Principles of physical chemistry:
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Englewood Cliffs, N.J.
Prentice-Hall
1966
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 576 S. Ill., graph. Darst. |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV041342740 | ||
| 003 | DE-604 | ||
| 005 | 00000000000000.0 | ||
| 007 | t | ||
| 008 | 131004s1966 ad|| |||| 00||| eng d | ||
| 035 | |a (OCoLC)251496274 | ||
| 035 | |a (DE-599)GBV19500891X | ||
| 040 | |a DE-604 |b ger | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-210 | ||
| 100 | 1 | |a Hamill, William H. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Principles of physical chemistry |c William H. Hamill ; Russell R. Williams, Jr. ; Colin MacKay |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Englewood Cliffs, N.J. |b Prentice-Hall |c 1966 | |
| 300 | |a XIV, 576 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Physikalische Chemie |0 (DE-588)4045959-7 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Physikalische Chemie |0 (DE-588)4045959-7 |D s |
| 689 | 0 | |8 1\p |5 DE-604 | |
| 700 | 1 | |a Williams, Russell R. |e Verfasser |4 aut | |
| 700 | 1 | |a Mackay, Colin |e Verfasser |4 aut | |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026791478&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-026791478 | ||
| 883 | 1 | |8 1\p |a cgwrk |d 20201028 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | |
Datensatz im Suchindex
| _version_ | 1804151416824004608 |
|---|---|
| adam_text | Titel: Principles of physical chemistry
Autor: Hamill, William H
Jahr: 1966
CONTENTS
Introduction and Description
of the Properties of Matter 1
l. I Physical Chemistry, 1
1.2 Thermodynamics, 2
1.3 Temperature, 4
1.4 Isothermal Gas Expansion, 5
1.5 Thermal Expansion of Gases, 8
1.6 The Ideal Gas Law, 10
1.7 Equations of State for Real Gases, 12
1.8 Liquefaction of Gases, 15
1.9 Properties of Liquids and Solids, 17
1.10 Solutions, 20
Summary, 24
Problems, 25
First Law of Thermodynamics
2.1 Conservation of Energy, 28
2.2 Heat and Heat Capacity, 30
2.3 Latent Heat Effects, 34
2.4 Expansion Work, 35
2.5 Thermal Expansion, 36
2.6 Isothermal Gas Expansion, 37
2.7 Volume Change at Constant P, T, 40
2.8 Electric Work, 41
2.9 Formulation of the First Law, 42
2.10 AE at Constant Volume, 45
2.11 Enthalpy or Heat Content, 46
2.12 Thermodynamic Properties, 47
2.13 Applications of the First Law to Ideal Gases, 48
Summary, 51
Problems, 52
28
vii
vlll Contents
Thermochemistry 56
3.1 Heats of Reaction, 56
3.2 Calorimetry, 57
3.3 Thermochemical Equations; Hess s Law, 59
3.4 Heats of Formation; Standard States, 63
3.5 Other Applications of Hess s Law, 66
3.6 Heats of Solution, 69
3.7 Thermochemistry of Ionic Solutions, 71
3.8 Temperature Dependence of Heat
of Reaction, 74
3.9 Adiabatic Processes, 78
Summary, 80
Problems, 81
Second Law of Thermodynamics 87
4.1 Spontaneous Changes, 87
4.2 A Criterion of Forbiddenness, 88
4.3 Equivalent Reversible Processes, 89
4.4 Recapitulation, 92
4.5 The Work Content, 92
4.6 The Gibbs Free Energy, 94
4.7 AFfor Gas Expansion, 95
4.8 AFat Constant Pressure, 96
4.9 AF for Chemical Change, 98
4.10 AF for Galvanic Cells, 100
4.11 Temperature Dependence of Maximum
Work Functions, 103
4.12 Temperature Dependence of AF, 104
Summary, 107
Problems, 108
Chemical Equilibrium in Gaseous Systems 112
5.1 Equilibrium States, 112
5.2 Free Energy Changes of Isothermal
Reactions in Ideal Gases, 113
5.3 The Reaction Function, 115
5.4 The Equilibrium Reaction Function, 118
5.5 The Reaction Isotherm, 119
5.6 The Equilibrium Function of Mole
Fractions, 121
5.7 Equilibrium Computations, 122
5.8 Temperature Dependence of Equilibrium
Functions, 128
5.9 Additivity of Free Energies; Standard Free
Energies of Formation, 131
5.10 The Free Energy Function, 134
5.11 Systems of Real Gases: The Fugacity, 135
Summary, 139
Problems, 140
Entropy and the Third Law of
Thermodynamics
6.1 Heat Engines, 146
6.2 Efficiency of Heat Engines, 148
6.3 The Entropy, 150
6.4 Reversibility and Irreversibility, 154
6.5 Entropy and Free Energy, 155
6.6 Pressure and Temperature Dependence of
Free Energy, 158
6.7 Entropy and Probability, 160
6.8 The Third Law of Thermodynamics, 161
6.9 Third Law Entropies, 162
Summary, 167
Problems, 168
Phase Equilibria and Colligative
Properties
7.1 Vaporization Equilibria, 172
7.2 Temperature Dependence of Vapor
Pressure, 174
7.3 Vapor Pressure of Solutions, 176
7.4 Heterogeneous Chemical Equilibria, 178
7.5 Free Energy of Dilution, 181
7.6 Boiling Point Elevation, 184
7.7 Freezing Point Depression, 186
7.8 Osmotic Pressure, 188
7.9 The Clapeyron Equation, 189
Summary, 191
Problems, 191
Equilibria in Solutions of
Nonelectrolytes
8.1 Ideal Solutions, 196
8.2 Solubility, 198
8.3 Distribution Coefficients, 200
x Contents
8.4 Chemical Equilibrium in Ideal Solutions, 202
8.5 Real Solutions, 205
8.6 The Activity, 206
8.7 Chemical Equilibrium in Real Solutions, 209
Summary, 211
Problems, 212
Phase Diagrams 214
9.1 The Gibbs Phase Rule, 214
9.2 One-Component Systems, 216
9.3 Two-Component Vapor-Liquid Systems, 219
9.4 Distillation Processes, 221
9.5 Two-Component Systems Exhibiting Two
Liquid Phases, 223
9.6 Solid-Liquid Equilibria in Two-Component
Systems, 226
9.7 Three-Component Systems, 230
Summary, 232
Problems, 232
Electrochemistry 235
10.1 Faraday s Law, 235
10.2 Conductance, 237
10.3 Equivalent Conductance, 238
10.4 Ionic Mobilities—Transference
Number, 241
10.5 Galvanic Cells, 243
10.6 Thermodynamics of Galvanic Cells, 246
10.7 Concentration Dependence of EMF, 249
10.8 Determination of the Standard EMF, 251
10.9 Standard Electrode Oxidation
Potentials, 253
10.10 Applications of EMF Measurements, 257
10.11 Debye-Huckel Theory, 261
10.12 Solubility of Strong Electrolytes, 263
10.13 Acids and Bases, 265
10.14 Weak Acids and Bases, 267
Summary, 270
Problems, 272
Rates of Chemical Reaction 275
11.1 Equilibrium and Reaction Rate, 275
11.2 Order of Reaction Rates, 277
11.3 First-Order Reaction Rates, 281
11.4 Second-Order Reaction Rates, 284
11.5 Reversible Reactions, 288
11.6 Complex Reactions, 289
11.7 Temperature Dependence—Activation
Energy, 293
11.8 The Activated Complex, 295
11.9 Kinetic Theory of Gases, 299
11.10 Theory of Reaction Rates, 303
11.11 Reactions of Atoms and Free Radicals, 306
Summary, 313
Problems, 315
Surface Chemistry
12.1 Colloids, 319
12.2 Osmotic Pressure of Colloidal
Suspensions, 320
12.3 Viscosity of Colloidal Suspensions, 322
12.4 Brownian Movement and Diffusion, 324
12.5 Sedimentation, 328
12.6 Light Scattering, 330
12.7 Surface Tension, 331
12.8 Surface Films, 333
12.9 Adsorption, 335
12.10 Electrical Properties of Surfaces, 337
Summary, 340
Problems, 341
Atomic Structure
13.1 The Electrical Nature of Matter, 345
13.2 Cathode Rays, 346
13.3 The Charge on the Electron, 348
13.4 The Nuclear Atom, 349
13.5 Isotopes, 351
13.6 The Mass Spectrometer, 352
13.7 X-Ray Spectra, 355
13.8 Composition of Nuclei, 356
13.9 Separation of Isotopes, 357
13.10 The Quantum Concept, 359
13.11 Atomic Spectra, 360
13.12 The Making of a Model or Theory, 362
13.13 The Bohr Model of the Hydrogen
Atom, 362
13.14 Critical Potentials, 365
xii Contents
13.15 The Wave Nature of Matter, 367
13.16 The Heisenberg Uncertainty
Principle, 369
13.17 The Wave Equation, 369
13.18 The Interpretation of i/r: The Born
Postulate, 372
13.19 The Wave Mechanical Model, 372
13.20 Particle in a One-Dimensional Box, 373
13.21 The Particle in a Three-Dimensional
Rectangular Box, 377
13.22 The Particle in a Cubic Box: An Example
of Degeneracy, 379
13.23 The Hydrogen Atom, 379
13.24 The Periodic System, 385
13.25 Electron Configurations of Ions, 388
Summary, 388
Problems, 391
Molecular Structure 394
14.1 The Binding of Atoms, 394
14.2 The Ionic Bond, 395
14.3 The Covalent Bond, 397
14.4 The Molecular Orbital Approach Using
Diatomic Molecules as an Example, 399
14.5 The Heitler-London Treatment of
Hydrogen, 402
14.6 The Geometry and Bonding of Polyatomic
Molecules, 405
14.7 Multiple Bonds: Localized and
Delocalized, 407
14.8 Polar Covalent Bonds, 411
14.9 Bonding in Complex Ions: Ligand Field
Theory, 415
14.10 Electric Moments, 419
14.11 Magnetic Moments, 421
14.12 Nuclear Magnetic Resonance
Spectroscopy, 424
14.13 Electron Spin Resonance, 429
14.14 Mossbauer Spectroscopy, 432
14.15 Rotational and Vibrational Energy, 434
14.16 Vibration-Rotation Spectra, 438
14.17 Electronic Spectra, 442
Summary, 446
Problems, 448
Contents xiii
Some Properties of Solids and Liquids 451
15.1 The Crystalline State, 451
15.2 The Space Lattice, 451
15.3 The Crystal Systems, 454
15.4 Diffraction of X-rays, 456
15.5 The Powder Method, 457
15.6 Cubic Systems, 458
15.7 Structure Determination by X-Rays, 461
15.8 Close Packing of Spheres, 466
15.9 A Classification of Solids According to
Bond Type, 467
15.10 Ionic Crystals, 467
15.11 Covalent and Molecular Crystals, 470
15.12 The Metals, 472
15.13 Semiconductors, 474
15.14 Structure of Liquids and (glasses, 475
15.15 Interatomic and Intermolecular
Forces, 477
Summary, 480
Problems, 481
Photochemistry and Radiation Chemistry 485
16.1 Photochemistry, 485
16.2 Absorption of Light by Atoms, 487
16.3 Absorption of Light by Molecules, 490
16.4 Hot Atom Reactions, 492
16.5 Flash Photolysis, 494
16.6 Dissociation-Recombination in Liquids, 495
16.7 Free Radical Polymerization, 497
16.8 Radiation Chemistry: Ionizing
Radiations, 499
16.9 Electron Impact Processes, 500
16.10 The Study of Ion-Molecule Reactions in
a Mass Spectrometer, 504
16.11 Radiolysis of Hydrogen Bromide, 506
16.12 Radiolysis of Water, 509
16.13 Radiolysis of Organic Systems, 512
Summary, 514
Problems, 516
Chemical Statistics
17.1 Introduction, 519
17.2 Equipartition of Energy, 519
519
xlv Contents
17.3 Quantum Effects, 522
17.4 Energy Distribution, 523
17.5 The Boltzmann Distribution Law, 525
17.6 The Partition Function, 528
17.7 Thermodynamic Properties, 530
17.8 Evaluation of Partition Functions, 535
17.9 Heat Capacity, 538
17.10 Maxwell-Boltzmann Distribution, 540
17.11 Transition State Theory of Reaction
Rates, 544
Summary, 547
Problems, 548
Appendixes 551
Index
567
|
| any_adam_object | 1 |
| author | Hamill, William H. Williams, Russell R. Mackay, Colin |
| author_facet | Hamill, William H. Williams, Russell R. Mackay, Colin |
| author_role | aut aut aut |
| author_sort | Hamill, William H. |
| author_variant | w h h wh whh r r w rr rrw c m cm |
| building | Verbundindex |
| bvnumber | BV041342740 |
| ctrlnum | (OCoLC)251496274 (DE-599)GBV19500891X |
| edition | 2. ed. |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01331nam a2200337 c 4500</leader><controlfield tag="001">BV041342740</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">00000000000000.0</controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">131004s1966 ad|| |||| 00||| eng d</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)251496274</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBV19500891X</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-210</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Hamill, William H.</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Principles of physical chemistry</subfield><subfield code="c">William H. Hamill ; Russell R. Williams, Jr. ; Colin MacKay</subfield></datafield><datafield tag="250" ind1=" " ind2=" "><subfield code="a">2. ed.</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Englewood Cliffs, N.J.</subfield><subfield code="b">Prentice-Hall</subfield><subfield code="c">1966</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XIV, 576 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Physikalische Chemie</subfield><subfield code="0">(DE-588)4045959-7</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Physikalische Chemie</subfield><subfield code="0">(DE-588)4045959-7</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="8">1\p</subfield><subfield code="5">DE-604</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Williams, Russell R.</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mackay, Colin</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HBZ Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026791478&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-026791478</subfield></datafield><datafield tag="883" ind1="1" ind2=" "><subfield code="8">1\p</subfield><subfield code="a">cgwrk</subfield><subfield code="d">20201028</subfield><subfield code="q">DE-101</subfield><subfield code="u">https://d-nb.info/provenance/plan#cgwrk</subfield></datafield></record></collection> |
| id | DE-604.BV041342740 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:54:29Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026791478 |
| oclc_num | 251496274 |
| open_access_boolean | |
| owner | DE-210 |
| owner_facet | DE-210 |
| physical | XIV, 576 S. Ill., graph. Darst. |
| publishDate | 1966 |
| publishDateSearch | 1966 |
| publishDateSort | 1966 |
| publisher | Prentice-Hall |
| record_format | marc |
| spelling | Hamill, William H. Verfasser aut Principles of physical chemistry William H. Hamill ; Russell R. Williams, Jr. ; Colin MacKay 2. ed. Englewood Cliffs, N.J. Prentice-Hall 1966 XIV, 576 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf Physikalische Chemie (DE-588)4045959-7 s 1\p DE-604 Williams, Russell R. Verfasser aut Mackay, Colin Verfasser aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026791478&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Hamill, William H. Williams, Russell R. Mackay, Colin Principles of physical chemistry Physikalische Chemie (DE-588)4045959-7 gnd |
| subject_GND | (DE-588)4045959-7 |
| title | Principles of physical chemistry |
| title_auth | Principles of physical chemistry |
| title_exact_search | Principles of physical chemistry |
| title_full | Principles of physical chemistry William H. Hamill ; Russell R. Williams, Jr. ; Colin MacKay |
| title_fullStr | Principles of physical chemistry William H. Hamill ; Russell R. Williams, Jr. ; Colin MacKay |
| title_full_unstemmed | Principles of physical chemistry William H. Hamill ; Russell R. Williams, Jr. ; Colin MacKay |
| title_short | Principles of physical chemistry |
| title_sort | principles of physical chemistry |
| topic | Physikalische Chemie (DE-588)4045959-7 gnd |
| topic_facet | Physikalische Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026791478&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT hamillwilliamh principlesofphysicalchemistry AT williamsrussellr principlesofphysicalchemistry AT mackaycolin principlesofphysicalchemistry |