Supramolecular templates: routes towards steering assembly and electronic properties at the nanoscale
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online-Zugang: | Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120516-1098765-1-0 Inhaltsverzeichnis |
| Beschreibung: | X, 145 S. Ill., graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Supramolecular templates |b routes towards steering assembly and electronic properties at the nanoscale |c Wolfgang Benedikt Krenner |
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Datensatz im Suchindex
| _version_ | 1804150014856921088 |
|---|---|
| adam_text | IMAGE 1
CONTENTS
ABSTRACT III
1 INTRODUCTION 1
2 THEORETICAL ASPECTS 7
2.1 SCANNING TUNNELING MICROSCOPY 8
2.1.1 THE TUNNELING JUNCTION 8
2.1.1.1 THE TUNNELING CURRENT 8
2.1.1.2 LOCAL DENSITY OF STATES IN DIFFERENTIAL CONDUCTANCE 14
2.2 SURFACE ELECTRONS 16
2.2.1 CONFINEMENT OF SURFACE ELECTRONS 19
2.3 MOLECULAR SELF-ASSEMBLY 23
2.3.1 ADSORPTION AND DIFFUSION OF MOLECULES 23
2.3.2 THEORETICAL CONSIDERATIONS 25
3 SCANNING TUNNELING MICROSCOPY 27
3.1 OPERATION PRINCIPLES 28
3.1.1 SCANNING THE STM TIP 28
3.1.2 SCANNING TUNNELING SPECTROSCOPY 30
3.2 BEETLE-TYPE LT-STM 32
3.2.1 UHV SYSTEM AND SAMPLE PREPARATION 33
3.2.2 CRYOSTAT 33
3.2.3 STM HEAD 35
3.3 JOULE THOMSON LT-STM 37
V I I
HTTP://D-NB.INFO/1033875562
IMAGE 2
CONTENTS
3.3.1 PERIPHERALS AND UHV SYSTEM 38
3.3.2 PREPARATION AND RECIPIENT CHAMBER 40
3.3.2.1 PREPARATION CHAMBER 40
3.3.2.2 RECIPIENT CHAMBER 43
3.3.3 CRYOSTAT 44
3.3.4 STM HEAD 46
3.3.5 PERFORMANCE AND TEST MEASUREMENTS 48
4 POSITIONING SINGLE CO ATOMS USING N FN -DIPHENYL OXALIC AMIDE
TEMPLATES ON A G ( L L L ) 5 1
4.1 MOLECULE PROPERTIES AND SAMPLE PREPARATION 52
4.2 SELF-ASSEMBLY ON A G ( L L L ) 53
4.2.1 MOLECULAR NANOWIRES 53
4.2.2 DENSE-PACKED MOLECULAR MONOLAYER 56
4.3 TEMPLATE FOR MONOMERIC COBALT POSITIONING 58
4.3.1 DEPOSITION ONTO NANOGRATINGS 58
4.3.2 DEPOSITION ONTO MONOLAYER TEMPLATES 59
4.4 COBALT POSITIONING AT VARIABLE TEMPERATURE AND CO-COVERAGE . 62
4.4.1 TEMPERATURE DEPENDENCY 64
4.4.2 OPTIMIZED PROTOCOL AT INCREASING COVERAGE 67
4.4.3 THEORETICAL ANALYSIS OF CO DISTRIBUTION 68
4.5 CONCLUSION 69
5 HIERARCHIC FORMATION O F BI-COMPONENT ORGANIC MOLECULAR NET
WORKS 7 1
5.1 MOLECULE PROPERTIES, SAMPLE PREPARATION, AND THEORETICAL AP
PROACH 73
5.2 DIFFERENT NETWORKS DEPENDING ON THE STOICHIOMETRY 75
5.3 NETWORK CHARACTERISTICS 8 1
5.4 THEORETICAL ANALYSIS OF BINDING MOTIFS AND HIERARCHIC ASSEMBLY 85
5.5 CONCLUSION 90
V I I I
IMAGE 3
CONTENTS
6 ELECTRON CONFINEMENT IN 2D MOLECULAR ARCHITECTURES 9 1
6.1 I D CONFINEMENT IN N,N -DIPHENYL OXALIC AMIDE NANOGRATINGS . 93
6.2 OD CONFINEMENT WITHIN SEXIPHENYL DICARBONITRILE NETWORKS . . . 97
6.2.1 KAGOM6 LATTICE 98
6.2.2 HONEYCOMB LATTICE 106
6.3 COMPARISON OF SCATTERING PROPERTIES I L L
6.4 COMPARATIVE STUDY OF MEASUREMENT TECHNIQUES 117
7 SUMMARY AND OUTLOOK 1 2 9
LIST OF PUBLICATIONS 133
REFERENCES 1 3 5
ACKNOWLEDGMENTS 143
I X
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| spelling | Krenner, Wolfgang Benedikt Verfasser aut Supramolecular templates routes towards steering assembly and electronic properties at the nanoscale Wolfgang Benedikt Krenner 2012 X, 145 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2012 Selbstorganisation (DE-588)4126830-1 gnd rswk-swf Kristallfläche (DE-588)4151344-7 gnd rswk-swf Silber (DE-588)4133759-1 gnd rswk-swf Organisches Molekül (DE-588)4133471-1 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Organisches Molekül (DE-588)4133471-1 s Selbstorganisation (DE-588)4126830-1 s Silber (DE-588)4133759-1 s Kristallfläche (DE-588)4151344-7 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:91-diss-20120516-1098765-1-0 http://mediatum.ub.tum.de/node?id=1098765 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120516-1098765-1-0 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025689254&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Krenner, Wolfgang Benedikt Supramolecular templates routes towards steering assembly and electronic properties at the nanoscale Selbstorganisation (DE-588)4126830-1 gnd Kristallfläche (DE-588)4151344-7 gnd Silber (DE-588)4133759-1 gnd Organisches Molekül (DE-588)4133471-1 gnd |
| subject_GND | (DE-588)4126830-1 (DE-588)4151344-7 (DE-588)4133759-1 (DE-588)4133471-1 (DE-588)4113937-9 |
| title | Supramolecular templates routes towards steering assembly and electronic properties at the nanoscale |
| title_auth | Supramolecular templates routes towards steering assembly and electronic properties at the nanoscale |
| title_exact_search | Supramolecular templates routes towards steering assembly and electronic properties at the nanoscale |
| title_full | Supramolecular templates routes towards steering assembly and electronic properties at the nanoscale Wolfgang Benedikt Krenner |
| title_fullStr | Supramolecular templates routes towards steering assembly and electronic properties at the nanoscale Wolfgang Benedikt Krenner |
| title_full_unstemmed | Supramolecular templates routes towards steering assembly and electronic properties at the nanoscale Wolfgang Benedikt Krenner |
| title_short | Supramolecular templates |
| title_sort | supramolecular templates routes towards steering assembly and electronic properties at the nanoscale |
| title_sub | routes towards steering assembly and electronic properties at the nanoscale |
| topic | Selbstorganisation (DE-588)4126830-1 gnd Kristallfläche (DE-588)4151344-7 gnd Silber (DE-588)4133759-1 gnd Organisches Molekül (DE-588)4133471-1 gnd |
| topic_facet | Selbstorganisation Kristallfläche Silber Organisches Molekül Hochschulschrift |
| url | http://mediatum.ub.tum.de/node?id=1098765 https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120516-1098765-1-0 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025689254&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT krennerwolfgangbenedikt supramoleculartemplatesroutestowardssteeringassemblyandelectronicpropertiesatthenanoscale |