Verfügbarkeit: The chemical components of tobacco and tobacco smoke

The chemical components of tobacco and tobacco smoke:

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Bibliographische Detailangaben
1. Verfasser:	Rodgman, Alan (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Boca Raton [u.a.] CRC Press 2013
Ausgabe:	2. ed.
Schlagworte:	Tobacco > Composition Tobacco smoke > Composition Chemie Tabakrauch Tabak
Online-Zugang:	Klappentext Inhaltsverzeichnis
Beschreibung:	Includes bibliographical references and index
Beschreibung:	XCIII, 2238 S. 1 CD-ROM (12 cm)
ISBN:	9781466515482

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Datensatz im Suchindex

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adam_text	Contents Foreword ......................................................................................................................................................................................xi Acknowledgments ......................................................................................................................................................................xiii Authors ........................................................................................................................................................................................xv List of Tables ..............................................................................................................................................................................xix List of Figures .........................................................................................................................................................................xxvii Introduction ..............................................................................................................................................................................xxix Chapter 1 Hydrocarbons ..........................................................................................................................................................1 1.1 Alkanes .........................................................................................................................................................1 1.2 Alkenes and Alkynes .................................................................................................................................15 1.3 Alicyclic Hydrocarbons ..............................................................................................................................34 1.4 Monocyclic Aromatic Hydrocarbons .........................................................................................................49 1.5 Polycyclic Aromatic Hydrocarbons ............................................................................................................56 1.5.1 Controversies over the Roffo Investigations ..................................................................................58 1.6 Summary ...................................................................................................................................................116 Chapter 2 Alcohols and Phytosterols ....................................................................................................................................117 2.1 Alcohols .....................................................................................................................................................117 2.2 Phytosterols ..............................................................................................................................................121 Chapters Aldehydes and Ketones .......................................................................................................................................245 3.1 Assertion of Aldehydes and Ketones as Ciliastatic Tobacco Smoke Components ..................................251 3.2 Ciliastasis Studies with Cigarette Smoke Condensate Fractions .............................................................256 3.3 Ciliastasis Studies with Individual Cigarette Mainstream Smoke Components ......................................256 3.4 Nose Inhalation of Environmental Tobacco Smoke vs. Mouth Inhalation of Mainstream Smoke ..........257 Chapter 4 Carboxylic Acids .................................................................................................................................................369 4.1 Carboxylic Acids ......................................................................................................................................369 4.2 Amino Acids and Related Compounds ....................................................................................................370 Chapters Esters ...................................................................................................................................................................441 Chapter 6 Lactones ..............................................................................................................................................................505 Chapter 7 Anhydrides ...........................................................................................................................................................531 Chapter 8 Carbohydrates and Their Derivatives ..................................................................................................................535 Chapter 9 Phenols and Quiñones .........................................................................................................................................561 9.1 Phenols ......................................................................................................................................................561 9.1.1 Identification and Quantitation of Phenols in Cigarette MSS .....................................................565 9.1.2 Bioassays to Determine the Contribution of Phenols to Cigarette Smoke Condensate Tumorigenicity ............................................................................................................................567 VI ( ( intents 9.1.3 Determination of the Nature of the Precursors in Tobacco of the Phenols m Smoke ....................................................................................................................................... 9.1.4 Effect of Cigarette Design Parameterson Yield of MSS Phenols ........... 9.2 Quiñones ............................................................................................................................................. Chapter 10 Ethers ................................................................................................................................................................... M} Overall Summary of Oxygen-Containing Components of Tobacco and/or Tobacco Smoke: Chapters 2 through 10............................................................................................................................. M} Chapter 11 Nitriles .................................................................................................................................................................. 741 Chapter 12 Acyclic Amines Chapter 13 Amides Chapter 14 Imides Chapter 15 N-Nitrosamines ................................................................................................................................................... S21 15.1 Volatile NNAs ..........................................................................................................................................825 15.2 Nonvolatile NNAs ....................................................................................................................................825 15.3 Tobacco-Specific NNAs ...........................................................................................................................832 15.4 /V-Nitrosamino Acids ................................................................................................................................833 15.5 Tobacco- Speci fie NNAs: An Exception among the Major MSS Toxicants .............................................839 15.6 Direct Transfer of TSNAs from Tobacco vs. Their Formation during the Smoking Process ..................841 15.7 Infrequently Studied Tobacco and/or Tobacco Smoke Secondary Amines and Their Λ -Nitroamines ... 841 15.8 Flue Curing and TSNAs .............................................................. ............................................................845 Chapter 16 Nitroalkanes, Nitroarenes. and Nitrophenols ......................................................................................................855 Chapter 17 Nitrogen Heterocyclic Components ....................................................................................................................861 17.1 Monocyclic Four and Five-Membered /V-Containing Ring Compounds .................................................861 17.1.1 Background .................................................................................................................................861 17.1.2 Four-Membered /V-Containing Rings .........................................................................................861 17.1.3 Five-Membered N-Containing Rings ..........................................................................................862 17.1.4 Compounds in Tobacco. Tobacco Smoke, and Tobacco Substitute Smoke with Multiple Five-Membered N-Containing Rings ..........................................................................................866 17.2 Monocyclic Six-Membered A -Containing Ring Compounds ..................................................................885 17.2.1 Introduction .................................................................................................................................885 17.2.2 Biosynthesis of Six-Membered /V-Containing Ring Compounds and the Five- and Six- Membered and Multiple Six-Membered Nitrogen Heterocycles of Tobacco ..............................885 17.2.3 Other Means for the Formation of the Six-Membered V-Containing Ring Compounds Found in Tobacco ........................................................................................................................888 17.2.4 Six-Membered/V-Containing Ring Compounds in Tobacco and Tobacco Smoke .....................888 17.2.4.1 Piperidine and the Tetra- and Dihydropyridines .........................................................889 17.2.4.2 Pyridines ......................................................................................................................889 17.2.4.3 Pyrazines .....................................................................................................................890 17.2.4.4 Pyrimidines ..................................................................................................................891 17.2.5 Compounds in Tobacco and Tobacco Smoke Containing a Five- and Six-Membered /V-Containing Ring ............................................................................................ 923 17.2.5.1 Nicotine and Tobacco Alkaloids with a Six-Membered /V-Containing Ring and a Second Five-Membered /V-Containing Ring .....................................................924 Contents vii 17.2.5.2 Compounds in Tobacco and Tobacco Smoke with Two or More Six-Membered A -Containing Rings .....................................................................................................926 17.3 Lactams ....................................................................................................................................................938 17.4 Oxazoles and Oxazines ............................................................................................................................938 17.5 Aza-Arenes ...............................................................................................................................................955 17.5.1 Alternate Exposures to Aza-Arenes ............................................................................................966 17.6 /V-Heterocyclic Amines ............................................................................................................................968 Chapter 18 Miscellaneous Components ..............................................................................................................................1007 18.1 Sulfur-Containing Components .............................................................................................................1007 18.2 Halogenated Components .......................................................................................................................1009 Chapter 19 Fixed and Variable Gases ..................................................................................................................................1055 19.1 Analytical Methods ................................................................................................................................1058 19.1.1 Carbon Dioxide and Carbon Monoxide ....................................................................................1058 19.1.2 Nitrogen Oxides ........................................................................................................................1058 19.1.3 Hydrogen Cyanide .....................................................................................................................1059 19.1.4 Ammonia ...................................................................................................................................1059 Chapter 20 Metallic and Nonmetallic Elements, Isotopes, Ions, and Salts .........................................................................1067 20.1 Elements, Isotopes, and Ions in Plants ...................................................................................................1067 20.1.1 Elements, Isotopes, and Ions in Tobacco ..................................................................................1067 20.1.2 Elements, Isotopes, and Ions in Tobacco Smoke .......................................................................1070 20.2 Methods for the Detection and Identification of Metals, Ions, and Isotopes in Tobacco and Tobacco Smoke ................................................................................................................................1071 20.3 The Transference of Elements, Isotopes, and Ions from Tobacco to Tobacco Smoke ...........................1072 20.3.1 Elements in Tobacco Smoke of Special Interest .......................................................................1072 20.3.1.1 Arsenic .......................................................................................................................1075 20.3.1.2 Beryllium ...................................................................................................................1075 20.3.1.3 Chromium, Cadmium, and Lead ...............................................................................1075 20.3.1.4 Chromium VI ............................................................................................................ 1075 20.3.1.5 Nickel .........................................................................................................................1075 20.3.1.6 Cobalt .........................................................................................................................1076 20.3.1.7 Mercury .....................................................................................................................1076 20.3.1.8 Selenium ....................................................................................................................1076 20.3.1.9 ^Polonium ................................................................................................................1076 20.3.1.10235Uraniumand238Uranium .......................................................................................1076 20.4 Summary ................................................................................................................................................1077 Chapter 21 Pesticides and Growth Regulators .....................................................................................................................1099 21.1 Synthetic Pesticides and Plant Growth Regulator Residues on Tobacco ...............................................1100 21.2 Naturally Occurring Plant Growth Regulators and Pesticides in Tobacco .............................................1101 21.3 Transfer Rates of Pesticides and Plant Growth Regulators to MSS ........................................................1102 21.4 Decomposition Products of Agrochemicals in MSS ...............................................................................1103 21.5 Methods for Analyses of Pesticides and Plant Growth Regulators .........................................................1104 21.6 Residues of Synthetic Pesticides and Plant Growth Regulators Identified in Tobacco and Tobacco Smoke .................................................................................................................................1104 Chapter 22 Genes, Nucleotides, and Enzymes .....................................................................................................................1151 22.1 General Discussion of Genetics ...............................................................................................................1151 22.2 Tobacco Genetics .....................................................................................................................................1152 22.3 Genes, Nucleotides, and Enzymes Identified in Tobacco ........................................................................1153 Acknowledgments ..............................................................................................................................................1156 viii Contents Chapter 23 Hoffmann Analytes ............................................................................................................................................1171 Chapter 24 Tobacco and/or Tobacco Smoke Components Used as Tobacco Ingredients ................................................... 1221 Acknowledgment ...............................................................................................................................................1298 Chapter 25 Pyrolysis ............................................................................................................................................................1303 25.1 Individual Tobacco Types .......................................................................................................................1304 25.2 Extracts from Tobacco ............................................................................................................................1308 25.3 Individual Tobacco Components .............................................................................................................1311 25.3.1 Nicotine ......................................................................................................................................1312 25.3.2 Organic Solvent-Soluble Components (Long-Chained Aliphatic Hydrocarbons, Phytosterols, Solanesol, High-Molecular-Weight Esters, etc.) ...................................................1314 25.3.3 Structural Components of Tobacco (Cellulose, Lignin, Pectins, etc.) ........................................1321 25.3.4 Acids ..........................................................................................................................................1326 25.3.5 Proteins and Amino Acids ........................................................................................................1327 25.4 Tobacco Additives ..................................................................................................................................1330 25.4.1 Additives Used in Tobacco Production .....................................................................................1330 25.4.1.1 Sucker Growth Inhibitors ..........................................................................................1330 25.4.1.2 Pesticides ....................................................................................................................1333 25.4.2 Additives Used in Cigarette Manufacture ..................................................................................1335 25.4.2.1 Casing Materials (Sugars, Cocoa, Licorice) ...............................................................1335 25.4.2.2 Humectants (Glycerol, Propylene Glycol) .................................................................1336 25.5 Cigarette Construction Materials (Paper, Adhesives, etc.) .....................................................................1337 25.6 Flavoring Ingredients .............................................................................................................................1339 Chapter 26 Carcinogens, Tumorigens, and Mutagens vs. Anticarcinogens, Inhibitors, and Antimutagens .........................1371 26.1 Carcinogens, Tumorigens, and Mutagens ................................................................................................1371 26.1.1 Polycyclic Aromatic Hydrocarbons ...........................................................................................1380 26.1.2 Other Classes of Carcinogens, Tumorigens, and Mutagens ......................................................1384 26.1.2.1 Aza-Arenes ................................................................................................................1384 26.1.2.2 N-Nitrosamines ..........................................................................................................1387 26.1.2.3 /V-Heterocyclic Amines .............................................................................................1387 26.2 Anticarcinogens, Inhibitors, and Antimutagens .....................................................................................1390 26.2.1 Alternate Exposures to Carcinogens, Tumorigens, and Mutagens ............................................1430 26.2.1.1 Alternate Exposures to Polycyclic Aromatic Hydrocarbons ......................................1430 26.2.1.2 Alternate Exposures to Aza-Arenes ...........................................................................1434 26.2.1.3 Alternate Exposures to N-Nitrosamines .....................................................................1434 26.2.1.4 Alternate Exposures to Af-Heterocyclic Amines ........................................................1441 26.3 Summary ................................................................................................................................................1444 Chapter 27 Free Radicals .....................................................................................................................................................1447 27.1 Introduction ............................................................................................................................................1447 27.2 Analytical Methods for Determination of Free Radicals .......................................................................1448 27.3 Free Radicals in Tobacco Smoke ...........................................................................................................1449 27.4 Historical Review of Free-Radical Research on Cigarette Smoke .........................................................1449 27.5 Proposed Mechanism for the Generation of Free Radicals in MSS .......................................................1462 Contents ¡x Chapter 28 Summary ............................................................................................................................................................1471 Bibliography ...........................................................................................................................................................................1475 Alphabetical Component Index ...................................................................................................................................................1713 Sequence of CAS Registry Numbers ...................................................................................................................................2065 THE CHEMICAL COMPONENTS OF TOBACCO ANO TOBACCO SMOKE SECOND EDITION Authored by two longtime researchers in tobacco science, The Chemical Components of Tobacco and Tobacco Smoke, Second Edition chronicles the progress made from late 2008 through 2011 by scientists in the field of tobacco science. The book examines the isolation and characterization of each component. It explores developments in pertinent analytical technology and results of experimental studies on biological activity, toxicity, and tumorigenicity, including the inhibition of adverse biological activity of one specific tobacco smoke component by another tobacco smoke component. Adding to the progress reported in the First Edition, the comprehensive Second Edition provides nearly 7,000 references on almost 9,600 components. The authors discuss the controversies over the extrapolation of the biological effect of a specific component adminis¬ tered individually by one route versus its biological effect when the component is in a highly complex mixture and is administered by a different route. They also cite studies in which cigarette design technologies were developed to control the per-cigarette mainstream smoke yield of Federal Trade Commission-defined tar and one or more specific tobacco smoke components of concern. New in the Second Edition: • Approximately 1,000 newly reported components have been inserted and several dozen duplicates have been deleted from various tables and from the Alphabetical Index • Improved and sharper chemical structures • Insertion of new pertinent references for the components in each of the major chapter tables devoted to a particular functional component • Updated Index organized by the CAS Registry Number listing of the components • Updated discussions in the Introduction and at the beginning of each chapter • A searchable companion CD-ROM containing the 350-page alphabetical Component Index Authors Alan Rodgman and Thomas A. Perfetti were jointly awarded the 2010 CORESTA (Cooperative Centre for Scientific Research Relative to Tobacco) Prize for their extensive work on documenting the vast literature on the chemical composition of tobacco and tobacco smoke in their original edition.
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spelling	Rodgman, Alan Verfasser aut The chemical components of tobacco and tobacco smoke Alan Rodgman ; Thomas A. Perfetti 2. ed. Boca Raton [u.a.] CRC Press 2013 XCIII, 2238 S. 1 CD-ROM (12 cm) txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Tobacco Composition Tobacco smoke Composition Chemie (DE-588)4009816-3 gnd rswk-swf Tabakrauch (DE-588)4184300-9 gnd rswk-swf Tabak (DE-588)4136670-0 gnd rswk-swf Tabak (DE-588)4136670-0 s Chemie (DE-588)4009816-3 s DE-604 Tabakrauch (DE-588)4184300-9 s Perfetti, Thomas A. Sonstige oth Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025905423&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Klappentext Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025905423&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Rodgman, Alan The chemical components of tobacco and tobacco smoke Tobacco Composition Tobacco smoke Composition Chemie (DE-588)4009816-3 gnd Tabakrauch (DE-588)4184300-9 gnd Tabak (DE-588)4136670-0 gnd
subject_GND	(DE-588)4009816-3 (DE-588)4184300-9 (DE-588)4136670-0
title	The chemical components of tobacco and tobacco smoke
title_auth	The chemical components of tobacco and tobacco smoke
title_exact_search	The chemical components of tobacco and tobacco smoke
title_full	The chemical components of tobacco and tobacco smoke Alan Rodgman ; Thomas A. Perfetti
title_fullStr	The chemical components of tobacco and tobacco smoke Alan Rodgman ; Thomas A. Perfetti
title_full_unstemmed	The chemical components of tobacco and tobacco smoke Alan Rodgman ; Thomas A. Perfetti
title_short	The chemical components of tobacco and tobacco smoke
title_sort	the chemical components of tobacco and tobacco smoke
topic	Tobacco Composition Tobacco smoke Composition Chemie (DE-588)4009816-3 gnd Tabakrauch (DE-588)4184300-9 gnd Tabak (DE-588)4136670-0 gnd
topic_facet	Tobacco Composition Tobacco smoke Composition Chemie Tabakrauch Tabak
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work_keys_str_mv	AT rodgmanalan thechemicalcomponentsoftobaccoandtobaccosmoke AT perfettithomasa thechemicalcomponentsoftobaccoandtobaccosmoke

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