Structure and transition behavior of novel thermo-responsive polymer films:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
|
| Schlagworte: | |
| Online-Zugang: | kostenfrei https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121214-1120910-0-0 Inhaltsverzeichnis |
| Beschreibung: | III, III, 140 S. Ill., graph. Darst. |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV040791485 | ||
| 003 | DE-604 | ||
| 005 | 20150324 | ||
| 007 | t | ||
| 008 | 130301s2012 ad|| m||| 00||| eng d | ||
| 035 | |a (OCoLC)835309300 | ||
| 035 | |a (DE-599)BVBBV040791485 | ||
| 040 | |a DE-604 |b ger |e rakwb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-384 |a DE-473 |a DE-703 |a DE-1051 |a DE-824 |a DE-29 |a DE-12 |a DE-91 |a DE-19 |a DE-1049 |a DE-92 |a DE-739 |a DE-898 |a DE-355 |a DE-706 |a DE-20 |a DE-1102 | ||
| 084 | |a WER 410d |2 stub | ||
| 084 | |a WER 659d |2 stub | ||
| 084 | |a WER 000d |2 stub | ||
| 084 | |a PHY 600d |2 stub | ||
| 100 | 1 | |a Zhong, Qi |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Structure and transition behavior of novel thermo-responsive polymer films |c Qi Zhong |
| 264 | 1 | |c 2012 | |
| 300 | |a III, III, 140 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a München, Techn. Univ., Diss., 2012 | ||
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |o urn:nbn:de:bvb:91-diss-20121214-1120910-0-0 |
| 856 | 4 | 1 | |u http://mediatum.ub.tum.de/node?id=1120910 |x Verlag |z kostenfrei |3 Volltext |
| 856 | 4 | |u https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121214-1120910-0-0 |x Resolving-System | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025769609&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 912 | |a ebook | ||
| 999 | |a oai:aleph.bib-bvb.de:BVB01-025769609 | ||
Datensatz im Suchindex
| _version_ | 1804150123816550400 |
|---|---|
| adam_text | IMAGE 1
CONTENTS
1 INTRODUCTION 1
2 THEORETICAL BACKGROUND 5
2.1 HOMOPOLYMERS AND BLOCK COPOLYMERS 5
2.1.1 MICROPHASE SEPARATION 5
2.1.2 BLOCK COPOLYMERS IN SOLUTION 8
2.1.3 BLOCK COPOLYMERS ON SURFACE 9
2.2 THERMO-RESPONSIVE POLYMERS 11
2.2.1 PHASE SEPARATION OF THERMO-RESPONSIVE POLYMERS 11
2.2.2 TRANSITION BEHAVIOR OF THERMO-RESPONSIVE POLYMERS 13
2.2.3 EFFECTS INFLUENCING TRANSITION BEHAVIOR 15
2.3 SCATTERING METHODS 17
2.3.1 BASIC PRINCIPLE 17
2.3.2 X-RAY REFLECTIVITY (XRR) 19
2.3.3 NEUTRON REFLECTIVITY (NR) 23
2.3.4 SMALL-ANGLE SCATTERING (SAS) 24
2.3.5 GRAZING INCIDENCE SMALL-ANGLE X-RAY SCATTERING (GISAXS) 28
3 SAMPLES AND EXPERIMENTAL METHODS 31
3.1 SAMPLE SYSTEM 31
3.1.1 HOMOPOLYMER PMDEGA 31
3.1.2 TRI-BLOCK COPOLYMER P(S-6-MDEGA-6-S) 32
3.2 SAMPLE PREPARATION 33
3.2.1 SPIN COATING 33
3.2.2 SOLUTION CASTING 34
3.3 MEASUREMENT METHOD 35
3.3.1 OPTICAL MICROSCOPY 35
I
HTTP://D-NB.INFO/1032145978
IMAGE 2
II CONTENTS
3.3.2 ATOMIC FORCE MICROSCOPY 35
3.3.3 WHITE LIGHT INTERFEROMETRY 37
3.3.4 X-RAY REFLECTIVITY (XRR) 38
3.3.5 SMALL-ANGLE X-RAY SCATTERING (SAXS) 39
3.3.6 SMALL-ANGLE NEUTRON SCATTERING (SANS) 40
3.3.7 GRAZING INCIDENCE SMALL-ANGLE X-RAY SCATTERING (GISAXS) 40
3.3.8 NEUTRON REFLECTIVITY 41
3.3.9 ATR-FTIR 44
4 THIN P M D E G A FILMS 4 7
4.1 STRUCTURAL INVESTIGATION OF THIN PMDEGA FILMS 47
4.1.1 SURFACE STRUCTURE OF THIN PMDEGA FILMS 48
4.1.2 INTERNAL STRUCTURE OF THIN PMDEGA FILMS 51
4.2 SWELLING BEHAVIOR OF THIN PMDEGA FILMS 52
4.2.1 SWELLING CAPABILITY OF THIN PMDEGA FILMS 52
4.2.2 SWELLING OF THIN PMDEGA FILMS PROBED BY NEUTRON REFLECTIVITY . . .
54
4.3 PHASE TRANSITION BEHAVIOR OF THIN PMDEGA FILMS 58
4.3.1 TRANSITION BEHAVIOR PROBED BY WHITE LIGHT INTERFEROMETRY 58
4.3.2 TRANSITION BEHAVIOR UNDER A SUDDEN THERMAL STIMULUS 61
4.4 BOUND WATER IN PMDEGA FILMS 64
4.5 SUMMARY 66
5 THIN P(S-6-MDEGA-6-S) FILMS 69
5.1 STRUCTURAL INVESTIGATION OF P(S-6-MDEGA-6-S) FILMS 70
5.1.1 SURFACE STRUCTURE OF THIN P(S-6-MDEGA-6-S) FILMS 70
5.1.2 INTERNAL STRUCTURE OF THIN P(S-6-MDEGA-6-S) FILMS 73
5.2 SWELLING BEHAVIOR OF THIN P(S-6-MDEGA-6-S) FILMS 76
5.2.1 SWELLING CAPABILITY PROBED BY WHITE LIGHT INTERFEROMETRY 76
5.2.2 SWELLING BEHAVIOR PROBED BY NEUTRON REFLECTIVITY 78
5.3 PHASE TRANSITION BEHAVIOR OF THIN P(S-6-MDEGA- B-S) FILMS 81
5.3.1 TRANSITION BEHAVIOR PROBED BY WHITE LIGHT INTERFEROMETRY 82
5.3.2 TRANSITION BEHAVIOR UNDER A SUDDEN THERMAL STIMULUS 83
5.4 BOUND WATER IN P(S-6-MDEGA-6-S) FILMS 87
5.5 SUMMARY 88
IMAGE 3
CONTENTS III
6 THICK P (S- 6-MDEGA- B-S) FILMS 91
6.1 FILMS FROM PMDEGA-SELECTIVE SOLVENTS PROBED BY SAXS 92
6.1.1 INTERNAL STRUCTURE OF FILMS FROM PMDEGA-SELECTIVE SOLVENTS . . . .
93
6.1.2 TRANSITION BEHAVIOR OF FILMS FROM PMDEGA-SELECTIVE SOLVENTS . . .
95
6.2 FILMS FROM PS-SELECTIVE SOLVENTS PROBED BY SAXS 100
6.2.1 INTERNAL STRUCTURE OF FILMS FROM PS-SELECTIVE SOLVENT 100
6.2.2 TRANSITION BEHAVIOR OF FILMS FROM PS-SELECTIVE SOLVENTS 102
6.3 TRANSITION BEHAVIOR OF FILMS PROBED BY SANS 108
6.3.1 TRANSITION BEHAVIOR OF FILMS FROM ETHANOL 108
6.3.2 TRANSITION BEHAVIOR OF FILMS FROM THF 110
6.4 SUMMARY I L L
7 SUMMARY AND OUTLOOK 113
BIBLIOGRAPHY 117
LIST O F PUBLICATIONS 135
ACKNOWLEDGMENTS 139
|
| any_adam_object | 1 |
| author | Zhong, Qi |
| author_facet | Zhong, Qi |
| author_role | aut |
| author_sort | Zhong, Qi |
| author_variant | q z qz |
| building | Verbundindex |
| bvnumber | BV040791485 |
| classification_tum | WER 410d WER 659d WER 000d PHY 600d |
| collection | ebook |
| ctrlnum | (OCoLC)835309300 (DE-599)BVBBV040791485 |
| discipline | Physik Werkstoffwissenschaften |
| format | Thesis Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01598nam a2200373 c 4500</leader><controlfield tag="001">BV040791485</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20150324 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">130301s2012 ad|| m||| 00||| eng d</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)835309300</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV040791485</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-384</subfield><subfield code="a">DE-473</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-1051</subfield><subfield code="a">DE-824</subfield><subfield code="a">DE-29</subfield><subfield code="a">DE-12</subfield><subfield code="a">DE-91</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-1049</subfield><subfield code="a">DE-92</subfield><subfield code="a">DE-739</subfield><subfield code="a">DE-898</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-706</subfield><subfield code="a">DE-20</subfield><subfield code="a">DE-1102</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">WER 410d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">WER 659d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">WER 000d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">PHY 600d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zhong, Qi</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Structure and transition behavior of novel thermo-responsive polymer films</subfield><subfield code="c">Qi Zhong</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">III, III, 140 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="502" ind1=" " ind2=" "><subfield code="a">München, Techn. Univ., Diss., 2012</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4113937-9</subfield><subfield code="a">Hochschulschrift</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="776" ind1="0" ind2="8"><subfield code="i">Erscheint auch als</subfield><subfield code="n">Online-Ausgabe</subfield><subfield code="o">urn:nbn:de:bvb:91-diss-20121214-1120910-0-0</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://mediatum.ub.tum.de/node?id=1120910</subfield><subfield code="x">Verlag</subfield><subfield code="z">kostenfrei</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2=" "><subfield code="u">https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121214-1120910-0-0</subfield><subfield code="x">Resolving-System</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025769609&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ebook</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-025769609</subfield></datafield></record></collection> |
| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV040791485 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:33:55Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025769609 |
| oclc_num | 835309300 |
| open_access_boolean | 1 |
| owner | DE-384 DE-473 DE-BY-UBG DE-703 DE-1051 DE-824 DE-29 DE-12 DE-91 DE-BY-TUM DE-19 DE-BY-UBM DE-1049 DE-92 DE-739 DE-898 DE-BY-UBR DE-355 DE-BY-UBR DE-706 DE-20 DE-1102 |
| owner_facet | DE-384 DE-473 DE-BY-UBG DE-703 DE-1051 DE-824 DE-29 DE-12 DE-91 DE-BY-TUM DE-19 DE-BY-UBM DE-1049 DE-92 DE-739 DE-898 DE-BY-UBR DE-355 DE-BY-UBR DE-706 DE-20 DE-1102 |
| physical | III, III, 140 S. Ill., graph. Darst. |
| psigel | ebook |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| record_format | marc |
| spelling | Zhong, Qi Verfasser aut Structure and transition behavior of novel thermo-responsive polymer films Qi Zhong 2012 III, III, 140 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2012 (DE-588)4113937-9 Hochschulschrift gnd-content Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:91-diss-20121214-1120910-0-0 http://mediatum.ub.tum.de/node?id=1120910 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121214-1120910-0-0 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025769609&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Zhong, Qi Structure and transition behavior of novel thermo-responsive polymer films |
| subject_GND | (DE-588)4113937-9 |
| title | Structure and transition behavior of novel thermo-responsive polymer films |
| title_auth | Structure and transition behavior of novel thermo-responsive polymer films |
| title_exact_search | Structure and transition behavior of novel thermo-responsive polymer films |
| title_full | Structure and transition behavior of novel thermo-responsive polymer films Qi Zhong |
| title_fullStr | Structure and transition behavior of novel thermo-responsive polymer films Qi Zhong |
| title_full_unstemmed | Structure and transition behavior of novel thermo-responsive polymer films Qi Zhong |
| title_short | Structure and transition behavior of novel thermo-responsive polymer films |
| title_sort | structure and transition behavior of novel thermo responsive polymer films |
| topic_facet | Hochschulschrift |
| url | http://mediatum.ub.tum.de/node?id=1120910 https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121214-1120910-0-0 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025769609&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT zhongqi structureandtransitionbehaviorofnovelthermoresponsivepolymerfilms |