N-heterocyclic carbenes of late transition metals in catalysis: anion influence and green chemistry applications
Gespeichert in:
1. Verfasser: | |
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Format: | Abschlussarbeit Buch |
Sprache: | English |
Veröffentlicht: |
München
Verl. Dr. Hut
2012
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Ausgabe: | 1. Aufl. |
Schriftenreihe: | Anorganische Chemie
|
Schlagworte: | |
Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
Beschreibung: | 161 S. graph. Darst. |
ISBN: | 9783843904919 |
Internformat
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Datensatz im Suchindex
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adam_text |
IMAGE 1
TABLE OF CONTENTS
1. INTRODUCTION 1
1.1 CARBENES AND ITS SPIN STATES 1
1.2 TYPES OF TRANSITION METAL CARBENE COMPLEXES 2
1.3 TYPES OF N-HETEROCYCLIC CARBENES 4
1.4 NHC-BASED METAL COMPLEXES IN CATALYSIS 5
1.5 COUNTERIONS OF COMPLEXES IN CATALYSIS 9
1.6 PALLADIUM-CATALYZED CHEMISTRY 10
1.7 SUZUKI-MIYAURA COUPLING REACTION 10
1.8 TRANSFER HYDROGENATION 13
1.9 OBJECTIVE 15
PHTHALIMIDO-FUNCTIONALIZED NHC PD(LL) COMPLEXES IN SUZUKI-MIYAURA
COUPLING REACTION 15
ANION INFLUENCES OF DICYCLOHEXYL-NHC LR(L) COMPLEXES IN TRANSFER
HYDROGENATION 17
HYDROXYL-FUNCTIONALIZED BIS-NHC RH(L) AND PD(LL) COMPLEXES AS HOMOGENOUS
AND HETERO
GENEOUS CATALYSTS IN TRANSFER HYDROGENATION AND SUZUKI-MIYAURA COUPLING
REACTION 19
REFERENCES 21
2. A COMPARISON OF PHTHALIMIDO-FUNCTIONALIZED N-HETERO
CYCLIC CARBENE COMPLEXES OF PALLADIUM(II) WITH DIFFERENT
CLASS OF LIGANDS: SYNTHESIS, CHARACTERIZATION, AND CATALYSIS
APPLICATION IN SUZUKI-MIYAURA COUPLING REACTION 29
2.1 INTRODUCTION 2 9
2.2 RESULTS AND DISCUSSION 31
2.2.1 SYNTHESIS OF LIGANDS AND PALLADIUM COMPLEXES 31
2.2.2 CRYSTAL STRUCTURES AND NMR ANALYSIS 33
2.2.3 CATALYTIC APPLICATION IN SUZUKI-MIYAURA COUPLING REACTION 4 0
2.3 CONCLUSION
EXPERIMENTAL SECTION
REFERENCES
55
5 7
71
HTTP://D-NB.INFO/1023999404
IMAGE 2
3. ANION INFLUENCES: KINETIC STUDIES OF CATIONIC AND NEUTRAL
DICYCLOHEXYLIMIDAZOL-2-YLIDENE COD IRIDIUM(I) COMPLEXES IN
TRANSFER HYDROGENATION USING IN-SITU IR 77
3.1 INTRODUCTION 77
3.2 RESULTS AND DISCUSSION 8 0
3.2.1 SYNTHESIS OF THE LR(L) COMPLEXES AND THEIR CRYSTAL STRUCTURES 80
3.2.2 MECHANISM OF TRANSFER HYDROGENATION 82
3.2.3 INITIAL STUDIES WITH [LR(L)(CYNHC)(COD)]CI CATALYST 83
3.2.4 ANALYTICAL METHOD USING IN-SITU INFRARED RED SPECTROMETER 85
3.2.5 SEQUENCE OF SUBSTRATE, BASE AND CATALYST ADDITION 86
3.2.6 VARIATION OF BASE LOADING 86
3.2.7 COMPARISON OF CATALYSTS WITH DIFFERENT ANIONS 90
3.2.8 KINETIC ISOTOPE EFFECTS 94
3.2.9 DISSOCIATION O F ANIONS 96
3.2.10 VARIABLE CONCENTRATION OF COD 97
3.2.11 [LR(L)(CYNHC)(COD)]CI AS CATALYST IN HYDROGENATION 98
3.3 CONCLUSION 98
EXPERIMENTAL SECTION 101
REFERENCES 111
4. SYMMETRICAL BRIDGED HYDROXYL-FUNCTIONALIZED BIS-N-
HETEROCYCLIC CARBENE RHODIUM(I) AND PALLADIUM(II) COMPLEXES
AND THEIR CATALYTIC APPLICATIONS IN TRANSFER HYDROGENATION
AND SUZUKI-MIYAURA COUPLING REACTION 115
4.1 INTRODUCTION 115
4.2 RESULTS AND DISCUSSION 117
4.2.1 SYNTHESIS AND CHARACTERIZATION OF MOLECULAR CARBENE COMPLEXES 117
LIGAND SYNTHESIS 117
ANION EXCHANGE REACTIONS 119
SYNTHESIS OF BIS-NHC RH(L), BIS-NHC AG(L), AND BIS-NHC PD(LL) COMPLEXES
120
IMMOBILIZATION OF 1D ON 4-(BROMOMETHYL) PHENOXYMETHYL POLYSTYRENE 123
4.2.2 CATALYTIC ACTIVITY OF BIS-NHC RH(L) COMPLEXES IN TRANSFER
HYDROGENATION 124
4.2.3 CATALYTIC ACTIVITY OF BIS-NHC PD(LL) COMPLEXES IN SUZUKI-MIYAURA
COUPLING REACTION 129
IMAGE 3
4.3 CONCLUSION 132
EXPERIMENTAL SECTION 133
REFERENCES 149
5. SUMMARY 153
PHTHALIMIDO-FUNCTIONALIZED NHC PD(LL) COMPLEXES IN SUZUKI-MIYAURA
COUPLING REACTION 153 ANION INFLUENCES OF DICYCLOHEXYL-NHC LR(L)
COMPLEXES IN TRANSFER HYDROGENATION 156
HYDROXYL-FUNCTIONALIZED BIS-NHC RH(L) AND PD(LL) COMPLEXES AS HOMOGENOUS
AND
HETEROGENOUS CATALYSTS IN TRANSFER HYDROGENATION AND SUZUKI-MIYAURA
COUPLING REACTION 159 |
any_adam_object | 1 |
author | Goh, Li Min Serena |
author_facet | Goh, Li Min Serena |
author_role | aut |
author_sort | Goh, Li Min Serena |
author_variant | l m s g lms lmsg |
building | Verbundindex |
bvnumber | BV040336803 |
classification_rvk | VK 5577 |
classification_tum | CHE 670d CHE 376d CHE 369d CHE 167d CHE 612d CHE 050d |
ctrlnum | (OCoLC)840903055 (DE-599)DNB1023999404 |
dewey-full | 547.593044242 546.6 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 547 - Organic chemistry 546 - Inorganic chemistry |
dewey-raw | 547.593044242 546.6 |
dewey-search | 547.593044242 546.6 |
dewey-sort | 3547.593044242 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie Physik Chemie |
edition | 1. Aufl. |
format | Thesis Book |
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spelling | Goh, Li Min Serena Verfasser aut N-heterocyclic carbenes of late transition metals in catalysis anion influence and green chemistry applications Li Min Serena Goh 1. Aufl. München Verl. Dr. Hut 2012 161 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2011 Katalyse (DE-588)4029921-1 gnd rswk-swf Iridiumkomplexe (DE-588)4223130-9 gnd rswk-swf Carbene (DE-588)4147281-0 gnd rswk-swf Stickstoffheterocyclen (DE-588)4183269-3 gnd rswk-swf Palladiumkomplexe (DE-588)4223138-3 gnd rswk-swf Rhodiumkomplexe (DE-588)4314155-9 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Carbene (DE-588)4147281-0 s Stickstoffheterocyclen (DE-588)4183269-3 s Iridiumkomplexe (DE-588)4223130-9 s Palladiumkomplexe (DE-588)4223138-3 s Rhodiumkomplexe (DE-588)4314155-9 s Katalyse (DE-588)4029921-1 s DE-604 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4071148&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025191132&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Goh, Li Min Serena N-heterocyclic carbenes of late transition metals in catalysis anion influence and green chemistry applications Katalyse (DE-588)4029921-1 gnd Iridiumkomplexe (DE-588)4223130-9 gnd Carbene (DE-588)4147281-0 gnd Stickstoffheterocyclen (DE-588)4183269-3 gnd Palladiumkomplexe (DE-588)4223138-3 gnd Rhodiumkomplexe (DE-588)4314155-9 gnd |
subject_GND | (DE-588)4029921-1 (DE-588)4223130-9 (DE-588)4147281-0 (DE-588)4183269-3 (DE-588)4223138-3 (DE-588)4314155-9 (DE-588)4113937-9 |
title | N-heterocyclic carbenes of late transition metals in catalysis anion influence and green chemistry applications |
title_auth | N-heterocyclic carbenes of late transition metals in catalysis anion influence and green chemistry applications |
title_exact_search | N-heterocyclic carbenes of late transition metals in catalysis anion influence and green chemistry applications |
title_full | N-heterocyclic carbenes of late transition metals in catalysis anion influence and green chemistry applications Li Min Serena Goh |
title_fullStr | N-heterocyclic carbenes of late transition metals in catalysis anion influence and green chemistry applications Li Min Serena Goh |
title_full_unstemmed | N-heterocyclic carbenes of late transition metals in catalysis anion influence and green chemistry applications Li Min Serena Goh |
title_short | N-heterocyclic carbenes of late transition metals in catalysis |
title_sort | n heterocyclic carbenes of late transition metals in catalysis anion influence and green chemistry applications |
title_sub | anion influence and green chemistry applications |
topic | Katalyse (DE-588)4029921-1 gnd Iridiumkomplexe (DE-588)4223130-9 gnd Carbene (DE-588)4147281-0 gnd Stickstoffheterocyclen (DE-588)4183269-3 gnd Palladiumkomplexe (DE-588)4223138-3 gnd Rhodiumkomplexe (DE-588)4314155-9 gnd |
topic_facet | Katalyse Iridiumkomplexe Carbene Stickstoffheterocyclen Palladiumkomplexe Rhodiumkomplexe Hochschulschrift |
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