Directed selectivity in organic synthesis: a practical guide
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2014
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | IX, 358 S. |
| ISBN: | 3527333754 9783527333752 |
Internformat
MARC
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Datensatz im Suchindex
| _version_ | 1809768947841499136 |
|---|---|
| adam_text |
CONTENTS
PREFACE VII *
ACKNOWLEDGEMENT IX
1 GENERAL
METHODS TO DIRECT SELECTIVITY 1
1.1 CHEMOSELECTIVITY 1
1.2 REGIOSELECTIVITY 7
1.3 STEREOSELECTIVITY 26
1.4 ENATIOSELECTIVITY 48
REFERENCES 60
2 DIRECTED SELECTIVITY: ACETYLENES AND ALKENES 65
2.1 ACETYLENES 65
2.2 ALKENES 74
2.2.1 HYDROGENATION AND REDUCTION 74
2.2.2 HYDROFORMYLATION 81
2.2.3 OXIDATION AND ALLYL OXIDATION 84
2.2.4 ALLYL SUBSTITUTION 89
2.2.5 CYCLOADDITION 110
2.2.6 SIGMATROPIC REARRANGEMENT 120
2.2.7 ENE REACTION 125
2.2.8 HECK CYDIZATION 128
2.2.9 PAUSON-KHAND REACTION 130
2.2.10 METATHESIS CYDIZATION 131
2.2.11 RADICAL- AND NUDEOPHILIC CYDIZATION 133
REFERENCES 135
3 DIRECTED SELECTIVITY WITH CARBONYL
DERIVATIVES 141
3.1 CARBONYL COMPOUNDS AS ELECTROPHILES 141
3.1.1 1,2-ADDITION OF NUDEOPHILES TO CARBONYLS 141
3.1.2 REDUCTION OF CARBONYL COMPOUNDS 151
3.1.3 ALLYLATION/CROTYLATION REACTIONS 163
3.2 CONJUGATE ADDITION TO CARBONYL COMPOUNDS 178
HTTP://D-NB.INFO/1034511033
VII
CONTENTS
3.2.1 CUPRATE ADDITIONS 178
3.2.2 ENOLATE ADDITIONS 181
3.2.3 FREE RADICAL ADDITION TO ENOATES 182
3.2.4 OLEFIN FORMATION BY ORGANOMETAL ADDITION TO ALKYNES 184
3.3 ENOLATE DERIVATIVES 185
3.4 MISCELLANEOUS 194
3.4.1 REARRANGEMENTS AND FRAGMENTATIONS 194
3.4.2 PERICYCLIC REACTIONS 198
3.4.3 LEWIS ACID-MEDIATED CARBONYL ENE REACTIONS 200
3.4.4 ORGANOMETAL-MEDIATED C-C CONNECTIONS 201
3.4.5 METAL COMPLEX FORMATION IN CARBONYL AND IMINE ADDITIONS 202
3.4.6 WITTIG-TYPE REACTIONS 205
3.4.7 OXIDATION REACTIONS 207
REFERENCES 208
4 SELECTIVITY AT SP
3
-CENTERS AND HETEROATOMS 217
4.1 EPOXIDES 217
4.2 ACETALS 249
4.3 ETHERS 266
4.4 ALCOHOLS AND PHENOLS 285
4.5 SULFUR COMPOUNDS 303
4.6 AMINES 318
4.7 HALOGEN COMPOUNDS 334
REFERENCES 345
INDEX 355 |
| any_adam_object | 1 |
| author | Gaich, Tanja Winterfeldt, Ekkehard 1932-2014 |
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| author_variant | t g tg e w ew |
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| dewey-full | 547.2 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.2 |
| dewey-search | 547.2 |
| dewey-sort | 3547.2 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| isbn | 3527333754 9783527333752 |
| language | English |
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| physical | IX, 358 S. |
| publishDate | 2014 |
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| publisher | Wiley-VCH |
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| spelling | Gaich, Tanja Verfasser (DE-588)1047127083 aut Directed selectivity in organic synthesis a practical guide Tanja Gaich and Ekkehard Winterfeldt Weinheim Wiley-VCH 2014 IX, 358 S. txt rdacontent n rdamedia nc rdacarrier Organische Synthese (DE-588)4075695-6 gnd rswk-swf Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf Organische Synthese (DE-588)4075695-6 s Chemische Reaktion (DE-588)4009853-9 s DE-604 Winterfeldt, Ekkehard 1932-2014 Verfasser (DE-588)121280004 aut Erscheint auch als Online-Ausgabe, EPUB 978-3-527-66729-1 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-66728-4 Erscheint auch als Online-Ausgabe, PDF 978-3-527-66730-7 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4329644&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026869786&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gaich, Tanja Winterfeldt, Ekkehard 1932-2014 Directed selectivity in organic synthesis a practical guide Organische Synthese (DE-588)4075695-6 gnd Chemische Reaktion (DE-588)4009853-9 gnd |
| subject_GND | (DE-588)4075695-6 (DE-588)4009853-9 |
| title | Directed selectivity in organic synthesis a practical guide |
| title_auth | Directed selectivity in organic synthesis a practical guide |
| title_exact_search | Directed selectivity in organic synthesis a practical guide |
| title_full | Directed selectivity in organic synthesis a practical guide Tanja Gaich and Ekkehard Winterfeldt |
| title_fullStr | Directed selectivity in organic synthesis a practical guide Tanja Gaich and Ekkehard Winterfeldt |
| title_full_unstemmed | Directed selectivity in organic synthesis a practical guide Tanja Gaich and Ekkehard Winterfeldt |
| title_short | Directed selectivity in organic synthesis |
| title_sort | directed selectivity in organic synthesis a practical guide |
| title_sub | a practical guide |
| topic | Organische Synthese (DE-588)4075695-6 gnd Chemische Reaktion (DE-588)4009853-9 gnd |
| topic_facet | Organische Synthese Chemische Reaktion |
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