Adsorption technology in water treatment: fundamentals, processes, and modeling
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
De Gruyter
2012
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | IX, 332 S. Ill., graph. Darst. |
| ISBN: | 311024022X 9783110240221 |
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| 245 | 1 | 0 | |a Adsorption technology in water treatment |b fundamentals, processes, and modeling |c Eckhard Worch |
| 264 | 1 | |a Berlin [u.a.] |b De Gruyter |c 2012 | |
| 300 | |a IX, 332 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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Datensatz im Suchindex
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IMAGE 1
CONTENTS
PREFACE XI
1 INTRODUCTION 1
1.1 BASIC CONCEPTS A N D DEFINITIONS 1
1.1.1 A D S O R P T I O N AS A SURFACE PROCESS 1
1.1.2 S O M E GENERAL T H E R M O D Y N A M I C CONSIDERATIONS 2
1.1.3 A D S O R P T I O N VERSUS A B S O R P T I O N 3
1.1.4 DESCRIPTION O F A D S O R P T I O N PROCESSES: T H E STRUCTURE O F
T H E
A D S O R P T I O N T H E O R Y 3
1.2 E N G I N E E R E D A D S O R P T I O N PROCESSES IN W A T E R T R E
A T M E N T 5
1.2.1 O V E R V I E W 5
1.2.2 D R I N K I N G W A T E R T R E A T M E N T 6
1.2.3 W A S T E W A T E R T R E A T M E N T 6
1.2.4 H Y B R I D PROCESSES IN W A T E R T R E A T M E N T 7
1.3 N A T U R A L SORPTION PROCESSES IN W A T E R T R E A T M E N T 8
2 ADSORBENTS AND ADSORBENT CHARACTERIZATION 11
2.1 I N T R O D U C T I O N A N D A D S O R B E N T CLASSIFICATION 11
2.2 E N G I N E E R E D A D S O R B E N T S 12
2.2.1 A C T I V A T E D C A R B O N 12
2.2.2 POLYMERIC A D S O R B E N T S 15
2.2.3 OXIDIC A D S O R B E N T S 16
2.2.4 SYNTHETIC ZEOLITES 17
2.3 N A T U R A L A N D LOW-COST A D S O R B E N T S 18
2.4 G E O S O R B E N T S IN E N V I R O N M E N T A L C O M P A R T M E
N T S 19
2.5 A D S O R B E N T CHARACTERIZATION 2 0
2.5.1 DENSITIES 2 0
2.5.2 POROSITIES 2 2
2.5.3 E X T E R N A L SURFACE A R E A 2 3
2.5.4 INTERNAL SURFACE A R E A 2 5
2.5.5 PORE-SIZE DISTRIBUTION 2 8
2.5.6 SURFACE CHEMISTRY 34
3 ADSORPTION EQUILIBRIUM I: GENERAL ASPECTS AND SINGLE-SOLUTE ADSORPTION
. . . 4 1
3.1 I N T R O D U C T I O N 4 1
3.2 E X P E R I M E N T A L D E T E R M I N A T I O N O F EQUILIBRIUM D
A T A 4 2
3.2.1 BASICS 4 2
HTTP://D-NB.INFO/1018440615
IMAGE 2
VI | C O N T E N T S
3.2.2 PRACTICAL ASPECTS O F ISOTHERM D E T E R M I N A T I O N 45
3.3 I S O T H E R M E Q U A T I O N S F O R SINGLE-SOLUTE A D S O R P T
I O N 4 7
3.3.1 CLASSIFICATION O F SINGLE-SOLUTE I S O T H E R M E Q U A T I O N S
4 7
3.3.2 IRREVERSIBLE ISOTHERM A N D O N E - P A R A M E T E R I S O T H E
R M 4 8
3.3.3 T W O - P A R A M E T E R ISOTHERMS 4 9
3.3.4 T H R E E - P A R A M E T E R ISOTHERMS 5 5
3.3.5 I S O T H E R M E Q U A T I O N S WITH M O R E T H A N T H R E E P
A R A M E T E R S 5 8
3.4 PREDICTION O F ISOTHERMS 5 9
3.5 T E M P E R A T U R E D E P E N D E N C E O F A D S O R P T I O N 64
3.6 SLURRY A D S O R B E R DESIGN 67
3.6.1 G E N E R A L ASPECTS 67
3.6.2 SINGLE-STAGE A D S O R P T I O N 69
3.6.3 TWO-STAGE A D S O R P T I O N 72
3.7 A P P L I C A T I O N O F I S O T H E R M D A T A IN KINETIC O R B R
E A K T H R O U G H
CURVE M O D E L S 7 4
4 ADSORPTION EQUILIBRIUM II: MULTISOLUTE ADSORPTION 77
4.1 I N T R O D U C T I O N 77
4.2 E X P E R I M E N T A L D E T E R M I N A T I O N O F EQUILIBRIUM D
A T A 7 8
4.3 O V E R V I E W O F EXISTING MULTISOLUTE A D S O R P T I O N M O D E
L S 8 0
4.4 MULTISOLUTE ISOTHERM E Q U A T I O N S 8 1
4.5 T H E IDEAL A D S O R B E D SOLUTION T H E O R Y ( I A S T ) 84
4.5.1 BASICS O F T H E I A S T 8 4
4.5.2 SOLUTION T O T H E I A S T F O R GIVEN EQUILIBRIUM CONCENTRATIONS
8 8
4.5.3 SOLUTION T O T H E I A S T F O R GIVEN INITIAL CONCENTRATIONS 90
4.6 T H E P H D E P E N D E N C E O F ADSORPTION: A SPECIAL CASE OF
COMPETITIVE A D S O R P T I O N 94
4.7 A D S O R P T I O N O F N A T U R A L ORGANIC M A T T E R ( N O M )
9 8
4.7.1 T H E SIGNIFICANCE O F N O M IN ACTIVATED C A R B O N A D S O R P
T I O N 9 8
4.7.2 M O D E L I N G O F N O M ADSORPTION: T H E ACTIVE C O M P O N E N
T A P P R O A C H (ADSORPTION ANALYSIS) 100
4.7.3 COMPETITIVE ADSORPTION O F MICROPOLLUTANTS A N D N O M 104
4.8 SLURRY A D S O R B E R DESIGN F O R MULTISOLUTE A D S O R P T I O N
I L L
4.8.1 BASICS I L L
4.8.2 N O M A D S O R P T I O N 112
4.8.3 C O M P E T I T I V E A D S O R P T I O N O F MICROPOLLUTANTS A N
D N O M 113
4.8.4 N O N E Q U I L I B R I U M A D S O R P T I O N IN SLURRY REACTORS
118
4.9 SPECIAL APPLICATIONS O F T H E ACTIVE C O M P O N E N T A P P R O A
C H 120
IMAGE 3
C O N T E N T S | VII
5 ADSORPTION KINETICS 123
5.1 INTRODUCTION 123
5.2 M A S S TRANSFER M E C H A N I S M S 123
5.3 E X P E R I M E N T A L D E T E R M I N A T I O N O F KINETIC CURVES
124
5.4 M A S S TRANSFER M O D E L S 127
5.4.1 G E N E R A L CONSIDERATIONS 127
5.4.2 FILM DIFFUSION 129
5.4.3 SURFACE DIFFUSION 136
5.4.4 P O R E DIFFUSION 143
5.4.5 C O M B I N E D SURFACE A N D P O R E DIFFUSION 149
5.4.6 SIMPLIFIED INTRAPARTICLE DIFFUSION M O D E L ( L D F M O D E L )
153
5.4.7 R E A C T I O N KINETIC M O D E L S 162
5.4.8 A D S O R P T I O N KINETICS IN M U L T I C O M P O N E N T
SYSTEMS 164
5.5 PRACTICAL ASPECTS: SLURRY A D S O R B E R DESIGN 166
6 ADSORPTION DYNAMICS IN FIXED-BED ADSORBERS 169
6.1 I N T R O D U C T I O N 169
6.2 E X P E R I M E N T A L D E T E R M I N A T I O N O F B R E A K T H
R O U G H CURVES 175
6.3 F I X E D - B E D PROCESS P A R A M E T E R S 176
6.4 MATERIAL BALANCES 179
6.4.1 TYPES O F M A T E R I A L BALANCES 179
6.4.2 INTEGRAL M A T E R I A L B A L A N C E 179
6.4.3 DIFFERENTIAL M A T E R I A L B A L A N C E 185
6.5 PRACTICAL ASPECTS 189
6.5.1 I N T R O D U C T I O N 189
6.5.2 TYPICAL O P E R A T I N G CONDITIONS 190
6.5.3 FIXED-BED VERSUS B A T C H A D S O R B E R 191
6.5.4 MULTIPLE A D S O R B E R SYSTEMS 193
7 FIXED-BED ADSORBER DESIGN 197
7.1 I N T R O D U C T I O N A N D M O D E L CLASSIFICATION 197
7.2 SCALE-UP M E T H O D S 198
7.2.1 MASS TRANSFER Z O N E ( M T Z ) M O D E L 198
7.2.2 L E N G T H O F U N U S E D B E D ( L U B ) M O D E L 202
7.2.3 R A P I D SMALL-SCALE C O L U M N TEST ( R S S C T ) 2 0 3
7.3 EQUILIBRIUM C O L U M N M O D E L ( E C M ) 207
7.4 C O M P L E T E B R E A K T H R O U G H CURVE M O D E L S 211
7.4.1 INTRODUCTION 211
7.4.2 H O M O G E N E O U S SURFACE DIFFUSION M O D E L ( H S D M ) 213
7.4.3 C O N S T A N T P A T T E R N A P P R O A C H T O T H E H S D M (
C P H S D M ) 217
IMAGE 4
VIII | C O N T E N T S
7.4.4 L I N E A R DRIVING FORCE ( L D F ) M O D E L 220
7.4.5 C O M P A R I S O N O F H S D M A N D L D F M O D E L 224
7.4.6 SIMPLIFIED B R E A K T H R O U G H CURVE M O D E L S WITH
ANALYTICAL SOLUTIONS 226
7.5 D E T E R M I N A T I O N O F M O D E L P A R A M E T E R S 232
7.5.1 G E N E R A L CONSIDERATIONS 232
7.5.2 SINGLE-SOLUTE A D S O R P T I O N 2 3 3
7.5.3 COMPETITIVE A D S O R P T I O N IN DEFINED MULTISOLUTE SYSTEMS 238
7.5.4 COMPETITIVE A D S O R P T I O N IN C O M P L E X SYSTEMS O F U N K
N O W N COMPOSITION . . . . 238
7.6 SPECIAL APPLICATIONS O F B R E A K T H R O U G H CURVE M O D E L S
240
7.6.1 MICROPOLLUTANT ADSORPTION IN P R E S E N C E O F N A T U R A L
ORGANIC M A T T E R 240
7.6.2 BIOLOGICALLY ACTIVE C A R B O N FILTERS 2 4 8
8 DESORPTION AND REACTIVATION 2 5 3
8.1 INTRODUCTION 253
8.2 PHYSICOCHEMICAL R E G E N E R A T I O N PROCESSES 254
8.2.1 D E S O R P T I O N I N T O T H E GAS P H A S E 254
8.2.2 D E S O R P T I O N I N T O T H E LIQUID P H A S E 256
8.3 REACTIVATION 2 6 1
9 GEOSORPTION PROCESSES IN WATER TREATMENT 265
9.1 I N T R O D U C T I O N 265
9.2 E X P E R I M E N T A L D E T E R M I N A T I O N O F GEOSORPTION D
A T A 267
9.3 T H E ADVECTION-DISPERSION E Q U A T I O N ( A D E ) A N D T H E
R E T A R D A T I O N C O N C E P T 2 6 8
9.4 SIMPLIFIED M E T H O D F O R D E T E R M I N A T I O N O F R I F R O
M
E X P E R I M E N T A L B R E A K T H R O U G H CURVES 271
9.5 B R E A K T H R O U G H CURVE M O D E L I N G 273
9.5.1 I N T R O D U C T I O N A N D M O D E L CLASSIFICATION 2 7 3
9.5.2 LOCAL EQUILIBRIUM M O D E L ( L E M ) 275
9.5.3 L I N E A R DRIVING FORCE ( L D F ) M O D E L 277
9.5.4 EXTENSION O F T H E LOCAL EQUILIBRIUM M O D E L 279
9.6 C O M B I N E D SORPTION A N D B I O D E G R A D A T I O N 280
9.6.1 G E N E R A L M O D E L A P P R O A C H 280
9.6.2 SPECIAL CASE: N A T U R A L ORGANIC M A T T E R ( N O M ) S O R P
T I O N A N D BIODEGRADATION 285
9.7 T H E INFLUENCE O F P H A N D N O M O N GEOSORPTION PROCESSES 287
9.7.1 P H - D E P E N D E N T SORPTION 287
9.7.2 INFLUENCE O F N O M O N MICROPOLLUTANT SORPTION 289
9.8 PRACTICAL ASPECTS: PREDICTION O F SUBSURFACE SOLUTE T R A N S P O R
T 2 9 1
9.8.1 G E N E R A L CONSIDERATIONS 291
IMAGE 5
C O N T E N T S | IX
9.8.2 PREDICTION O F SORPTION COEFFICIENTS 2 9 3
9.8.3 PREDICTION O F T H E DISPERSIVITY 295
10 APPENDIX 297
10.1 CONVERSION O F FREUNDLICH COEFFICIENTS 297
10.2 E V A L U A T I O N O F SURFACE DIFFUSION COEFFICIENTS F R O M E X
P E R I M E N T A L D A T A 2 9 8
10.3 C O N S T A N T P A T T E R N SOLUTION T O T H E H O M O G E N E O
U S SURFACE DIFFUSION M O D E L ( C P H S D M ) 302
N O M E N C L A T U R E 307
REFERENCES 319
INDEX 327 |
| any_adam_object | 1 |
| author | Worch, Eckhard 1951- |
| author_GND | (DE-588)11571832X |
| author_facet | Worch, Eckhard 1951- |
| author_role | aut |
| author_sort | Worch, Eckhard 1951- |
| author_variant | e w ew |
| building | Verbundindex |
| bvnumber | BV040123007 |
| classification_rvk | AR 22550 VN 7260 |
| ctrlnum | (OCoLC)796217219 (DE-599)DNB1018440615 |
| dewey-full | 660.284235 628.162 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering 628 - Sanitary engineering |
| dewey-raw | 660.284235 628.162 |
| dewey-search | 660.284235 628.162 |
| dewey-sort | 3660.284235 |
| dewey-tens | 660 - Chemical engineering 620 - Engineering and allied operations |
| discipline | Chemie / Pharmazie Allgemeines Bauingenieurwesen |
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| id | DE-604.BV040123007 |
| illustrated | Illustrated |
| indexdate | 2024-07-21T00:31:55Z |
| institution | BVB |
| isbn | 311024022X 9783110240221 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-024979054 |
| oclc_num | 796217219 |
| open_access_boolean | |
| owner | DE-29T DE-83 DE-634 DE-91 DE-BY-TUM DE-92 DE-706 |
| owner_facet | DE-29T DE-83 DE-634 DE-91 DE-BY-TUM DE-92 DE-706 |
| physical | IX, 332 S. Ill., graph. Darst. |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | De Gruyter |
| record_format | marc |
| spelling | Worch, Eckhard 1951- Verfasser (DE-588)11571832X aut Adsorption technology in water treatment fundamentals, processes, and modeling Eckhard Worch Berlin [u.a.] De Gruyter 2012 IX, 332 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Adsorption (DE-588)4000536-7 gnd rswk-swf Wasseraufbereitung (DE-588)4064698-1 gnd rswk-swf Abwasserreinigung (DE-588)4000313-9 gnd rswk-swf Wasseraufbereitung (DE-588)4064698-1 s Abwasserreinigung (DE-588)4000313-9 s Adsorption (DE-588)4000536-7 s DE-604 Erscheint auch als Online-Ausgabe 978-3-11-024023-8 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3950633&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024979054&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Worch, Eckhard 1951- Adsorption technology in water treatment fundamentals, processes, and modeling Adsorption (DE-588)4000536-7 gnd Wasseraufbereitung (DE-588)4064698-1 gnd Abwasserreinigung (DE-588)4000313-9 gnd |
| subject_GND | (DE-588)4000536-7 (DE-588)4064698-1 (DE-588)4000313-9 |
| title | Adsorption technology in water treatment fundamentals, processes, and modeling |
| title_auth | Adsorption technology in water treatment fundamentals, processes, and modeling |
| title_exact_search | Adsorption technology in water treatment fundamentals, processes, and modeling |
| title_full | Adsorption technology in water treatment fundamentals, processes, and modeling Eckhard Worch |
| title_fullStr | Adsorption technology in water treatment fundamentals, processes, and modeling Eckhard Worch |
| title_full_unstemmed | Adsorption technology in water treatment fundamentals, processes, and modeling Eckhard Worch |
| title_short | Adsorption technology in water treatment |
| title_sort | adsorption technology in water treatment fundamentals processes and modeling |
| title_sub | fundamentals, processes, and modeling |
| topic | Adsorption (DE-588)4000536-7 gnd Wasseraufbereitung (DE-588)4064698-1 gnd Abwasserreinigung (DE-588)4000313-9 gnd |
| topic_facet | Adsorption Wasseraufbereitung Abwasserreinigung |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3950633&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024979054&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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