Functionalized hybrid silicones: catalysis, synthesis and application
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online-Zugang: | Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120319-1097001-1-0 Inhaltsverzeichnis |
| Beschreibung: | 174 S. Ill., graph. Darst. |
Internformat
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Datensatz im Suchindex
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|---|---|
| adam_text | IMAGE 1
CONTENTS
CONTENTS
1. INTRODUCTION 1
1.1 HYDROSILYLATION 1
1.2 POLYSILALKYLENE SILOXANES AS HYBRID SILICONES 2
1.3 OBJECTIVES OF THIS WORK 5
2. CATALYSIS 6
2.1 PLATINUM CATALYSTS AND REACTION MECHANISM 6
2.2 TEST AND COMPARISON OF DIFFERENT HYDROSILYLATION CATALYSTS 8
2.3 PT0 2 AS HETEROGENEOUS HYDROSILYLATION CATALYST 11
2.4 HYDROSILYLATION OF ISOPROPENYL COMPOUNDS 21
2.4.1 MECHANISTIC MODELS FOR THE HYDROSILYLATION OF ALLYL COMPOUNDS 22
2.4.2 GENERAL OBSERVATIONS 24
2.4.3 KINETIC CONSIDERATIONS 25
2.4.4 SCOPE AND LIMITS OF THE REACTION 27
2.4.5 DEUTERATION EXPERIMENTS AND MECHANISTIC PROPOSAL 30
3. SYNTHESIS AND FUNCTIONALIZATION OF HYBRID SILICONES 36
3.1 STATE OF THE ART 36
3.2 SYNTHESIS OF SI-H-TERMINATED HYBRID SILICONES 41
3.3 FUNCTIONALIZATION OF HYBRID SILICONES 52
3.3.1 FUNCTIONALIZATION WITH ALCOHOLS 52
3.3.2 FUNCTIONALIZATION WITH EPOXIDES 55
3.3.3 FUNCTIONALIZATION WITH AMINES 56
3.3.4 FUNCTIONALIZATION WITH (METH)ACRYLATES 58
3.3.5 FUNCTIONALIZATION WITH ANHYDRIDES 59
3.3.6 FUNCTIONALIZATION WITH TRIALKOXYSILANES 60
3.3.7 FUNCTIONALIZATION WITH ACETATES 61
3.3.8 FUNCTIONALIZATION WITH ETHER GROUPS 63
3.3.9 FUNCTIONALIZATION WITH ALIPHATIC, CYCLOALIPHATIC OR AROMATIC
GROUPS 65
3.3.10 FURTHER FUNCTIONALIZATIONS 66
HTTP://D-NB.INFO/1034279874
IMAGE 2
CONTENTS
4. STABILITY OF DIFFERENTLY-SUBSTITUTED SILICON-CONTAINING MODEL
COMPOUNDS....68
5. SYNTHESIS AND APPLICATION OF FUNCTIONALIZED HYBRID SILICONES 71
5.1 EPOXY-FUNCTIORIAL HYBRID SILICONES 72
5.1.1 PHOTOCHEMICAL CURING OF EPOXY-FUNCTIONAL HYBRID SILICONES 72
5.1.2 THERMAL CURING OF EPOXY-FUNCTIONAL HYBRID SILICONES 88
5.2 PREPARATION AND THERMAL CURING OF AMINO-FUNCTIONAL HYBRID SILICONES
94
5.3 PREPARATION AND CURING OF TRIMETHOXYSILYL-FUNCTIONAL HYBRID
SILICONES 107
6. SUMMARY AND CONCLUSION 119
7. EXPERIMENTAL 123
7.1 GENERAL 123
7.2 COMPARISON OF DIFFERENT HYDROSILYLATION CATALYSTS 123
7.3 HYDROSILYLATION OF ISOPROPENYL COMPOUNDS 126
7.4 SYNTHESIS OF DIFFERENT SIH-TERMINATED HYBRID SILICONES 131
7.5 TEST REACTIONS FOR THE FUNCTIONALIZATION OF SIH-TERMINATED HYBRID
SILICONES 136
7.6 DETERMINATION OF THE STABILITY OF DIFFERENT MODEL COMPOUNDS 148
7.7 SYNTHESIS AND PHOTOCHEMICAL CURING OF EPOXY-FUNCTIONAL HYBRID
SILICONES 148
7.8 THERMAL CURING OF EPOXY-FUNCTIONAL HYBRID SILICONES 154
7.9 SYNTHESIS AND CURING OF AMINO-TERMINATED HYBRID SILICONES 156
7.10 SYNTHESIS AND CURING OF TRIMETHOXYSILYL-TERMINATED HYBRID SILICONES
161
REFERENCES 165
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| discipline | Chemie / Pharmazie Chemie |
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| spelling | Putzien, Sophie Verfasser aut Functionalized hybrid silicones catalysis, synthesis and application Sophie Luise Miriam Putzien 2012 174 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2012 Silicone (DE-588)4127342-4 gnd rswk-swf Funktionalisierung Chemie (DE-588)4279323-3 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Silicone (DE-588)4127342-4 s Funktionalisierung Chemie (DE-588)4279323-3 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:91-diss-20120319-1097001-1-0 http://mediatum.ub.tum.de/node?id=1097001 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120319-1097001-1-0 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025689304&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Putzien, Sophie Functionalized hybrid silicones catalysis, synthesis and application Silicone (DE-588)4127342-4 gnd Funktionalisierung Chemie (DE-588)4279323-3 gnd |
| subject_GND | (DE-588)4127342-4 (DE-588)4279323-3 (DE-588)4113937-9 |
| title | Functionalized hybrid silicones catalysis, synthesis and application |
| title_auth | Functionalized hybrid silicones catalysis, synthesis and application |
| title_exact_search | Functionalized hybrid silicones catalysis, synthesis and application |
| title_full | Functionalized hybrid silicones catalysis, synthesis and application Sophie Luise Miriam Putzien |
| title_fullStr | Functionalized hybrid silicones catalysis, synthesis and application Sophie Luise Miriam Putzien |
| title_full_unstemmed | Functionalized hybrid silicones catalysis, synthesis and application Sophie Luise Miriam Putzien |
| title_short | Functionalized hybrid silicones |
| title_sort | functionalized hybrid silicones catalysis synthesis and application |
| title_sub | catalysis, synthesis and application |
| topic | Silicone (DE-588)4127342-4 gnd Funktionalisierung Chemie (DE-588)4279323-3 gnd |
| topic_facet | Silicone Funktionalisierung Chemie Hochschulschrift |
| url | http://mediatum.ub.tum.de/node?id=1097001 https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120319-1097001-1-0 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025689304&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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