Fundamentals of chemical engineering thermodynamics:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Upper Saddle River, NJ [u.a.]
Pearson Education International
2013
|
| Ausgabe: | International ed., 1. print. |
| Schriftenreihe: | Prentice Hall international series in the physical and chemical engineering sciences
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | XXIII, 669 S. graph. Darst. |
| ISBN: | 9780133134353 0133134350 |
Internformat
MARC
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| 100 | 1 | |a Matsoukas, Themis |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Fundamentals of chemical engineering thermodynamics |c Themis Matsoukas |
| 250 | |a International ed., 1. print. | ||
| 264 | 1 | |a Upper Saddle River, NJ [u.a.] |b Pearson Education International |c 2013 | |
| 300 | |a XXIII, 669 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 490 | 0 | |a Prentice Hall international series in the physical and chemical engineering sciences | |
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Datensatz im Suchindex
| _version_ | 1804149610799693824 |
|---|---|
| adam_text | Contents
Preface
xiii
Acknowledgments
xvii
About the Author
xix
Nomenclature
xxi
Part I Pure Fluids
1
Chapter
1
Scope and Language of Thermodynamics
3
1.1
Molecular Basis of Thermodynamics
5
1.2
Statistical versus Classical Thermodynamics
11
1.3
Definitions
13
1.4
Units
22
1.5
Summary
26
1.6
Problems
26
Chapter
2
Phase Diagrams of Pure Fluids
29
2.1
The PVT Behavior of Pure Fluid
29
2.2
Tabulation of Properties
40
2.3
Compressibility Factor and the ZP Graph
43
2.4
Corresponding States
45
2.5
Virial Equation
53
2.6
Cubic Equations of State
57
2.7
PVT Behavior of Cubic Equations of State
61
2.8
Working with Cubic Equations
64
2.9
Other Equations of State
67
2.10
Thermal Expansion and Isothermal Compression
71
2.11
Empirical Equations for Density
72
2.12
Summary
77
2.13
Problems
78
VII
v¡i¡
Contents
Chapter
3
Energy and the First Law
85
3.1
Energy and Mechanical Work
86
3.2
Shaft Work and PV Work
88
3.3
Internal Energy and Heat
94
3.4
First Law for a Closed System
96
3.5
Elementary Paths
99
3.6
Sensible Heat—Heat Capacities
107
3.7
Heat of Vaporization I17
3.8
Ideal-Gas State
122
3.9
Energy Balances and Irreversible Processes
131
3.10
Summary
137
3.11
Problems I38
Chapter
4
Entropy and the Second Law
145
4.1
The Second Law in a Closed System
146
4.2
Calculation of Entropy
149
4.3
Energy Balances Using Entropy
159
4.4
Entropy Generation
163
4.5
Carnot Cycle
164
4.6
Alternative Statements of the Second Law
173
4.7
Ideal and Lost Work
179
4.8
Ambient Surroundings as a Default Bath
—
Exergy
185
4.9
Equilibrium and Stability
187
4.10
Molecular View of Entropy
191
4.11
Summary
195
4.12
Problems
197
Chapter
5
Calculation of Properties
201
5.1
Calculus of Thermodynamics
201
5.2
Integration of Differentials
209
5.3
Fundamental Relationships
210
5.4
Equations for Enthalpy and Entropy
213
5.5
Ideal-Gas State
215
5.6
Incompressible Phases
216
5.7
Residual Properties
218
5.8
Pressure-Explicit Relations
224
5.9
Application to Cubic Equations
226
5.10
Generalized Correlations
231
5.11
Reference States
232
Contents ix
5.12 Thermodynamic Charts 238
5.13
Summary
241
5.14 Problems 242
Chapter
6
Balances in Open
Systems 247
6.1
Flow Streams
248
6.2
Mass Balance
249
6.3
Energy Balance in Open System
251
6.4
Entropy Balance
254
6.5
Ideal and Lost Work
262
6.6
Thermodynamics of Steady-State Processes
268
6.7
Power Generation
291
6.8
Refrigeration
297
6.9
Liquefaction
305
6.10
Unsteady-State Balances
311
6.11
Summary
319
6.12
Problems
320
Chapter
7
VLE of Pure Fluid
331
7.1
Two-Phase Systems
331
7.2
Vapor-Liquid Equilibrium
334
7.3
Fugacity
337
7.4
Calculation of
Fugacity
339
7.5
Saturation Pressure from Equations of State
347
7.6
Phase Diagrams from Equations of State
350
7.7
Summary
352
7.8
Problems
353
Part II Mixtures
359
Chapter
8
Phase Behavior of Mixtures
361
8.1
The Txy Graph
362
8.2
The Pxy Graph
365
8.3
Azeotropes
372
8.4
The xy Graph
373
8.5
VLE at Elevated Pressures and Temperatures
375
8.6
Partially
Miscible
Liquids
376
8.7
Ternary Systems
382
8.8
Summary
8.9
Problems
Chapter
9
Properties of Mixtures
9.1
Composition
9.2
Mathematical Treatment of Mixtures
9.3
Properties of Mixing
9.4
Mixing and Separation
9.5
Mixtures in the Ideal-Gas State
9.6
Equations of State for Mixtures
9.7
Mixture Properties from Equations of State
9.8
Summary
9.9
Problems
Contents
385
386
391
392
394
399
401
403
409
411
418
418
Chapter
10
Theory of Vapor-Liquid Equilibrium
423
10.1
Gibbs Free Energy of Mixture
423
10.2
Chemical Potential
427
10.3
Fugacity
in a Mixture
431
10.4
Fugacity
from Equations of State
434
10.5
VLE of Mixture Using Equations of State
436
10.6
Summary
441
10.7
Problems
442
Chapter
11
Ideal Solution
447
11.1
Ideality in Solution
447
11.2
Fugacity
in Ideal Solution
450
11.3
VLE in Ideal Solution-Raoult s Law
452
11.4
Energy Balances
461
11.5
Noncondensable Gases
466
11.6
Summary
470
11.7
Problems
470
Chapter
12 Nonideal
Solutions
475
12.1
Excess Properties
475
12.2
Heat Effects of Mixing
482
12.3
Activity Coefficient
490
12.4
Activity Coefficient and Phase Equilibrium
493
12.5
Data Reduction: Fitting Experimental Activity Coefficients
498
12.6
Models for the Activity Coefficient
501
12.7
Summary
517
12.8
Problems
519
Contents xi
Chapter
13
Miscibility, Solubility, and Other Phase Equilibria
529
13.1
Equilibrium between Partially
Miscible
Liquids
529
13.2
Gibbs Free Energy and Phase Splitting
532
13.3
Liquid Miscibility and Temperature
540
13.4
Completely Immiscible Liquids
542
13.5
Solubility of Gases in Liquids
547
13.6
Solubility of Solids in Liquids
559
13.7
Osmotic Equilibrium
564
13.8
Summary
570
13.9
Problems
570
Chapter
14
Reactions
575
14.1
Stoichiometry
575
14.2
Standard Enthalpy of Reaction
578
14.3
Energy Balances in Reacting Systems
583
14.4
Activity
588
14.5
Equilibrium Constant
596
14.6
Composition at Equilibrium
604
14.7
Reaction and Phase Equilibrium
606
14.8
Reaction Equilibrium Involving Solids
611
14.9
Multiple Reactions
614
14.10
Summary
618
14.11
Problems
619
Bibliography
627
Appendix A Critical Properties of Selected Compounds
629
Appendix
B Ideal-Gas
Heat Capacities
633
Appendix
С
Standard Enthalpy and Gibbs Free Energy of Reaction
635
Appendix
D UNIFAC
Tables
639
Appendix
E
Steam Tables
643
Index
657
|
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| id | DE-604.BV040526551 |
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| indexdate | 2024-07-10T00:25:46Z |
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| isbn | 9780133134353 0133134350 |
| language | English |
| lccn | 2012025140 |
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| spelling | Matsoukas, Themis Verfasser aut Fundamentals of chemical engineering thermodynamics Themis Matsoukas International ed., 1. print. Upper Saddle River, NJ [u.a.] Pearson Education International 2013 XXIII, 669 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Prentice Hall international series in the physical and chemical engineering sciences Includes bibliographical references and index Thermodynamics Textbooks Chemical engineering Textbooks Phasenumwandlung (DE-588)4132140-6 gnd rswk-swf Thermodynamik (DE-588)4059827-5 gnd rswk-swf Chemische Verfahrenstechnik (DE-588)4069941-9 gnd rswk-swf Thermochemie (DE-588)4078260-8 gnd rswk-swf Technische Chemie (DE-588)4078178-1 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Chemische Verfahrenstechnik (DE-588)4069941-9 s Thermodynamik (DE-588)4059827-5 s DE-604 Technische Chemie (DE-588)4078178-1 s Thermochemie (DE-588)4078260-8 s Phasenumwandlung (DE-588)4132140-6 s 1\p DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025372711&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Matsoukas, Themis Fundamentals of chemical engineering thermodynamics Thermodynamics Textbooks Chemical engineering Textbooks Phasenumwandlung (DE-588)4132140-6 gnd Thermodynamik (DE-588)4059827-5 gnd Chemische Verfahrenstechnik (DE-588)4069941-9 gnd Thermochemie (DE-588)4078260-8 gnd Technische Chemie (DE-588)4078178-1 gnd |
| subject_GND | (DE-588)4132140-6 (DE-588)4059827-5 (DE-588)4069941-9 (DE-588)4078260-8 (DE-588)4078178-1 (DE-588)4123623-3 |
| title | Fundamentals of chemical engineering thermodynamics |
| title_auth | Fundamentals of chemical engineering thermodynamics |
| title_exact_search | Fundamentals of chemical engineering thermodynamics |
| title_full | Fundamentals of chemical engineering thermodynamics Themis Matsoukas |
| title_fullStr | Fundamentals of chemical engineering thermodynamics Themis Matsoukas |
| title_full_unstemmed | Fundamentals of chemical engineering thermodynamics Themis Matsoukas |
| title_short | Fundamentals of chemical engineering thermodynamics |
| title_sort | fundamentals of chemical engineering thermodynamics |
| topic | Thermodynamics Textbooks Chemical engineering Textbooks Phasenumwandlung (DE-588)4132140-6 gnd Thermodynamik (DE-588)4059827-5 gnd Chemische Verfahrenstechnik (DE-588)4069941-9 gnd Thermochemie (DE-588)4078260-8 gnd Technische Chemie (DE-588)4078178-1 gnd |
| topic_facet | Thermodynamics Textbooks Chemical engineering Textbooks Phasenumwandlung Thermodynamik Chemische Verfahrenstechnik Thermochemie Technische Chemie Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025372711&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT matsoukasthemis fundamentalsofchemicalengineeringthermodynamics |