Late transition metal amido complexes: electronic structure and reactivity
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online-Zugang: | Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120515-1106483-1-5 Inhaltsverzeichnis |
| Beschreibung: | 177 S. graph. Darst. |
Internformat
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Datensatz im Suchindex
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|---|---|
| adam_text | IMAGE 1
TABLE O F CONTENTS
A INTRODUCTION 11
1 LATE TRANSITION METAL AMIDO COMPLEXES: METAL-LIGAND BONDING AND
REACTIVITY 12
2 LATE TRANSITION METAL AMIDO COMPLEXES: RELEVANCE FOR CATALYSIS AND MLC
16
3 GOAL AND MOTIVATION 19
B RESULTS AND DISCUSSION 21
1 REACTIVITY O F IRIDIUM(I) PNP AMIDO COMPLEX TOWARDS PROTONATION AND
OXIDATION 22
1.1 INTRODUCTION 23
1.2 RESULTS AND DISCUSSION 25
1.3 CONCLUSION 30
1.4 EXPERIMENTAL SECTION 30
1.5 CYCLIC VOLTAMMETRY 33
1.6 COMPUTATIONAL METHODS 34
2 A SQUARE-PLANAR RUTHENIUM(II) COMPLEX WITH LOW-SPIN CONFIGURATION 38
2.1 INTRODUCTION 39
2.2 RESULTS AND DISCUSSION 40
2.3 CONCLUSION 45
2.4 SYNTHETIC AND ANALYTICAL DETAILS 46
2.5 SINGLE CRYSTAL X-RAY DIFFRACTION 48
2.6 SPECTROSCOPIC RESULTS 49
2.7 COMPUTATIONAL RESULTS 56
3 SQUARE-PLANAR RUTHENIUM(II) PNP PINCER COMPLEXES: CONTROL OF
ELECTRONIC STRUCTURE BY TUNING O F N-M T :-DONATION 64
3.1 INTRODUCTION 65
3.2 RESULTS AND DISCUSSION 69
3.3 CONCLUSIONS 78
3.4 SYNTHETIC AND ANALYTICAL DETAILS 79
3.5 SPECTROSCOPIC RESULTS 82
3.6 COMPUTATIONAL RESULTS 87
HTTP://D-NB.INFO/1026863589
IMAGE 2
4 AMMONIA FORMATION BY METAL-LIGAND COOPERATIVE HYDROGENOLYSIS
O F A NITRIDO LIGAND 89
4.1 ABSTRACT 90
4.2 INTRODUCTION 90
4.3 RESULTS AND DISCUSSION 92
4.4 CONCLUSIONS 99
4.5 SYNTHETIC AND ANALYTICAL DETAILS 101
4.6 CRYSTALLOGRAPHIC DETAILS 107
4.7 COMPUTATIONAL EXAMINATIONS 109
5 LEARNING FROM THE NEIGHBOURS: IMPROVING HOMOGENEOUS CATALYSTS WITH
FUNCTIONAL LIGANDS MOTIVATED BY HETEROGENEOUS AND BIO-CATALYSIS 124
5.1 INTRODUCTION 125
5.2 INSPIRATION FROM HETEROGENEOUS CATALYSIS: HOMOGENEOUS
POLYMERIZATION CATALYSTS WITH LEWIS ACIDIC CO-LIGANDS 126
5.3 BIO-INSPIRED HOMOGENEOUS CATALYSIS: METAL-LIGAND
COOPERATING (MLC) CATALYSIS 130
5.4 CONCLUDING REMARKS 15 5
C SUMMARY 157
D ZUSAMMENFASSUNG 165
E LIST O F PUBLICATION 173
1 JOURNAL PUBLICATIONS 174
1 PRESENTATIONS 174
F CURRICULUM VITAE 175
|
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| discipline | Chemie / Pharmazie Chemie |
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| spelling | Askevold, Björn Birger 1982- Verfasser (DE-588)1026863449 aut Late transition metal amido complexes electronic structure and reactivity Björn Birger Askevold 2012 177 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2012 Chemische Synthese (DE-588)4133806-6 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Übergangsmetallkomplexe (DE-588)4131837-7 s Chemische Synthese (DE-588)4133806-6 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:91-diss-20120515-1106483-1-5 http://mediatum.ub.tum.de/node?id=1106483 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120515-1106483-1-5 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025175301&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Askevold, Björn Birger 1982- Late transition metal amido complexes electronic structure and reactivity Chemische Synthese (DE-588)4133806-6 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4133806-6 (DE-588)4131837-7 (DE-588)4113937-9 |
| title | Late transition metal amido complexes electronic structure and reactivity |
| title_auth | Late transition metal amido complexes electronic structure and reactivity |
| title_exact_search | Late transition metal amido complexes electronic structure and reactivity |
| title_full | Late transition metal amido complexes electronic structure and reactivity Björn Birger Askevold |
| title_fullStr | Late transition metal amido complexes electronic structure and reactivity Björn Birger Askevold |
| title_full_unstemmed | Late transition metal amido complexes electronic structure and reactivity Björn Birger Askevold |
| title_short | Late transition metal amido complexes |
| title_sort | late transition metal amido complexes electronic structure and reactivity |
| title_sub | electronic structure and reactivity |
| topic | Chemische Synthese (DE-588)4133806-6 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Chemische Synthese Übergangsmetallkomplexe Hochschulschrift |
| url | http://mediatum.ub.tum.de/node?id=1106483 https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120515-1106483-1-5 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025175301&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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