Heterogeneous catalysis of mixed oxides: perovskite and heteropoly catalysts
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
2013
|
| Ausgabe: | 1. ed. |
| Schriftenreihe: | Studies in surface science and catalysis
176 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 181 S. Ill., graph. Darst. |
| ISBN: | 9780444538338 |
Internformat
MARC
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| 100 | 1 | |a Misono, Makoto |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Heterogeneous catalysis of mixed oxides |b perovskite and heteropoly catalysts |c Makoto Misono |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2013 | |
| 300 | |a X, 181 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-026052399 | ||
Datensatz im Suchindex
| _version_ | 1804150443644813312 |
|---|---|
| adam_text | Contents
Preface
їх
1.
Basis of Heterogeneous Catalysis
1
1.1
Catalyst and Catalysis
2
1.1.1
Rate and Equilibrium of Chemical Reaction and
Role of Catalyst
2
1.1.2
Three Essential Functions of Catalyst
3
1.1.3
Essence of Catalytic Functions Based on Reaction Mechanism
4
1.1.4
A Short History of Industrial Catalysts
5
1.1.5
Classification of Catalysts
8
1.1.6
Practical Applications of Catalysts
9
1.1.7
Components and Shape of Industrial Catalysts
9
1.2
Rate of Catalytic Reaction and Reaction Mechanism
10
1.2.1
Reaction Rate
10
1.2.2
Adsorption on Solid Surface; Rate and Isotherm
11
1.2.3
Rate Equation of Catalytic Reaction
11
1.2.4
Reactor Type and Rate Expression
14
1.2.5
Elucidation of Reaction Mechanism
15
1.2.6
Mass and Heat Transfer
17
1.2.7
Deactivation of Catalyst
19
1.2.8
Comparison of Heterogeneous, Homogeneous
and Biocatalysis
20
1.3
Catalyst Design
20
1.4
Preparation and Characterization of Catalysts
22
References
23
2.
Chemistry and Catalysis of Mixed Oxides
25
2.1
Chemistry of Binary Oxides
26
2.1.1
Structure of Binary Oxides (or Single Metal Oxides)
26
2.1.2
Lattice Defects and Nonstoichiometry (Berthollide
Compounds)
28
2.1.3
Surface Structure of Single Metal Oxides
28
2.1.4
Chemical Properties of Single Metal Oxides
31
2.1.5
Catalysis of Single Metal Oxides
34
2.2
Chemistry of Mixed Oxides
36
2.2.1
Structure of Mixed Oxides
36
2.2.2
Valence and Defects in Mixed Oxides
39
2.2.3
Acidity and Basicity
40
Contents
2.2.4
Redox
Properties
43
2.2.5
Mixed Oxides for Supports
45
2.3
Catalysis of Mixed Oxides
45
2.3.1
Acid and Base Catalysis
46
2.3.2
Oxidation Catalysis
49
2.3.3
Hydrogénation,
Dehydrogenation, and Metathesis
51
2.4
Synergistic Effects in Mixed Oxide Catalysis
53
2.4.1
Combination of Acid and Base Catalysis
53
2.4.2
Combination of Dual Functions in Selective Oxidation
54
2.4.3
Roles of Catalyst Supports
55
2.5
Participation of Solid Bulk in Catalysis of Metal Oxides
56
2.5.1
Surface Layer Hypothesis
56
2.5.2
Redox
Mechanism of Cu-Hydroxyapatite and Catalytic
Activity
58
2.5.3
Iron Oxide;
Redox
Mechanism and Active Phase
for
Butène
to Butadiene
60
2.5.4
Two Bulk-Type Catalysis of Solid Heteropoly Catalysts
61
2.5.5
Concluding Remarks on the Role of Solid Bulk of Catalyst
63
References
63
3.
Catalysis of Perovskite and Related Mixed Oxides
67
3.1
Structures and Properties of Perovskite Family
68
3.1.1
Structure
68
3.1.2
Nonstoichjometry and Vacancies
68
3.1.3
Thermal and Chemical Stability
69
3.1.4
Applications Utilizing Electric, Magnetic, and Chemical
Properties
69
3.2
Catalytic Properties of Perovskites
70
3.3
Design of Perovskites Catalysts
71
3.3.1
Strategy for Catalyst Design of Perovskite-Type Mixed Oxides
73
3.3.2
Selection of B-Site Transition Element
73
3.3.3
Valence Control of B-Site Elements
75
3.3.4
Synergistic Effects of B-Site Elements
78
3.3.5
Combination of Valence Control and Synergistic Effect
79
3.3.6
Enhancement of Surface Area
80
3.4
Catalysis of Valence-Controlled LaCoO3 and La2CuO4
83
3.4.1
la^^S^CoOi
83
3.4.2
La2-xA/xCu1_yB/yO4
(A :
Ba,
Sr,
and
Ca;
B :
Zr
and AI) 88
3.5
Practical Applications of Perovskite Catalysts
92
3.5.1
Household Appliances
92
3.5.2
Catalytic Combustion
93
3.5.3
Automotive Catalysts with High Durability
93
3.5.4
Removal of Soot and NO*, in Exhaust from Diesel Vehicles
94
3.5.5
Membrane Reactor for Reforming of Hydrocarbons
94
References
94
4.
Catalysis of Heteropoly Compounds (Polyoxometalates)
97
4.1
Generai
Characteristics of Heteropoly Catalysis
98
Contents
4.2
Chemistry of Heteropoly Compounds in Solution
100
4.2.1
Formation and Stability of Heteropolyanions
100
4.2.2
Acidic Properties in Solution
101
4.2.3
Redox
Properties in Solution
101
4.3
Structure of Heteropoly Compounds in the Solid State
102
4.3.1
Hierarchical Structure of Solid Heteropoly Compounds
102
4.3.2
Primary Structures
104
4.3.3
Secondary Structures
105
4.3.4
Tertiary Structure; Particle Size, Surface Area, and
Pore Structure
110
4.3.5
Stability
114
4.4
Chemical Properties of Heteropoly Compounds in the
Solid State
115
4.4.1 Pseudoliquid
Behavior
115
4.4.2
Acidic Properties
120
4.4.3
Reduction and Oxidation
(Redox)
Properties
124
4.5
Catalysis of Heteropoly Compounds
129
4.5.1
Three Types of Catalysis in the Solid State
129
4.5.2
Acid Catalysis
132
4.5.3
Oxidation Catalysis
137
4.5.4
Bifunctional Catalysis
144
4.6
Supported Heteropoly Catalysts
146
4.6.1
Necessity of Supported Heteropoly Catalysts
146
4.6.2
Heteropoly Compounds Supported on SiO2
147
4.6.3
Industrial Production of Ethyl Acetate from
Ethylene
and Acetic Acid
149
References
151
5.
Mixed Oxides as Catalyst Supports
157
5.1
Roles of Catalyst Supports
157
5.1.1
Improvement of the Catalytically Active Component Itself
158
5.1.2
Improvement of the Catalyst as a Whole
158
5.2
Perovskites as Catalyst Supports
159
5.2.1
Perovskites Supports
159
5.2.2
Perovskite Supports for Automotive Catalysts
160
5.3
Ceria-Zirconia and Related Mixed Oxides
161
5.3.1
Storage Effect for Oxygen and Nitrogen Oxide
161
5.3.2
Mixed Oxide Supports for Noble Metals of Automotive
Catalysts
162
5.4
Heteropolyacids (Polyoxometalates) as Catalyst Supports
164
5.5
Zeolites as Catalyst Support
165
5.5.1
Dispersion of Metal Ions by Ion Exchange
165
5.5.2
Pd Supported on ZSM-5 for NO—CH4—O2 Reaction
167
References
172
Index
175
|
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| id | DE-604.BV041075500 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:39:00Z |
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| isbn | 9780444538338 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026052399 |
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| owner_facet | DE-91G DE-BY-TUM DE-703 |
| physical | X, 181 S. Ill., graph. Darst. |
| publishDate | 2013 |
| publishDateSearch | 2013 |
| publishDateSort | 2013 |
| publisher | Elsevier |
| record_format | marc |
| series | Studies in surface science and catalysis |
| series2 | Studies in surface science and catalysis |
| spelling | Misono, Makoto Verfasser aut Heterogeneous catalysis of mixed oxides perovskite and heteropoly catalysts Makoto Misono 1. ed. Amsterdam [u.a.] Elsevier 2013 X, 181 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Studies in surface science and catalysis 176 Heterogene Katalyse (DE-588)4123377-3 gnd rswk-swf Sauerstoffverbindungen (DE-588)4179220-8 gnd rswk-swf Heterogene Katalyse (DE-588)4123377-3 s Sauerstoffverbindungen (DE-588)4179220-8 s DE-604 Studies in surface science and catalysis 176 (DE-604)BV000863094 176 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026052399&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Misono, Makoto Heterogeneous catalysis of mixed oxides perovskite and heteropoly catalysts Studies in surface science and catalysis Heterogene Katalyse (DE-588)4123377-3 gnd Sauerstoffverbindungen (DE-588)4179220-8 gnd |
| subject_GND | (DE-588)4123377-3 (DE-588)4179220-8 |
| title | Heterogeneous catalysis of mixed oxides perovskite and heteropoly catalysts |
| title_auth | Heterogeneous catalysis of mixed oxides perovskite and heteropoly catalysts |
| title_exact_search | Heterogeneous catalysis of mixed oxides perovskite and heteropoly catalysts |
| title_full | Heterogeneous catalysis of mixed oxides perovskite and heteropoly catalysts Makoto Misono |
| title_fullStr | Heterogeneous catalysis of mixed oxides perovskite and heteropoly catalysts Makoto Misono |
| title_full_unstemmed | Heterogeneous catalysis of mixed oxides perovskite and heteropoly catalysts Makoto Misono |
| title_short | Heterogeneous catalysis of mixed oxides |
| title_sort | heterogeneous catalysis of mixed oxides perovskite and heteropoly catalysts |
| title_sub | perovskite and heteropoly catalysts |
| topic | Heterogene Katalyse (DE-588)4123377-3 gnd Sauerstoffverbindungen (DE-588)4179220-8 gnd |
| topic_facet | Heterogene Katalyse Sauerstoffverbindungen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026052399&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000863094 |
| work_keys_str_mv | AT misonomakoto heterogeneouscatalysisofmixedoxidesperovskiteandheteropolycatalysts |