................................... 351
Index
.......................................... 353
Lithium
batteries
were introduced relatively recently in
comparison to lead- or nickel-based batteries, which have been
around for over
100
years. Nevertheless, in the space of
20
years,
they have acquired a considerable market share
-
particularly for
the supply of mobile devices. We are still a long way from
exhausting the possibilities that they offer. Numerous projects
will undoubtedly further improve their performances in the years
to come. For large-scale storage systems, other types of batteries
are also worthy of consideration: hot batteries and
redox
flow
systems, for example.
This book begins by showing the diversity of applications for
secondary batteries and the main characteristics required of them
in terms of storage. After a chapter presenting the definitions and
measuring methods used in the world of electrochemical storage,
and another that gives examples of the applications of batteries,
the remainder of this book is given over to describing the
batteries developed recently (end of the 20th Century) which are
now being commercialized, as well as those with a bright future.
The authors also touch upon the increasingly rapid evolution of
the technologies, particularly regarding lithium batteries, for
which the avenues of research are extremely varied.
Christian Glaize is Professor at the University of
Montpellier,
France. He is also Researcher in the Materials and Energy Group
(GEM) of the Institute for Electronics
(IES),
France.
Sylvie
Genies
is a project manager at the French Alternative
Energies and Atomic Energy Commission (Commissariat
à
l Energie Atomique et aux Energies Alternatives) in Grenoble,
France.
www.iste.co.uk
WILEY
|
| any_adam_object | 1 |
| author | Glaize, Christian Genies, Sylvie |
| author_facet | Glaize, Christian Genies, Sylvie |
| author_role | aut aut |
| author_sort | Glaize, Christian |
| author_variant | c g cg s g sg |
| building | Verbundindex |
| bvnumber | BV041433719 |
| classification_rvk | VN 6050 ZN 8730 |
| ctrlnum | (OCoLC)867682404 (DE-599)GBV756057914 |
| dewey-full | 621.312423 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 621 - Applied physics |
| dewey-raw | 621.312423 |
| dewey-search | 621.312423 |
| dewey-sort | 3621.312423 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Chemie / Pharmazie Elektrotechnik / Elektronik / Nachrichtentechnik |
| format | Book |
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| id | DE-604.BV041433719 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:56:34Z |
| institution | BVB |
| isbn | 9781848214965 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026880637 |
| oclc_num | 867682404 |
| open_access_boolean | |
| owner | DE-703 DE-83 DE-29T DE-1046 |
| owner_facet | DE-703 DE-83 DE-29T DE-1046 |
| physical | XVIII, 354 S. Ill., graph. Darst. |
| publishDate | 2013 |
| publishDateSearch | 2013 |
| publishDateSort | 2013 |
| publisher | ISTE [u.a.] |
| record_format | marc |
| series2 | Electrical engineering series |
| spelling | Glaize, Christian Verfasser aut Lithium batteries and other electrochemical storage systems Christian Glaize ; Sylvie Geniès London [u.a.] ISTE [u.a.] 2013 XVIII, 354 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Electrical engineering series Energiespeicherung (DE-588)4014722-8 gnd rswk-swf Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd rswk-swf Elektrochemische Energiequelle (DE-588)4151755-6 gnd rswk-swf Elektrochemische Energieumwandlung (DE-588)4151758-1 gnd rswk-swf Batterie (DE-588)4004687-4 gnd rswk-swf Lithiumbatterie (DE-588)4167901-5 gnd rswk-swf Energiespeicherung (DE-588)4014722-8 s Batterie (DE-588)4004687-4 s DE-604 Lithium-Ionen-Akkumulator (DE-588)7681721-0 s Lithiumbatterie (DE-588)4167901-5 s Elektrochemische Energieumwandlung (DE-588)4151758-1 s Elektrochemische Energiequelle (DE-588)4151755-6 s 1\p DE-604 Genies, Sylvie Verfasser aut Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026880637&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Klappentext Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026880637&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Glaize, Christian Genies, Sylvie Lithium batteries and other electrochemical storage systems Energiespeicherung (DE-588)4014722-8 gnd Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd Elektrochemische Energiequelle (DE-588)4151755-6 gnd Elektrochemische Energieumwandlung (DE-588)4151758-1 gnd Batterie (DE-588)4004687-4 gnd Lithiumbatterie (DE-588)4167901-5 gnd |
| subject_GND | (DE-588)4014722-8 (DE-588)7681721-0 (DE-588)4151755-6 (DE-588)4151758-1 (DE-588)4004687-4 (DE-588)4167901-5 |
| title | Lithium batteries and other electrochemical storage systems |
| title_auth | Lithium batteries and other electrochemical storage systems |
| title_exact_search | Lithium batteries and other electrochemical storage systems |
| title_full | Lithium batteries and other electrochemical storage systems Christian Glaize ; Sylvie Geniès |
| title_fullStr | Lithium batteries and other electrochemical storage systems Christian Glaize ; Sylvie Geniès |
| title_full_unstemmed | Lithium batteries and other electrochemical storage systems Christian Glaize ; Sylvie Geniès |
| title_short | Lithium batteries and other electrochemical storage systems |
| title_sort | lithium batteries and other electrochemical storage systems |
| topic | Energiespeicherung (DE-588)4014722-8 gnd Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd Elektrochemische Energiequelle (DE-588)4151755-6 gnd Elektrochemische Energieumwandlung (DE-588)4151758-1 gnd Batterie (DE-588)4004687-4 gnd Lithiumbatterie (DE-588)4167901-5 gnd |
| topic_facet | Energiespeicherung Lithium-Ionen-Akkumulator Elektrochemische Energiequelle Elektrochemische Energieumwandlung Batterie Lithiumbatterie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026880637&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026880637&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT glaizechristian lithiumbatteriesandotherelectrochemicalstoragesystems AT geniessylvie lithiumbatteriesandotherelectrochemicalstoragesystems |