Materials science of polymers for engineers:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Munich
Hanser [u.a.]
2012
|
| Ausgabe: | 3. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIX, 595 S. graph. Darst. 25 cm |
| ISBN: | 9781569905142 9781569905241 |
Internformat
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| 245 | 1 | 0 | |a Materials science of polymers for engineers |c Tim A. Osswald ; Georg Menges |
| 246 | 1 | 3 | |a Material science of polymers for engineers |
| 250 | |a 3. ed. | ||
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Datensatz im Suchindex
| _version_ | 1804149515380326400 |
|---|---|
| adam_text | Titel: Material science of polymers for engineers
Autor: Osswald, Tim
Jahr: 2012
Contents
Preface to the First Edition............................................................................VII
Preface to the Third Edition ...............................................IX
1 Introduction ................................................................................................3
1.1 The 6 P s..........................................................................................................3
1.2 General Information ......................................................................................6
1.3 Identification of Polymers..............................................................................13
1.4 Sustainability - The 6Ih P..............................................................................15
References ..............................................................................................................20
2 Historical Background ............................................................................21
2.1 From Natural to Synthetic Rubber................................................................21
2.2 Cellulose and the $10,000 Idea......................................................................27
2.3 Gala!ith - The Milk Stone..............................................................................30
2.4 Leo Baekeland and the Plastics Industry ....................................................31
2.5 Herman Mark and the American Polymer Education................................34
2.6 Wallace Hume Carothers and Synthetic Polymers......................................37
2.7 Polyethylene - A Product of Brain and Brawn............................................39
2.8 The Super Fiber and the Woman Who Invented It......................................42
2.9 One Last Word - Plastics ..............................................................................44
References ..............................................................................................................47
3 Structure of Polymers..............................................................................49
3.1 Macromolecular Structure of Polymers........................................................49
3.2 Molecular Bonds and Inter-Molecular Attraction........................................50
3.3 Molecular Weight ..........................................................................................51
3.4 Conformation and Configuration of Polymer Molecules
3.5 Arrangement of Polymer Molecules ................
3.5.1 Thermoplastic Polymers...................
3.5.2 Amorphous Thermoplastics................
3.5.3 Semi-Crystalline Thermoplastics ...........
3.5.4 Thermosets and Cross-Linked Elastomers
3.6 Copolymers and Polymer Blends...................
3.7 Polymer Additives...............................
3.7.1 Flame Retardants ........................
3.7.2 Stabilizers ..............................
3.7.3 Antistatic Agents ........................
3.7.4 Fillers..................................
3.7.5 Blowing Agents..........................
References .........................................
4 Thermal Properties of Polymers ...............
4.1 Material Properties..............................
4.1.1 Thermal Conductivity.....................
4.1.2 Specific Heat............................
4.1.3 Density.................................
4.1.4 Thermal Diffusivity.......................
4.1.5 Linear Coefficient of Thermal Expansion.....
4.1.6 Thermal Penetration......................
4.1.7 Glass Transition Temperature..............
4.1.8 Melting Temperature .....................
4.2 Measuring Thermal Data .........................
4.2.1 Differential Thermal Analysis (DTA) ........
4.2.2 Differential Scanning Calorimeter (DSC).....
4.2.3 Thermomechanical Analysis (TMA).........
4.2.4 Thermogravimetry (TGA)..................
4.2.5 Density Measurements....................
References .......................................
5 Rheology of Polymer Melts....................
5.1 Introduction..........................
5.1.1 Continuum Mechanics..................
5.1.2 The Generalized Newtonian Fluid...........
5.1.3 Normal Stresses in Shear Flow.............
5.1.4 Deborah Number.........
56
59
60
60
62
72
73
75
75
77
78
78
79
82
83
85
85
91
93
96
97
98
99
99
99
100
101
103
104
105
109
111
111
111
113
115
116
5.2 Viscous Flow Models......................................................................................119
5.2.1 The Power Law Model......................................................................119
5.2.2 The BircLCarreau-Yasuda Model....................................................121
5.2.3 The Bingham Fluid..........................................................................122
5.2.4 Elongational Viscosity ....................................................................122
5.2.5 Rheology of Curing Thermosets ....................................................125
5.2.6 Suspension Rheology......................................................................127
5.3 Simplified Flow Models Common in Polymer Processing..........................129
5.3.1 Simple Shear Flow ..........................................................................129
5.3.2 Pressure Flow Through a Slit ........................................................130
5.3.3 Pressure Flow through a Tube - Hagen-Poiseuille Flow ............130
5.3.4 Couette Flow ....................................................................................131
5.4 Viscoelastic Flow Models ..............................................................................132
5.4.1 Differential Viscoelastic Models ....................................................132
5.4.2 Integral Viscoelastic Models ..........................................................135
5.5 Rheometry ......................................................................................................138
5.5.1 The Melt Flow Indexer....................................................................139
5.5.2 The Capillary Viscometer................................................................139
5.5.3 Computing Viscosity Using the Bagley and
Weissenberg-Rabinowitsch Equations ..........................................141
5.5.4 Viscosity Approximation Using the Representative
Viscosity Method ............................................................................142
5.5.5 The Cone-Plate Rheometer..............................................................143
5.5.6 The Couette Rheometer ..................................................................144
5.5.7 Extensional Rheometry ..................................................................145
5.6 Surface Tension..............................................................................................148
References .......................................................................................157
6 Introduction to Processing ....................................................................163
6.1 Extrusion ........................................................................................................163
6.1.1 The Plasticating Extruder ..............................................................166
6.1.1.1 The Solids Conveying Zone ............................................................168
6.1.1.2 The Melting Zone .......................................171
6.1.1.3 The Metering Zone..........................................................................174
6.1.2 Extrusion Dies..................................................................................175
6.1.2.1 Sheeting Dies....................................................................................176
6.1.2.2 Tubular Dies ....................................................................................177
6.2 Mixing Processes............................................................................................179
6.2.1 Distributive Mixing..........................................................................181
6.2.1.1 Effect of Orientation........................................................................182
......................184
6.2.2 Dispersive Mixing..........................
6.2.2.1 Break-Up of Particulate Agglomerates .....................
6.2.2.2 Break-Up of Fluid Droplets...............................
„ ..............loy
6.2.3 Mixing Devices..............................
6.2.3.1 Static Mixers..........................................
6.2.3.2 Banbury Mixer ........................................
6.2.3.3 Mixing in Single Screw Extruders ........................
6.2.3.4 Co-Kneader ......................................................................................19
103
6.2.3.5 Twin Screw Extruders ..................................
6.2.4 Energy Consumption During Mixing............................................198
6.2.5 Mixing Quality and Efficiency........................................................199
6.2.6 Plasticization..........................................
6.3 Injection Molding ..........................................................................................206
6.3.1 The Injection Molding Cycle ..........................................................207
6.3.2 The Injection Molding Machine...........................
6.3.2.1 The Plasticating and Injection Unit................................................210
6.3.2.2 The Clamping Unit..........................................................................211
6.3.2.3 The Mold Cavity ...........................................................213
6.4 Special Injection Molding Processes............................................................216
6.4.1 Multi-Component Injection Molding..............................................216
6.4.2 Co-Injection Molding ......................................................................218
6.4.3 Gas-Assisted Injection Molding (GAIM)........................................219
6.4.4 Injection-Compression Molding ....................................................221
6.4.5 Reaction Injection Molding (RIM)..................................................222
6.4.6 Liquid Silicone Rubber Injection Molding....................................225
6.5 Secondary Shaping........................................................................................226
6.5.1 Fiber Spinning..................................................................................226
6.5.2 Film Production................................................................................227
6.5.2.1 Cast Film Extrusion ........................................................................227
6.5.2.2 Film Blowing....................................................................................228
6.5.3 Blow Molding.................................................230
6.5.3.1 Extrusion Blow Molding..................................................................230
6.5.3.2 Injection Blow Molding ..................................................................232
6.5.3.3 Thermoforming..................................................................233
6.6 Calendering..............................................................................235
6.7 Coating..............................................................23#
6.8 Compression Molding................................................240
6.9 Foaming................................................................242
6.10 Rotational Molding ..................~ f,
...........................................244
6.11 Computer Simulation in Polymer Processing..............................................245
6.11.1 Mold Filling Simulation..................................................................246
6.11.2 Orientation Predictions ..................................................................248
6.11.3 Shrinkage and Warpage Predictions..............................................249
References ..............................................................................................................260
7 Anisotropy Development During Processing ..................................263
7.1 Orientation in the Final Part ........................................................................263
7.1.1 Processing Thermoplastic Polymers..............................................263
7.1.2 Processing Thermoset Polymers....................................................271
7.2 Predicting Orientation in the Final Part......................................................275
7.2.1 Planar Orientation Distribution Function ....................................276
7.2.2 Single Particle Motion ....................................................................278
7.2.3 Jeffery s Model ................................................................................279
7.2.4 Folgar-Tucker Model........................................................................280
7.2.5 Tensor Representation of Fiber Orientation..................................281
7.2.5.1 Predicting Orientation in Complex Parts Using
Computer Simulation......................................................................282
7.3 Fiber Damage..................................................................................................287
References ..............................................................................................................293
8 Solidification of Polymers ......................................................................295
8.1 Solidification of Thermoplastics....................................................................295
8.1.1 Thermodynamics During Cooling..................................................295
8.1.2 Morphological Structure ................................................................299
8.1.3 Crystallization..................................................................................300
8.1.4 Heat Transfer During Solidification ..............................................303
8.2 Solidification of Thermosets..........................................................................307
8.2.1 Curing Reaction ..............................................................................308
8.2.2 Cure Kinetics....................................................................................309
8.2.3 Heat Transfer During Cure ............................................................314
8.3 Residual Stresses and Warpage of Polymeric Parts....................................316
8.3.1 Residual Stress Models.............................................................319
8.3.1.1 Residual Stress Model Without Phase Change Effects................321
8.3.1.2 Model to Predict Residual Stresses with
Phase Change Effects......................................................................322
8.3.2 Other Simple Models to Predict Residual Stresses and Warpage 324
8.3.2.1 Uneven Mold Temperature..............................................................326
8.3.2.2 Residual Stress in a Thin Thermoset Part ....................................327
8.3.2.3 Anisotropy Induced Curvature Change ........................................328
n 329
8 33 Predicting Warpage in Actual Parts.......................
..........336
References .........................................
9 Mechanical Behavior of Polymers........................................................341
34!
9.1 Basic Concepts of Stress and Strain ............................................................^
9.1.1 Plane Stress...........................................
9.1.2 Plane Strain...........................................
343
9.2 Viscoelastic Behavior of Polymers................................
9.2.1 Stress Relaxation Test......................................................................344
9.2.2 Time-Temperature Superposition (WLF-Equation) ......................346
9.2.3 The Boltzmann Superposition Principle........................................347
9.3 Applying Linear Viscoelasticity to Describe the Behavior of Polymers .. 348
9.3.1 The Maxwell Model..........................................................................34^
9.3.2 Kelvin Model....................................................................................33(1
9.3.3 Jeffrey Model....................................................................................33^
9.3.4 Standard Linear Solid Model..........................................................354
9.3.5 The Generalized Maxwell Model....................................................356
9.4 The Short-Term Tensile Test..........................................................................361
9.4.1 Rubber Elasticity..............................................................................362
9.4.2 The Tensile Test and Thermoplastic Polymers..............................367
9.5 Creep Test........................................................................................................374
9.5.1 Isochronous and Isometric Creep Plots ........................................378
9.6 Dynamic Mechanical Tests............................................................................379
9.6.1 Torsion Pendulum...................................... 379
9.6.2 Sinusoidal Oscillatory Test..............................................................383
9.7 Effects of Structure and Composition on Mechanical Properties....... 385
9.7.1 Amorphous Thermoplastics.............................. 385
9.7.2 Semi-Crystalline Thermoplastics ..................................................388
9.7.3 Oriented Thermoplastics ................................ 390
9.7.4 Crosslinked Polymers................................... 395
9.8 Mechanical Behavior of Filled and Reinforced Polymers ..........................397
9.8.1 Anisotropic Strain-Stress Relation ........................ 399
9.8.2 Aligned Fiber Reinforced Composite Laminates ............. 400
9.8.3 Transformation of Fiber Reinforced Composite Laminate
Properties ....................................................4Q2
9.8.4 Reinforced Composite Laminates with a Fiber Orientation
Distribution Function....................................4q4
9.9 Strength Stability Under Heat ..................................405
References.....
................................................ 421
10 Failure and Damage of Polymers..........................................................423
10.1 Fracture Mechanics........................................................................................423
10.1.1 Fracture Predictions Based on the Stress Intensity Factor..........424
10.1.2 Fracture Predictions Based on an Energy Balance......................426
10.1.3 Linear Viscoelastic Fracture Predictions Based on /-Integrals . 428
10.2 Short-Term Tensile Strength ........................................................................430
10.2.1 Brittle Failure ..................................................................................430
10.2.2 Ductile Failure..................................................................................434
10.2.3 Failure of Highly Filled Systems or Composites ..........................437
10.3 Impact Strength..............................................................................................440
10.3.1 Impact Test Methods........................................................................446
10.3.2 Fracture Mechanics Analysis of Impact Failure ..........................450
10.4 Creep Rupture ................................................................................................455
10.4.1 Creep Rupture Tests........................................................................456
10.4.2 Fracture Mechanics Analysis of Creep Rupture ..........................459
10.5 Fatigue ............................................................................................................459
10.5.1 Fatigue Test Methods ......................................................................460
10.5.2 Fracture Mechanics Analysis of Fatigue Failure..........................468
10.6 Friction and Wear ..........................................................................................470
10.7 Stability of Polymer Structures ....................................................................473
10.8 Environmental Effects on Polymer Failure..................................................475
10.8.1 Weathering ......................................................................................475
10.8.2 Chemical Degradation ....................................................................480
10.8.3 Thermal Degradation of Polymers ................................................482
References ..............................................................................................................486
11 Electrical Properties of Polymers........................................................489
11.1 Dielectric Behavior ........................................................................................489
11.1.1 Dielectric Coefficient ......................................................................489
11.1.2 Mechanisms of Dielectrical Polarization ......................................493
11.1.3 Dielectric Dissipation Factor..........................................................496
11.1.4 Implications of Electrical and Thermal Loss in a Dielectric--------499
11.2 Electric Conductivity......................................................................................500
11.2.1 Electric Resistance..........................................................................500
11.2.2 Physical Causes of Volume Conductivity......................................501
11.3 Application Problems ....................................................................................504
11.3.1 Electric Breakdown..........................................................................504
11.3.2 Electrostatic Charge........................................................................508
..........................................509
11.3.4 Electromagnetic Interference Shielding (1;MI Shielding)............3 9
...........510
11.4 Magnetic Properties ...................................................................._U)
11.4.1 Magnetizability........................................
114 2 Magnetic Resonance....................................
..................511
References .........................................
12 Optical Properties of Polymers ............................................................3,3
12.1 Index of Refraction ........................................................................................513
12.2 Photoelasticity and Birefringence ................................................................316
12.3 Transparency, Reflection, Absorption, and Transmittance........................520
12.4 Gloss................................................................................................................326
12.5 Color................................................................................................................327
12.6 Infrared Spectroscopy....................................................................................331
12.7 Infrared Pyrometry........................................................................................533
12.8 Heating with Infrared Radiation ..................................................................534
References ..............................................................................................................536
13 Permeability Properties of Polymers..................................................537
13.1 Sorption ..........................................................................................................537
13.2 Diffusion and Permeation..............................................................................539
13.3 Measuring S, D, and P....................................................................................544
13.4 Corrosion of Polymers and Cracking [5]......................................................545
13.5 Diffusion of Polymer Molecules and Self-diffusion ....................................548
References ..............................................................................................................548
14 Acoustic Properties of Polymers..........................................................549
14.1 Speed of Sound ..............................................................................................549
14.2 Sound Reflection ..............................................................551
14.3 Sound Absorption ..................................................................552
References ............................................................................553
Appendix ..............................................................................................................555
Appendix I......................................................................................................556
Appendix II ..........................
Appendix III.....
................................................................................................dod
Appendix IV - Balance Equations........................................................................584
Continuity Equation ......................................................................................584
Energy Equation for a Newtonian Fluid ......................................................584
Momentum Balance ......................................................................................585
Momentum Equation in Terms of r..............................................................585
Navier-Stokes Equation..................................................................................585
Index......................................................................................................................587
|
| any_adam_object | 1 |
| author | Osswald, Tim A. 1958- |
| author_GND | (DE-588)1062689453 |
| author_facet | Osswald, Tim A. 1958- |
| author_role | aut |
| author_sort | Osswald, Tim A. 1958- |
| author_variant | t a o ta tao |
| building | Verbundindex |
| bvnumber | BV040453513 |
| callnumber-first | T - Technology |
| callnumber-label | TA455 |
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| callnumber-search | TA455.P58 |
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| callnumber-subject | TA - General and Civil Engineering |
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| classification_tum | WER 550f |
| ctrlnum | (OCoLC)813278497 (DE-599)BVBBV040453513 |
| dewey-full | 620.1/92 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 620 - Engineering and allied operations |
| dewey-raw | 620.1/92 |
| dewey-search | 620.1/92 |
| dewey-sort | 3620.1 292 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Physik Werkstoffwissenschaften Werkstoffwissenschaften / Fertigungstechnik |
| edition | 3. ed. |
| format | Book |
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| genre | 1\p (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV040453513 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:24:15Z |
| institution | BVB |
| isbn | 9781569905142 9781569905241 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025301104 |
| oclc_num | 813278497 |
| open_access_boolean | |
| owner | DE-573 DE-12 DE-703 DE-1102 DE-M347 DE-91G DE-BY-TUM DE-29T DE-210 DE-83 DE-898 DE-BY-UBR DE-1051 DE-11 |
| owner_facet | DE-573 DE-12 DE-703 DE-1102 DE-M347 DE-91G DE-BY-TUM DE-29T DE-210 DE-83 DE-898 DE-BY-UBR DE-1051 DE-11 |
| physical | XIX, 595 S. graph. Darst. 25 cm |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | Hanser [u.a.] |
| record_format | marc |
| spelling | Osswald, Tim A. 1958- Verfasser (DE-588)1062689453 aut Materials science of polymers for engineers Tim A. Osswald ; Georg Menges Material science of polymers for engineers 3. ed. Munich Hanser [u.a.] 2012 XIX, 595 S. graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Matières plastiques ram Polymères ram Plastics Polymers Werkstoffkunde (DE-588)4079184-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Stoffeigenschaft (DE-588)4192147-1 gnd rswk-swf 1\p (DE-588)4123623-3 Lehrbuch gnd-content Kunststoff (DE-588)4033676-1 s Werkstoffkunde (DE-588)4079184-1 s DE-604 Polymere (DE-588)4046699-1 s Stoffeigenschaft (DE-588)4192147-1 s 2\p DE-604 Menges, Georg Sonstige oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025301104&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Osswald, Tim A. 1958- Materials science of polymers for engineers Matières plastiques ram Polymères ram Plastics Polymers Werkstoffkunde (DE-588)4079184-1 gnd Polymere (DE-588)4046699-1 gnd Kunststoff (DE-588)4033676-1 gnd Stoffeigenschaft (DE-588)4192147-1 gnd |
| subject_GND | (DE-588)4079184-1 (DE-588)4046699-1 (DE-588)4033676-1 (DE-588)4192147-1 (DE-588)4123623-3 |
| title | Materials science of polymers for engineers |
| title_alt | Material science of polymers for engineers |
| title_auth | Materials science of polymers for engineers |
| title_exact_search | Materials science of polymers for engineers |
| title_full | Materials science of polymers for engineers Tim A. Osswald ; Georg Menges |
| title_fullStr | Materials science of polymers for engineers Tim A. Osswald ; Georg Menges |
| title_full_unstemmed | Materials science of polymers for engineers Tim A. Osswald ; Georg Menges |
| title_short | Materials science of polymers for engineers |
| title_sort | materials science of polymers for engineers |
| topic | Matières plastiques ram Polymères ram Plastics Polymers Werkstoffkunde (DE-588)4079184-1 gnd Polymere (DE-588)4046699-1 gnd Kunststoff (DE-588)4033676-1 gnd Stoffeigenschaft (DE-588)4192147-1 gnd |
| topic_facet | Matières plastiques Polymères Plastics Polymers Werkstoffkunde Polymere Kunststoff Stoffeigenschaft Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025301104&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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