Organized organic ultrathin films: fundamentals and applications
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2013
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XII, 214 S. Ill., graph. Darst. |
| ISBN: | 9783527327331 9783527654666 |
Internformat
MARC
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| 245 | 1 | 0 | |a Organized organic ultrathin films |b fundamentals and applications |c ed. by Katsuhiko Ariga |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2013 | |
| 300 | |a XII, 214 S. |b Ill., graph. Darst. | ||
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| 500 | |a Literaturangaben | ||
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| 650 | 4 | |a Nanostructured materials | |
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Datensatz im Suchindex
| _version_ | 1804149620611219456 |
|---|---|
| adam_text | Contents
Preface
IX
List of Contributors
Xl
1
Introduction
1
Katsuhiko
Ariga
2
Self-Assembled Monolayer (SAM)
7
Toshihiro Kondo, Ryo Yamada, and Kohei Uosaki
2.1
Introduction
7
2.2
Preparation and Characterization
8
2.2.1
Organothiols on
Au
8
2.2.2
Organosilanes on SiO, Surfaces
15
2.2.3
SAMs on Si Surface via Si—
С
Bonding
17
2.3
Functions and Applications
20
2.3.1
Surface Coating and Patterning
21
2.3.2
Sensor Applications
23
2.3.3
Nanotribology
26
2.3.4
Advanced Applications
28
2.3.4.1
Electron Transfer
28
2.3.4.2
Photoinduced Electron Transfer
29
2.3.4.3
Luminescence
34
2.3.4.4
Catalytic Activity
34
2.4
Future Perspective
36
References
37
3
Langmuir-Blodgett (LB) Film
43
Ken-ichi limura and Teiji
Kato
3.1
Concept and Mechanism
43
3.2
Preparation and Characterization
43
3.2.1
Gibbs Monolayers
43
3.2.2
Langmuir Monolayers
45
3.2.2.1
Basic Measurements of Properties of Langmuir Monolayers
45
3.2.2.2
А
-T
isobars
47
VI Contents
3.2.2.3
π-Α
isotherms
50
3.2.2.4
Stability of Langmuir Monolayers
52
3.2.3
In situ Characterization of Monolayers at the
Subphase
Surface
56
3.2.3.1
Brewster-Angle Microscopy (BAM)
56
3.2.3.2
Fourier Transform Infrared (FTIR) Spectroscopy
57
3.2.3.3
X-ray Reflectometry and Grazing-Incidence X-ray Diffractometry
6
í
3.2.4
Transfer to Solid Supports
63
3.2.4.1
Instruments for LB Film Deposition
65
3.2.4.2
Turnover of Amphiphile Molecules during Deposition
67
3.2.4.3
Horizontal Lifting-Up Deposition
69
3.2.4.4
Horizontal Scooping-Up
71
3.3
Functions and Applications
73
3.3.1
Molecular Recognition
73
3.3.1.1
Molecular Recognition by Hydrogen Bonding and Electrostatic
Interaction at the Air/Water Interface
73
3.3.1.2
Chiral Discrimination at the Air/Water Interface
77
3.3.1.3
Macrocyclic Hosts
79
3.3.1.4
Dynamic Host Cavity
80
3.3.2
Multilayer Films for Photoelectronic Functions
83
3.3.2.1
Molecular
Photodiode
83
3.3.2.2
Fullerene
C60 Containing LB Film
85
3.3.2.3
Optical Logic Gate/
Photoswitch 87
3.3.3
Biomimetic Functions
88
3.3.3.1
Biomembrane
Models-Langmuir Monolayers of Lipids
89
3.3.3.2
Lung Surfactants
93
3.3.3.3
Biomimetic Mineralization
94
3.3.4
Advanced Applications
95
3.3.4.1
Sensors
95
3.3.4.2
Photoresponsive Films
98
References
99
4
Layer-by-Layer (LbL) Assembly
107
Katsuhiko
Ariga
4.1
Concept and Mechanism
107
4.2
Preparation and Characterization
109
4.2.1
Applicable Materials and Interactions
109
4.2.2
Thin-Film Preparation: Fundamental Procedure and
Characterization
114
4.2.3
Various Driving Forces and Techniques
120
4.2.4
Three-Dimensional Assemblies
129
4.3
Functions and Applications
136
4.3.1
Physicochemical Applications of LbL Thin Films
137
4.3.2
Biomedical
Applications of LbL Thin Films
143
4.4
Brief Summary and Perspectives
153
Further Reading
154
Contents
VII
5
Other Thin
Films 157
Mineo
Hashizume, Takeshi Serizawa, and Norihiro Yamada
5.1
Bilayer Vesicle and Cast Film
157
5.1.1
Definition of a Bilayer Structure, a Bilayer Membrane, and a Bilayer
Vesicle
157
5.1.2
Formation of a Bilayer Structure
159
5.1.2.1
Bilayer Forming Amphiphiles
159
5.1.2.2
Properties of Bilayer Membrane and Diagnostics of Bilayer
Formation
162
5.1.2.3
Mechanism and Preparation of Bilayer Formation
164
5.1.2.4
Future of the Bilayer Vesicle
366
5.1.3
Cast Films Containing a Bilayer Structure
166
5.2
Self-Assembled Fibers, Tubes, and Ribbons
169
5.2.1
Introduction
369
5.2.2
Finding a Helical Superstructure
369
5.2.3
Organogel
172
5.2.4
Control of Aggregate Morphology
173
5.2.4.1
Composite Structure with Two or More Different Parts
175
5.2.4.2
Hydrogen Bonding to Immobilize Orderly Molecular
Arrangement
3 75
5.2.4.3
Hierarchic Interaction and Further Interaction
177
5.3
Polymer Brush Layer
379
5.3.1
Definition of Polymer Brushes
179
5.3.2
Preparation of Polymer Brushes
180
5.3.3
Properties and Applications of Concentrated Polymer Brashes
182
5.4
Organic-Inorganic Hybrids
184
5.5
Colloidal Layers
393
5.6
Newly Appearing Techniques
J
95
5.6.1
Material-Binding
Peptide
395
5.6.2
Block-Copolymer Films
197
5.6.3
Nanoimprint Lithography
200
References
200
Index
205
Organic ultrathin films are ubiquitous in the biological world and are
familiar to us in our daily lives (e.g. soap bubbles). Such films are usu¬
ally prepared by dry processes, for example, vapor deposition. However,
thin films composed of complicated organic molecules and
biomateri¬
als
cannot easily be fabricated using such techniques. Wet processes on
the other hand have proved both suitable and versatile in this respect,
and thus films with higher functionality for advanced technologies are
now becoming widely accessible.
This book covers the fundamentals and practical techniques of
organized organic ultrathin films prepared by wet processes. Most of
the film structures selected for inclusion in the book are important in
biotechnology. The categories of films covered include monomolecular
films (monolayers) both on a water surface and on a solid plate,
Langmuir-Blodgett films (transferred multilayer films on a solid plate
from a water surface), layer-by-layer films (adsorbed multilayer films on
a solid support), and spontaneously assembled films in solution.
The book is the first comprehensive monograph on organized organic
ultrathin films that spans both basic knowledge and recent develop¬
ments in the research field. It serves as a handy reference book for
researchers at the forefront of R&D in both traditional surface science
and applied nanotechnology.
Dr. Katsuhiko
Ariga
is the Director of Supermolecuies Unit and Principal Investigator
of World Premier International (WPI) Research Center for Materials Nanoarchitectonics
(MANA),
the National Institute for Materials Science (NIMS). He received his B.Eng.,
M.Eng., and Ph.D. degrees from the Tokyo Institute of Technology (TIT). He was Assistant
Professor at TIT, worked as a postdoctoral fellow at the University of Texas at Austin, USA,
and then served as a group leader in tine Supermolecuies Project at japan Science and
Technology Agency (JST). Thereafter, Dr.
Ariga
worked as Associate Professor at the
Nara
Institute of Science and Technology, and then became involved with the ERATO Nanospace
Project at JST. In January
2004,
Dr.
Ariga
moved to NIMS. He was also appointed Professor
at several Universities. His research field is based on supermolecular chemistry and surface
science, including the boundary research areas of organic chemistry, physical chemistry,
biochemistry, and materials chemistry. His major interests are the fabrication of novel
functional nanostructures based on molecular recognition and self-assembly, including
Langmuir-Blodgett films, layer-by-layer films, and mesoporous materials.
ISBN
978-3-527-32733-1
www.wiley-vch.de
|
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| id | DE-604.BV040532865 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:25:56Z |
| institution | BVB |
| isbn | 9783527327331 9783527654666 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025378909 |
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| spelling | Organized organic ultrathin films fundamentals and applications ed. by Katsuhiko Ariga Weinheim Wiley-VCH 2013 XII, 214 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturangaben Organic thin films Nanostructured materials Organische Verbindungen (DE-588)4043816-8 gnd rswk-swf Dünne Schicht (DE-588)4136925-7 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Organische Verbindungen (DE-588)4043816-8 s Dünne Schicht (DE-588)4136925-7 s DE-604 Ariga, Katsuhiko 1962- (DE-588)138360731 edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-65468-0 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-65467-3 Erscheint auch als Online-Ausgabe, PDF 978-3-527-65469-7 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025378909&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025378909&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Organized organic ultrathin films fundamentals and applications Organic thin films Nanostructured materials Organische Verbindungen (DE-588)4043816-8 gnd Dünne Schicht (DE-588)4136925-7 gnd |
| subject_GND | (DE-588)4043816-8 (DE-588)4136925-7 (DE-588)4143413-4 |
| title | Organized organic ultrathin films fundamentals and applications |
| title_auth | Organized organic ultrathin films fundamentals and applications |
| title_exact_search | Organized organic ultrathin films fundamentals and applications |
| title_full | Organized organic ultrathin films fundamentals and applications ed. by Katsuhiko Ariga |
| title_fullStr | Organized organic ultrathin films fundamentals and applications ed. by Katsuhiko Ariga |
| title_full_unstemmed | Organized organic ultrathin films fundamentals and applications ed. by Katsuhiko Ariga |
| title_short | Organized organic ultrathin films |
| title_sort | organized organic ultrathin films fundamentals and applications |
| title_sub | fundamentals and applications |
| topic | Organic thin films Nanostructured materials Organische Verbindungen (DE-588)4043816-8 gnd Dünne Schicht (DE-588)4136925-7 gnd |
| topic_facet | Organic thin films Nanostructured materials Organische Verbindungen Dünne Schicht Aufsatzsammlung |
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