Supercritical water: a green solvent: properties and uses
"This is the only book on the market that covers the issue of supercritical water in such a comprehensive way. The book begins with an introduction that defines supercritical fluids in general and supercritical water in particular and relates it to water along the saturation curve"--
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, N.J.
Wiley
2012
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Zusammenfassung: | "This is the only book on the market that covers the issue of supercritical water in such a comprehensive way. The book begins with an introduction that defines supercritical fluids in general and supercritical water in particular and relates it to water along the saturation curve"-- |
| Beschreibung: | XVI, 202 S. graph. Darst. |
| ISBN: | 9780470889473 |
Internformat
MARC
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Datensatz im Suchindex
| _version_ | 1804149489604231168 |
|---|---|
| adam_text | CONTENTS
Preface
ix
List of Acronyms and Symbols
xiii
1
Introduction
1
І.і
Phase Diagrams of Single Fluids
/ 1
1.2
The Critical Point
/ 3
1.3
Supercritical Fluids as Solvents
/ 5
1.4
Gaseous and Liquid Water
/ 8
1.5
Near-CriticalWater
/ 15
1.6
Summary
/ 17
2
Bulk Properties of SCW
22
2.1
Equations of StateflSoS)
/ 22
2.1.1
PVT Data for SCW
/ 22
2.1.2
Classical Equations of State of SCW
/ 24
2.1.3
Scaling Equations of State for SCW
/ 26
2.1.4
EoS of Supercritical Heavy Water
/ 29
2.2
Tbermophysical Properties of SCW
/ 30
2.2.1
Heat Capacity
/ 30
2.2.2
Enthalpy and Entropy
/ 32
2.2.3
Sound Velocity
/ 34
2.3
Electrical and Optical Properties
/ 34
2.3.1
Static Relative Permittivity
/ 34
2.3.2
Electrical Conductivity
/ 37
2.3.3
Light Refraction
/ 38
2.4
Transport Properties
/ 39
2.4.1
Viscosity
/ 39
2.4.2
Self-Diffusion
/ 41
VÍ
CONTENTS
2.4.3
Thermal
Conductivity
/ 42
2.5
Ionic Dissociation of SCW
/ 44
2.6
Properties Related to the Solvent Power of SCW
/ 47
2.7
Summary
/ 49
3
Molecular Properties of SCW
57
3.1
Diffraction Studies of SCW Structure
/ 60
3.1.1
Х
-Ray Diffraction Studies of SCW Structure
/ 61
3.1.2
Neutron Diffraction Studies of SCW Structure
/ 62
3.2
Computer Simulations of SCW
/ 66
3.2.1
Monte Carlo Simulations
/ 67
3.2.2
Molecular Dynamics Simulations
/ 70
3.3
Spectroscopic Studies of SCW
/ 74
3.3.1
Infrared Absorption Spectroscopy
/ 74
3.3.2
Raman Scattering Spectroscopy
/ 77
3.3.3
Nuclear Magnetic Resonance
/ 79
3.3.4
Dielectric Relaxation Spectroscopy
/ 82
3.4
The Extent of Hydrogen Bonding in SCW
/ 83
3.5
The Dynamics of Water Molecules in SCW
/ 90
3.6
Summary
/ 92
4
SCW as a Green Solvent
100
4.1
Solutions of Gases in SCW
/ 101
4.1.1
Phase Equilibria
/ 101
4.1.2
Interactions in the Solutions
/ 104
4.2
Solutions of Organic Substances in SCW
/ 106
4.2.1
Phase Equilibria
/ 106
4.2.2
Interactions in the Solutions
/
111
4.3
Solutions of Salts and Ions in SCW
/ 115
4.3.1
Solubilities of Salts and Electrolytes
/ 115
4.3.2
Thermodynamic Properties
/ 121
4.3.3
Transport Properties
/ 123
4.3.4
Ion Association in SCW
/ 129
4.3.5
Ion
Hydration
in SCW
/ 134
4.4
Binary Mixtures of Cosolvents with SCW
/ 138
4.5
Summary
/ 141
5
Applications of SCW
151
5.1
Conversion of Organic Substances to Fuel
/ 152
5.1.1
Conversion to Hydrogen and Natural Gas
/ 152
5.1.2
Conversion to Liquid Fuel
/ 156
5.2
Supercritical Water Oxidation
/ 157
CONTENTS
VU
5.2.1 General
Aspects
of SCWO Process
/ 158
5.2.2
Examples
of SCWO Applications
/ 160
5.3
Uses of SCW in Organic Synthesis
/ 162
5.4
Uses in Powder Technology of Inorganic Substances
/ 164
5.5
Geothermal Aspects of SCW
/ 166
5.6
Application of SCW in Nuclear Reactors
/ 169
5.7
Corrosion Problems with SCW
/ 171
5.8
Summary
/ 174
Author Index
183
Subject Index
199
|
| any_adam_object | 1 |
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| author_facet | Marcus, Yizhak |
| author_role | aut |
| author_sort | Marcus, Yizhak |
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| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541/.3482 |
| dewey-search | 541/.3482 |
| dewey-sort | 3541 43482 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| format | Book |
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| id | DE-604.BV040428001 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:23:51Z |
| institution | BVB |
| isbn | 9780470889473 |
| language | English |
| lccn | 2011049802 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025280554 |
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| physical | XVI, 202 S. graph. Darst. |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | Wiley |
| record_format | marc |
| spelling | Marcus, Yizhak Verfasser aut Supercritical water a green solvent: properties and uses Yizhak Marcus Hoboken, N.J. Wiley 2012 XVI, 202 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier "This is the only book on the market that covers the issue of supercritical water in such a comprehensive way. The book begins with an introduction that defines supercritical fluids in general and supercritical water in particular and relates it to water along the saturation curve"-- Wasser (DE-588)4064689-0 gnd rswk-swf Überkritischer Zustand (DE-588)4186602-2 gnd rswk-swf Lösungsmittel (DE-588)4036160-3 gnd rswk-swf Grüne Chemie (DE-588)7563215-9 gnd rswk-swf Wasser (DE-588)4064689-0 s Lösungsmittel (DE-588)4036160-3 s DE-604 Überkritischer Zustand (DE-588)4186602-2 s Grüne Chemie (DE-588)7563215-9 s Digitalisierung UB Regensburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025280554&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Marcus, Yizhak Supercritical water a green solvent: properties and uses Wasser (DE-588)4064689-0 gnd Überkritischer Zustand (DE-588)4186602-2 gnd Lösungsmittel (DE-588)4036160-3 gnd Grüne Chemie (DE-588)7563215-9 gnd |
| subject_GND | (DE-588)4064689-0 (DE-588)4186602-2 (DE-588)4036160-3 (DE-588)7563215-9 |
| title | Supercritical water a green solvent: properties and uses |
| title_auth | Supercritical water a green solvent: properties and uses |
| title_exact_search | Supercritical water a green solvent: properties and uses |
| title_full | Supercritical water a green solvent: properties and uses Yizhak Marcus |
| title_fullStr | Supercritical water a green solvent: properties and uses Yizhak Marcus |
| title_full_unstemmed | Supercritical water a green solvent: properties and uses Yizhak Marcus |
| title_short | Supercritical water |
| title_sort | supercritical water a green solvent properties and uses |
| title_sub | a green solvent: properties and uses |
| topic | Wasser (DE-588)4064689-0 gnd Überkritischer Zustand (DE-588)4186602-2 gnd Lösungsmittel (DE-588)4036160-3 gnd Grüne Chemie (DE-588)7563215-9 gnd |
| topic_facet | Wasser Überkritischer Zustand Lösungsmittel Grüne Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025280554&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT marcusyizhak supercriticalwateragreensolventpropertiesanduses |