Carbohydrates - tools for stereoselective synthesis:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2013
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XVII, 376 S. graph. Darst. |
| ISBN: | 9783527323791 9783527654543 |
Internformat
MARC
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| 020 | |a 9783527654543 |c oBook |9 978-3-527-65454-3 | ||
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| 245 | 1 | 0 | |a Carbohydrates - tools for stereoselective synthesis |c ed. by Mike Martin Kwabena Boysen |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2013 | |
| 300 | |a XVII, 376 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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Datensatz im Suchindex
| _version_ | 1807955190448390144 |
|---|---|
| adam_text |
IMAGE 1
CONTENTS
FOREWORD X I
PREFACE X I I I
LIST O F CONTRIBUTORS XV
PART I CARBOHYDRATE AUXILIARIES 7
1 REACTIONS O F NUCLEOPHILES WITH ELECTROPHILES BOUND TO CARBOHYDRATE
AUXILIARIES 3 ZHIWEI MIAO
1.1 INTRODUCTION 3
1.2 STRECKER REACTIONS 3
1.3 UGI REACTIONS 8
1.4 ALLYLATIONS 1 3
1.5 MANNICH-TYPE REACTIONS 1 5
1.6 ADDITION O F PHOSPHITES 1 9
1.7 DYNAMIC KINETIC RESOLUTION O F A-CHLORO CARBOXYLIC ESTERS 22
REFERENCES 24
2 1,4-ADDITION O F NUCLEOPHILES T O A,|3-UNSATURATED CARBONYL COMPOUNDS
2 7
KIICHIRO TOTANI A N D KIN-ICHI TADANO 2.1 INTRODUCTION 2 7
2.2 1,4-ADDITIONS TO ACRYLIC AMIDES A N D ACRYLIC ESTERS 2 7 2.3
1,4-ADDITION TO 4- A N D 2-PYRIDONES 4 0
REFERENCES 4 5
3 REACTION O F ENOLATES 4 7
NOUREDDINE KHIAR, INMACULADA FEMDNDEZ, ANA ALCUDIA, MARIA VICTORIA
GARCIA AND ROCIO RECIO 3.1 INTRODUCTION 4 7
3.2 ALDOL ALKYLATION 4 8
3.3 ALDOL ADDITION 56
HTTP://D-NB.INFO/998577863
IMAGE 2
V I | CONTENTS
3.4 CONCLUDING REMARKS 6 0
REFERENCES 62
*4 CYCLOADDITIONS 65
MIKE M.K. BOYSEN
4.1 DIELS-ALDER REACTIONS 65
4.1.1 DIENOPHILES ATTACHED TO THE AUXILIARY 65 4.1.2 DIENES ATTACHED TO
THE AUXILIARY 8 3
4.2 1,3-DIPLOAR CYCLOADDITIONS 9 3
4.2.1 1,3-DIPOLES ATTACHED TO THE AUXILIARY 93
4.2.2 DIPOLAROPHILES ATTACHED TO T H E AUXILIARY 1 0 1 4.3 [2 + 2]
CYCLOADDITIONS 1 0 1
REFERENCES 1 0 4
5 CYCLOPROPANATION 707
NOUREDDINE KHIAR, INMACULADA FERNANDEZ, ANA ALCUDIA, MARIA VICTORIA
GARCIA A N D ROCIO REDO 5.1 INTRODUCTION 1 0 7
5.2 EPOXIDATION 1 1 3
5.3 CONSTRUCTION O F CHIRAL SULFUR A N D PHOSPHORUS CENTERS 1 1 7
5.4 CHIRAL PHOSPHORUS COMPOUNDS 1 2 0
5.5 CONCLUDING REMARKS 1 2 2
REFERENCES 1 2 3
PART II CARBOHYDRATE REAGENTS 725
6 HYDRIDE REDUCTIONS AND 1,2-ADDITIONS O F NUDEOPHILES T O CARBONYL
COMPOUNDS USING CARBOHYDRATE-BASED REAGENTS AND ADDITIVES 727 O M A R
BOUTUREIRA AND BENJAMIN G. DAVIS
6.1 INTRODUCTION 1 2 7
6.2 HYDRIDE REDUCTIONS 127
6.2.1 MODIFIED ALUMINOHYDRIDES 1 2 8 6.2.2 MODIFIED BOROHYDRIDES 1 2 9
6.3 1,2-ADDITIONS O F NUDEOPHILES TO CARBONYL COMPOUNDS 1 3 5
REFERENCES 1 4 0
7 ALDOL-TYPE REACTIONS 1 4 3
INMACULADA FERNDNDEZ, NOUREDDINE KHIAR, ANA ALCUDIA, MARIA VICTORIA
GARCIA A N D ROCIO REDO 7.1 INTRODUCTION 1 4 3
7.2 TITANIUM LEWIS ACIDS FOR ENOLATE FORMATION 1 4 3
IMAGE 3
CONTENTS | V I I
7.3 1,2-ADDITIONS O F NUCLEOPHILES TO CARBONYL COMPOUNDS USING
STOICHIOMETRIC REAGENTS 149 7.3.1 ALLYL-TITANIUM REAGENTS 1 4 9 7.3.2
ALLYLSILICON REAGENTS 1 5 1
REFERENCES 1 5 3
PART III CARBOHYDRATE LIGANDS 755
8 HYDROGENATION REACTIONS 757
CARMEN CLAVER, SERGIO CASTILLDN, MONTSERRAT DIIGUEZ AND OSCAR PDMIES 8.1
INTRODUCTION 1 5 7
8.2 HYDROGENATION O F C=C A N D C=N BONDS 1 5 8
8.2.1 HYDROGENATION O F C=C BONDS 1 5 8
8.2.2 HYDROGENATION O F C=N BONDS 1 5 8
8.3 P-DONOR LIGANDS 1 5 9
8.3.1 PHOSPHINITE LIGANDS 1 6 0
8.3.2 PHOSPHITE LIGANDS 1 6 6
8.3.3 PHOSPHINE LIGANDS INCLUDING MIXED DONOR LIGANDS 1 7 3
8.4 P - N DONORS 1 7 7
8.5 P - S DONORS 1 7 8
ACKNOWLEDGMENTS 1 8 0
REFERENCES 180
9 HYDROFORMYLATIONS, HYDROVINYLATIONS, AND HYDROCYANATIONS 7 83 MIKE
M.K. BOYSEN
9.1 HYDROFORMYLATION REACTIONS. 1 8 3
9.1.1 DIPHOSPHITE LIGANDS 1 8 4
9.1.2 DIPHOSPHINITE LIGANDS 1 9 8
9.1.3 DIPHOSPHINE LIGANDS 2 0 0
9.1.4 MIXED PHOSPHORUS DONOR A N D P-S DONOR LIGANDS 2 0 1
9.2 HYDROVINYLATION REACTIONS 2 0 2
9.2.1 MONOPHOSPHINITE A N D MONOPHOSPHITE LIGANDS 2 0 3
9.3 HYDROCYANATION REACTIONS 206
9.3.1 DIPHOSPHINITE LIGANDS 206
9.4 HYDROSILYLATION REACTIONS 2 1 1
9.4.1 MONOPHOSPHITE LIGANDS 2 1 1
9.4.2 DIPHOSPHITE A N D PHOSPHITE-PHOSPHOROAMIDITE LIGANDS 2 1 2
9.4.3 P-S DONOR LIGANDS 2 1 2
9.5 CONCLUSION 2 1 4
REFERENCES 2 1 5
IMAGE 4
V I I I I CONTENTS
10 CARBOHYDRATE-DERIVED LIGANDS IN ASYMMETRIC TSUJI-TROST
REACTIONS 2 7 7 MONTSERRAT DIEGUEZ AND OSCAR PDMIES 10.1 INTRODUCTION 2
1 7
10.2 LIGANDS 2 2 0
10.2.1 P-DONOR LIGANDS 2 2 0
10.2.1.1 PHOSPHINE LIGANDS 2 2 0
10.2.1.2 PHOSPHINITE LIGANDS 2 2 1
10.2.1.3 PHOSPHITE LIGANDS 2 2 3
10.2.1.4 PHOSPHOROAMIDITE LIGANDS 2 2 7
10.2.1.5 P-P'LIGANDS 2 2 8
10.2.2 S-DONOR LIGANDS 2 3 1
10.2.3 HETERODONOR LIGANDS 2 3 3
10.2.3.1 P-S LIGANDS 2 3 3
10.2.3.2 P-N LIGANDS 236
10.2.3.3 P - 0 LIGANDS 2 4 0
10.2.3.4 N-S LIGANDS 2 4 0
10.3 CONCLUSIONS 242
ACKNOWLEDGMENTS 242 REFERENCES 242
11 CARBOHYDRATE-DERIVED LIGANDS IN ASYMMETRIC HECK REACTIONS 2 4 5
MONTSERRAT DI&GUEZ AND OSCAR PDMIES
11.1 INTRODUCTION 2 4 5
11.2 LIGANDS 247
11.3 CONCLUSIONS 2 5 0
ACKNOWLEDGMENTS 2 5 1
REFERENCES 251
12 1,4-ADDITION O F NUCLEOPHILES T O A.P-UNSATURATED CARBONYL COMPOUNDS
253 YOLANDA DIAZ, M. ISABEL MATHEU, DAVID BENITO AND SERGIO CASTILLDN
12.1 COPPER-CATALYZED REACTIONS-INTRODUCTION 253 12.2 COPPER-CATALYZED
REACTIONS-LIGANDS 257 12.2.1 BIDENTATE P,P-LIGANDS 257 12.2.1.1 XYLO
LIGANDS 257
12.2.1.2 RIBO LIGANDS 257 12.2.1.3 D-GIUCO-, D-AUO-, I-TALO-, A N D D
-GAIACTO-LIGANDS 2 5 8 12.2.2 BIDENTATE P,N-LIGANDS 2 6 1
12.2.2.1 XYLO A N D RIBO LIGANDS 2 6 1
12.2.2.2 D-GIUCO LIGANDS 2 6 1
12.2.3 BIDENTATE P,S- A N D O.S-LIGANDS 2 6 1
12.2.4 MONODENTATE P O R S-LIGANDS 263
12.2.5 MISCELLANEOUS LIGANDS WITH PERIPHERAL DONOR CENTERS. N,N-, N,0-,
A N D P,N-LIGANDS 265
IMAGE 5
CONTENTS | I X
12.3 ENANTIOSELECTIVE COPPER-CATALYZED 1,4-ADDITION O F ORGANOMETALLICS
T O
A,P-UNSATURATED CARBONYL COMPOUNDS 266 12.3.1 SUBSTRATE: 2-CYCLOHEXENONE
266 12.3.1.1 BIDENTATE DIPHOSPHITE A N D DIPHOSPHINITE LIGANDS 266
12.3.1.2 BIDENTATE LIGANDS WITH DIFFERENT COORDINATING FUNCTIONAL
GROUPS: P / P ,
P/N, S/O, A N D S/P 267
12.3.1.3 MONODENTATE P- OR S-LIGANDS 2 8 0 12.3.1.4 MISCELLANEOUS
LIGANDS WITH PERIPHERAL DONOR CENTERS. N,N-, N,0-, A N D
P,N-LIGANDS 2 8 1
12.3.2 SUBSTRATE: 2-CYCLOPENTENONE, 2-CYCLOHEPTENONE 2 8 1
12.3.3 LINEAR SUBSTRATES: TRANS-NON-3-EN-2-ONE A N D
FRANS-5-METHYL-3-HEXEN-2-ONE 2 8 1 12.4 RHODIUM-CATALYZED REACTIONS 286
12.5 CONCLUSIONS 2 8 7
REFERENCES 2 8 8
13 1,2-ADDITION O F NUDEOPHILES T O CARBONYL COMPOUNDS 2 9 3
M. ISABEL MATHEU, YOLANDA DIAZ, PATRICIA MARCE AND SERGIO CASTILLDM
13.1 INTRODUCTION 2 9 3
13.2 ADDITION O F ORGANOMETALLIC REAGENTS TO ALDEHYDES 2 9 4
13.2.1 ADDITION O F DIETHYLZINC TO ALDEHYDES. N , 0 DONOR LIGANDS
(AMINOALCOHOLS) 294 13.2.2 ADDITION O F TRIALKYLALUMINIUM COMPOUNDS TO
ALDEHYDES. P,P A N D P,0-DONOR LIGANDS 3 0 2 13.2.3
ZINC-TRIFLATE-CATALYZED ADDITION O F ALKYNES TO ALDEHYDES A N D IMINES.
N , 0 LIGANDS 3 0 5
13.3 ADDITION O F TRIMETHYLSILYL CYANIDE TO KETONES. P = 0 , 0 LIGANDS 3
0 8
13.4 CONCLUSION 3 1 1
REFERENCES 3 1 2
14 CYDOPROPANATION 3 1 3
MIKE M.K. BOYSEN
REFERENCES 3 1 8
PART IV CARBOHYDRATE ORGANOCATALYSTS 319
15 OXIDATIONS 327
O. ANDREA WONG, BRIAN NETTLES A N D YIAN SHI 15.1 OXIDATIONS 3 2 1
15.1.1 EPOXIDATIONS WITH KETONE CATALYSTS A N D OXONE 3 2 1
15.1.2 OXIDATION O F MISCELLANEOUS SUBSTRATES 3 4 5
15.2 CONCLUSION 346
REFERENCES 3 4 7
IMAGE 6
X CONTENTS
16 ENANTIOSELECTIVE ADDITION REACTIONS CATALYZED BY CARBOHYDRATE-DERIVED
ORGANOCATALYSTS 35 7 JUN-AN MA AND CUANG-WU ZHANG 16.1 INTRODUCTION 3 5
1
16.2 STRECKER, MANNICH, A N D NITRO-MANNICH REACTIONS 3 5 1
16.2.1 STRECKER REACTIONS 3 5 2
16.2.2 MANNICH REACTIONS 3 5 5
16.2.3 NITRO-MANNICH REACTIONS 356
16.3 MICHAEL ADDITIONS 358
16.3.1 BIFUNCTIONAL PRIMARY AMINO-THIOUREA CATALYSTS 3 5 8 16.3.2
BIFUNCTIONAL SECONDARY AMINO-THIOUREA CATALYSTS 362
16.3.3 BIFUNCTIONAL TERTIARY AMINO-THIOUREA CATALYSTS 3 6 3 16.4
MISCELLANEOUS REACTIONS 3 6 4
16.4.1 RADICAL-CHAIN REACTIONS 365
16.4.2 ALDOL REACTIONS 3 6 7
16.5 OUTLOOK 3 6 7
ACKNOWLEDGMENT 3 6 8
REFERENCES 3 6 8
INDEX 377 |
| any_adam_object | 1 |
| author2 | Boysen, Mike M. K. 1972- |
| author2_role | edt |
| author2_variant | m m k b mmk mmkb |
| author_GND | (DE-588)124511023 |
| author_facet | Boysen, Mike M. K. 1972- |
| building | Verbundindex |
| bvnumber | BV040767828 |
| classification_rvk | VK 5800 VK 8580 |
| classification_tum | CHE 620f CHE 330f |
| ctrlnum | (OCoLC)828622862 (DE-599)DNB998577863 |
| dewey-full | 547.78 547.2 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.78 547.2 |
| dewey-search | 547.78 547.2 |
| dewey-sort | 3547.78 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| format | Book |
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| indexdate | 2024-08-21T00:33:47Z |
| institution | BVB |
| isbn | 9783527323791 9783527654543 |
| language | English |
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| physical | XVII, 376 S. graph. Darst. |
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| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Carbohydrates - tools for stereoselective synthesis ed. by Mike Martin Kwabena Boysen Weinheim Wiley-VCH 2013 XVII, 376 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Stereoselektive Synthese (DE-588)4135601-9 gnd rswk-swf Kohlenhydrate (DE-588)4164517-0 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Kohlenhydrate (DE-588)4164517-0 s Stereoselektive Synthese (DE-588)4135601-9 s DE-604 Boysen, Mike M. K. 1972- (DE-588)124511023 edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-65456-7 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-65455-0 Erscheint auch als Online-Ausgabe, PDF 978-3-527-65457-4 text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3385129&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025746263&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Carbohydrates - tools for stereoselective synthesis Stereoselektive Synthese (DE-588)4135601-9 gnd Kohlenhydrate (DE-588)4164517-0 gnd |
| subject_GND | (DE-588)4135601-9 (DE-588)4164517-0 (DE-588)4143413-4 |
| title | Carbohydrates - tools for stereoselective synthesis |
| title_auth | Carbohydrates - tools for stereoselective synthesis |
| title_exact_search | Carbohydrates - tools for stereoselective synthesis |
| title_full | Carbohydrates - tools for stereoselective synthesis ed. by Mike Martin Kwabena Boysen |
| title_fullStr | Carbohydrates - tools for stereoselective synthesis ed. by Mike Martin Kwabena Boysen |
| title_full_unstemmed | Carbohydrates - tools for stereoselective synthesis ed. by Mike Martin Kwabena Boysen |
| title_short | Carbohydrates - tools for stereoselective synthesis |
| title_sort | carbohydrates tools for stereoselective synthesis |
| topic | Stereoselektive Synthese (DE-588)4135601-9 gnd Kohlenhydrate (DE-588)4164517-0 gnd |
| topic_facet | Stereoselektive Synthese Kohlenhydrate Aufsatzsammlung |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3385129&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025746263&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT boysenmikemk carbohydratestoolsforstereoselectivesynthesis |