NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | VI, 198 S. Ill., graph. Darst. |
Internformat
MARC
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Datensatz im Suchindex
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| adam_text | IMAGE 1
TABLE OF CONTENTS
1. INTRODUCTION AND OUTLINE 1
1.1. ACYLGUANIDINES 1
1.2. ORGANOCATALYSIS 3
2. THE H-BONDING NETWORK OF ACYLGUANIDINE COMPLEXES: COMBINED
INTERMOLECULAR 2HJ H,P AND IHJS,P SCALAR COUPLINGS PROVIDE AN INSIGHT
INTO THE GEOMETRIC ARRANGEMENT 7
2.1. ABSTRACT 8
2.2. MANUSCRIPT 9
2.3. SUPPORTING INFORMATION 17
3. INMR INVESTIGATIONS ON BISCARBOXYLATE-(ACYL)GUANIDINE COMPLEXES... 29
3.1. INTRODUCTION 30
3.2. STRATEGY FOR THE SYNTHESIS OF THE BISCARBOXYLATED TWEEZERS 33
3.3. STRATEGY FOR THE SYNTHESIS OF THE LABELLED BISCARBOXYLATED TWEEZERS
36
3.4. NMR INVESTIGATIONS ON DIFFERENT (ACYL)GUANIDINE COMPLEXES 41
3.5. CONCLUSIONS 50
3.6. EXPERIMENTAL PART 52
3.7. REFERENCES 58
V
HTTP://D-NB.INFO/1042668906
IMAGE 2
4. BRONSTED ACID CATALYSIS - HYDROGEN BONDING VS. ION PAIRING IN IMINE
ACTIVATION 63
4.1. ABSTRACT 64
4.2. MANUSCRIPT 65
4.3. SUPPORTING INFORMATION 80
4.4. ADDITIONAL EXPERIMENTAL FINDINGS 90
5. NMR INVESTIGATIONS ON SPECIES PRESENT IN THIOUREA CATALYZED
REACTIONS 99
5.1. INTRODUCTION 100
5.2. RESULTS AND DISCUSSION 105
5.2.1. INVESTIGATIONS ON JACOBSEN S CATALYST 1 105
5.2.2. INVESTIGATIONS ON ALDIMINE 2 124
5.2.3. INVESTIGATIONS ON THE 1:1 MIXTURE OF 1 AND 2 131
5.2.4. INVESTIGATIONS ON THE SUBSTRATES 5, 6 AND 7 156
5.2.5. INVESTIGATIONS ON JACOBSEN S CATALYST 3 158
5.2.6. INVESTIGATIONS ON SCHREINER S CATALYST 4 163
5.3. SUMMARY AND OUTLOOK 169
5.4. SIGNAL ASSIGNMENTS 172
5.5. EXPERIMENTAL PAN 189
5.6. REFERENCES 190
6. SUMMARY AND OUTLOOK 19S
VI
|
| any_adam_object | 1 |
| author | Drettwan, Diana |
| author_facet | Drettwan, Diana |
| author_role | aut |
| author_sort | Drettwan, Diana |
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| building | Verbundindex |
| bvnumber | BV041200155 |
| classification_rvk | VK 5075 |
| ctrlnum | (OCoLC)856866710 (DE-599)BVBBV041200155 |
| dewey-full | 547.704426 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.704426 |
| dewey-search | 547.704426 |
| dewey-sort | 3547.704426 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| language | English |
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| physical | VI, 198 S. Ill., graph. Darst. |
| publishDate | 2012 |
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| spelling | Drettwan, Diana Verfasser aut NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis vorgelegt von Diana Drettwan 2012 VI, 198 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Regensburg, Univ., Diss., 2012 Intermolekulare Reaktion (DE-588)4605677-4 gnd rswk-swf Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf Acylgruppe (DE-588)4141351-9 gnd rswk-swf Rezeptor (DE-588)4049722-7 gnd rswk-swf Wasserstoffbrückenbindung (DE-588)4064787-0 gnd rswk-swf NMR-Spektroskopie (DE-588)4075421-2 gnd rswk-swf Thioharnstoff (DE-588)4290009-8 gnd rswk-swf Guanidinoverbindungen (DE-588)4327504-7 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Guanidinoverbindungen (DE-588)4327504-7 s Acylgruppe (DE-588)4141351-9 s Rezeptor (DE-588)4049722-7 s Intermolekulare Reaktion (DE-588)4605677-4 s NMR-Spektroskopie (DE-588)4075421-2 s DE-604 Thioharnstoff (DE-588)4290009-8 s Chemische Reaktion (DE-588)4009853-9 s Katalyse (DE-588)4029921-1 s Wasserstoffbrückenbindung (DE-588)4064787-0 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026175048&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Drettwan, Diana NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis Intermolekulare Reaktion (DE-588)4605677-4 gnd Chemische Reaktion (DE-588)4009853-9 gnd Acylgruppe (DE-588)4141351-9 gnd Rezeptor (DE-588)4049722-7 gnd Wasserstoffbrückenbindung (DE-588)4064787-0 gnd NMR-Spektroskopie (DE-588)4075421-2 gnd Thioharnstoff (DE-588)4290009-8 gnd Guanidinoverbindungen (DE-588)4327504-7 gnd Katalyse (DE-588)4029921-1 gnd |
| subject_GND | (DE-588)4605677-4 (DE-588)4009853-9 (DE-588)4141351-9 (DE-588)4049722-7 (DE-588)4064787-0 (DE-588)4075421-2 (DE-588)4290009-8 (DE-588)4327504-7 (DE-588)4029921-1 (DE-588)4113937-9 |
| title | NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis |
| title_auth | NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis |
| title_exact_search | NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis |
| title_full | NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis vorgelegt von Diana Drettwan |
| title_fullStr | NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis vorgelegt von Diana Drettwan |
| title_full_unstemmed | NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis vorgelegt von Diana Drettwan |
| title_short | NMR spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in Brønsted acid and thiourea catalysis |
| title_sort | nmr spectroscopic investigations on intermolecular interactions in acylguanidine receptor complexes and in bronsted acid and thiourea catalysis |
| topic | Intermolekulare Reaktion (DE-588)4605677-4 gnd Chemische Reaktion (DE-588)4009853-9 gnd Acylgruppe (DE-588)4141351-9 gnd Rezeptor (DE-588)4049722-7 gnd Wasserstoffbrückenbindung (DE-588)4064787-0 gnd NMR-Spektroskopie (DE-588)4075421-2 gnd Thioharnstoff (DE-588)4290009-8 gnd Guanidinoverbindungen (DE-588)4327504-7 gnd Katalyse (DE-588)4029921-1 gnd |
| topic_facet | Intermolekulare Reaktion Chemische Reaktion Acylgruppe Rezeptor Wasserstoffbrückenbindung NMR-Spektroskopie Thioharnstoff Guanidinoverbindungen Katalyse Hochschulschrift |
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