Mixed matrix membranes for gas separation: = (Mixed-Matrix-Membranen zur Gastrennung)
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online-Zugang: | Volltext Volltext http://d-nb.info/1034425722/34 Inhaltsverzeichnis |
| Beschreibung: | XV, 123 S. Ill., graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Mixed matrix membranes for gas separation |b = (Mixed-Matrix-Membranen zur Gastrennung) |c von Muhammad Hussain |
| 246 | 1 | 1 | |a (Mixed-Matrix-Membranen zur Gastrennung) |
| 264 | 1 | |c 2013 | |
| 300 | |a XV, 123 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Erlangen-Nürnberg, Univ., Diss., 2013 | ||
| 650 | 0 | 7 | |a Gastrennung |0 (DE-588)4156082-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Polydimethylsiloxan |0 (DE-588)4175157-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Zeolith |0 (DE-588)4067660-2 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Kompositmembran |0 (DE-588)4302635-7 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Kompositmembran |0 (DE-588)4302635-7 |D s |
| 689 | 0 | 1 | |a Polydimethylsiloxan |0 (DE-588)4175157-7 |D s |
| 689 | 0 | 2 | |a Zeolith |0 (DE-588)4067660-2 |D s |
| 689 | 0 | 3 | |a Gastrennung |0 (DE-588)4156082-6 |D s |
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Datensatz im Suchindex
| _version_ | 1804150442656006144 |
|---|---|
| adam_text | IMAGE 1
TABLE OFCONTENT V
TABLE OF CONTENT
SYMBOL INDEX IX
ABSTRACT XII
KURZFASSUNG XIV
1 INTRODUCTION 1
2 FUNDAMENTAL A N D STATE OF T H E ART 4
3 THEORY 6
3.1 G A S SEPARATION WITH M E M B R A N E S 6
3.2 THEORY O F G A S T R A N S P O R T I N MEMBRANES 8
3.3 SOLUBILITY BASED G A S SEPARATION ; 10
3.4 CONCENTRATION POLARIZATION EFFECT 11
3.5 ZEOLITES 13
3.5.1 ZEOLITE ZSM-5 (MFI) 14
3.5.2 PROPERTIES OFZEOLITES 16
3.6 INORGANIC MEMBRANESFOR G A S SEPARATION 16
3.6.1 DENSE INORGANIC MEMBRANES 17
3.6.2 MICROPOROUS CERAMIC MEMBRANES 17
3.6.2.1 AMORPHOUS INOTGANIC MEMBRANES 17
3.6.2.2 ZEOLITE MEMBRANES 18
3.7 POLYMERIC MEMBRANES ....21
3.7.1 RUBBERY POLYMERIC MEMBRANES 23
3.7.1.1 POLYDIMETHYLSILOXANE (PDMS) 2 3
3.7.2 GLASSY POLYMERIC MEMBRANE 23
3.8 HYBRID M E M B R A N E MATERIALS 24
3.8.1 NON-ZEOLITE/POLYMER MIXED MATRIX MEMBRANES 25
3.8.2 ZEOLITE/POLYMER MIXED MATRIX MEMBRANES 25
3.8.2.1 COMPATIBILITY BETWEEN POLYMER AND ZEOLITE MATERIAL 2 6
HTTP://D-NB.INFO/1036118444
IMAGE 2
TABLE OFCONTENT , VI
3.9 IONIC LIQUID MEMBRANES 28
3.10 MODELING O F MIXED M A T R I X MEMBRANES 29
3.10.1 EXISTING MODELS 3 0
3.10.1.1 PARALLEL AND SERIES MODEL 3 0
3.10.1.2 OTHER EXISTING MODELS 31
3.10.2 MAXWELL MODEL 3 2
4 DEFINITION OF THE TASK 3 3
5 EXPERIMENTAL PROCEDURE 3 5
5.1 GAS PERMEABILITY MEASUREMENTS 3 5
5.1.1 EXPERIMENTAL SETUP 35
5.1.2 SINGLE GAS PERMEATION EXPERIMENTS 36
5.1.3 DEAD ENDEXPERIMENTS FOR THE MIXTURE O F GASES 37
5.1.4 CROSS FLOW EXPERIMENTS 37
5.2 DATA ANALYSIS 38
5.2.1 SINGLE GAS PERMEABILITY CALCULATIONS 38
5.2.2 MIXED GAS PERMEATION CALCULATIONS 39
5.3 G A S SOLUBILITY MEASUREMENTS 4 0
5.3.1 MAGNETIC SUSPENSION BALANCE 40
5.4 POROSITY MEASUREMENT 42
5.5 SCANNING ELECTRON MICROSCOPY (SEM) 44
5.6 THERMO-GRAVIMETRIC ANALYSIS (TGA) 4 4
5.7 MEMBRANE SYNTHESIS PROCEDURE 4 5
5.7.1 POLYDIMETHYLSILOXANE (PDMS) MEMBRANES 45
5.7.2 MIXED-MATRIX-MEMBRANES 46
5.7.3 IONIC LIQUID COATED ZEOLITE -MIXED MATRIX MEMBRANES 4 6
5.7.3.1 ZEOLITE COATING WITH ILS 4 6
5.8 SANDWICH-MEMBRANES 4 7
5.8.1 STACKED MEMBRANES 48
6 RESULTS A N D DISCUSSION 4 9
IMAGE 3
TABLE OFCONTENT VII
6.1 P D M S M E M B R A N E 4 9
6.1.1 SINGLE GAS PERMEABILITY 4 9
6.1.2 GAS MIXTURES - DEAD END EXPERIMENTS 50
6.1.3 GAS MIXTURES - CROSS FLOW EXPERIMENTS 5 4
6.2 MIXED MATRIX MEMBRANES: POLYDIMETHYLSILOXANE (PDMS) FILLED WITH
ZEOLITE (ZSM-5) 57
6.2.1 SINGLE GAS PERMEABILITY 57
6.2.2 GAS MIXTURES - CROSS FLOW EXPERIMENTS 59
6.2.3 EFFECT O F COMPOSITION 61
6.2.4 TEMPERATURE STABILITY O F THE MEMBRANES 62
( 6.2.5 ADSORPTION (SOLUBILITY) 63
6.2.6 MODELING O F MEMBRANES 6 5
6.2.6.1 IDENTIFICATION O F INTERFACIAL GAP 6 5
6.2.6.2 APPLICATION O F MAXWELL MODEL FOR SIEVE IN CAGE MORPHOLOGY 6 6
6.3 I L COATED ZEOLITE MIXED M A T R I X M E M B R A N E 7 0
6.3.1 MODIFICATION O F ZEOLITE/POLYMER MATERIALS B Y IONIC LIQUIDS 7 0
6.3.2 EFFECT O F IONIC LIQUID (IL) COATEDZEOLITE ON PERMEABILITY O F
GASES 7 0
6.3.3 CHARACTERIZATION O F IL-COATING 72
6.3.4 SOLID DENSITY MEASUREMENT 7 3
6.3.5 SCANNING ELECTRON MICROSCOPY (SEM) 74
6.3.6 MODELING FOR TERNARY MEMBRANE SYSTEM 76
6.3.6.1 COMPARISON O F MODELING RESULTS 7 9
6.4 SANDWICH M E M B R A N E S A N D STACKED M E M B R A N E S .81
6.4.1 SINGLE GAS PERMEABILITY 81
6.4.2 GAS MIXTURES - DEAD ENDEXPERIMENTS 83
6.4.3 GAS MIXTURES - CROSS FLOW EXPERIMENTS 85
6.4.4 MODELING O F EXPERIMENTAL RESULTS 88
6.4.4.1 MODEL DESIGN FOR SINGLE GASES 88
6.4.4.2 COMPARISON O F MODEL WITH EXPERIMENTS 89
6.4.4.3 GAS MIXTURES - DEAD END EXPERIMENTS 91
6.4.4.4 GAS MIXTURES - CROSS FLOW EXPERIMENTS 9 5
7 CONCLUSION 9 9
8 APPENDIX I L L
CALCULATIONS F O R T H E MODELING P A R T 117
P U R E POLYMER-PENETRATION MODEL (CASE-A) 118
IMAGE 4
TABLE OFCONTENT
VIII
POLYMER-IL PENETRATION MODEL (CASE-B) 120
POLYMER-IL-ZEOLITE PENETRATION MODEL (CASE-C) 122
|
| any_adam_object | 1 |
| author | Hussain, Muhammad |
| author_GND | (DE-588)103555089X |
| author_facet | Hussain, Muhammad |
| author_role | aut |
| author_sort | Hussain, Muhammad |
| author_variant | m h mh |
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| dewey-full | 660.2842 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660.2842 |
| dewey-search | 660.2842 |
| dewey-sort | 3660.2842 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| spelling | Hussain, Muhammad Verfasser (DE-588)103555089X aut Mixed matrix membranes for gas separation = (Mixed-Matrix-Membranen zur Gastrennung) von Muhammad Hussain (Mixed-Matrix-Membranen zur Gastrennung) 2013 XV, 123 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Erlangen-Nürnberg, Univ., Diss., 2013 Gastrennung (DE-588)4156082-6 gnd rswk-swf Polydimethylsiloxan (DE-588)4175157-7 gnd rswk-swf Zeolith (DE-588)4067660-2 gnd rswk-swf Kompositmembran (DE-588)4302635-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Kompositmembran (DE-588)4302635-7 s Polydimethylsiloxan (DE-588)4175157-7 s Zeolith (DE-588)4067660-2 s Gastrennung (DE-588)4156082-6 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:29-opus-45913 https://open.fau.de/handle/openfau/3309 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-45913 Resolving-System kostenfrei Volltext http://d-nb.info/1034425722/34 Langzeitarchivierung Nationalbibliothek DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026051742&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hussain, Muhammad Mixed matrix membranes for gas separation = (Mixed-Matrix-Membranen zur Gastrennung) Gastrennung (DE-588)4156082-6 gnd Polydimethylsiloxan (DE-588)4175157-7 gnd Zeolith (DE-588)4067660-2 gnd Kompositmembran (DE-588)4302635-7 gnd |
| subject_GND | (DE-588)4156082-6 (DE-588)4175157-7 (DE-588)4067660-2 (DE-588)4302635-7 (DE-588)4113937-9 |
| title | Mixed matrix membranes for gas separation = (Mixed-Matrix-Membranen zur Gastrennung) |
| title_alt | (Mixed-Matrix-Membranen zur Gastrennung) |
| title_auth | Mixed matrix membranes for gas separation = (Mixed-Matrix-Membranen zur Gastrennung) |
| title_exact_search | Mixed matrix membranes for gas separation = (Mixed-Matrix-Membranen zur Gastrennung) |
| title_full | Mixed matrix membranes for gas separation = (Mixed-Matrix-Membranen zur Gastrennung) von Muhammad Hussain |
| title_fullStr | Mixed matrix membranes for gas separation = (Mixed-Matrix-Membranen zur Gastrennung) von Muhammad Hussain |
| title_full_unstemmed | Mixed matrix membranes for gas separation = (Mixed-Matrix-Membranen zur Gastrennung) von Muhammad Hussain |
| title_short | Mixed matrix membranes for gas separation |
| title_sort | mixed matrix membranes for gas separation mixed matrix membranen zur gastrennung |
| title_sub | = (Mixed-Matrix-Membranen zur Gastrennung) |
| topic | Gastrennung (DE-588)4156082-6 gnd Polydimethylsiloxan (DE-588)4175157-7 gnd Zeolith (DE-588)4067660-2 gnd Kompositmembran (DE-588)4302635-7 gnd |
| topic_facet | Gastrennung Polydimethylsiloxan Zeolith Kompositmembran Hochschulschrift |
| url | https://open.fau.de/handle/openfau/3309 https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-45913 http://d-nb.info/1034425722/34 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026051742&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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