Elements of physical chemistry:
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Hauptverfasser: | , |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Oxford
Oxford Univ. Press
2013
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Ausgabe: | 6. ed. |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | Includes bibliographical references and index |
Beschreibung: | XXIII, 591 S. Ill., graph. Darst. |
ISBN: | 9780199608119 |
Internformat
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245 | 1 | 0 | |a Elements of physical chemistry |c Peter Atkins ; Julio de Paula |
250 | |a 6. ed. | ||
264 | 1 | |a Oxford |b Oxford Univ. Press |c 2013 | |
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Datensatz im Suchindex
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adam_text | Titel: Elements of physical chemistry
Autor: Atkins, Peter W
Jahr: 2013
Füll contents
List of The chemist s toolkits xx 1.7 Diffusion and effusion 30
List of tables xxi 1.8 Molecular collisions 32
Foundations 1 Real gases 33
----------------------------------------------------------------------- 1.9 Molecular interactions 33
Matter 1 1.10 The critical temperature 34
0.1 Mass and amount of substance 2 1.11 The compression factor 36
0.2 Volume 4 1-12 The virial equation of State 36
0.3 Density 4 L13 The van der Waals equation of State 37
0.4 Extensive and intensive properties 4 114 The liquefaction of gases 40
FURTHER INFORMATION 1.1: KINETIC
MOLECULAR THEORY 41 .
Energy 5
0.5 Velocity and momentum 5 CHECKLIST OF KEY CONCEPTS 42
0.6 Acceleration 6 ROAD MAP OF KEY EQUATIONS 43
QUESTIONS AND EXERCISES 43
Chapter 2
Thermodynamics: the First Law 47
0.7 Force 6
0.8 Pressure 6
0.9 Work and energy 8
0.10 Temperature 10 -------------------------------------------------------------------------
0.11 Quantization and the Boltzmann distribution 10 The conservation of energy 48
0.12 Equipartition 12 2.1 Systems and surroundings 48
Electromagnetic radiation 12 22 Work and heat 49
. r. . x. , 2.3 The molecular Interpretation of work,
0.13 Electromagnetic waves 12 . ,
heat, and temperature 50
0.14 Photons 13 . TU . , ,
2.4 The measurement of work 51
Building on the foundations 14 2.5 The measurement of heat 55
QUESTIONS AND EXERCISES 15 2.6 Heat influx during expansion 58
Chapter 1 Internal energy and enthalpy 58
The properties of gases 18 2.7 The internal energy 59
2.8 Internal energy as a State function 60
Equations of State 18 2.9 The enthalpy 62
1.1 The perfect gas equation of State 19 2.10 The temperature Variation of the enthalpy 63
1.2 Using the perfect gas law 22 CHECKLIST OF KEY CONCEPTS 65
1.3 Mixtures of gases: partial pressures 23 ROAD MAP OF KEY EQUATIONS 66
QUESTIONS AND EXERCISES 66
Impact on environmental science 1.1:
The gas laws and the weather 25
Chapter 3
Thermodynamics: applications of the
The molecular model of gases 26
1.4 The pressure of a gas according to the First Law 69
kinetic model 27 ------------------------:-------------------------------------------------
1.5 The average speed of gas molecules 27 Physical change 69
1.6 The Maxwell distribution of speeds 28 3.1 The enthalpy of phase transition 70
xiv FÜLL CONTENTS
Impact on biochemistry 3.1: Chapter 5
Differential scanning calorimetry 73 Physical equilibria: pure substances 113
3.2 Atomic and molecular change 74
Chemical change 78
3.3 Enthalpies of combustion 78
Impact on technology 3.2: Fuels 79
Impact on biochemistry 3.3: Food and
The thermodynamics of transition 113
5.1 The condition of stability 114
5.2 The Variation of Gibbs energy with pressure 114
5.3 The Variation of Gibbs energy with
temperature 116
energy reserves 80
3.4 The combination of reaction enthalpies 80 Phase diagrams 118
3.5 Standard enthalpies of formation 82 5.4 Phase boundaries 119
3.6 The Variation of reaction enthalpy with 5.5 The location of phase boundaries 120
temperature 83
CHECKLIST OF KEY CONCEPTS 85
5.6 Characteristic points 124
Impact on technology 5.1:
ROAD MAP OF KEY EQUATIONS 86 Supercritical fluids 125
QUESTIONS AND EXERCISES 86 ^ _, Tu .
5.7 The phase rule 126
5.8 Phase diagrams of typical materials 127
Chapter 4
_ ...... __ 5.9 The molecular structure of liquids 129
Thermodynamics: the Second Law 90
_____________________________________________ CHECKLIST OF KEY CONCEPTS 130
ROAD MAP OF KEY EQUATIONS 131
Entropy 91
QUESTIONS AND EXERCISES 131
4.1 The direction of spontaneous change 91
4.2 Entropy and the Second Law 92 ChaDter 6
Impact on technology 4.1: Heat engines, Physical equilibria: the properties of mixtures 133
refrigerators, and heat pumps 93--------------------------------------------------------------------------
4.3 The entropy change accompanying The thermodynamic description of mixtures 133
expansion 94
4.4 The entropy change accompanying heating 95
6.1 Measures of concentration 134
6.2 Partial molar properties 135
4.5 The entropy change accompanying a
phase transition 97 6-3 Spontaneous mixing 138
4.6 Entropy changes in the surroundings 99 6A Ideal Solutions 139
4.7 The molecular interpretation of entropy 100 6-5 Ideal-dilute Solutions 142
4.8 Absolute entropies and the Third Law of Impact on biology 6.1: Gas solubility
thermodynamics 101 and breathing 145
4.9 The molecular interpretation of
6.6 Real Solutions: activities 146
Third-Law entropies 103 ~ ... . ^. 1Aft
Colhgative properties 4B
4.10 The Standard reaction entropy 105 ¦
6.7 The modification of boiling and freezing
4.11 The spontaneity of chemical reactions 105 points W
The Gibbs energy 106 6.8 Osmosis t.49
4.12 Focussing on the System 106 Phase diagrams of mixtures 152
4.13 Properties ofthe Gibbs energy 107 69 Mixtures of volatile liquids 153
Impact OO biology 4.2: Ufe and the * 10 liouid-liauid nhas« riiaorarr.s ^
Second Law 108
6.10 Liquid-liquid phase diagrams
6.11 Liquid-solid phase diagrams
CHECKLIST OF KEY CONCEPTS 109
ROAD MAP OF KEY EQUATIONS m ,mpact on »chnc-logy 6.2: Ultrapuritv
QUESTIONS ANP EXERCISES 110
and controtfed impurity
156
FÜLL CONTENTS XV
6.12 The Nernst distribution law 159 Solubility equilibria 202
CHECKLIST OF KEY CONCEPTS 160 8.8 The solubility constant 202
ROAD MAP OF KEY EQUATIONS 160
QUESTIONS AND EXERCISES 161
8.9 The common-ion effect 203
8.10 The effect of added salts on solubility 204
CHECKLIST OF KEY CONCEPTS 205
Chapter 7 ROAD MAP OF KEY EQUATIONS 206
Chemical equilibria: the principles 165 QUESTIONS AND EXERCISES 206
Thermodynamic background 165 Chapter 9
7.1 The reaction Gibbs energy 166
7.2 The Variation of ArG with composition 167
7.3 Reactions at equilibrium 169
7.4 The Standard reaction Gibbs energy 170
Chemical equilibria: electrochemistry 209
Ions in Solution 209
9.1 The Debye-Hückel theory 210
9.2 The migration of ions 213
Impact on biochemistry 7.1: Coupled
reactions in biochemical processes 172 Impact on biochemistry 9.1: Ion
Channels and pumps 216
Electrochemical cells 217
7.5 The equilibrium composition 173
7.6 The equilibrium constant in terms of
concentration 175 9.3 Half-reactions and electrodes 217
7.7 The molecular interpretation of equilibrium 9.4 Reactions at electrodes 219
constants 176 ,_ ,, . . r
9.5 Vaneties of cell 221
The response of equilibria to the conditions 177 qq The cell reaction 222
7.8 The effect of temperature 177 9.7 The cell potential 222
7.9 The effect of compression 179 9.8 Cells at equilibrium 224
7.10 The presence of a catalyst 181 9.9 Standard potentials 225
Impact on biochemistry 7.2: Binding of 9.10 The Variation of potential with pH 225
oxygen to myoglobin and haemoglobin 181 911 The determination of pH 227
CHECKLIST OF KEY CONCEPTS 182
ROAD MAP OF KEY EQUATIONS 183 Applications of Standard potentials 228
QUESTIONS AND EXERCISES 183 9.12 The electrochemical series 228
Chapter 8
Chemical equilibria: Solutions 186
9.13 The determination of thermodynamic
funetions 228
Impact on technology 9.2: Fuel cells 230
CHECKLIST OF KEY CONCEPTS 231
ROAD MAP OF KEY EQUATIONS 231
QUESTIONS AND EXERCISES 232
Proton transfer equilibria 186
8.1 Bransted-Lowry theory 186
8.2 Protonation and deprotonation 187 Chapter 10
8.3 Polyprotic acids 192 Chemical kinetics: the rates of reactions 235
8.4 Amphiprotic Systems 195
Salts in water 196
8.5 Acid-base titrations 196
8.6 Buffer action 198
Empirical chemical kinetics 236
10.1 Spectrophotometry 236
10.2 Experimental techniques 237
Reaction rates 238
Impact on medicine 8.1: Buffer action
inblood 200 10.3 The definition of rate 238
8.7 Indicators 200 10.4 Rate laws and rate constants 239
XVi FÜLL CONTENTS
10.5 Reaction order 240 Chapter 12
10.6 The determination of the rate law 241 Quantum theory 287
The emergence of quantum theory 287
10.7 Integrated rate laws 243
10.8 Half-lives and time constants 247
12.1 Atomic and molecular spectra:
The temperature dependence of reaction rates 248 discrete energies 288
10.9 The Arrhenius Parameters 249 12.2 The photoelectric effect: light as particles 289
10.10 Collision theory 251 12.3 Electron diffraction: electrons as waves 290
The dynamics of microscopic Systems 292
12.4 The Schrödinger equation 292
10.11 Transition-state theory 253
CHECKLIST OF KEY CONCEPTS 256
ROAD MAP OF KEY EQUATIONS 257
QUESTIONS AND EXERCISES 257 12-5 The Born Interpretation 293
12.6 The uncertainty principle 295
Chapter 11 Applications of quantum mechanics 297
Chemical kinetics: accounting for the
rate laws 261
12.7 Translation 298
12.8 Rotational motion 303
Reaction schemes 261 12.9 Vibration: the harmonic oscillator 307
11.1 The approach to equilibrium 261 FURTHER INFORMATION 12.1: THE
SEPARATION OF VARIABLES PROCEDURE 310
11.2 Relaxation methods 263 CHECKLIST OF KEY CONCEPTS 311
11.3 Consecutive reactions 265 ROAD MAP OF KEY EQUATIONS 311
Reaction mechanisms 266 QUESTIONS AND EXERCISES 312
11.4 Elementary reactions 266
11.5 The formulation of rate laws 267
11.6 The steady-state approximation 268
Chapter 13
Quantum chemistry: atomic structure 315
11.7 The rate-determining step 269 Hydrogenic atoms 315
11.8 Kinetic control 270
11.9 Unimolecular reactions 270
Reactions in Solution 272
11.10 Activation control and diffusion control 272
11.11 Diffusion 273
13.1 The spectra of hydrogenic atoms 316
13.2 The permitted energies of hydrogenic
atoms 316
13.3 Quantum numbers 318
13.4 The wavefunctions: s Orbitals 321
13.5 The wavefunctions: p and d orbitals 324
Homogeneous catalysis 276 , _ ... x o-,i-
13.6 Electron spin 325
11.12 Acid and base catalysis 276 13.7 Spectral transitions and selection rules 326
11.13 Enzymes 277
Chain reactions 280
The structures of many-electron atoms 327
13.8 The orbital approximation 327
11.14 The structure of chain reactions 280 139 The Pauli principle 328
11 .15 The rate laws of chain reactions 281 13.10 Perietration and shielding 328
FURTHER INFORMATION 11.1: 10i-, tu u -w .• •¦ W»
F.CK S LAWS OF DIFFUSION 282 ^ ^ ^^^ V™**
CHECKLIST OF KEY CONCEPTS 283 13.12 The occupation ofd orbitals 330
ROAD MAP OF KEY EQUATIONS 283 13-13 The configurations of cations and aniöns 331
QUESTIONS AND EXERCisfs 284 13.14 Self-consisteWfleld orbitals 33.
FÜLL CONTENTS xwil
Periodic trends in atomic properties 332 Chapter 15
13.15 Atomic radius 332 Molecular interaction« 376
13.16 Ionization energy and electron äffinity 333
The spectra of complex atoms 335
van der Waals interactions 376
15.1 Interactions between partial charges 377
13.17 Term symbols 335 152 Electric dipole moments 377
13.18 Spin-orbit coupling 338 153 interactions between dipoles 380
13.19 Selection rules 338 154 induced dipole moments 382
Impact onastronomy 13.1: 155 Dispersion interactions 384
The spectroscopy of stars 338
FURTHER INFORMATION 13.1: The total interaction 385
THE PAULI PRINCIPLE 339 156 Hydrogen bonding 385
15.7 The hydrophobic effect 386
15.8 Modelling the total interaction 387
Impact on medicine 15.1: Molecular
recognition and drug design 389
Chapter 14
Quantum chemistry: the chemical bond 344 Molecules in motion 390
CHECKLIST OF KEY CONCEPTS 340
ROAD MAP OF KEY EQUATIONS 341
QUESTIONS AND EXERCISES 341
------------------------------------------------------------------------ CHECKLIST OF KEY CONCEPTS 390
Introductory concepts 345 ROAD MAP OF KEY EQUATIONS 391
L , ,. . tl_ QUESTIONS AND EXERCISES 391
14.1 The Classification of bonds 345
14.2 Potential energy curves 345
Chapter 16
Valence bond theory 346 Macromolecules and aggregate* 394
Biological and synthetic macromolecules 395
14.3 Diatomic molecules 346
14.4 Polyatomic molecules 348
14.5 Promotion and hybridization 349 161 Models of structure 395
14.6 Resonance 352 Impact on biochemistry 16.1:
The prediction of protein structure 399
14.7 The language of valence bonding 353
Molecular orbitals 353
14.8 Linear combinations of atomic orbitals 353
14.9 Bonding and antibonding orbitals 355
16.2 Mechanical properties of polymers 401
16.3 Electrical properties of polymers 403
Mesophases and disperse Systems 403
16.4 Liquid crystals 403
14.10 The structures of homonuclear diatomic
molecules 356 Classification of disperse Systems 404
14.11 The structures of heteronuclear diatomic 166 Surface, structure. and stability 405
molecules 363 Impact on biochemistry 16.2:
14.12 The structures of polyatomic molecules 365
Biological membranes 407
14.13 The Hückel method 366 16J The etectric double layer 408
16.8 Liquid surfaces and Surfactants 409
Computational chemistry 369
14.14 Techniques 369
14.15 Graphical Output 370
14.16 Applications 371
CHECKLIST OF KEY CONCEPTS 372
Determination of size and shape 411
16.9 Average molar masses 412
1Ö;10 Mass spectrometry 413
16.11 Ultracentrrfugation 414
ROAD MAP OF KEY EQUATIONS 373 16.12 Electrophoresis 415
QUESTIONS AND EXERCISES 373 16.13 Laser light scattering 415
XVÜi FÜLL CONTENTS
CHECKLIST OF KEY CONCEPTS 416 Catalytic activity at surfaces 463
ROAD MAP OF KEY EQUATIONS 417
QUESTIONS AND EXERCISES 417
18.6 Unimolecular reactions 463
18.7 The Langmuir-Hinshelwood mechanism 464
ChaDter 17 1® ^ The Eley-Rideal mechanism 464
Metallic, ionic. and covalent solids 420 Impact on technology 18.1: Examples of
___________________________________________________ heterogeneous catalysis 465
Bonding in solids 420 Processes at electrodes 467
17.1 The band theory of solids 421 -|8.9 The electrode-solution interface 467
17.2 The occupation of bands 422 18.10 The rate of electron transfer 468
17.3 The optical properties of junctions 424 18.11 Voltammetry 470
17.4 Superconductivity 424 18.12 Electrolysis 472
17.5 The ionic model of bonding 425 CHECKLIST OF KEY CONCEPTS 473
17.6 Lattice enthalpy 425 ROAD MAP OF KEY EQUATIONS 474
17.7 The originoflattice enthalpy 427 QUESTIONS AND EXERCISES 474
17.8 Covalent networks 429
Impact on technology 17.1: Nanowires 429 ^napter
Spectroscopy: molecular rotations and
17.9 Magnetic properties of solids 430 vibrations 477
Crystal structure 432
17.10 Unit cells 432
Rotational spectroscopy 478
17.11 The Identification of crystal planes. 433 19-1 The rotational energy levels of molecules 478
17.12 The determination of structure 435 192 Forbidden and allowed rotational states 482
17 13 Bragg s law 437 19-3 Populations at thermal equilibrium 483
17.14 Experimental techniques 438 194 Rotational transitions: microwave
spectroscopy 484
17.15 Metal crystals 440
17.16 Ionic crystals 442
17.17 Molecular crystals 443
Impact on biochemistry 17.2: Vibrational spectroscopy 489
X-ray crystallography of biological , 9 7 The Kations of molecules 489
macromolecules 444
19.8 Vibrational transitions 490
19.5 Linewidths 486
19.6 Rotational Raman spectra 488
CHECKLIST OF KEY CONCEPTS 445
ROAD MAP OF KEY EQUATIONS 446
QUESTIONS AND EXERCISES 446 19.10 Vibrational Raman spectra of diatomic
19.9 Anharmonicity 491
molecules 492
Chapter 18 19-11 The vibrations of polyatomic molecules 492
Solid surfaces 449 19.12 Vibration-rotation spectra 495
19.13 Vibrational Raman spectra of polyatomic
The growth and structure of surfaces 449 molecules 496
18.1 Surface growth 450 Impact on the environment 19.1:
Climate change 497
18.2 Surface composition and structure 450 Ano
CHECKLIST OF KEY CONCEPTS *98
The extent of adsorption 455 ROAD MAP OF KEY EQUATIONS 499
18.3 Physisorption and chemisorption 455 QUESTIONS AND EXERCISES 4Ö9
18.4 Adsorption isotherms 456
18.5 The rates of surface processes 461
FÜLL CONTENTS XIX
Chapter 20 Electron paramagnetic resonance 543
Spectroscopy: electronic transitions 503 21 8 Theg-value 544
21.9 Hyperfine structure 545
Ultraviolet and visible spectra 503
CHECKLIST OF KEY CONCEPTS 547
20.1 Practical considerations 505 ROAD MAP OF KEY EQUATIONS 548
20.2 Absorption intensities 505 QUESTIONS AND EXERCISES 549
20.3 The Franck-Condon principle 507
20.4 Specific types of transitions 508 Chapter 22
Impact on biochemistry 20.1: Vision 509 Statistical thermodynamics 551
Radiative and non-radiative decay 510 The Boltzmann distribution 551
20.5 Fluorescence 511 22 * The general form of the Boltzmann
20.6 Phosphorescence 511 distribution 552
20.7 Quenching 512 22.2 The origins of the Boltzmann distribution 553
Impact on biochemistry 20.2: The partJtjon functJon 553
Photosynthesis 517
20 8 Lasers 518 22 3 The interpretation of the partition function 554
22.4 Examples of partition funetions 555
22.5 The molecular partition function 557
Photoelectron spectroscopy 522
FURTHER INFORMATION 20.1:
THE BEER-LAMBERT LAW 524 Thermodynamic properties 557
22.6 The internal energy 557
FURTHER INFORMATION 20.2:
THE EINSTEIN TRANSITION PROBABILITIES 524
CHECKLIST OF KEY CONCEPTS 525 22-7 The heat capacity 559
ROAD MAP OF KEY EQUATIONS 526 22.8 The entropy 560
QUESTIONS AND EXERCISES 526 22.9 The Gibbs energy 560
22.10 The equilibrium constant 561
Chapter 21 further Information 22.1: the
Spectroscopy: magnetic resonance 529 CALCULATION OF PARTITION FUNCTIONS 563
-------------------------------------------------------------------------------- FURTHER INFORMATION 22.2: THE
Nuclear magnetic resonance 529 EQUILIBRIUM CONSTANT FROM THE
PARTITION FUNCTION 564
21.1 Nuclei in magnetic fields 530 CHECKLIST OF KEY CONCEPTS 564
21.2 Thetechnique 532 ROAD MAP OF KEY EQUATIONS 565
^ . M . . .,.._ QUESTIONS AND EXERCISES 565
The Information in NMR spectra 533
21.3 The chemical shift 533
21.4 The fine structure 535
Resource section 569
21.5 Spin relaxation 539 1 Quantities and units 570
21.6 Conformational conversion and chemical 2 Data section 572
exchange 541
,., T .. . klktD c . 1 Thermodynamic data 572
21.7 Two-dimensional NMR 542
2 Standard potentials 579
Impact on medicine 21.1:
Magnetic resonance imaging 542
Index 581
|
any_adam_object | 1 |
author | Atkins, Peter W. 1940- de Paula, Julio |
author_GND | (DE-588)128437782 (DE-588)132130599 |
author_facet | Atkins, Peter W. 1940- de Paula, Julio |
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author_sort | Atkins, Peter W. 1940- |
author_variant | p w a pw pwa p j d pj pjd |
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bvnumber | BV040498861 |
classification_rvk | VE 5010 |
classification_tum | CHE 100f |
ctrlnum | (OCoLC)812410971 (DE-599)BSZ371675383 |
discipline | Chemie / Pharmazie Physik Chemie |
edition | 6. ed. |
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indexdate | 2024-07-10T00:25:03Z |
institution | BVB |
isbn | 9780199608119 |
language | English |
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physical | XXIII, 591 S. Ill., graph. Darst. |
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record_format | marc |
spelling | Atkins, Peter W. 1940- Verfasser (DE-588)128437782 aut Elements of physical chemistry Peter Atkins ; Julio de Paula 6. ed. Oxford Oxford Univ. Press 2013 XXIII, 591 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Physikalische Chemie (DE-588)4045959-7 s DE-604 de Paula, Julio Verfasser (DE-588)132130599 aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025345672&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Atkins, Peter W. 1940- de Paula, Julio Elements of physical chemistry Physikalische Chemie (DE-588)4045959-7 gnd |
subject_GND | (DE-588)4045959-7 (DE-588)4123623-3 |
title | Elements of physical chemistry |
title_auth | Elements of physical chemistry |
title_exact_search | Elements of physical chemistry |
title_full | Elements of physical chemistry Peter Atkins ; Julio de Paula |
title_fullStr | Elements of physical chemistry Peter Atkins ; Julio de Paula |
title_full_unstemmed | Elements of physical chemistry Peter Atkins ; Julio de Paula |
title_short | Elements of physical chemistry |
title_sort | elements of physical chemistry |
topic | Physikalische Chemie (DE-588)4045959-7 gnd |
topic_facet | Physikalische Chemie Lehrbuch |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025345672&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT atkinspeterw elementsofphysicalchemistry AT depaulajulio elementsofphysicalchemistry |