Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English German |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | VIII, 194 S. Ill., graph. Darst. |
Internformat
MARC
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| 100 | 1 | |a Isken, Philipp |d 1985- |e Verfasser |0 (DE-588)1041793138 |4 aut | |
| 245 | 1 | 0 | |a Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries |c vorgelegt von Philipp Isken |
| 264 | 1 | |c 2013 | |
| 300 | |a VIII, 194 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Münster, Univ., Diss., 2013 | ||
| 546 | |a Kurzfassung in dt. und engl. Sprache | ||
| 650 | 0 | 7 | |a Polymethacrylate |0 (DE-588)4175249-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Lithium-Ionen-Akkumulator |0 (DE-588)7681721-0 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Polymethacrylate |0 (DE-588)4175249-1 |D s |
| 689 | 0 | 1 | |a Lithium-Ionen-Akkumulator |0 (DE-588)7681721-0 |D s |
| 689 | 0 | |5 DE-604 | |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-026864670 | ||
Datensatz im Suchindex
| _version_ | 1804151532607766528 |
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| adam_text | CONTENTS
1 MOTIVATION 1
2 BASICS 3
2.1 LITHIUM-ION BATTERIES 3
2.1.1 FUNCTIONAL PRINCIPLE 3
2.1.2 ANODE 5
2.1.3 CATHODE 7
2.1.4 LIQUID ELECTROLYTE 9
2.1.5 POLYMER ELECTROLYTES 12
2.2 POLYMER SYNTHESIS 15
2.2.1 FREE RADICAL POLYMERIZATION 15
2.2.2 ATOM TRANSFER RADICAL POLYMERIZATION 17
2.2.3 SELF-ORGANIZATION 18
2.3 ELECTROCHEMICAL METHODS 20
2.3.1 CONDUCTIVITY 20
2.3.2 CYCLIC VOLTAMMETRY 23
2.3.3 ELECTROCHEMICAL STABILITY WINDOW 23
2.3.4 ANODIC DISSOLUTION OF ALUMINUM 24
2.3.5 CHARGE / DISCHARGE EXPERIMENTS 25
2.4 SPECTROSCOPIC METHODS 27
2.4.1 RAMAN SPECTROSCOPY 27
2.4.2 NMR SPECTROSCOPY 28
2.4.3 SPECTROSCOPIC INVESTIGATION OF LITHIUM ION SOLVATION 30
2.4.4 PFG-NMR SPECTROSCOPY 33
3 EXPERIMENTAL 37
3.1 CHEMICALS 37
3.2 SYNTHESIS OF THE POLYMER HOSTS 38
3.2.1 STATISTICAL CO-POLYMER 38
3.2.2 BLOCK CO-POLYMER 39
3.2.3 CARBONATE CONTAINING POLYMER 40
3.3 PREPARATION OF THE LIQUID ELECTROLYTES 41
3.4 PREPARATION OF THE GEL POLYMER ELECTROLYTES 41
3.5 THERMAL AND MECHANICAL TECHNIQUES 41
3.5.1 DIFFERENTIAL SCANNING CALORIMETRY (DSC) 41
3.5.2 THERMAL GRAVIMETRIC ANALYSIS (TGA) 42
V
HTTP://D-NB.INFO/1043353496
CONTENTS
3.5.3 DYNAMIC MECHANICAL ANALYSIS (DMA) 42
3.6 ELECTROCHEMICAL METHODS 42
3.6.1 CONDUCTIVITY 42
3.6.2 SWAGELOK CELLS 43
3.6.3 ELECTROCHEMICAL STABILITY WINDOW (ESW) 44
3.6.4 INVESTIGATION OF THE ALUMINUM DISSOLUTION 44
3.6.5 LITHIUM PLATING / STRIPPING 45
3.6.6 INVESTIGATIONS WITH ACTIVE MATERIALS 45
3.7 SPECTROSCOPY 47
3.7.1 RAMAN 47
3.7.2 NMR 47
4 POLYMER SYNTHESIS AND CHARACTERIZATION 49
4.1 STATISTICAL CO-POLYMER 49
4.1.1 SYNTHESIS 49
4.1.2 MECHANICAL STABILITY 50
4.1.3 THERMAL ANALYSIS 52
4.1.4 RAMAN INVESTIGATIONS 53
4.2 BLOCK CO-POLYMERS 56
4.2.1 SYNTHESIS 56
4.2.2 FILM PREPARATION 58
4.3 MORPHOLOGY 58
4.3.1 THERMAL ANALYSIS 60
4.4 CARBONATE-CONTAINING POLYMERS 61
4.4.1 SYNTHESIS 61
4.4.2 THERMAL ANALYSIS 62
4.5 SUMMARY 62
5 GPE BASED ON STATISTICAL CO-POLYMERS GELLED WITH 1M LIPFG IN EC:DMC
1:1 65
5.1 SELECTION OF THE LITHIUM SALT 65
5.1.1 CONDUCTIVITY MEASUREMENT PROCEDURE 66
5.1.2 DEPENDENCE OF THE CONDUCTIVITY ON THE CONDUCTING SALT .... 67
5.1.3 ESW 69
5.1.4 PROTECTION OF THE ALUMINUM CURRENT COLLECTOR 70
5.2 CONDUCTIVITY OF GEL POLYMER ELECTROLYTES CONTAINING 1M LIPFG IN
EC:DMC
1:1 73
5.2.1 INFLUENCE OF THE POLYMER TO LIQUID ELECTROLYTE RATIO 73
5.2.2 TEMPERATURE DEPENDENT CONDUCTIVITY 75
5.3 THERMAL PROPERTIES 78
5.3.1 TGA MEASUREMENTS 78
5.3.2 DSC MEASUREMENTS 79
5.4 ESW 81
5.5 LITHIUM PLATING / STRIPPING 82
VI
CONTENTS
5.6 INVESTIGATIONS WITH ACTIVE MATERIALS 83
5.6.1 LFP / LITHIUM HALF CELLS 84
5.6.2 GRAPHITE / LITHIUM HALF CELLS 85
5.6.3 CV - GRAPHITE 86
5.6.4 CV - LFP 87
5.6.5 LFP / GRAPHITE FULL CELLS 88
5.6.6 NCM / GRAPHITE FULL CELLS 91
5.7 SUMMARY 93
6 GPE BASED ON BLOCK CO-POLYMERS GELLED WITH 1M LIPFG IN EC:DMC 1:1 95
6.1 MOTIVATION 95
6.2 THERMAL PROPERTIES 97
6.2.1 DSC MEASUREMENTS 97
6.2.2 TGA MEASUREMENTS 98
6.3 CONDUCTIVITY 100
6.4 NCM / GRAPHITE FULL CELLS 101
6.4.1 C-RATE EXPERIMENTS 101
6.4.2 CONSTANT CURRENT CYCLING 102
6.5 SUMMARY 102
7 GPE BASED ON STATISTICAL CO-POLYMERS GELLED WITH 1M
IJBF4
IN EC:ADN
1:1 105
7.1 MOTIVATION 105
7.2 THERMAL INVESTIGATION 107
7.2.1 TGA 107
7.2.2 DSC 108
7.3 CONDUCTIVITY 110
7.4 ESW 112
7.5 INVESTIGATIONS WITH ACTIVE MATERIALS 113
7.5.1 CV - GRAPHITE 113
7.5.2 CV - LFP 114
7.5.3 LFP / GRAPHITE FULL CELLS 115
7.5.4 NCM / GRAPHITE FULL CELLS 117
7.6 SUMMARY 119
8 LITHIUM ION SOLVATION IN GEL POLYMER ELECTROLYTES 121
8.1 MOTIVATION 121
8.2 NMR 123
8.2.1 EC:DMC-BASED ELECTROLYTES 123
8.2.2 EC:ADN-BASED ELECTROLYTES 126
8.3 RAMAN SPECTROSCOPY 129
8.3.1 EC:DMC-BASED ELECTROLYTES 129
8.3.2 EC:ADN-BASED ELECTROLYTES 135
VII
CONTENTS
8.4 INFLUENCE OF THE POLYMER-LI
+
INTERACTION ON THE LITHIUM ION TRANSPORT
PROPERTIES 139
8.4.1 DIFFUSION COEFFICIENTS OF THE SOLVENTS 140
8.4.2 DIFFUSION COEFFICIENTS OF THE IONS 143
8.5 SUMMARY 146
9 CONCLUSIONS 149
10 ABBREVIATIONS 187
11 ACKNOWLEDGEMENTS 189
12 CURRICULUM VITAE 191
13 LIST OF PUBLICATIONS 193
VIII
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| any_adam_object | 1 |
| author | Isken, Philipp 1985- |
| author_GND | (DE-588)1041793138 |
| author_facet | Isken, Philipp 1985- |
| author_role | aut |
| author_sort | Isken, Philipp 1985- |
| author_variant | p i pi |
| building | Verbundindex |
| bvnumber | BV041417518 |
| ctrlnum | (OCoLC)864595516 (DE-599)GBV769119743 |
| dewey-full | 547.8404572 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.8404572 |
| dewey-search | 547.8404572 |
| dewey-sort | 3547.8404572 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| illustrated | Illustrated |
| indexdate | 2024-07-10T00:56:19Z |
| institution | BVB |
| language | English German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026864670 |
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| physical | VIII, 194 S. Ill., graph. Darst. |
| publishDate | 2013 |
| publishDateSearch | 2013 |
| publishDateSort | 2013 |
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| spelling | Isken, Philipp 1985- Verfasser (DE-588)1041793138 aut Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries vorgelegt von Philipp Isken 2013 VIII, 194 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Münster, Univ., Diss., 2013 Kurzfassung in dt. und engl. Sprache Polymethacrylate (DE-588)4175249-1 gnd rswk-swf Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Polymethacrylate (DE-588)4175249-1 s Lithium-Ionen-Akkumulator (DE-588)7681721-0 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026864670&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Isken, Philipp 1985- Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries Polymethacrylate (DE-588)4175249-1 gnd Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd |
| subject_GND | (DE-588)4175249-1 (DE-588)7681721-0 (DE-588)4113937-9 |
| title | Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries |
| title_auth | Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries |
| title_exact_search | Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries |
| title_full | Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries vorgelegt von Philipp Isken |
| title_fullStr | Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries vorgelegt von Philipp Isken |
| title_full_unstemmed | Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries vorgelegt von Philipp Isken |
| title_short | Synthesis and characterization of methacrylate based gel polymer electrolytes for lithium-ion batteries |
| title_sort | synthesis and characterization of methacrylate based gel polymer electrolytes for lithium ion batteries |
| topic | Polymethacrylate (DE-588)4175249-1 gnd Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd |
| topic_facet | Polymethacrylate Lithium-Ionen-Akkumulator Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026864670&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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