Polyethylene: end-use properties and their physical meaning
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
München [u.a.]
Hanser
2013
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XI, 140 S. Ill., graph. Darst. |
| ISBN: | 9781569905203 9781569905210 |
Internformat
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| 264 | 1 | |a München [u.a.] |b Hanser |c 2013 | |
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| 650 | 0 | 7 | |a Polyethylene |0 (DE-588)4076241-5 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
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IMAGE 1
INTRODUCTION IX
1 EDUCATIONAL MINIMUM: MANUFACTURE, STRUCTURE, AND MECHANICAL PROPERTIES
O F POLYETHYLENE RESINS 1
1.1 CLASSIFICATION AND APPLICATIONS OF POLYETHYLENE RESINS 1
1.2 CATALYSTS FOR SYNTHESIS OF POLYETHYLENE RESINS 4
1.3 INDUSTRIAL PROCESSES FOR THE MANUFACTURE OF POLYETHYLENE RESINS 6
1.4 CHEMISTRY OF ETHYLENE POLYMERIZATION REACTIONS 8
1.5 MOLECULAR WEIGHT DISTRIBUTION OF POLYMERS AND METHODS OF ITS
ANALYSIS 11
1.6 EXAMPLES OF MOLECULAR WEIGHT DISTRIBUTION OF POLYETHYLENE RESINS . .
. . 14
1.7 COPOLYMER STATISTICS AND ITS APPLICATION TO DESCRIPTION OF LLDPE AND
VLDPE RESINS 20
1.8 COMPOSITIONAL UNIFORMITY OF COMMERCIAL POLYETHYLENE RESINS 22
1.9 MORPHOLOGY OF POLYETHYLENE RESINS 26
1.10 MECHANICAL DEFORMATION OF POLYETHYLENE RESINS 29
REFERENCES 31
2 MELT INDEX AND MELT FLOW RATIO O F POLYETHYLENE RESIN 35
2.1 INTRODUCTION 35
2.2 BASICS OF POLYMER RHEOLOGY; MELT FLOW THROUGH A CAPILLARY 37
2.2.1 FLOW OF POLYMER MELT THROUGH A CYLINDRICAL CAPILLARY 39
2.2.2 MELT INDEX OF NEWTONIAN LIQUID 40
2.3 MELT FLOW OF MONODISPERSE POLYETHYLENE RESINS 41
2.4 ADDITIVITY RULES FOR VISCOSITY; CALCULATION OF MELT INDEXES AND MELT
FLOW RATIOS FROM MOLECULAR WEIGHT DISTRIBUTION DATA 43
2.4.1 ADDITIVITY RULES FOR ZERO-SHEAR VISCOSITY Q 0 43
2.4.2 ADDITIVITY RULES FOR EFFECTIVE VISCOSITY AND GENERAL EXPRESSIONS
FOR FLOW OF NON-NEWTONIAN MULTI-COMPONENT MELT 44
HTTP://D-NB.INFO/1022144979
IMAGE 2
2.5 EXAMPLES OF MELT FLOW RATES AND MELT FLOW RATIOS FOR POLYETHYLENE
RESINS OF DIFFERENT TYPES 48
2.5.1 LLDPE RESINS PRODUCED WITH SUPPORTED ZIEGLER-NATTA CATALYSTS 48
2.5.2 HDPE RESINS WITH BROAD MOLECULAR WEIGHT DISTRIBUTIONS 51 2.5.3
EFFECT OF LONG-CHAIN BRANCHING 53
REFERENCES 54
3 MELTING POINT O F POLYETHYLENE RESIN 57
3.1 INTRODUCTION 57
3.2 MELTING POINT OF HDPE RESIN 58
3.3 DSC MELTING CURVES AND MELTING POINTS OF LLDPE AND VLDPE RESINS
PRODUCED WITH SINGLE-SITE CATALYSTS 61
3.3.1 CRYSTALLIZATION PROCESS OF COMPOSITIONALLY UNIFORM ETHYLENE/
A-OLEFIN COPOLYMERS 64
3.3.2 MODEL FOR SECONDARY CRYSTALLIZATION 65
3.3.3 COMBINED DSC MODEL FOR LLDPE AND VLDPE RESINS 66
3.4 DSC MELTING CURVES AND MELTING POINTS OF LLDPE RESINS PRODUCED WITH
MULTI-SITE ZIEGLER-NATTA CATALYSTS 68
REFERENCES 71
4 CRYSTALLINITY DEGREE AND DENSITY O F POLYETHYLENE RESINS 73
4.1 CRYSTALLINITY DEGREE 73
4.1.1 MEASUREMENT METHODS 73
4.1.2 DEFINITION OF CRYSTALLINITY DEGREE OF LLDPE AND VLDPE RESINS BASED
ON COPOLYMER STATISTICS 75
4.2 DENSITY 76
4.2.1 MEASUREMENT METHODS 77
4.2.2 PHYSICAL MEANING OF POLYETHYLENE DENSITY 77
REFERENCES 80
5 END-USE MECHANICAL PROPERTIES O F POLYETHYLENE FILM 83
5.1 MECHANICAL PROPERTIES OF POLYETHYLENE RESINS 83
5.1.1 EFFECT OF TESTING SPEED ON MECHANICAL PROPERTIES 84
5.1.2 ORIENTATION IN POLYETHYLENE FILM 85
5.2 DART IMPACT STRENGTH OF LLDPE FILM 87
5.2.1 DESCRIPTION OF DART IMPACT TEST 87
5.2.2 MODEL OF DART IMPACT TEST 89
5.2.2.1 EFFECTS OF MECHANICAL PROPERTIES OF RESINS 92
IMAGE 3
5.2.2.2 COMPARISON OF FILM MADE FROM ETHYLENE/BUTENE AND
ETHYLENE/HEXENE COPOLYMERS 93
5.2.2.3 EFFECT OF COPOLYMER COMPOSITION 94
5.2.2.4 COMPOSITIONALLY UNIFORM AND COMPOSITIONALLY NONUNIFORM RESINS 95
5.3 TEAR STRENGTH OF LLDPE AND LDPE FILM 97
5.3.1 DESCRIPTION OF TEAR TEST 97
5.3.2 PHYSICAL DETAILS OF TEAR TEST 97
5.3.3 MODEL OF TEAR TEST 102
5.3.3.1 EFFECT OF PENDULUM SPEED 107
5.3.3.2 EFFECTS OF MECHANICAL PROPERTIES OF RESINS 107
5.3.3.3 EFFECT OF FILM ORIENTATION 108
5.3.3.4 COMPARISON OF TEAR STRENGTH OF ETHYLENE/BUTENE AND
ETHYLENE/HEXENE COPOLYMERS 110
5.3.3.5 LOW DENSITY POLYETHYLENE 110
5.4 COMPARISON OF FACTORS DETERMINING RESULTS OF TEAR TEST AND DART
IMPACT TEST OF LLDPE FILM ILL
REFERENCES 112
6 END-USE TESTING O F HIGH MOLECULAR WEIGHT HDPE AND MDPE RESINS 115
6.1 TOP LOAD TEST OF HDPE CONTAINERS 115
6.1.1 MECHANICS OF TOP LOAD TEST 116
6.2 DYNAMIC BURST TEST OF HDPE TUBING AND PIPES 118
6.3 STATIC BURST TEST AND LONG-TERM FATIGUE IN POLYETHYLENE 119
6.3.1 PRINCIPAL EQUATION FOR LOW-STRESS FAILURE 120
6.3.2 PHYSICAL MECHANISM OF POLYMER FAILURE UNDER LOW STRESS 122
6.4 ENVIRONMENTAL STRESS-CRACKING RESISTANCE 125
6.4.1 DESCRIPTION OF ESCR TEST 125
6.4.2 PHYSICS OF ENVIRONMENTAL STRESS CRACKING 126
6.4.3 STRUCTURAL PARAMETERS OF HDPE RESINS AFFECTING ESCR 127 6.4.4
RELATIONSHIP BETWEEN ESCR AND LONG-TERM FATIGUE IN POLYETHYLENE 130
6.4.5 MECHANISM OF ENVIRONMENTAL STRESS CRACKING 132
REFERENCES 135
INDEX 139 |
| any_adam_object | 1 |
| author | Kissin, Yury V. 1937- |
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| dewey-sort | 3547.8434 |
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| discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften Werkstoffwissenschaften / Fertigungstechnik |
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| spelling | Kissin, Yury V. 1937- Verfasser (DE-588)115431063 aut Polyethylene end-use properties and their physical meaning Yury V. Kissin München [u.a.] Hanser 2013 XI, 140 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polyethylene (DE-588)4076241-5 gnd rswk-swf Polyethylene (DE-588)4076241-5 s DE-604 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4031440&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025309089&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kissin, Yury V. 1937- Polyethylene end-use properties and their physical meaning Polyethylene (DE-588)4076241-5 gnd |
| subject_GND | (DE-588)4076241-5 |
| title | Polyethylene end-use properties and their physical meaning |
| title_auth | Polyethylene end-use properties and their physical meaning |
| title_exact_search | Polyethylene end-use properties and their physical meaning |
| title_full | Polyethylene end-use properties and their physical meaning Yury V. Kissin |
| title_fullStr | Polyethylene end-use properties and their physical meaning Yury V. Kissin |
| title_full_unstemmed | Polyethylene end-use properties and their physical meaning Yury V. Kissin |
| title_short | Polyethylene |
| title_sort | polyethylene end use properties and their physical meaning |
| title_sub | end-use properties and their physical meaning |
| topic | Polyethylene (DE-588)4076241-5 gnd |
| topic_facet | Polyethylene |
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