Hierarchically structured zinc imidazolate mesophases:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online-Zugang: | kostenfrei http://d-nb.info/1037076397/34 https://nbn-resolving.org/urn:nbn:de:bvb:19-158606 Inhaltsverzeichnis |
| Beschreibung: | XV, 164 S. Ill., graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Hierarchically structured zinc imidazolate mesophases |c Sebastian Junggeburthh |
| 264 | 1 | |c 2013 | |
| 300 | |a XV, 164 S. |b Ill., graph. Darst. | ||
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| 502 | |a München, Univ., Diss., 2013 | ||
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Datensatz im Suchindex
| _version_ | 1804150659392471040 |
|---|---|
| adam_text | IMAGE 1
IV. TABLE OF CONTENTS
1 INTRODUCTION 1
2 CHARACTERIZATION METHODS 18
2.1 X-RAY DIFFRACTION (XRD) 18
2.2 TRANSMISSION ELECTRON MICROSCOPY (TEM) 158 161 20
2.3 SCANNING ELECTRON MICROSCOPY (SEM) AND ENERGY-DISPERSIVE X-RAY
SPECTROSCOPY (EDX) 22
2.4 SOLID-STATE NMR SPECTROSCOPY 162 163 23
2.5 SOLUTION NMR SPECTROSCOPY 24
2.6 INFRARED SPECTROSCOPY (IR) 64 24
2.7 ATOMIC FORCE MICROSCOPY (AFM) 165 25
2.8 MASS SPECTROMETRY (MS) 164 25
2.9 DIFFERENTIAL THERMAL/THERMOGRAVIMETRIC ANALYSIS (DTA-TG) 25
2.10 ELEMENTAL ANALYSIS: CHNS AND INDUCTIVELY COUPLED PLASMA ATOMIC
EMISSION SPECTROSCOPY (ICP-AES) : 26
3 OPERATIVE PROCEDURES 27
3.1 ORBITAL SHAKER 27
3.2 ULTRASONIC BATH 27
3.3 FURNACE 27
3.4 CENTRIFUGE 27
3.5 SPIN COATING 28
3.6 CHEMICALS 28
4 TOWARDS MESOSTRUCTURED ZINC IMIDAZOLATE FRAMEWORKS 30
4.1 ABSTRACT 30
4.2 INTRODUCTION 31
4.3 RESULTS AND DISCUSSION 34
4.3.1 SYNTHESIS AND CHARACTERIZATION 34
4.3.2 X-RAY POWDER DIFFRACTION 34
4.3.3 IR SPECTROSCOPY 37
4.3.4 SOLID-STATE NMR SPECTROSCOPY 39
4.3.5 ELEMENTAL ANALYSIS 45
4.3.6 TRANSMISSION ELECTRON MICROSCOPY 47
4.3.7 STRUCTURE DISCUSSION 49
4.3.8 THERMAL BEHAVIOUR 51
4.3.9 CONVERSION INTO ZIF-8 55
4.3.10 DISCUSSION 58
4.4 CONCLUSION 59
4.5 EXPERIMENTAL SECTION 60
4.6 ACKNOWLEDGEMENTS 62
4.7 SUPPORTING INFORMATION 63
5 ULTRATHIN 2D COORDINATION POLYMER NANOSHEETS BY SURFACTANT-MEDIATED
SYNTHESIS 66
5.1 ABSTRACT 66
HTTP://D-NB.INFO/1042304165
IMAGE 2
5.2 INTRODUCTION 67
5.3 RESULTS AND DISCUSSION 69
5.3.1 MESOSTRUCTURE SYNTHESIS AND CHARACTERIZATION 69
5.3.2 BASIC LAYERED STRUCTURE 73
5.3.3 TRANSMISSION ELECTRON MICROSCOPY 76
5.3.4 SURFACTANT EXTRACTION 80
5.3.5 EXFOLIATION 84
5.3.6 NANOTUBE FORMATION 88
5.3.7 FORMATION MECHANISM 89
5.4 CONCLUSION 90
5.5 EXPERIMENTAL SECTION 90
5.6 ACKNOWLEDGEMENT 93
5.7 SUPPORTING INFORMATION 94
6 TOWARD BEIM-MIFS BASED ON CARBOXYLIC ACIDS WITH EXTENDED ALKYL CHAINS
96
6.1 PROPANOIC ACID (PRO) 96
6.1.1 X-RAY POWDER DIFFRACTION AND TEM MEASUREMENTS 96
6.1.2 SOLID-STATE NMR SPECTROSCOPY 100
6.1.3 ELEMENTAL ANALYSIS 103
6.1.4 CONCLUSION 104
6.2 BUTYRIC ACID (BUTO) 105
6.2.1 SYNTHESIS OF ZINC BUTYRATE (ZN(BUTO )2) 105
6.2.2 [ZN(BEIM)BUTO] AND BELM-MIF(BUTO) 106
6.2.3 X-RAY POWDER DIFFRACTION 107
6.2.4 SOLID-STATE NMR SPECTROSCOPY 108
6.2.5 ELEMENTAL ANALYSIS 110
6.2.6 CONCLUSION ILL
6.3 CHAPTER SUMMARY 112
6.4 EXPERIMENTAL SECTION 112
6.4.1 SYNTHESIS OF ZN(BUTO )2 112
6.4.2 SYNTHESIS OF [ZN(BEIM)R], R = PRO, BUTO 113
6.4.3 SYNTHESIS OF BELM-MIF(R), R = PRO, BUTO 113
7 THE MESOSTRUCTURED ZINC BENZIMIDAZOLATE BEIM-MIF-40 114
7.1 X-RAY POWDER DIFFRACTION AND TEM MEASUREMENTS 114
7.2 SOLID-STATE NMR SPECTROSCOPY 116
7.3 IR SPECTROSCOPY 118
7.4 ELEMENTAL ANALYSIS 119
8 BEIM-MIF-30- A LAMELLAR MESOSTRUCTURED ZINC BENZIMIDAZOLATE PHASE 121
8.1 XRD POWDER DIFFRACTION AND TEM MEASUREMENTS 121
8.2 SOLID-STATE NMR SPECTROSCOPY 123
8.3 ELEMENTAL ANALYSIS 127
8.4 DISCUSSION 127
XIV
IMAGE 3
9 FUNCTIONALIZATION OF POLY[M 2 -ACETATO-M 2 -
BENZIMIDAZOLATO ZINC(II)] 129
9.1 2-CHLOROMETHYLBENZIMIDAZOLE (CIME-BELM) AND 5-BROMO-1
H-BENZIMIDAZOLE (BRBELM) 129
9.1.1 X-RAY POWDER DIFFRACTION 130
9.1.2 SOLID-STATE NMR SPECTROSCOPY 131
9.1.3 ELEMENTAL ANALYSIS 133
9.2 5-AMINOBENZIMIDAZOLE(NH2BEIM) 133
9.3 [ZN(NH 2 BEIM)OAC] 134
9.3.1 X-RAY POWDER DIFFRACTION 134
9.3.2 ELEMENTAL ANALYSIS 135
9.3.3 SOLID-STATE NMR SPECTROSCOPY 135
9.3.4 CONCLUSION 137
9.4 5-AZIDOBENZIMIDAZOLE (N3BEIM(H)) 138
9.5 [ZN(N 3 BEIM)OAC] 138
9.5.1 X-RAY POWDER DIFFRACTION 138
9.5.2 ELEMENTAL ANALYSIS 139
9.5.3 SOLID-STATE NMR SPECTROSCOPY 140
9.5.4 IR-SPECTROSCOPY 141
9.5.5 CONCLUSION 142
9.6 OUTLOOK 142
9.7 EXPERIMENTAL SECTION 144
9.7.1 SYNTHESIS OF [ZN(BRBEIM)OAC] 144
9.7.2 SYNTHESIS OF NH 2 BEIM(H) 145
9.7.3 SYNTHESIS OF [ZN(NH 2 BEIM)OAC] 146
9.7.4 SYNTHESIS OF N3BEIM(H) 146
9.7.5 SYNTHESIS OF [ZN(N 3 BEIM)OAC] 147
9.8 SUPPORTING INFORMATION 148
10 REFERENCES 149
11 PUBLICATIONS 163
XV
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| spelling | Junggeburth, Sebastian Verfasser aut Hierarchically structured zinc imidazolate mesophases Sebastian Junggeburthh 2013 XV, 164 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Univ., Diss., 2013 (DE-588)4113937-9 Hochschulschrift gnd-content Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:19-158606 http://edoc.ub.uni-muenchen.de/15860/ Verlag kostenfrei Volltext http://d-nb.info/1037076397/34 Langzeitarchivierung Nationalbibliothek https://nbn-resolving.org/urn:nbn:de:bvb:19-158606 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026196446&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Junggeburth, Sebastian Hierarchically structured zinc imidazolate mesophases |
| subject_GND | (DE-588)4113937-9 |
| title | Hierarchically structured zinc imidazolate mesophases |
| title_auth | Hierarchically structured zinc imidazolate mesophases |
| title_exact_search | Hierarchically structured zinc imidazolate mesophases |
| title_full | Hierarchically structured zinc imidazolate mesophases Sebastian Junggeburthh |
| title_fullStr | Hierarchically structured zinc imidazolate mesophases Sebastian Junggeburthh |
| title_full_unstemmed | Hierarchically structured zinc imidazolate mesophases Sebastian Junggeburthh |
| title_short | Hierarchically structured zinc imidazolate mesophases |
| title_sort | hierarchically structured zinc imidazolate mesophases |
| topic_facet | Hochschulschrift |
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