Modeling and prediction of polymer nanocomposite properties:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH-Verl.
2013
|
| Schriftenreihe: | Polymer nano-, micro- & macrocomposites
4 |
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XVI, 298 S. Ill., graph. Darst. 25 cm |
| ISBN: | 9783527331505 3527331506 |
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| 245 | 1 | 0 | |a Modeling and prediction of polymer nanocomposite properties |c ed. by Vikas Mittal |
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Datensatz im Suchindex
| _version_ | 1807955451369750528 |
|---|---|
| adam_text |
IMAGE 1
CONTENTS
LIST O F CONTRIBUTORS X I PREFACE X V
1 CONVERGENCE O F EXPERIMENTAL AND MODELING STUDIES 1 VIKAS MITT A I 1.1
INTRODUCTION 1
1.2 REVIEW O F VARIOUS MODEL SYSTEMS 1
REFERENCES 10
2 SELF-CONSISTENT FIELD THEORY MODELING O F POLYMER NANOCOMPOSITES 11
VALERIY V. GINZBURG
2.1 INTRODUCTION 11
2.2 THEORETICAL METHODS 13
2.2.1 INCOMPRESSIBLE SCFT 13
2.2.2 COMPRESSIBLE SCFT 17
2.3 APPLICATIONS O F SCFT MODELING: PREDICTING THE NANOCOMPOSITE PHASE
BEHAVIOR 18 2.3.1 ORGANICALLY MODIFIED NANOCLAYS I N A HOMOPOLYMER
MATRIX 18 2.3.2 ORGANICALLY MODIFIED NANOCLAYS I N A BINARY BLEND
CONTAINING END-
FUNCTIONALIZED POLYMERS 24 2.4 SUMMARY A N D OUTLOOK 3 2
ACKNOWLEDGMENTS 33 REFERENCES 33
3 MODERN EXPERIMENTAL AND THEORETICAL ANALYSIS METHODS O F
PARTICULATEFILLED NANOCOMPOSITES STRUCTURE 39 CEORGII V. KOZLOV, YURII
C. YANOVSKII, AND CENNADII E. ZAIKOV 3.1 INTRODUCTION 39
3.2 EXPERIMENTAL 4 0
3.3 RESULTS A N D DISCUSSION 42
3.4 CONCLUSIONS 60
REFERENCES 61
HTTP://D-NB.INFO/1024048217
IMAGE 2
V I | CONTENTS
4 REPTATION MODEL FOR THE DYNAMICS AND RHEOLOGY O F PARTICLE
REINFORCED POLYMER CHAINS 63 KALONJI K. KABANEMI ANDJEAN-FRANQOIS HDTU
4.1 INTRODUCTION 63
4.2 TERMINAL RELAXATION TIME 66
4.2.1 LINEAR ENTANGLED CHAINS 66
4.2.2 LINEAR ENTANGLED CHAINS WITH RIGID SPHERICAL NANOPARTIDES 66 4.3
DETACHMENT/REATTACHMENT DYNAMICS 72 4.4 CONSTITUTIVE EQUATION 74
4.5 NUMERICAL RESULTS 75
4.5.1 STEP SHEAR STRAIN 75
4.5.2 STEADY SHEAR FLOW 78
4.5.3 START-UP O F STEADY SHEAR FLOW 84
4.5.4 EXPERIMENTAL VALIDATION 8 5
4.6 DISCUSSION A N D GENERALIZATION O F THE MODEL 88
4.6.1 PRELIMINARIES 88
4.6.2 DIFFUSION O F A N ATTACHED CHAIN 89
4.6.3 MULTIMODE CONSTITUTIVE EQUATION 91 4.7 CONCLUSIONS 92
REFERENCES 93
5 MULTISCALE MODELING APPROACH FOR POLYMERIC NANOCOMPOSITES 95 PAOLA
POSOCCO, SABRINA PRICL, AND MAURIZIO FERMEGLIA 5.1 MULTISCALE MODELING O
F POLYMER-BASED NANOCOMPOSITE MATERIALS:
TOWARD "VIRTUAL DESIGN" 95 5.2 ATOMISTIC SCALE: BASIC INSTINCTS 101
5.2.1 SODIUM MONTMORILLONITE SILYLATION: UNEXPECTED EFFECT O F T H E
AMINOSILANE CHAIN LENGTH 101 5.2.2 WATER-BASED
MONTMORILLONITE/POLY(ETHYLENE OXIDE) NANOCOMPOSITES: A MOLECULAR
VIEWPOINT 106
5.3 MESOSCALE: CONNECTING STRUCTURE TO PROPERTIES 109 5.3.1 WATER-BASED
MONTMORILLONITE/POLY(ETHYLENE OXIDE) NANOCOMPOSITES AT THE MESOSCALE 109
5.3.2 NANOPARTIDES AT T H E RIGHT PLACE: TUNING NANOSTRUCTURE
MORPHOLOGY O F SELF-ASSEMBLED NANOPARTIDES I N DIBLOCK COPOLYMERS 112
5.4 MACROSCALE: WHERE IS THE DETAIL? THE MATTER AT C O N T I N U U M 119
5.4.1 SMALL IS DIFFERENT. SIZE A N D SHAPE EFFECTS O F NANOPARTIDES
O N THE ENHANCEMENT EFFICIENCY IN PCNS 119 5.5 CONCLUSIONS 123
REFERENCES 125
IMAGE 3
CONTENTS J V I I
6 MODELING O F OXYGEN PERMEATION AND MECHANICAL PROPERTIES O F
POLYPROPYLENE-LAYERED SILICATE NANOCOMPOSITES USING DOE DESIGNS 129
VIKAS MITT A I 6.1 INTRODUCTION 129
6.2 MATERIALS A N D METHODS 131
6.2.1 MATERIALS 131
6.2.2 FILLER SURFACE MODIFICATION A N D COMPOSITE PREPARATION 131 6.2.3
CHARACTERIZATION A N D MODELING TECHNIQUES 131 6.3 RESULTS A N D
DISCUSSION 132
6.4 CONCLUSIONS 141
ACKNOWLEDGMENT 141 REFERENCES 141
7 MULTISCALE STOCHASTIC FINITE ELEMENTS MODELING O F POLYMER
NANOCOMPOSITES 143 ANTONIOS KONTSOS AND JEFFERSON A. CUACSRA 7.1
INTRODUCTION 143
7.2 MULTISCALE STOCHASTIC FINITE ELEMENTS METHOD 144 7.2.1 MODELING
STATE-OF-THE-ART A N D MSFEM MOTIVATION 144 7.2.2 DEFINITION O F A
REPRESENTATIVE MATERIAL REGION (MR) 145 7.2.3 SPATIAL RANDOMNESS
IDENTIFICATION 146 7.2.4 MULTISCALE HOMOGENIZATION MODEL 148 7.2.5 MONTE
CARLO FINITE ELEMENT MODEL 152 7.3 APPLICATIONS A N D RESULTS 153
7.3.1 ESTIMATION O F BULK MECHANICAL PROPERTIES 153 7.3.2 MODELING O F
NANOINDENTATION DATA 161 REFERENCES 165
8 MODELING O F THERMAL CONDUCTIVITY O F POLYMER NANOCOMPOSITES 169 WEI
LIN 8.1 MODELS FOR THERMAL CONDUCTIVITY O F POLYMER C O M P O S I T E S
- A HISTORICAL REVIEW O N EFFECTIVE M E D I U M APPROXIMATIONS AND
MICROMECHANICAL
MODELS 169
8.1.1 PARALLEL A N D SERIES MODELS 170
8.1.2 MAXWELL'S MODEL (MAXWELL-GARNETT EQUATION) 172 8.1.3 FRICKE'S
MODEL 172
8.1.4 HAMILTON-CROSSER MODEL 174
8.1.5 HASHIN'S MODEL 175
8.1.6 NIELSEN'S MICROMECHANICS MODEL 176 8.1.7 EQUIVALENT INCLUSION
METHOD 178 8.1.8 BENVENISTE-MILOH MODEL 180 8.1.9 DAVIS' MODEL 182
8.1.10 EMPIRICAL MODEL BY AGARI A N D U N O 182 8.1.11 HASSELMAN-JOHNSON
MODEL 183
IMAGE 4
V I I I | CONTENTS
8.1.12 BRUGGEMAN ASYMMETRIC EQUATION 183
8.1.13 FELSKE'S MODEL 185
8.2 A GENERALIZED EFFECTIVE MEDIUM THEORY 186 8.2.1 ATA 187
8.2.2 CPA 188
8.2.3 FURTHER EXTENSION O F ATA A N D CPA TO ANISOTROPIC FILLER WITH
ORIENTATION DISTRIBUTIONS 189 8.2.4 INCORPORATION O F SIZE DISTRIBUTION
FUNCTIONS INTO ATA A N D CPA 190 8.2.5 INCORPORATION O F INTERFACIAL
THERMAL RESISTANCE INTO ATA A N D CPA 191 8.3 CHALLENGES FOR MODELING
THERMAL CONDUCTIVITY O F POLYMER
NANOCOMPOSITES 191 8.3.1 SIZE EFFECT A N D SURFACE EFFECT 191 8.3.2
SENSITIVITY O F K F TO A SPECIFIC ENVIRONMENT 192 8.3.3 INTERFACIAL
RESISTANCE PLAYS A VERY IMPORTANT ROLE 193
8.3.4 FILLER-INDUCED CHANGE I N K " M 195 8.3.5 DISPERSION A N D
DISTRIBUTION 196 ACKNOWLEDGMENTS 196 REFERENCES 197
9 NUMERICAL-ANALYTICAL MODEL FOR NANOTUBE-REINFORCED NANOCOMPOSITES 201
ANTONIO PANTANO 9.1 INTRODUCTION 201
9.2 NUMERICAL-ANALYTICAL MODEL 204
9.2.1 THE MORI-TANAKA METHOD 204
9.2.1.1 CALCULATION O F T H E CORRELATION MATRIX A? 1' 206 9.2.1.2
CALCULATION O F THE STIFFNESS MATRIX O F THE EQUIVALENT INCLUSION Q 207
9.2.2 FEM MODEL DESIGN 207
9.2.2.1 RVE GEOMETRY 207 9.2.2.2 MATRIX CONSTITUTIVE MODEL 208 9.2.2.3
CARBON NANOTUBE 208 9.2.2.4 CONTACT MODEL 208
9.2.2.5 DEFORMATION MODE 209 9.2.2.6 CALCULATION O F THE EQUIVALENT
YOUNG'S MODULUS O F THE MWCNT 209 9.2.2.7 CALCULATION O F THE ESHELBY
TENSOR 209 9.3 RESULTS 210
9.4 CONCLUSIONS 212
APPENDIX 9.A 212 REFERENCES 213
10 DISSIPATIVE PARTICLES DYNAMICS MODEL FOR POLYMER NANOCOMPOSITES 215
SHIN-PON JU, YAO-CHUN WANG, AND WEN-JAY LEE 10.1 INTRODUCTION 215
10.2 SCHEME FOR MULTISCALE MODELING 218
IMAGE 5
CONTENTS I X
10.2.1 DISSIPATIVE PARTICLE DYNAMICS SIMULATION METHOD 219
10.2.2 COARSE-GRAINED MAPPING 219 10.2.3 MIXING ENERGY A N D
COMPRESSIBILITY 220 10.2.4 DISSIPATIVE PARTICLE DYNAMICS SCALES TO
PHYSICAL SCALES 222 10.3 TWO CASE STUDIES 222
10.3.1 PE/PLLA COMPOSITE 222 10.3.2 CNT/PE/PLLA COMPOSITE 228 10.4
FUTURE WORK 234
REFERENCES 234
11 COMPUTER-AIDED PRODUCT DESIGN O F WHEAT STRAW POLYPROPYLENE
COMPOSITES 237 ROIS FATONI, ALI ALMANSOORI, ALI ELKAMEL, A N D LEONARDO
SIMON 11.1 NATURAL FIBER PLASTIC COMPOSITES 237
11.1.1 HISTORY A N D CURRENT MARKET SITUATION 237 11.1.2 TECHNICAL
ISSUES A N D CURRENT RESEARCH PROGRESS 238 11.2 WHEAT STRAW
POLYPROPYLENE COMPOSITES 240 11.3 PRODUCT DESIGN A N D COMPUTER-AIDED
PRODUCT DESIGN 242 11.4 MODELING NATURAL FIBER POLYMER COMPOSITES 245
11.5 MIXTURE DESIGN O F EXPERIMENTS 247
REFERENCES 252
12 MODELING O F THE CHEMORHEOLOGICAL BEHAVIOR O F THERMOSETTING POLYMER
NANOCOMPOSITES 255 LUIGI TORRE, DEBORA PUGLIA, ANTONIO LANNONI, AND
ANDREA TERENZI 12.1 INTRODUCTION 255
12.2 T H E CURE KINETICS MODEL 258
12.3 THE CHEMOVISCOSITY MODEL 263
12.4 RELATIONSHIP BETWEEN T G A N D A 268
12.5 CASE STUDY 1: CARBON NANOFIBERS I N UNSATURATED POLYESTER 268
12.5.1 CURE KINETIC ANALYSIS 271 12.5.2 CHEMORHEOLOGICAL ANALYSIS 275
12.6 CASE STUDY 2: MONTMORILLONITE I N EPOXY RESIN 277 12.6.1 CURE
KINETIC ANALYSIS 279 12.6.2 RELATION BETWEEN T G A N D DEGREE O F CURE
281
12.6.3 CHEMORHEOLOGICAL ANALYSIS 282 REFERENCES 285
INDEX 289 |
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| publishDate | 2013 |
| publishDateSearch | 2013 |
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| publisher | Wiley-VCH-Verl. |
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| series | Polymer nano-, micro- & macrocomposites |
| series2 | Polymer nano-, micro- & macrocomposites |
| spelling | Modeling and prediction of polymer nanocomposite properties ed. by Vikas Mittal Weinheim Wiley-VCH-Verl. 2013 XVI, 298 S. Ill., graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Polymer nano-, micro- & macrocomposites Vol. 4 Literaturangaben Nanokomposit (DE-588)4768127-5 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Polymere (DE-588)4046699-1 s Nanokomposit (DE-588)4768127-5 s DE-604 Mittal, Vikas (DE-588)140061096 edt Polymer nano-, micro- & macrocomposites 4 (DE-604)BV040393302 4 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4071685&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025883714&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Modeling and prediction of polymer nanocomposite properties Polymer nano-, micro- & macrocomposites Nanokomposit (DE-588)4768127-5 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4768127-5 (DE-588)4046699-1 |
| title | Modeling and prediction of polymer nanocomposite properties |
| title_auth | Modeling and prediction of polymer nanocomposite properties |
| title_exact_search | Modeling and prediction of polymer nanocomposite properties |
| title_full | Modeling and prediction of polymer nanocomposite properties ed. by Vikas Mittal |
| title_fullStr | Modeling and prediction of polymer nanocomposite properties ed. by Vikas Mittal |
| title_full_unstemmed | Modeling and prediction of polymer nanocomposite properties ed. by Vikas Mittal |
| title_short | Modeling and prediction of polymer nanocomposite properties |
| title_sort | modeling and prediction of polymer nanocomposite properties |
| topic | Nanokomposit (DE-588)4768127-5 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Nanokomposit Polymere |
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