Chemistry and the environment:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge [u.a.]
Cambridge Univ. Press
2012
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | XII, 427 S. Ill., graph. Darst. |
| ISBN: | 9781107021556 9781107682573 |
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Datensatz im Suchindex
| _version_ | 1804149267162464256 |
|---|---|
| adam_text | Contents
Preface
page
xi
Acknowledgments
xiii
Introduction
1
1
The Earth
4
1.1
Origin of the Earth
4
a. Big Bang
4
b. The solar system
7
с
The Earth
10
1.2
Structure of the Earth
14
a. Classical measurements
14
b. Internal structure of the Earth
17
1.3
Geological periods and dating
21
a. Geological periods
21
b. Radioactive dating
23
с
Isotopie fractionation
26
1.4
Features of the Earth s development
31
a. Plate tectonics
31
b. Chemistry mediated by water and biota
34
с
Global chemistry of life
35
2
Environmental dynamics
37
2.1
Introduction
37
a. Basic concepts
37
b. Time dependence of concentration
40
с
Field
43
d. Transport
44
2.2
Fluid dynamics
45
a. Basic properties of the flux density
45
b. Open physicochemical systems
49
с
Continuity equations
51
d. Equations of motion
54
e. Applications of the equations of motion
56
f. Applications of the continuity equation
65
2.3
Chemical thermodynamics
69
a. Basic concepts
70
b. Phase equilibria
81
Contents
2.4 Chemical
kinetics
91
a.
Basic
concepts
92
b.
Description of elementary reactions
92
с
Temperature dependence of reaction rates
94
3
The Spheres
98
3.1
The
lithosphère
99
a. Abundance of the elements
100
b. The rock-forming minerals
102
с
Igneous rocks
109
d. Sedimentary rocks
112
e. Metamorphic rocks
114
3.2
The hydrosphere
115
a. Chemical composition of natural waters
116
b. Analytical characteristics of environmental waters
117
c. Physicochemical
properties of water
121
3.3
The atmosphere
124
a. Chemical composition
124
b. Hydrosphere-atmosphere equilibria
126
с
The physics of the atmosphere
128
3.4
Biota
131
a. Chemical composition of biota
131
b. The cell
135
4
Chemistry of the atmosphere
140
4.1
Tropospheric chemistry
142
a. The hydroxyl radical
142
b. Nonmethane hydrocarbons
151
с
Tropospheric aerosols
154
d. Henry s law and deposition
155
4.2
Stratospheric chemistry
156
a. The Chapman mechanism: Ox
157
b. The radicals W)x
159
с
The radicals NOX
160
d. The radicals
С10х
and coupling of the cycles
161
e. The ozone hole
163
f. Midlatitude ozone depletion
166
5
Chemistry of the hydrosphere
169
5.1
Acid-base chemistry
170
a. Acid-base properties of water
171
b. An acid and its conjugate base
172
c. Oligovalent
acids
178
d. Polwaient
яслЛч
187
Contents
5.2
Coordination
chemistry
189
a. Complex formation
190
b. Lewis acids and bases
194
с
Coordination chemistry of natural waters
196
5.3
Electrolytic properties
200
a. Redox
chemistry of natural waters
201
b. Aqueous solutions of electrolytes
206
6
Chemistry of the pedosphere
217
6.1
Structure of soil
218
a. Soil profile
218
b. Regolith and groundwater
220
6.2
Physics of soil water
222
a. The saturated zone
222
b. The
vadose zone
224
с
Flowing groundwater
226
6.3
Chemistry of soils
228
a. Structure of soil minerals
230
b. The soil solution
236
с
Soil adsorption phenomena
238
d. Soil colloid phenomena
246
e. Soil organic matter
248
7
Global cycles of the elements
250
7.1
Biogeochemical cycles
250
7.2
Carbon
251
a. Reservoirs of carbon
251
b. Fluxes of carbon dioxide
253
с
Fluxes of methane
255
d. Anthropogenic sources of atmospheric carbon dioxide
255
7.3
Nitrogen
256
a. Natural nitrogen fixation
256
b. Industrial nitrogen fixation
261
7.4
Phosphorus
263
7.5
Sulfur
265
a. Natural sulfur cycles
266
b. Anthropogenic sulfur cycles
267
7.6
Chlorine
270
7.7
Aluminium and silicon
272
8
The chemicals industry
273
8.1
Introduction
273
a. Energy
274
b. A
survey of the chemicals industry
275
v¡¡j
Contents
c.
The agriculture and food industries
277
d. Chemical production
279
8.2
Heavy industry
282
a. Cement
282
b. Coal and steel
285
с
Metals
289
d. Pulp and paper
292
8.3
The inorganic chemicals industry
294
a. The electrolytic cell
296
b. Sodium hydroxide
299
с
Sodium carbonate
299
d. Chlorine
302
8.4
The biotechnology industry
304
8.5
Sustainable synthetic chemistry: Green chemistry
304
9
Environmental impact of selected chemicals
310
9.1
Pesticides
310
a. Insecticides
312
b. Herbicides
315
с
Fungicides
318
d. Enantiomeric xenobiotics
320
9.2
Organochlorine compounds
323
a.
Dioxins
and (polychloro)biphenyls
323
b. Hexachlorocyclohexane, HCH, and pentachlorocyclohexene,
PCCH
326
с
Bromocyclenes
328
9.3
Metal compounds
328
9.4
Detergents
330
a. Soaps
331
b. Syndets
332
с
The Gibbs isotherm
334
9.5
Water treatment
335
a. Domestic water
336
b. Industrial water
338
с
General methods
339
10
The chemistry of climate change
343
10.1
The physics of thermal radiation
344
a. Quantitative expressions
344
b. Radiation theory
345
с
Application to the Sun-Earth system
348
10.2
Astronomical forcing
352
a. The insolation formula
353
b. Time dependence of insolation
355
с
Climate recorded in sediments and glacial ice
358
Contents
10.3 Modern
climate
360
a. Causes
of climate
change
361
b. Energy
flux densities in the atmosphere
361
с
Radiant forcing
362
d. Global warming potential
365
e. Climate sensitivity
365
f. Climate change
367
Appendix
1 371
Al.l Symbols of the elements
371
A1.2 Atomic weights of the elements
372
A
1.3
The international system of units, SI
375
A
1.4
Nonstandard
units and suffixes
376
A
1.5
Transport properties
377
A
1.6
Electricity
377
Al.
7
General chemistry
378
Al.
8
Fundamental constants
379
A
1.9
α
-Amino
acids of proteins
379
A
1.10
The Greek alphabet
380
Appendix
2 381
A2.1 Polyvalent acids
381
A2.2 Mononuclear complexes
385
a. Polynuclear complexes
387
Appendix
3 389
A3.1 The activity of electrolytes
389
a. The
Debye-Hückel
limiting law
389
Appendix
4 393
A4.1 Convection
393
Appendix
5 396
A5.1 Parameters of the insolation formula, Equation
10.29 396
a. The 24-h mean insolation at a geographical latitude
φ
396
b.
The ecliptic
398
References
401
Name index
415
Subject index
417
Chemistry and the Environment
From the origin of the Earth to climate change, this textbook presents the chemistry of
the environment using the full strength of physical, inorganic, and organic chemistry,
in addition to the necessary mathematics and physics, using modern notation and
terminology. It provides a broad yet thorough description of the environment and the
environmental impact of human activity using scientific principles.
Chemistry and the Environment describes the chemistry of Earth s atmosphere,
hydrosphere, and
lithosphère
(including soils) and the biogeochemical cycles. The
book presents a variety of industrial processes, from paper and steel to energy and
pesticide production, focusing discussion on the environmental impact of these pro¬
cesses and showing how increasing environmental awareness has led to improved
methods. The text provides an accessible account of environmental chemistry while
paying attention to the fundamental basis of the science, showing derivations of
formulas and giving primary references and historical insight. The authors make
consistent use of professionally accepted nomenclature (IUPAC and SI), allowing
transparent access to the material by students and scientists from other fields.
The authors created this textbook primarily for their own courses, and it has been
developed through many years of feedback from students and colleagues. The book
will be invaluable for advanced undergraduate and graduate students in environmental
chemistry courses, and for professionals in chemistry and allied fields.
Sven
E.
Harnung
is a Senior Lecturer in the Department of Chemistry at the Univer¬
sity of Copenhagen and was Head of Department for
12
years. He teaches courses
on environmental, inorganic, physical, and analytical chemistry, including pharma¬
ceutical applications. His current research concentrates on magnetic studies of
single-molecule magnets. He is the author of three chemistry textbooks in Danish.
Dr. Harming has organized several congresses, including an International Union of
Pure and Applied Chemistry (IUPAC) General Assembly. He has been a member of
the Danish National Committee for Chemistry for more than
30
years, and he is a
Fellow of IUPAC. He has served as a board member of the journals
Acta Chemica
Scandinavica and Physical Chemistry Chemical Physics.
Matthew S. Johnson is a Senior Lecturer at the Department of Chemistry at the Uni¬
versity of Copenhagen. He teaches courses on environmental chemistry, physical and
quantum chemistry, and scientific writing. His main research interest is atmospheric
chemistry, including kinetics, spectroscopy, and stable isotopes in atmospheric trace
gases. He is a coauthor of more than
70
articles in peer-reviewed journals. He has
invented and patented a method for efficient emissions control and improving build¬
ing energy efficiency. He was awarded a Fulbright Fellowship to study stratospheric
chemistry at the Max-lab electron storage ring in Lund, Sweden. He has worked as a
researcher for Honeywell and Medtronic and has research collaborations with many
groups around the world, including Ford Motor Company and the Tokyo Institute of
Technology.
|
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| discipline | Chemie / Pharmazie Geologie / Paläontologie Geographie |
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| genre_facet | Einführung |
| id | DE-604.BV040264987 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:20:19Z |
| institution | BVB |
| isbn | 9781107021556 9781107682573 |
| language | English |
| lccn | 2011053164 |
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| spelling | Harnung, Sven E. Verfasser (DE-588)1023555476 aut Chemistry and the environment Sven E. Harnung ; Matthew S. Johnson 1. publ. Cambridge [u.a.] Cambridge Univ. Press 2012 XII, 427 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Geowissenschaften Environmental chemistry SCIENCE / Earth Sciences / General bisacsh Ökologische Chemie (DE-588)4135167-8 gnd rswk-swf Geowissenschaften (DE-588)4020288-4 gnd rswk-swf Geochemie (DE-588)4020198-3 gnd rswk-swf (DE-588)4151278-9 Einführung gnd-content Ökologische Chemie (DE-588)4135167-8 s Geowissenschaften (DE-588)4020288-4 s DE-604 Geochemie (DE-588)4020198-3 s Johnson, Matthew S. 1966- Verfasser (DE-588)1027327273 aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025120690&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025120690&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Harnung, Sven E. Johnson, Matthew S. 1966- Chemistry and the environment Geowissenschaften Environmental chemistry SCIENCE / Earth Sciences / General bisacsh Ökologische Chemie (DE-588)4135167-8 gnd Geowissenschaften (DE-588)4020288-4 gnd Geochemie (DE-588)4020198-3 gnd |
| subject_GND | (DE-588)4135167-8 (DE-588)4020288-4 (DE-588)4020198-3 (DE-588)4151278-9 |
| title | Chemistry and the environment |
| title_auth | Chemistry and the environment |
| title_exact_search | Chemistry and the environment |
| title_full | Chemistry and the environment Sven E. Harnung ; Matthew S. Johnson |
| title_fullStr | Chemistry and the environment Sven E. Harnung ; Matthew S. Johnson |
| title_full_unstemmed | Chemistry and the environment Sven E. Harnung ; Matthew S. Johnson |
| title_short | Chemistry and the environment |
| title_sort | chemistry and the environment |
| topic | Geowissenschaften Environmental chemistry SCIENCE / Earth Sciences / General bisacsh Ökologische Chemie (DE-588)4135167-8 gnd Geowissenschaften (DE-588)4020288-4 gnd Geochemie (DE-588)4020198-3 gnd |
| topic_facet | Geowissenschaften Environmental chemistry SCIENCE / Earth Sciences / General Ökologische Chemie Geochemie Einführung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025120690&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025120690&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT harnungsvene chemistryandtheenvironment AT johnsonmatthews chemistryandtheenvironment |