Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online-Zugang: | Volltext Inhaltsverzeichnis |
| Beschreibung: | Nebentitel: Untersuchung einzelner funktionaler Moleküle auf Metalloberflächen mit dem Rastertunnelmikroskop |
| Beschreibung: | 137 S. Ill., graph. Darst. CD-ROM (12 cm) |
Internformat
MARC
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| 100 | 1 | |a Mielke, Johannes |e Verfasser |0 (DE-588)1043518827 |4 aut | |
| 245 | 1 | 0 | |a Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy |c Johannes Mielke |
| 246 | 1 | 3 | |a Untersuchung einzelner funktionaler Moleküle auf Metalloberflächen mit dem Rastertunnelmikroskop |
| 264 | 1 | |c 2013 | |
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| 502 | |a Berlin, Freie Univ., Diss., 2013 | ||
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Datensatz im Suchindex
| _version_ | 1804151486225055744 |
|---|---|
| adam_text | CONTENTS
INTRODUCTION 9
I. PHYSICAL BACKGROUND AND EXPERIMENTAL METHODS 11
1. PHYSICS OF THE TUNNELING EFFECT 13
1.1. ONE-DIMENSIONAL TUNNELING 14
1.2. BARDEEN S APPROACH 15
1.3. TUNNELING IN THE STM GEOMETRY 16
2. SCANNING TUNNELING MICROSCOPY 18
2.1. IMAGING 18
2.2. SPECTROSCOPY 20
2.3. MANIPULATION 22
3. EXPERIMENTAL DETAILS 24
3.1. OMICRON LOW TEMPERATURE STM 25
3.2. ARHUS VARIABLE TEMPERATURE STM (SPECS) 27
3.3. SAMPLE PREPARATION 28
3.4. MOLECULE DEPOSITION 29
3.5. LASER SYSTEMS 30
3.6. STATISTICAL EVALUATION METHODS 30
3.6.1. DRIFT CORRECTION 31
3.6.2. DETERMINING THE MOLECULAR STATE 32
3.6.3. RANDOM PATTERNS 33
3.6.4. TIME DEPENDENCE 34
3.6.5. RANDOM DISTANCES 35
3.6.6. POISSON AND SKELLAM DISTRIBUTION 36
3.6.7. THE %
2
DISTRIBUTION AND THE P VALUE 37
3.6.8. PRINCIPLE COMPONENT ANALYSIS 37
II. EXPERIMENTS AND RESULTS 39
4. TETRA-PHENYL-PORPHYRIN (TPP) 41
4.1. THE CHOICE OF PORPHYRINS 42
4.2. PORPHYRINS IN NATURE 43
4.3. PORPHYRINS ON SURFACES 44
4.4. LOW TEMPERATURE MEASUREMENTS 44
4.4.1. MOLECULAR APPEARANCE 44
7
HTTP://D-NB.INFO/1045035017
CONTENTS
4.4.2. MOLECULAR ASSEMBLY 49
4.4.3. SPECTROSCOPY 50
4.4.4. HEATED TPP 52
4.5. ROOM TEMPERATURE MEASUREMENTS 54
4.5.1. IMAGING AT ROOM TEMPERATURE 54
4.5.2. MOLECULAR APPEARANCE AT RT 54
4.5.3. INFLUENCE OF DEFECTS 56
4.5.4. ORDERED PATTERNS 58
4.5.5. TIME DEPENDENCE OF THE SWITCHING 58
4.5.6. DISTRIBUTION OF SWITCHING EVENTS 62
4.5.7. NUMBER OF UP AND DOWN SWITCHING MOLECULES 65
4.5.8. BR
4
TPP ON AG(LLL) 67
4.6. MANIPULATION 73
4.6.1. SWITCHING VOLTAGE THRESHOLD 73
4.6.2. CREATING ADATOMS 74
4.6.3. MANIPULATION OF TPP ON AND OFF ADATOMS 76
4.7. COVALENT ASSEMBLIES 79
4.7.1. CREATION OF DIMERS 79
4.7.2. SWITCHING OF SINGLE DIMERS 80
4.7.3. SWITCHING OF DIMERS IN TWO-DIMER-ISLANDS 83
4.7.4. ROOM TEMPERATURE SWITCHING OF DIMERS 85
4.8. THEORY 87
4.8.1. THE DARK AND BRIGHT STATE OF TPP ON AU( 111) 87
4.8.2. ANNEALED TPP 93
4.9. CONCLUSION 96
5. NANOCARS 98
5.1. CARBORANE CARS 99
5.1.1. AU(LLL) 100
5.1.2. CU(110) 101
5.1.3. AG(LLL) 103
5.1.4. CU(LLL) 104
5.1.5. NACL 106
5.2. ADAMANTANE CARS 110
5.2.1. AU(LLL) ILL
5.2.2. CU(LLL) 114
5.3. CONCLUSIONS 116
SUMMARY 117
III.
APPENDIX 121
A. CD CONTENTS 123
B. PUBLICATION LIST . 124
C. ACKNOWLEDGMENTS 125
BIBLIOGRAPHY 126
|
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| dewey-ones | 530 - Physics |
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| dewey-search | 530.417 |
| dewey-sort | 3530.417 |
| dewey-tens | 530 - Physics |
| discipline | Physik |
| format | Thesis Book |
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| language | English |
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| spelling | Mielke, Johannes Verfasser (DE-588)1043518827 aut Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy Johannes Mielke Untersuchung einzelner funktionaler Moleküle auf Metalloberflächen mit dem Rastertunnelmikroskop 2013 137 S. Ill., graph. Darst. CD-ROM (12 cm) txt rdacontent n rdamedia nc rdacarrier Nebentitel: Untersuchung einzelner funktionaler Moleküle auf Metalloberflächen mit dem Rastertunnelmikroskop Berlin, Freie Univ., Diss., 2013 (DE-588)4113937-9 Hochschulschrift gnd-content Erscheint auch als Online-Ausgabe urn:nbn:de:kobv:188-fudissthesis000000095380-8 http://www.diss.fu-berlin.de/diss/receive/FUDISS_thesis_000000095380 kostenfrei Volltext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026835751&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Mielke, Johannes Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy |
| subject_GND | (DE-588)4113937-9 |
| title | Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy |
| title_alt | Untersuchung einzelner funktionaler Moleküle auf Metalloberflächen mit dem Rastertunnelmikroskop |
| title_auth | Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy |
| title_exact_search | Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy |
| title_full | Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy Johannes Mielke |
| title_fullStr | Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy Johannes Mielke |
| title_full_unstemmed | Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy Johannes Mielke |
| title_short | Investigation of single functional molecules on metal surfaces by scanning tunneling microscopy |
| title_sort | investigation of single functional molecules on metal surfaces by scanning tunneling microscopy |
| topic_facet | Hochschulschrift |
| url | http://www.diss.fu-berlin.de/diss/receive/FUDISS_thesis_000000095380 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026835751&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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