Applied cross-coupling reactions:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2013
|
| Schriftenreihe: | Lecture notes in chemistry
80 |
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | X, 245 S. graph. Darst. 24 cm |
| ISBN: | 9783642323676 3642323677 |
Internformat
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| 245 | 1 | 0 | |a Applied cross-coupling reactions |c Yasushi Nishihara ed. |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 2013 | |
| 300 | |a X, 245 S. |b graph. Darst. |c 24 cm | ||
| 336 | |b txt |2 rdacontent | ||
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| 500 | |a Literaturangaben | ||
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Datensatz im Suchindex
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IMAGE 1
CONTENTS
PART I METAL-CATALYZED CROSS-COUPLING REACTIONS 1 A HISTORIC OVERVIEW O
F THE METAL-CATALYZED CROSS-COUPLING REACTIONS 3
1.1 GENERAL INTRODUCTION 3
1.2 THE CROSS-COUPLING REACTIONS ADDRESSED IN THIS TEXTBOOK . . . . 5
1.2.1 KUMADA-TAMAO-CORRIU COUPLING 5
1.2.2 MURAHASHI COUPLING 6
1.2.3 SONOGASHIRA-HAGIHARA COUPLING 7
1.2.4 NEGISHI COUPLING 7
1.2.5 MIGITA-KOSUGI-STILLE COUPLING 8
1.2.6 SUZUKI-MIYAURA COUPLING 8
1.2.7 HIYAMA COUPLING 9
1.3 PERSPECTIVES 10
REFERENCES 11
2 MECHANISMS AND FUNDAMENTAL REACTIONS 17
2.1 TRANSMETALATION IN SUZUKI-MIYAURA COUPLING 17
2.1.1 STOICHIOMETRIC REACTIONS OF SUZUKI-MIYAURA COUPLING 19
2.1.2 BASE-ASSISTED TRANSMETALATION 20
2 .1 .3 THE TURNOVER LIMITING STEP IN SUZUKI-MIYAURA COUPLING 22
2.1.4 PATHWAYS FOR TRANSMETALATION 23
2.1.5 COMPUTATIONAL STUDIES O F THE TRANSMETALATION STEP IN
SUZUKI-MIYAURA COUPLING 25
2 .1 .6 AN INTERCONVERSION BETWEEN TRIFLUOROBORATE AND BORONIC ACID 28
HTTP://D-NB.INFO/1024100499
IMAGE 2
VIII C O N T E N T S
2.2 THE "COPPER EFFECT" IN MIGITA-KOSUGI-STILLE COUPLING 30
2.2.1 A CINE SUBSTITUTION REACTION 30
2.2.2 THE COPPER EFFECT 32
2.2.3 PERSPECTIVES 34
2.3 SUMMARY 35
REFERENCES 35
PART II APPLICATIONS O F THE CROSS-COUPLING REACTIONS
3 NATURAL PRODUCT SYNTHESIS 43
3.1 INTRODUCTION 43
3.2 KUMADA-TAMAO-CORRIU COUPLING (SP 3 -SP 2 ) 4 4
3.3 SONOGASHIRA-HAGIHARA COUPLING (SP-SP") 4 6
3.4 NEGISHI COUPLING 4 9
3.4.1 SP 2 -SP 2 NEGISHI COUPLING 4 9
3.4.2 SP 3 -SP 2 NEGISHI COUPLING 50
3.4.3 SP-SP 2 NEGISHI COUPLING 52
3.4.4 CARBOMETALATION AND NEGISHI COUPLING SEQUENCES 52
3.4.5 UTILITY OF NEGISHI COUPLING TOWARD CARBONYL COMPOUND SYNTHESIS 54
3.5 MIGITA-KOSUGI-STILLE COUPLING 56
3.5.1 SYNTHETIC METHODS OF ORGANOTIN COMPOUNDS 56
3.5.2 SP 2 -SP 2 M I G I T A - K O S U G I - S T I L L E COUPLING 57
3.5.3 OTHER MIGITA-KOSUGI-STILLE COUPLINGS 62
3.6 SUZUKI-MIYAURA COUPLING 63
3.6.1 SP 2 -SP 2 S U Z U K I - M I Y A U R A COUPLING 64
3.6.2 SP 3 -SP 2 S U Z U K I - M I Y A U R A COUPLING 69
3.7 HIYAMA COUPLING (SP 2 -SP 2 ) 71
3.8 SUMMARY 74
REFERENCES 74
4 PHARMACEUTICALS 85
4.1 INTRODUCTION 85
4.2 SUZUKI-MIYAURA COUPLING 86
4.3 NEGISHI COUPLING 94
4.4 MIGITA-KOSUGI-STILLE COUPLING 99
4.5 KUMADA-TAMAO-CORRIU COUPLING 101
4.6 SONOGASHIRA-HAGIHARA COUPLING 103
4.7 SUMMARY 105
REFERENCES 106
IMAGE 3
C O N T E N T S L X
5 LIQUID CRYSTALS H I
5.1 INTRODUCTION I L L
5.2 KUMADA-TAMAO-CORRIU COUPLING 113
5.3 MIGITA-KOSUGI-STILLE COUPLING 115
5.4 SUZUKI-MIYAURA COUPLING 118
5.5 SONOGASHIRA-HAGIHARA COUPLING 125
5.6 SUMMARY 132
REFERENCES 133
6 CONJUGATED POLYMERS 137
6.1 INTRODUCTION 137
6.2 KUMADA-TAMAO-CORRIU COUPLING 138
6.3 NEGISHI COUPLING 144
6.4 MIGITA-KOSUGI-STILLE COUPLING 147
6.5 SUZUKI-MIYAURA COUPLING 152
6.6 SONOGASHIRA-HAGIHARA COUPLING 158
6.7 HIYAMA COUPLING 166
6.8 SUMMARY 168
REFERENCES 168
PART III RECENT ADVANCES IN CROSS-COUPLING REACTIONS
7 RECENT ADVANCES IN CROSS-COUPLING REACTIONS WITH ARYL CHLORIDES,
TOSYLATES, AND MESYLATES 177
7.1 INTRODUCTION 177
7.2 KUMADA-TAMAO-CORRIU COUPLING 178
7.3 NEGISHI COUPLING 180
7.4 MIGITA-KOSUGI-STILLE COUPLING 182
7.5 SUZUKI-MIYAURA COUPLING 184
7.6 HIYAMA COUPLING 191
7.7 SONOGASHIRA-HAGIHARA COUPLING 193
7.8 SUMMARY 196
REFERENCES 196
8 RECENT ADVANCES IN CROSS-COUPLING REACTIONS WITH ALKYL HALIDES 203
8.1 INTRODUCTION 203
8.2 KUMADA-TAMAO-CORRIU COUPLING 205
8.3 NEGISHI COUPLING 209
8.4 MIGITA-KOSUGI-STILLE COUPLING 213
8.5 SUZUKI-MIYAURA COUPLING 214
IMAGE 4
X C O N T E N T S
8.6 HIYAMA COUPLING 221
8.7 SONOGASHIRA-HAGIHARA COUPLING 223
8.8 SUMMARY 225
REFERENCES 225
APPENDIX 23 1
INDEX 239 |
| any_adam_object | 1 |
| author2 | Nishihara, Yasushi |
| author2_role | edt |
| author2_variant | y n yn |
| author_facet | Nishihara, Yasushi |
| building | Verbundindex |
| bvnumber | BV041059372 |
| classification_rvk | VK 6000 |
| classification_tum | CHE 620f |
| ctrlnum | (OCoLC)841580904 (DE-599)DNB1024100499 |
| dewey-full | 547.2 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.2 |
| dewey-search | 547.2 |
| dewey-sort | 3547.2 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| format | Book |
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| illustrated | Illustrated |
| indexdate | 2024-08-03T00:41:28Z |
| institution | BVB |
| isbn | 9783642323676 3642323677 |
| language | English |
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| physical | X, 245 S. graph. Darst. 24 cm |
| publishDate | 2013 |
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| publishDateSort | 2013 |
| publisher | Springer |
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| series | Lecture notes in chemistry |
| series2 | Lecture notes in chemistry |
| spelling | Applied cross-coupling reactions Yasushi Nishihara ed. Berlin [u.a.] Springer 2013 X, 245 S. graph. Darst. 24 cm txt rdacontent n rdamedia nc rdacarrier Lecture notes in chemistry 80 Literaturangaben Kreuzkupplungsreaktion (DE-588)1033635499 gnd rswk-swf Kreuzkupplungsreaktion (DE-588)1033635499 s DE-604 Nishihara, Yasushi edt Erscheint auch als Online-Ausgabe Applied Cross-Coupling Reactions Lecture notes in chemistry 80 (DE-604)BV000000216 80 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4072949&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026036538&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Applied cross-coupling reactions Lecture notes in chemistry Kreuzkupplungsreaktion (DE-588)1033635499 gnd |
| subject_GND | (DE-588)1033635499 |
| title | Applied cross-coupling reactions |
| title_auth | Applied cross-coupling reactions |
| title_exact_search | Applied cross-coupling reactions |
| title_full | Applied cross-coupling reactions Yasushi Nishihara ed. |
| title_fullStr | Applied cross-coupling reactions Yasushi Nishihara ed. |
| title_full_unstemmed | Applied cross-coupling reactions Yasushi Nishihara ed. |
| title_short | Applied cross-coupling reactions |
| title_sort | applied cross coupling reactions |
| topic | Kreuzkupplungsreaktion (DE-588)1033635499 gnd |
| topic_facet | Kreuzkupplungsreaktion |
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