High performance chelation ion chromatography:
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
RSC Publ.
2011
|
| Schriftenreihe: | RSC chromatography monographs
14 |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 303 S. Ill., graph. Darst. 24 cm |
| ISBN: | 9781849730419 |
Internformat
MARC
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Datensatz im Suchindex
| _version_ | 1804150522078298112 |
|---|---|
| adam_text | Titel: High performance chelation ion chromatography
Autor: Nesterenko, Pavel N
Jahr: 2011
Contents
Chapter 1 Chelation and its Role in Contemporary Liquid
Chromatography 1
1.1 Basic Chromatographie Principles 1
1.2 Chelation as a Mechanism for Obtaining Separation
Selectivity 3
1.3 Terminology and Definitions 4
1.4 Historical Developments 6
1.5 The Evolution of Chelating Stationary Phases 9
1.6 The Current State of HPCIC and Context 11
References 13
Chapter 2 Retention Mechanism and Chelation Theory 16
2.1 Introduction 16
2.2 Surface and Solution Complexation 16
2.2.1 Complexation Kinetics 17
2.3 Equilibria Within the Chelating Ion Exchanger 21
2.3.1 Distribution Ratio Within a Mixed Mode
Mechanism 23
2.3.2 Selectivity in Non-complexing Mobile Phases 24
2.3.3 Secondary Equilibria Within the Mobile Phase 26
2.4 Temperature Effects in HPCIC 27
2.4.1 Thermodynamic Effects 27
2.4.2 Kinetic Effects 28
2.5 Mobile Phase pH 29
2.6 Organic Solvent Additives 31
References 32
RSC Chromatography Monographs No. 14
High Performance Chelation Ion Chromatography
By Pavel N. Nesterenko, Phil Jones and Brett Pauli
© The Royal Society of Chemistry 2011
Published by the Royal Society of Chemistry, www.rsc.org
viii Contents
Chapter 3 Chelating Stationary Phases 35
3.1 Introduction 35
3.2 Types and Properties of Chelating Ion Exchange
Ligands 36
3.2.1 Adsorption of Metal Ions 37
3.2.2 Ligand Chemical Stability 37
3.2.3 Suitable Coordinating Sites 37
3.2.4 Functional Selectivity 37
3.2.5 Suitable Acid-Base Properties and Surface
Charge 39
3.3 Chelating Ion Exchangers with Covalently Bonded
Chelating Groups 42
3.3.1 Types of Chelating Ion Exchangers and
Synthetic Methods 42
3.3.2 Polymer Based Chelating Ion Exchangers 46
3.3.3 Silica Based Chelating Ion Exchangers 54
3.3.4 Commercially Available Chelating Ion
Exchange Phases 64
3.4 Stationary Phase Matrix Effects 67
3.4.1 Surface Distribution of Covalently Bound
Ligands 70
3.4.2 Effects of Phase and Particle Porosity 73
3.4.3 Effect of Stationary Phase Structure upon
Separation Selectivity 74
3.4.4 Monolithic Chelating Ion Exchangers 77
3.5 Dynamically Modified and Impregnated Stationary
Phases 79
3.5.1 Impregnated (Pre-coated) Phases Using
Metallochromic Ligands 80
3.5.2 Dynamically Modified Phases 95
References 108
Chapter 4 Elution 116
4.1 Mobile Phase Parameters Influencing Separation
Performance in HPCIC 116
4.1.1 Ionic Strength 116
4.1.2 Temperature Effects 124
4.1.3 pH of the Mobile Phase 130
4.1.4 Organic Solvents in HPCIC 132
4.1.5 Addition of Oxidising and Reducing Agents 134
4.2 Elution Modes 135
4.2.1 Isocratic Elution 135
4.2.2 Gradient Elution 147
References 154
Contents ix
Chapter 5 Liquid-Liquid Chromatographie Methods 158
5.1 High Speed Counter-current Chromatography of
Metal Ions 158
5.1.1 Extracting Ligands and Metal Ion Selectivity 161
5.1.2 Efficiency of Metal Separations using HSCCC 167
5.1.3 Applications 169
5.2 High-performance Extraction Chromatography 170
5.2.1 Stationary Phase Supports 175
5.2.2 Ligand Loading Stability and Retention
Mechanism 177
5.2.3 Type of Extracting Reagent 178
5.2.4 Applications 180
References 191
Chapter 6 Detection 194
6.1 Background 194
6.2 Post-column Reactions for the Photometrie Detection
of Metal Ions 195
6.2.1 Construction of Post-column Reactors 196
6.2.2 Reagents for Post-column Derivitisation 203
6.2.3 Recent Developments in High-sensitivity
Reagents for Post-column Reactions 219
6.3 Practical Methods for Improving Limits of Detection
in Liquid Chromatography 222
6.3.1 The Detection Limit 222
6.3.2 Types of Baseline Noise 224
6.3.3 Noise Reduction Methods 226
6.4 Other Types of Post-column Reaction Detection 230
6.4.1 Displacement Reactions 230
6.4.2 Fluorescence Detection 232
6.4.3 Chemiluminescence Post-column Reaction
Detection 233
6.5 Hyphenated Techniques 234
References 236
Chapter 7 Practical Applications 242
7.1 Potential HPCIC Applications 242
7.2 Relative Advantages of HPCIC 243
7.3 Fresh and Potable Waters 250
7.4 Saline Samples 254
7.4.1 Seawater and Estuarine Water 255
7.4.2 Highly Saline Waters 261
7.4.3 Commercial Products and Fine Chemicals 262
7.5 Solid Samples 269
7.5.1 Sediments, Soils and Minerals 270
7.5.2 Biological Materials and Foodstuffs 277
7.5.3 Miscellaneous 280
References 282
Subject Index 284
|
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| isbn | 9781849730419 |
| language | English |
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| spelling | Nesterenko, Pavel N. Verfasser (DE-588)1025013239 aut High performance chelation ion chromatography Pavel N. Nesterenko ; Phil Jones ; Brett Paull Cambridge RSC Publ. 2011 X, 303 S. Ill., graph. Darst. 24 cm txt rdacontent n rdamedia nc rdacarrier RSC chromatography monographs 14 Jones, Phil Verfasser aut Paull, Brett Verfasser (DE-588)1025012836 aut RSC chromatography monographs 14 (DE-604)BV041129265 14 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026105242&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nesterenko, Pavel N. Jones, Phil Paull, Brett High performance chelation ion chromatography RSC chromatography monographs |
| title | High performance chelation ion chromatography |
| title_auth | High performance chelation ion chromatography |
| title_exact_search | High performance chelation ion chromatography |
| title_full | High performance chelation ion chromatography Pavel N. Nesterenko ; Phil Jones ; Brett Paull |
| title_fullStr | High performance chelation ion chromatography Pavel N. Nesterenko ; Phil Jones ; Brett Paull |
| title_full_unstemmed | High performance chelation ion chromatography Pavel N. Nesterenko ; Phil Jones ; Brett Paull |
| title_short | High performance chelation ion chromatography |
| title_sort | high performance chelation ion chromatography |
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