Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online-Zugang: | kostenfrei kostenfrei Inhaltsverzeichnis |
| Beschreibung: | VIII, 213 Bl. graph. Darst. |
Internformat
MARC
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| 245 | 1 | 0 | |a Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains |c Hui Shi |
| 264 | 1 | |c 2012 | |
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Datensatz im Suchindex
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| adam_text | IMAGE 1
TABLE O F CONTENTS
TABLE OF CONTENTS
ACKNOWLEDGEMENTS I
ABSTRACT..... III
TABLE OF CONTENTS IV
CHAPTER 1
INTRODUCTION 1 I 4
1.1. GENERAL BACKGROUND 2
1.2. RING OPENING ON ACIDIC CATALYSTS 6
1.3. RING OPENING VIA AFUNCTIONAL CATALYSIS 6
1.3.1. RING OPENING OF BICYCLIC AND MONOCYCLIC HYDROCARBONS ON
AFUNCTIONAL
CATALYSTS 7
1.3.2. FUNDAMENTAL CONSIDERATIONS 8
1.4. HYDROGENOLYSIS O F ALKANES AND CYCLOALKANES ON NOBLE METALS 13
1.4.1. RING OPENING OF FIVE-MEMBERED NAPHTHENES ON MONOFUNCTIONAL METAL
CATALYSTS 14
1.4.2. RING OPENING OF SIX-MEMBERED NAPHTHENES ON MONOFUNCTIONAL METAL
CATALYSTS AND MODEL SURFACES 16
1.5. SCOPE O F THIS THESIS 18
1.6. REFERENCES 21
CHAPTER 2
CATALYTIC CONSEQUENCES O F PARTICLE SIZE AND ELECTRONIC PROPERTIES OF
SUPPORTED PT CLUSTERS IN THE RING OPENING O F CYCLOPENTANE ON PT/AL 2
C 3
24
2.1. INTRODUCTION 25
- IV -
HTTP://D-NB.INFO/1036385795
IMAGE 2
TABLE O F CONTENTS
2.2. EXPERIMENTAL 26
2.2.1. CATALYST PREPARATION 26
2.2.2. CATALYST CHARACTERIZATION 27
2.2.3. KINETIC MEASUREMENTS 28
2.3. RESULTS AND DISCUSSIONS 30
2.3.1. PARTICLE SIZE AND DISPERSION MEASUREMENTS 30
2.3.2. CATALYTIC ACTIVITY IN THE RING OPENING OF CYCLOPENTANE 35
2.3.3. UNDERSTANDING THE EFFECT OF PT PRECURSOR ON RING OPENING ACTIVITY
BY
PROBING THE ELECTRONIC STATES OF SMALL PT CLUSTERS 44
. 2.3.4. EFFECT OF CI: ON THE ACTIVATION BARRIER OR ON THE REACTANT
COVERAGE? 49
2.3.5. ORIGIN(S) OF THE ANTIPATHETIC STRUCTURE SENSITIVITY 52
2.3.6. RESOLVING THE DISCREPANCIES IN THE OBSERVED STRUCTURE SENSITIVITY
BETWEEN
THE LITERATURE AND THIS WORK 55
2.4. CONCLUSIONS 56
2.5. ACKNOWLEDGEMENTS 57
2.6. APPENDIX 58
2.7. REFERENCES 61
CHAPTER 3
ON THE ACTIVE SITES AND REACTIVE INTERMEDIATES IN THE HYDROGENOLYTIC
CLEAVAGE OF C-C BONDS IN CYCLOHEXANE OVER SUPPORTED IRIDIUM CLUSTERS
64
3.1. INTRODUCTION 65
3.2. EXPERIMENTAL 67
3.2.1. CATALYST PREPARATION 67
3.2.2. CATALYST CHARACTERIZATION 68
3.2.3. STEADY STATE KINETIC MEASUREMENTS 70
3.3. RESULTS 71
- V -
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| spelling | Shi, Hui 1983- Verfasser (DE-588)1033340650 aut Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains Hui Shi 2012 VIII, 213 Bl. graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2012 Hydrogenolyse (DE-588)4160911-6 gnd rswk-swf Cycloalkane (DE-588)4148484-8 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Cycloalkane (DE-588)4148484-8 s Hydrogenolyse (DE-588)4160911-6 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:91-diss-20121213-1127957-0-6 https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121213-1127957-0-6 Resolving-System kostenfrei Volltext http://mediatum.ub.tum.de/node?id=1127957 Verlag kostenfrei Volltext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025872072&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Shi, Hui 1983- Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains Hydrogenolyse (DE-588)4160911-6 gnd Cycloalkane (DE-588)4148484-8 gnd |
| subject_GND | (DE-588)4160911-6 (DE-588)4148484-8 (DE-588)4113937-9 |
| title | Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains |
| title_auth | Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains |
| title_exact_search | Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains |
| title_full | Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains Hui Shi |
| title_fullStr | Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains Hui Shi |
| title_full_unstemmed | Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains Hui Shi |
| title_short | Structural requirements and reaction pathways of hydrogenolytic C-C bond cleavage in naphthenes over supported platinum and iridium domains |
| title_sort | structural requirements and reaction pathways of hydrogenolytic c c bond cleavage in naphthenes over supported platinum and iridium domains |
| topic | Hydrogenolyse (DE-588)4160911-6 gnd Cycloalkane (DE-588)4148484-8 gnd |
| topic_facet | Hydrogenolyse Cycloalkane Hochschulschrift |
| url | https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121213-1127957-0-6 http://mediatum.ub.tum.de/node?id=1127957 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025872072&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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