New and future developments in catalysis - catalysis by nanoparticles:
New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts an...
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
2013
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Zusammenfassung: | New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes. The use of catalysts in the nanoscale offers various advantages (increased efficiency and less byproducts), and these are discussed in this volume along with the various catalytic processes using nanoparticles. However, this is not without any risks and the safety aspects and effects on humans and the environment are still unknown. The present data as well as future needs are all part of this volume along with the economics involved. Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areasA clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular caseOutlines the catalytic processes applicable to energy generation and design of green processes |
| Beschreibung: | Includes index. |
| Beschreibung: | XII, 499 S. |
| ISBN: | 9780444538741 |
Internformat
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| 500 | |a Includes index. | ||
| 520 | |a New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes. The use of catalysts in the nanoscale offers various advantages (increased efficiency and less byproducts), and these are discussed in this volume along with the various catalytic processes using nanoparticles. However, this is not without any risks and the safety aspects and effects on humans and the environment are still unknown. The present data as well as future needs are all part of this volume along with the economics involved. Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areasA clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular caseOutlines the catalytic processes applicable to energy generation and design of green processes | ||
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Datensatz im Suchindex
| _version_ | 1804151461954715648 |
|---|---|
| adam_text | Contents
Introduction
ix
Contributors
xi
1.
Gold-Based Catalysts for CO Oxidation,
the Water-Gas Shift, and Desulfurization
Processes
JOSE A. RODRIGUEZ
1.1
Introduction
1
1.2
Bonding Interactions Between Gold and Metal
Oxide or Carbide Surfaces
2
1.3
Oxidation of Carbon Monoxide on Au-Oxide
and
Au
-Carbide Surfaces
3
1.4
Water-Gas Shift Reaction on Au-Oxide
Surfaces
6
1.5
Decomposition of Sulfur Dioxide on Au-Oxide
and Au-Carbide Surfaces
12
1.6
Conclusions
18
Acknowledgments
18
References
18
2.
Structural and Electronic Properties of
Group
6
Transition Metal Oxide Clusters
SHENGGANG LI AND DAVID A. DIXON
2.1
Introduction
21
2.2
Accurate Thermochemistry for Transition Metal
Oxide Clusters
22
2.3
Group
6
Transition Metal Oxides
28
2.4
Group
6
Transition Metal Hydroxides:
Hydrolysis of Metal Oxide Clusters
40
Conclusions
50
Acknowledgments
51
References
51
3.
Nanoparticle Catalysis for Reforming of
Biomass-Derived Fuels
MAURA KOEHLE AND ASHISH MHADESHWAR
3.1
Introduction
63
3.2 Biogas
Reforming
65
3.3
Oxygenates Reforming
81
3.4
Conclusions
90
Acknowledgment
91
References
91
4-
Nanoparticles in Biocatalysis
KHE1REDDINE EL-BOUBBOU AND CHRISTOPHER
С
LANDRY
4.1
What is Biocatalysis?
95
4.2
Nanomaterials as Enzyme Supports
96
4.3
Bionanocatalysis
114
4.4
Conclusion
117
References
117
5.
Thin Iron
Heme
Enzyme Films on
Electrodes and Nanoparticles for
Biocatalysis
SADAGOPAN KRISHNAN AND JAMES F. RUSLING
5.1
Why Enzyme Biocatalysis on Electrodes and
Nanoparticles?
125
5.2
Cyt P450 Electrocatalysis on Electrodes
128
5.3
Cyt P450 Biocatalysis on Nanoparticles
141
5.4
Summary and Prospects for the Future
143
Acknowledgments
145
References
145
6.
Nanoparticles as Enzyme Mimics
RUTE ANDRÉ, FILIPE
NATALIO
AND WOLFGANG TREMEL
6.1
Introduction
149
6.2
Nanoparticles and Their Properties in Solution,
Uptake in Cells, and Clearance
151
6.3
Chemically Active Nanoparticles
154
6.4
Other Oxidoreductase Mimics
—Superoxide
Dismutases and
Oxidases
164
6.5
Conclusions/Outlook
167
References
169
VI
CONTENTS
7.
A
Physical Approach to Monitoring
Biological Activity of Nanoparticulates
AMAR NATH
7.1
Fibrous Character of Carbon Nanotubes
(CNT)
176
7.2
Biological Activity of Nano-Sized Particulates of
Some Oxides
177
7.3
in Vitro versus In Vivo Testing for Biotoxicity of
Nanomaterials
177
7.4
Fundamental Approach to the Problem of
Health Hazards Posed by Inhalation of
Nanoparticulates of Diverse Chemicals
177
7.5
Experimental Evidence Forming the Basis of the
Proposed Model
178
7.6
Physico-Chemical Approach to Monitoring
Bioactivity
179
7.7
Thermally Stimulated Luminescence,
Conductivity, and Exoelectron Emission
[51-59] 180
7.8
How Can Emission
Mössbauer
Spectroscopy
(EMS) Help in Identification and Estimation of
Bioactive Defects?
181
7.9
Remedial Measures: Procedures Adopted
for Preparation and Passivation of
Defect Sites
183
7.10
Summary
184
Acknowledgments
184
References
184
8.
Morphology-Tailored
Titania
Nanoparticles
9.
Metal Oxide Nanotube, Nanorod, and
Quantum Dot Photocatalysis
VICENTE RIVES
8.1
8.2
8.3
8.4
8.5
8.6
8.7
192
Introduction
189
Ionic Liquids
191
Combustion-Assisted Methods
Gas Flame Combustion
193
Sonochemical Methods
195
Reverse
Microemulsion 197
Methods Starting from Metallic
Titanium
197
Anodization
198
Modification of Commercial
Titania
201
8.10
Miscellaneous Methods
206
8.11
Conclusions
208
Acknowledgment
208
References
208
8.8
8.9
KENNETH J. BALKUS JR.
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
Introduction
213
Semiconductor Photocatalysts
214
Advantages of Nanoparticles
216
Nanoparticle Synthesis
217
Doping
223
Metal Nanoparticles
224
Quantum Dots
226
Carbon Heterojunctions
230
Water Splitting
231
9.10
CO2 Reduction
233
9.11
Solar Photocatalysis
234
9.12
Photodynamic Therapy
PDT
235
9.13
Future Directions
236
Acknowledgments
237
References
237
10.
Photocatalytic Nanooxides: The Case
ofTiO2andZnO
ANA IGLESIAS-JUEZ, ANNA KUBACKA,
GERARDO COLÓN
AND MARCOS
FERNÁNDEZ-GARCÍA
10.1
Introduction
245
10.2
The Case of Bare Oxides
246
10.3
Doping and Composite Systems Based in
Titania
and Zinc Oxides
253
Acknowledgments
263
References
263
11.
Recent Advances in Photocatalytic
Processes by Nanomaterials
A.R. KHATAEE AND M. FATHINIA
11.1
Photocatalysts and Mechanisms of
Photocatalysis Processes
267
11.2
Applications of Photocatalysts
270
11.3
Challenges and Issues with Possible Solutions
in Photocatalytic Processes
276
11.4
Conclusions
282
Acknowledgment
282
References
283
12.
Insights into Heterogeneous Catalysis
through Surface Science Techniques
СР.
VINOD
CONTENTS
Vil
12.1
Introduction
289
12.2
X-ray
Photoelectron
Spectroscopy Under Near
Ambient Conditions (APXPS)
290
12.3
Vibrational Spectroscopy at High
Pressures
292
12.4
Surface Science Studies Using High Pressure
Techniques
295
12.5
Conclusion and Outlook
302
Acknowledgments
302
References
302
13.
Block Copolymer Lithography
DAVID A.BOYD
13.1
Introduction
305
13.2
introduction to Block copolymers
306
13.3
Catalysis
317
13.4
New Frontiers: Plasmonics
325
13.5
Outlook
327
References
328
14-
Multi-Metallic Nanoparticles as More
Efficient Catalysts for Fuel Cell Reactions
SHAOJUN GUO, SALLY FAE HO AND SHOUHENG SUN
14.1
Introduction
333
14.2
Multi-Metallic Alloy NPs
334
14.3
Dumbbell NPs
338
14.4
Core/Shell NPs
341
14-5
Conclusions and Perspectives
344
References
344
15.
Hydrogénation
by Nanoparticle
Catalysts
НЕМА
RAMSURN AND RAM B. GUPTA
15.1
Introduction
347
15.2
Hydrogénation
Catalysts
349
15.3
Hydrogénation
by Monometallic
Nanoparticles
351
15.4
Hydrogénation
by Bimetallic
Nanoparticles
365
15.5
Hydrogénation
by Multimetallic
Nanoparticles
370
15.6
Future Outlook: Nanoparticle-Catalyzed
Hydrodeoxygenation
371
15.7
Summary
372
Acknowledgment
372
References
372
16.
Silicone
Stabilized Nanoparticles as
Hybrid Phase Catalysts for Selective
Hydrolytic Oxidation of Hydrosilanes
BHANU
P.S.
CHAUHAN, ALOK
SÄRKAR
AND
MONI
CHAUHAN
16.1
Introduction
375
16.2
What are
Silanolsľ
379
16.3
Pt-nanoparticle Catalyzed Hydrolytic
Oxidation of Organosilanes
381
16.4
Investigation of the Nature of Catalysts
386
16.5
Mechanistic Proposal
389
16.6
Polymerization of Bis-Silanols via
Dehydrocoupling Reaction
389
16.7
Conclusion
392
16.8
Experimental Section
393
Acknowledgments
398
References
398
17.
Basics of PEMFC Including the Use
of Carbon-Supported Nanoparticles
FRÉDÉRIC MAILLARD,
NATHALIE JOB AND MARIAN
CHATENET
17.1
Introduction
401
17.2
Basics of PEFMC Operation
403
17.3
Durability Issues in Fuel Cells
414
17.4
Beyond Classical Carbon-Supported Pt-Based
Nanoparticles
417
17.5
Conclusion
420
Acknowledgments
420
References
420
18.
Supported Gold Nanoparticles as
Heterogeneous Catalysts
ANA
PRIMO
AND
HERMENEGILDO
GARCIA
18.1
Introduction and Historical Perspective of
Recent Gold Catalysis Developments
425
18.2
Methodologies to Obtain Gold Nanoparticles
Supported on Insoluble Solids
426
18.3
Role of Support
430
18.4
Role of Metal Oxides in Gold Catalysis
434
18.5
Gold Nanoparticles as Catalysts in Organic
Reactions
439
18.6
Aerobic Oxidation of Alcohols
442
18.7
Selective
Nitro
Hydrogénations
Group
445
VIH
CONTENTS
18.8
Concluding Remarks and Future
Prospects
447
References
448
19.
Developing Semiconductive Catalysts
with Three-Dimensional Nanobranches via
Solution Routes
HU
AJUN
ZHOU AND Z. RYAN
TIAN
19.
1 Advantages of Morphological Branching-out
for Semiconductive Heterogeneous Catalysts
from Solution Syntheses
451
19.2
Simple Multi-pods
453
19.3
Nanobranched Multi-pods
455
19.4
From Complex Multi-pods to Koosh Balls
457
19.5
Nanotetrapod in a Hollow Nanotetrapod: The
Power of Selective Dissolution
458
19.6
Secondary Nanobranches on Primary ID
Structures
459
19.7
Secondary Nanobranches on 2D and
3D
Primary Structures
460
19.8
Tertiary and Quaternary Structures from
Hierarchical Nanobranch Growths
461
19.9
Micropatterned Arrays of Tertiary Cactus
Structures
463
19.10 3D
Self-Assembled Nanobranches
464
19.11 3D
Networks of Interconnecting
Nanowires
464
19.12
What Next?
467
References
468
20.
Nanoparticle Catalysis by Surface
Plasmon
MENGTAO SUN
20.1
Introduction
473
20.2
Plasmon-Driven Surface Catalyzed
Reaction
474
20.3
Conclusions
486
Acknowledgments
486
References
487
Index
489
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| indexdate | 2024-07-10T00:55:12Z |
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| isbn | 9780444538741 |
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| spelling | New and future developments in catalysis - catalysis by nanoparticles ed. by Steven L. Suib Amsterdam [u.a.] Elsevier 2013 XII, 499 S. txt rdacontent n rdamedia nc rdacarrier Includes index. New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes. The use of catalysts in the nanoscale offers various advantages (increased efficiency and less byproducts), and these are discussed in this volume along with the various catalytic processes using nanoparticles. However, this is not without any risks and the safety aspects and effects on humans and the environment are still unknown. The present data as well as future needs are all part of this volume along with the economics involved. Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areasA clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular caseOutlines the catalytic processes applicable to energy generation and design of green processes Catalysis Nanoparticles Nanopartikel (DE-588)4333369-2 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf Katalyse (DE-588)4029921-1 s Nanopartikel (DE-588)4333369-2 s DE-604 Suib, Steven L. Sonstige oth Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026819527&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
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| title | New and future developments in catalysis - catalysis by nanoparticles |
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| title_exact_search | New and future developments in catalysis - catalysis by nanoparticles |
| title_full | New and future developments in catalysis - catalysis by nanoparticles ed. by Steven L. Suib |
| title_fullStr | New and future developments in catalysis - catalysis by nanoparticles ed. by Steven L. Suib |
| title_full_unstemmed | New and future developments in catalysis - catalysis by nanoparticles ed. by Steven L. Suib |
| title_short | New and future developments in catalysis - catalysis by nanoparticles |
| title_sort | new and future developments in catalysis catalysis by nanoparticles |
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