Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online-Zugang: | kostenfrei http://d-nb.info/1028392664/34 https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-38741 Inhaltsverzeichnis |
| Beschreibung: | XII, 201 S. Ill., graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations |c von Dirk Jung |
| 264 | 1 | |c 2012 | |
| 300 | |a XII, 201 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Erlangen-Nürnberg, Univ., Diss., 2012 | ||
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| 912 | |a ebook | ||
| 999 | |a oai:aleph.bib-bvb.de:BVB01-025458832 | ||
Datensatz im Suchindex
| _version_ | 1804149742731526144 |
|---|---|
| adam_text | IMAGE 1
TABLE OF CONTENTS
1 MOTIVATION 1
2 LITERATURE SURVEY 5
2.1 STRUCTURE, FUNCTION AND APPLICATION OF SELECTED ENZYMES 5
2.1.1 CHLOROPEROXIDASE (CPO, E.C. 1.11.1.10) 5
2.1.2 GLUCOSE OXIDASE (GOX, E.C. 1.1.3.4) 8
2.1.3 LACCASE (LACC, E.C. 1.10.3.2) 9
2.1.4 MANGANESE PEROXIDASE (MNP, E.C. 1.11.1.13) 12
2.2 MESOPOROUS SILICEOUS MATERIALS 14
2.3 ENZYME IMMOBILIZATION 17
2.3.1 GENERAL ASPECTS 17
2.3.2 ENZYME IMMOBILIZATION ON MESOPOROUS SUPPORTS 18
2.4 BIOTECHNOLOGY 26
2.4.1 INDUSTRIAL BIOCATALYIS: GENERAL REMARKS 28
2.4.2 BIOCATALYSIS WITH ENZYMES IMMOBILIZED ON MESOPOROUS SUPPORTS 30 3
EXPERIMENTAL SECTION 4 6
3.1 REAGENTS 4 6
3.2 INSTRUMENTATION AND METHODS 4 8
3.2.1 POWDER X-RAY DIFFRACTION 48
3.2.2 SORPTION MEASUREMENTS 48
3.2.3 SMALL ANGLE NEUTRON SCATTERING 4 8
3.2.4 UV/VIS - SPECTROSCOPY 4 9
3.2.5 IR - SPECTROSCOPY 49
3.2.6 NMR SPECTROSCOPY 49
3.2.7 ELEMENTAL ANALYSIS 49
3.2.8 CYCLIC VOLTAMMETRY 49
3.2.9 HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC) 50
3.2.10 GAS CHROMATOGRAPHY / MASS SPECTROSCOPY (GC/MS) 52
3.3 ACTIVITY ASSAYS 53
3.3.1 CHLOROPEROXIDASE 53
3.3.2 GLUCOSE OXIDASE 53
3.3.3 LACCASE 54
3.3.4 MANGANESE PEROXIDASE 54
3.4 SYNTHESES 56
3.4.1 SYNTHESIS OF THE MESOPOROUS SUPPORTS 56
3.4.2 SURFACE MODIFICATION OF THE MESOPOROUS SUPPORTS 57
3.4.3 SYNTHESIS O F ORGANIC COMPOUNDS 57
3.4.4 IMMOBILIZATION EXPERIMENTS 61
3.4.5 BIOCATALYTIC EXPERIMENTS 62
4 RESULTS AND DISCUSSION 64
4.1 SYNTHESIS AND CHARACTERIZATION OF VARIOUS SB A-16 - TYPE MATERIALS
64
4.1.1 NITROGEN SORPTION 66
HTTP://D-NB.INFO/1029799628
IMAGE 2
4.1.2 ARGON SORPTION 72
4.1.3 BENZENE SORPTION 73
4.1.4 POWDER X-RAY DIFFRACTION AND TRANSMISSION ELECTRON MICROSCOPY 75
4.1.5 SMALL ANGLE NEUTRON SCATTERING 78
4.1.6 SOLID STATE NMR SPECTROSCOPY 83
4.1.7 MODEL OF DYNAMIC MICELLE DISTANCES (DMD) 84
4.2 SYNTHESIS AND SURFACE MODIFICATION O F SBA-15 87
4.2.1 INFRARED SPECTROSCOPY 87
4.2.2 SOLID STATE NMR SPECTROSCOPY 89
4.3 SYNTHESIS AND CHARACTERIZATION OF MESO-CELLULAR FOAMS 90
4.3.1 NITROGEN SORPTION 90
4.3.2 POWDER X-RAY DIFFRACTION AND SMALL ANGLE NEUTRON SCATTERING 9 3
4.4 ENZYME IMMOBILIZATION 95
4.4.1 ADSORPTION OF CHLOROPEROXIDASE 95
4.4.2 CROSS-LINKED ENZYMES IN THE PORE CAGES OF MESOCELLULAR FOAMS 109
4.5 CATALYTIC EXPERIMENTS 150
4.5.1 OXIDATION OF INDOLE TO OXINDOLE 150
4.5.2 BIODEGRADATION O F DIBENZOTHIOPHENE 166
4.5.3 PRODUCTION OF PHARMACEUTICAL^ RELEVANT BUILDING BLOCKS 175
5 SUMMARY AND CONCLUSIONS 189
6 REFERENCES 194
|
| any_adam_object | 1 |
| author | Jung, Dirk |
| author_GND | (DE-588)1028939639 |
| author_facet | Jung, Dirk |
| author_role | aut |
| author_sort | Jung, Dirk |
| author_variant | d j dj |
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| bvnumber | BV040631579 |
| collection | ebook |
| ctrlnum | (OCoLC)823253168 (DE-599)DNB1028392664 |
| dewey-full | 660.634 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660.634 |
| dewey-search | 660.634 |
| dewey-sort | 3660.634 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| spelling | Jung, Dirk Verfasser (DE-588)1028939639 aut Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations von Dirk Jung 2012 XII, 201 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Erlangen-Nürnberg, Univ., Diss., 2012 Carrier (DE-588)4602818-3 gnd rswk-swf Reaktionstechnik (DE-588)4136173-8 gnd rswk-swf Immobilisiertes Enzym (DE-588)4161361-2 gnd rswk-swf Enzymatische Oxidation (DE-588)4468528-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Carrier (DE-588)4602818-3 s Immobilisiertes Enzym (DE-588)4161361-2 s Enzymatische Oxidation (DE-588)4468528-2 s Reaktionstechnik (DE-588)4136173-8 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:29-opus-38741 https://open.fau.de/handle/openfau/2715 Verlag kostenfrei Volltext http://d-nb.info/1028392664/34 Langzeitarchivierung Nationalbibliothek https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-38741 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025458832&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Jung, Dirk Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations Carrier (DE-588)4602818-3 gnd Reaktionstechnik (DE-588)4136173-8 gnd Immobilisiertes Enzym (DE-588)4161361-2 gnd Enzymatische Oxidation (DE-588)4468528-2 gnd |
| subject_GND | (DE-588)4602818-3 (DE-588)4136173-8 (DE-588)4161361-2 (DE-588)4468528-2 (DE-588)4113937-9 |
| title | Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations |
| title_auth | Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations |
| title_exact_search | Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations |
| title_full | Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations von Dirk Jung |
| title_fullStr | Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations von Dirk Jung |
| title_full_unstemmed | Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations von Dirk Jung |
| title_short | Immobilization of enzymes on mesoporous supports and their application in continuous-flow biotransformations |
| title_sort | immobilization of enzymes on mesoporous supports and their application in continuous flow biotransformations |
| topic | Carrier (DE-588)4602818-3 gnd Reaktionstechnik (DE-588)4136173-8 gnd Immobilisiertes Enzym (DE-588)4161361-2 gnd Enzymatische Oxidation (DE-588)4468528-2 gnd |
| topic_facet | Carrier Reaktionstechnik Immobilisiertes Enzym Enzymatische Oxidation Hochschulschrift |
| url | https://open.fau.de/handle/openfau/2715 http://d-nb.info/1028392664/34 https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-38741 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025458832&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT jungdirk immobilizationofenzymesonmesoporoussupportsandtheirapplicationincontinuousflowbiotransformations |