Nuclear and radiochemistry: fundamentals and applications
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis Klappentext |
| Beschreibung: | 25 cm |
| ISBN: | 9783527329014 9783527653331 |
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Datensatz im Suchindex
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CONTENTS
PREFACE XI
VOLUME 1
1 FUNDAMENTAL CONCEPTS 1
1.1 THE ATOM 2
1.2 ATOMIC PROCESSES 2
1.3 DISCOVERY OF THE ATOMIC NUCLEUS 4
1.4 NUCLEAR DECAY TYPES 6
1.5 SOME PHYSICAL CONCEPTS NEEDED IN NUCLEAR CHEMISTRY 11
1.5.1 FUNDAMENTAL FORCES 11
1.5.2 ELEMENTS FROM CLASSICAL MECHANICS 12
1.5.3 RELATIVISTIC MECHANICS 12
1.5.4 THE DE BROGLIE WAVELENGTH 14
1.5.5 HEISENBERG UNCERTAINTY PRINCIPLE 15
1.5.6 THE STANDARD MODEL OF PARTICLE PHYSICS 16
1.5.7 FORCE CARRIERS 19
REFERENCE 20
FURTHER READING 20
2 RADIOACTIVITY IN NATURE 23
2.1 DISCOVERY OF RADIOACTIVITY 23
2.2 RADIOACTIVE SUBSTANCES IN NATURE 26
REFERENCES 30
FURTHER READING 30
3 RADIOELEMENTS AND RADIOISOTOPES AND THEIR ATOMIC MASSES
3.1 PERIODIC TABLE OF THE ELEMENTS 33
3.2 ISOTOPES AND THE CHART OF NUCLIDES 34
3.3 NUCLIDE MASSES AND BINDING ENERGIES 39
3.4 EVIDENCE FOR SHELL STRUCTURE IN NUCLEI 47
3.5 PRECISION MASS SPECTROMETRY 49
REFERENCES 55
FURTHER READING 55
HTTP://D-NB.INFO/1030002703
VI | CONTENTS
4 OTHER PHYSICAL PROPERTIES OF NUCLEI 57
4.1 NUCLEAR RADII 57
4.2 NUCLEAR ANGULAR MOMENTA 63
4.3 MAGNETIC DIPOLE MOMENTS 65
4.4 ELECTRIC QUADRUPOLE MOMENTS 67
4.5 STATISTICS AND PARITY 69
4.6 EXCITED STATES 70
REFERENCES 71 '
FURTHER READING 71
5 THE NUCLEAR FORCE AND NUCLEAR STRUCTURE 73
5.1 NUCLEAR FORCES 73
5.2 CHARGE INDEPENDENCE AND ISOSPIN 76
5.3 NUCLEAR MATTER 81
5.4 FERMI GAS MODEL 82
5.5 SHELL MODEL 84
5.6 COLLECTIVE MOTION IN NUCLEI 94
5.7 NILSSON MODEL 101
5.8 THE PAIRING FORCE AND QUASI-PARTICLES 104
5.9 MACROSCOPIC-MICROSCOPIC MODEL 106
5.10 INTERACTING BOSON APPROXIMATION 108
5.11 FURTHER COLLECTIVE EXCITATIONS: COULOMB EXCITATION, HIGH-SPIN
STATES,
GIANT RESONANCES 110
REFERENCES 117
FURTHER READING 117
6 DECAY MODES 119
6.1 NUCLEAR INSTABILITY AND NUCLEAR SPECTROSCOPY 119
6.2 ALPHA DECAY 119
6.2.1 HINDRANCE FACTORS 125
6.2.2 ALPHA-DECAY ENERGIES 126
6.3 CLUSTER RADIOACTIVITY 126
6.4 PROTON RADIOACTIVITY 129
6.5 SPONTANEOUS FISSION 132
6.6 BETA DECAY 148
6.6.1 FUNDAMENTAL PROCESSES 148
6.6.2 ELECTRON CAPTURE-TO-POSITRON RATIOS 158
6.6.3 NUCLEAR MATRIX ELEMENTS 160
6.6.4 PARITY NON-CONSERVATION 162
6.6.5 MASSIVE VECTOR BOSONS 164
6.6.6 CABIBBO-KOBAYASHI-MASKAWA MATRIX 165
6.7 ELECTROMAGNETIC TRANSITIONS 170
6.7.1 MULTIPOLE ORDER AND SELECTION RULES 172
6.7.2 TRANSITION PROBABILITIES 174
6.7.3 INTERNAL CONVERSION COEFFICIENTS 179
CONTENTS | VII
6.7.4 ANGULAR CORRELATIONS 183
REFERENCES 186
FURTHER READING 187
7 RADIOACTIVE DECAY KINETICS 189
7.1 LAW AND ENERGY OF RADIOACTIVE DECAY 189
7.2 RADIOACTIVE EQUILIBRIA 191
7.3 SECULARS RADIOACTIVE EQUILIBRIUM 193
7.4 TRANSIENT RADIOACTIVE EQUILIBRIUM 196
7.5 HALF-LIFE OF MOTHER NUCLIDE SHORTER THAN HALF-LIFE OF DAUGHTER
NUCLIDE 197
7.6 SIMILAR HALF-LIVES 198
11 BRANCHING DECAY 199
7.8 SUCCESSIVE TRANSFORMATIONS 200
REFERENCE 202
FURTHER READING 203
8 NUCLEAR RADIATION 205
8.1 GENERAL PROPERTIES 205
8.2 HEAVY CHARGED PARTICLES (A 1) 207
8.3 BETA RADIATION 214
8.4 GAMMA RADIATION 220
8.5 NEUTRONS 227
8.6 SHORT-LIVED ELEMENTARY PARTICLES IN ATOMS AND MOLECULES 232
REFERENCES 233
FURTHER READING 234
9 MEASUREMENT OF NUCLEAR RADIATION 235
9.1 ACTIVITY AND COUNTING RATE 235
9.2 GAS-FILLED DETECTORS 239
9.2.1 IONIZATION CHAMBERS 243
9.2.2 PROPORTIONAL COUNTERS 244
9.2.3 GEIGER-MIILLER COUNTERS 246
9.3 SCINTILLATION DETECTORS 248
9.4 SEMICONDUCTOR DETECTORS 250
9.5 CHOICE OF DETECTORS 256
9.6 SPECTROMETRY 259
9.7 DETERMINATION OF ABSOLUTE DISINTEGRATION RATES 262
9.8 USE OF COINCIDENCE AND ANTICOINCIDENCE CIRCUITS 263
9.9 LOW-LEVEL COUNTING 263
9.10 NEUTRON DETECTION AND MEASUREMENT 264
9.11 TRACK DETECTORS 266
9.11.1 PHOTOGRAPHIC EMULSIONS AND AUTORADIOGRAPHY 266
9.11.2 DIELECTRIC TRACK DETECTORS 267
9.11.3 CLOUD CHAMBERS 268
CONTENTS
9.11.4 BUBBLE CHAMBERS 268
9.11.5 SPARK CHAMBERS 269
9.12 DETECTORS USED IN HEALTH PHYSICS 269
9.12.1 PORTABLE COUNTERS AND SURVEY METERS 269
9.12.2 FILM BADGES 270
9.12.3 POCKET ION CHAMBERS 270
9.12.4 THERMOLUMINESCENCE DOSIMETERS 270
9.12.5 CONTAMINATION MONITORS 270
9.12.6 WHOLE-BODY COUNTERS 271
REFERENCE 271
FURTHER READING 271
10 STATISTICAL CONSIDERATIONS IN RADIOACTIVITY MEASUREMENTS 273
10.1 DISTRIBUTION OF RANDOM VARIABLES 273
10.2 PROBABILITY AND PROBABILITY DISTRIBUTIONS 275
10.3 MAXIMUM LIKELIHOOD 282
10.4 EXPERIMENTAL APPLICATIONS 283
10.5 STATISTICS OF PULSE-HEIGHT DISTRIBUTIONS 285
10.6 SETTING UPPER LIMITS WHEN NO COUNTS ARE OBSERVED 287
FURTHER READING 288
11 TECHNIQUES IN NUCLEAR CHEMISTRY 289
11.1 SPECIAL ASPECTS OF THE CHEMISTRY OF RADIONUCLIDES 289
11.1.1 SHORT-LIVED RADIONUCLIDES AND THE ROLE OF CARRIERS 289
11.1.2 RADIONUCLIDES OF HIGH SPECIFIC ACTIVITY 291
11.1.3 MICROAMOUNTS OF RADIOACTIVE SUBSTANCES 292
11.1.4 RADIOCOLLOIDS 297
11.1.5 TRACER TECHNIQUES 299
11.2 TARGET PREPARATION 300
11.3 MEASURING BEAM INTENSITY AND FLUXES 306
11.4 NEUTRON SPECTRUM IN NUCLEAR REACTORS 308
11.4.1 THERMAL NEUTRONS 308
11.4.2 EPITHERMAL NEUTRONS AND RESONANCES 310
11.4.3 REACTION RATES IN THERMAL REACTORS 311
11.5 PRODUCTION OF RADIONUCLIDES 311
11.5.1 PRODUCTION IN NUCLEAR REACTORS 311
11.5.2 PRODUCTION BY ACCELERATORS 318
11.5.3 SEPARATION TECHNIQUES 324
11.5.4 RADIONUCLIDE GENERATORS 329
11.6 USE OF RECOIL MOMENTA 331
11.7 PREPARATION OF SAMPLES FOR ACTIVITY MEASUREMENTS 336
11.8 DETERMINATION OF HALF-LIVES 337
11.9 DECAY-SCHEME STUDIES 339
11.10 IN-BEAM NUCLEAR REACTION STUDIES 342
REFERENCES 355
FURTHER READING 357
CONTENTS | IX
VOLUME 2
12 NUCLEAR REACTIONS 361
13 CHEMICAL EFFECTS OF NUCLEAR TRANSMUTATIONS 465
14 INFLUENCE OF CHEMICAL BONDING ON NUCLEAR PROPERTIES 487
T
15 NUCLEAR ENERGY, NUCLEAR REACTORS, NUCLEAR FUEL, AND FUEL CYCLES 507
16 SOURCES OF NUCLEAR BOMBARDING PARTICLES 559
17 RADIOELEMENTS 581
18 RADIONUCLIDES IN CEO- AND COSMOCHEMISTRY 677
19 DATING BY NUCLEAR METHODS 711
20 RADIOANALYSIS 729
21 RADIOTRACERS IN CHEMISTRY 765
22 RADIONUCLIDES IN THE LIFE SCIENCES 783
23 TECHNICAL AND INDUSTRIAL APPLICATIONS OF RADIONUCLIDES
AND NUCLEAR RADIATION 801
24 RADIONUCLIDES IN THE GEOSPHERE AND THE BIOSPHERE 813
25 DOSIMETRY AND RADIATION PROTECTION 861
APPENDIX 883
INDEX 891
The third edition of this classic textbook in the field is completely updated and expanded
to two volumes to include the latest developments. This handbook and ready reference
comprehensively covers nuclear and radiochemistry in a well-structured and readily
accessible manner, dealing with the theory and fundamentals in the first half, followed
by chapters devoted to such specific topics as nuclear energy and reactors, radionuclides
in geo- and cosmochemistry, radioanalysis, radiotracers in chemistry, and radionuclides
in the life sciences. The result is a valuable resource for both newcomers as well as
established scientists in the field.
Jens-Vofker Kratz is Professor of Nuclear Chemistry at Johannes Gutenberg
University in Mainz, Germany. He also obtained his degrees in Chemistry at
this University, followed by a postdoc at Berkeley with Glenn T. Seaborg. Before
moving back to Mainz, he worked as a Group Leader between 1974 and 1982
at GSI in Darmstadt. He has served as a member and chair of a number of
scientific committees and is editor of Radiochimica Acta. He has received
numerous prices, including the Otto Hahn Award. |
| any_adam_object | 1 |
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| building | Verbundindex |
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| discipline | Chemie / Pharmazie |
| format | Book |
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| indexdate | 2024-08-03T00:48:45Z |
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| isbn | 9783527329014 9783527653331 |
| language | English |
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| spelling | Kratz, Jens-Volker 1944-2024 Verfasser (DE-588)1043270779 aut Nuclear and radiochemistry fundamentals and applications Jens-Volker Kratz and Karl Heinrich Lieser Weinheim Wiley-VCH 25 cm txt rdacontent n rdamedia nc rdacarrier Radiochemie (DE-588)4138529-9 gnd rswk-swf Kernchemie (DE-588)4138530-5 gnd rswk-swf Kernchemie (DE-588)4138530-5 s Radiochemie (DE-588)4138529-9 s DE-604 Lieser, Karl Heinrich Verfasser (DE-588)115500723 aut Erscheint auch als Online-Ausgabe, EPUB 978-3-527-65335-5 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-65334-8 Erscheint auch als Online-Ausgabe, PDF 978-3-527-65336-2 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4239515&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026129965&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Regensburg - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026129965&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Kratz, Jens-Volker 1944-2024 Lieser, Karl Heinrich Nuclear and radiochemistry fundamentals and applications Radiochemie (DE-588)4138529-9 gnd Kernchemie (DE-588)4138530-5 gnd |
| subject_GND | (DE-588)4138529-9 (DE-588)4138530-5 |
| title | Nuclear and radiochemistry fundamentals and applications |
| title_auth | Nuclear and radiochemistry fundamentals and applications |
| title_exact_search | Nuclear and radiochemistry fundamentals and applications |
| title_full | Nuclear and radiochemistry fundamentals and applications Jens-Volker Kratz and Karl Heinrich Lieser |
| title_fullStr | Nuclear and radiochemistry fundamentals and applications Jens-Volker Kratz and Karl Heinrich Lieser |
| title_full_unstemmed | Nuclear and radiochemistry fundamentals and applications Jens-Volker Kratz and Karl Heinrich Lieser |
| title_short | Nuclear and radiochemistry |
| title_sort | nuclear and radiochemistry fundamentals and applications |
| title_sub | fundamentals and applications |
| topic | Radiochemie (DE-588)4138529-9 gnd Kernchemie (DE-588)4138530-5 gnd |
| topic_facet | Radiochemie Kernchemie |
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