Supramolecular chemistry of fullerenes and carbon nanotubes:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2012
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XVI, 403 S. Ill., graph. Darst. 240 mm x 170 mm |
| ISBN: | 9783527327898 3527327894 9783527650156 |
Internformat
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Datensatz im Suchindex
| _version_ | 1805146351714959360 |
|---|---|
| adam_text |
IMAGE 1
.1
. 2
.3
.3.1 .3.2 .4
.4.1 .4.2
.5
.1
. 2
.3
.4
. 1
.2
.2.1
. 2 . 2
.2.3
.3 .4
CONTENTS
PREFACE X I
LIST O F CONTRIBUTORS X I I I
CARBON NANOSTRUCTURES: COVALENT A N D MACROMOLECULAR CHEMISTRY 1
FRANCESCO GIACALONE, M" ANGELES HERRANZ, AND NAZARIO MARTIN INTRODUCTION
1
FULLERENE-CONTAINING POLYMERS 2 C A R B O N NANOTUBES 10 DEFECT
FUNCTIONALIZATION 11 SIDEWALL FUNCTIONALIZATION 13 G R A P H E N E S 16
COVALENT FUNCTIONALIZATION 17 NONCOVALENT FUNCTIONALIZATION 17 S U M M A
R Y A N D CONCLUSIONS 2 0 REFERENCES 2 0
HYDROGEN-BONDED FULLERENE ASSEMBLIES 2 7
JOSE SANTOS, BEATRIZ M. ILLESCAS, LUIS SANCHEZ, AND NAZARIO MARTIN
INTRODUCTION 2 7
HYDROGEN-BONDED FULLERENE-BASED SUPRAMOLECULAR STRUCTURES 2 8
HYDROGEN-BONDED FULLERENE-BASED DONOR-ACCEPTOR STRUCTURES 3 2
APPLICATIONS 4 6
REFERENCES 4 9
RECEPTORS FOR PRISTINE FULLERENES BASED O N CONCAVE-CONVEX N - N
INTERACTIONS 5 5
TAKESHI KAWASE INTRODUCTION 5 5
FULLERENE RECEPTORS BASED O N TRADITIONAL H O S T S 5 6 SIMPLE
TRADITIONAL H O S T S 56 MODIFIED TRADITIONAL H O S T MOLECULES 5 9
RECEPTORS BEARING A DIMERIC STRUCTURE O F TRADITIONAL H O S T
MOLECULES 62
HYDROCARBON RECEPTORS 6 4 RECEPTORS BEARING A CURVED CONJUGATED SYSTEM
66
HTTP://D-NB.INFO/1016558430
IMAGE 2
VI C O N T E N T S
3.4.1 RECEPTORS BASED O N BOWL-SHAPED CONJUGATED SYSTEMS 66
3.4.2 RECEPTORS BEARING A CYLINDRICAL CAVITY 6 7
3.4.3 C A R B O N NANORINGS 6 8
3.5 CONCLUSIONS 72
REFERENCES 72
4 COOPERATIVE EFFECTS IN T H E SELF-ASSEMBLY O F FULLERENE
DONOR ENSEMBLES 79
JEAN-FRANGOIS NIERENGARTEN 4.1 INTRODUCTION 79
4.2 ALLOSTERIC COOPERATIVITY 8 0
4.2.1 GENERAL PRINCIPLE 8 0
4.2.2 ALLOSTERIC COOPERATIVITY I N SUPRAMOLECULAR FULLERENE D O N O R
ENSEMBLES 81 4.3 CHELATE COOPERATIVITY 88
4.3.1 GENERAL PRINCIPLE 88
4.3.2 BINDING O F A DIVALENT LIGAND AA TO A DIVALENT RECEPTOR BB 91
4.3.3 BINDING O F A DIVALENT A S Y M M E T R I C LIGAND AC TO A
C O M P L E M E N T A R Y RECEPTOR BD 95 4.4 CONCLUSIONS 9 8
4.5 EXPERIMENTAL DETAILS 99
4.5.1 GENERAL 100
4.5.2 UV-VISIBLE TITRATIONS 100
4.5.3 LUMINESCENCE TITRATIONS 100
REFERENCES 104
5 FULLERENE-CONTAINING ROTAXANES A N D CATENANES 107
AURELIO MATEO-ALONSO
5.1 INTRODUCTION 107
5.1.1 SYNTHETIC STRATEGIES 107
5.1.1.1 ROTAXANES 107
5.1.1.2 CATENANES 108
5.1.2 BISTABLE ROTAXANES A N D CATENANES 109
5.2 FULLERENE ROTAXANES A N D CATENANES 110
5.2.1 METAL COORDINATION 110
5.2.2 N STACKING INTERACTIONS 111
5.2.3 H Y D R O G E N BONDS 113
5.3 CONCLUSIONS 123
REFERENCES 124
6 BIOMIMETIC MOTIFS TOWARD T H E CONSTRUCTION
O F ARTIFICIAL REACTION CENTERS J 2 7 BRUNO GRIMM A N D DIRK M. GULDI
6.1 INTRODUCTION 127
6.2 SUPRAMOLECULAR ARCHITECTURES FOR SOLAR ENERGY CONVERSION 130
IMAGE 3
C O N T E N T S V I I
6.2.1 GENERAL CONSIDERATIONS 130
6.2.2 C O U L O M B INTERACTIONS 134
6.2.3 TI-TI STACKING 137
6.2.4 H Y D R O G E N BONDING 143
6.2.5 METAL-LIGAND COORDINATION 150
6.3 OUTLOOK 154
REFERENCES 154
7 SUPRAMOLECULAR CHEMISTRY O F FULLERENE-CONTAINING
MICELLES A N D GELS 159 HONGGUANG LI, SUKUMARAN SANTHOSH BABU, AND
TAKASHI NAKANISHI 7.1 INTRODUCTION 159
7.2 SOLUBILIZATION O F PRISTINE C S O I N SURFACTANT ASSEMBLIES 160
7.2.1 SOLUBILIZAITON I N MICELLES 160
7.2.2 SOLUBILIZATION I N VESICLES 162
7.3 SELF-ASSEMBLIES O F AMPHIPHILIC C 6 0 DERIVATIVES 164
7.4 GELS O F FULLERENES 166
7.5 CONCLUSIONS A N D OUTLOOK 169
REFERENCES 170
8 FULLERENE-CONTAINING SUPRAMOLECULAR POLYMERS A N D DENDRIMERS 173
TAKEHARU HAINO AND TOSHIAKI IKEDA 8.1 INTRODUCTION 173
8.2 FABRICATION O F [60]FULLERENE POLYMERIC ARRAY 174
8.3 SUPRAMOLECULAR POLYMERIZATION O F FUNCTIONALIZED [60]FULLERENE 178
8.3.1 IONIC INTERACTION 179
8.3.2 H Y D R O G E N BONDING INTERACTION 182
8.3.3 H O S T - G U E S T INTERACTION 185
8.4 SUPRAMOLECULAR [60]FULLERENE D E N D R I M E R 188
8.4.1 D E N D R I M E R S WITH PERIPHERAL FULLERENE 188
8.4.2 D E N D R I M E R S WITH I N N E R FULLERENE 193
8.5 CONCLUSIONS 198
REFERENCES 198
9 [60]FULLERENE-CONTAINING THERMOTROPIC LIQUID CRYSTALS 203
DANIEL CUILLON, BERTRAND DONNIO, AND ROBERT DESCHENAUX 9.1 INTRODUCTION
203
9.2 NONCOVALENT C 6O DERIVATIVES 204
9.2.1 T H E LIQUID-CRYSTALLINE SUPRAMOLECULAR COMPLEX O F C 6O W I T H A
CYCLOTRIVERATRYLENE DERIVATIVE 204 9.2.2 SUPRAMOLECULAR COMPLEX C O M P
O S E D O F RIGID DENDRITIC PORPHYRIN A N D FULLERENE 206
9.2.3 SELF-ASSEMBLED C O L U M N S O F C 6 0 2 0 7
9.2.4 PHTHALOCYANINE-[60]FULLERENE DYADS I N LIQUID CRYSTALS 208 9.3
COVALENT C 6 0 DERIVATIVES 208
IMAGE 4
VIII C O N T E N T S
9.3.1 LIQUID-CRYSTALLINE METHANOFULLERENE- A N D
FULLEROPYRROLIDINE-BASED
POLY(ARYL ESTER) D E N D R O N S 208 9.3.2 LIQUID-CRYSTALLINE
FULLEROPYRROLIDINE-BASED POLY(BENZYL ETHER) D E N D R O N S 212
9.3.3 LIQUID-CRYSTALLINE FULLERO(CODENDRIMERS) 218
9.3.4 POLYPEDAL [60]FULLERENES 223
9.3.5 CONICAL-LIKE "SHUTTLECOCK" [60]FULLERENES 2 2 7 9.4 CONCLUSIONS
232
REFERENCES 233
10 SUPRAMOLECULAR CHEMISTRY O F FULLERENES O N SOLID SURFACES 237
ROBERTO OTERO, JOSE MARIA CALLEGO, NAZARIO MARTIN, AND RODOLFO MIRANDA
10.1 INTRODUCTION 237
10.2 FULLERENES O N N O N P A T T E R N E D METAL SURFACES 238
10.2.1 NATURE A N D STRENGTH O F FULLERENE-METAL INTERACTIONS 238
10.2.2 TRANSLATIONAL A N D ORIENTATIONAL O R D E R O F FULLERENE LAYERS
O N FLAT METAL SURFACES 239 10.2.3 CONVENTIONAL APPROACHES TO 2D
FULLERENE SUPRAMOLECULAR CHEMISTRY; FULLERENE FUNCTIONALIZATION 2 4 0
10.3 SURFACE TEMPLATES FOR FULLERENE ADSORPTION 243
10.3.1 0D P O I N T DEFECTS A N D SINGLE-MOLECULE ARRAYS 243
10.3.2 I D LINE DEFECTS: MOLECULAR C H A I N S 244
10.3.3 2D N A N O M E S H E S 246
10.4 SUPRAMOLECULAR AGGREGATION O F FULLERENES A N D O T H E R ORGANIC
SPECIES O N SURFACES 248
10.4.1 SELF-ASSEMBLED MONOLAYERS AS H O S T S FOR FULLERENES O N SOLID
SURFACES 249
10.4.2 COASSEMBLY O F FULLERENES A N D O T H E R ORGANIC SPECIES 251
10.5 OUTLOOK 258
REFERENCES 259
11 SUPRAMOLECULAR CHEMISTRY O F CARBON NANOTUBES 263
BRUNO JOUSSEIME, ARIANNA FILORAMO, AND STEPHANE CAMPIDELLI 11.1
INTRODUCTION 263
11.2 SUPRAMOLECULAR C A R B O N N A N O T U B E HYBRIDS 264
11.2.1 C A R B O N N A N O T U B E A N D SURFACTANTS 264
11.2.1.1 SUSPENSION O F SINGLE-WALL C A R B O N NANOTUBES (WHY, HOW, A N
D
W H A T FOR?) 264
11.2.2 N STACKING INTERACTIONS 270
11.2.2.1 PYRENE DERIVATIVES 2 7 0
11.2.2.2 O T H E R CYCLIC AROMATIC C O M P O U N D S 276 11.2.2.3
PORPHYRINS A N D DERIVED STRUCTURES 2 7 7
11.2.3 POLYMERS A N D W R A P P I N G 280
11.2.4 FILLING NANOTUBES 283
IMAGE 5
11.3
12
1 2 . 1
1 2 . 2
1 2 . 2 . 1
1 2 . 2 . 2
12.2.3
12.2.4 12.3 12.3.1 12.3.2 12.3.3
12.3.4 12.4
13
13.1 13.2 13.2.1 13.2.1.1 13.2.1.2 13.2.1.3 13.2.1.4 13.2.1.5 13.2.1.6
13.2.2 13.3
13.3.1 13.3.2 13.4
14
14.1 14.2
CONTENTS IX
C O N C L U S I O N S 288
REFERENCES 288
SUPRAMOLECULAR CHEMISTRY O F FULLERENES A N D CARBON NANOTUBES A T
INTERFACES: TOWARD APPLICATIONS 301 RICCARDO MAREGA, DAVIDE GIUST,
ADRIAN KREMER, A N D DAVIDE BORTIFAZI
INTRODUCTION 301
FULLERENE INTERFACES 3 0 2 FULLERENES AT T H E LIQUID-LIQUID A N D
MICELLAR INTERFACES 303 FULLERENES AT T H E SOLID-LIQUID INTERFACE 3 0 7
FULLERENES AT T H E GAS-SOLID INTERFACE 3 1 0 FULLERENES AT T H E
BIOLOGICAL INTERFACE 313 C A R B O N NANOTUBES 317 C A R B O N NANOTUBES
AT T H E LIQUID-LIQUID INTERFACE 3 1 7 C A R B O N NANOTUBES AT T H E
SOLID-LIQUID INTERFACE 3 2 0 C A R B O N NANOTUBES AT T H E GAS-SOLID
INTERFACE 3 2 5
C A R B O N NANOTUBES AT T H E BIOLOGICAL INTERFACE 3 2 7 CONCLUSIONS
334
REFERENCES 3 3 5
APPLICATIONS O F SUPRAMOLECULAR ENSEMBLES WITH FULLERENES A N D CNTS:
SOLAR CELLS A N D TRANSISTORS 349 HIROSHI IMAHORI AND TOMOKAZU UMEYAMA
INTRODUCTION 349
SOLAR CELLS 350
FULLERENE-BASED SOLAR CELLS 3 5 0 SELF-ASSEMBLED MONOLAYERS 3 5 0
LAYER-BY-LAYER DEPOSITION 3 5 3
ELECTROCHEMICAL DEPOSITION 3 5 4 SOLUTION-PROCESSED BULK HETEROJUNCTION
SOLAR CELLS 3 5 9 H Y D R O G E N B O N D I N G SYSTEMS 3 6 0
COORDINATION BONDING SYSTEMS 3 6 2 C A R B O N NANOTUBES 363 TRANSISTORS
366
FULLERENES 3 6 6
C A R B O N NANOTUBES 366 S U M M A R Y 368
REFERENCES 369
EXPERIMENTAL DETERMINATION O F ASSOCIATION CONSTANTS INVOLVING
FULLERENES 3 7 5 EMILIO M. PEREZ ALVAREZ AND NAZARIO MARTIN P L A N N I
N G A TITRATION EXPERIMENT 375 P E R F O R M I N G A TITRATION 3 7 6
IMAGE 6
X C O N T E N T S
14.3 CHOOSING T H E SPECTROSCOPIC M E T H O D 378
14.4 ANALYZING T H E DATA 379
14.5 D E T E R M I N I N G STOICHIOMETRY 3 8 0
14.6 ESTIMATING ERRORS 381
14.7 FULLERENES AS GUESTS: SPECTROSCOPIC PROPERTIES 381
14.8 DETERMINATION O F T H E BINDING CONSTANT O F A N EXTTF-BASED
H O S T TOWARD C 60: A PRACTICAL EXAMPLE 3 8 5 14.9 CONCLUSIONS 389
REFERENCES 3 9 0
INDEX 391 |
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| indexdate | 2024-07-21T00:28:31Z |
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| isbn | 9783527327898 3527327894 9783527650156 |
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| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Supramolecular chemistry of fullerenes and carbon nanotubes ed. by Nazario Martin ... Weinheim Wiley-VCH 2012 XVI, 403 S. Ill., graph. Darst. 240 mm x 170 mm txt rdacontent n rdamedia nc rdacarrier Fullerene (DE-588)4305238-1 gnd rswk-swf Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd rswk-swf Supramolekulare Chemie (DE-588)4306141-2 gnd rswk-swf Fullerene (DE-588)4305238-1 s Kohlenstoff-Nanoröhre (DE-588)4581365-6 s Supramolekulare Chemie (DE-588)4306141-2 s DE-604 Martín, Nazario (DE-588)139240225 edt X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3902515&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024832789&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Supramolecular chemistry of fullerenes and carbon nanotubes Fullerene (DE-588)4305238-1 gnd Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd Supramolekulare Chemie (DE-588)4306141-2 gnd |
| subject_GND | (DE-588)4305238-1 (DE-588)4581365-6 (DE-588)4306141-2 |
| title | Supramolecular chemistry of fullerenes and carbon nanotubes |
| title_auth | Supramolecular chemistry of fullerenes and carbon nanotubes |
| title_exact_search | Supramolecular chemistry of fullerenes and carbon nanotubes |
| title_full | Supramolecular chemistry of fullerenes and carbon nanotubes ed. by Nazario Martin ... |
| title_fullStr | Supramolecular chemistry of fullerenes and carbon nanotubes ed. by Nazario Martin ... |
| title_full_unstemmed | Supramolecular chemistry of fullerenes and carbon nanotubes ed. by Nazario Martin ... |
| title_short | Supramolecular chemistry of fullerenes and carbon nanotubes |
| title_sort | supramolecular chemistry of fullerenes and carbon nanotubes |
| topic | Fullerene (DE-588)4305238-1 gnd Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd Supramolekulare Chemie (DE-588)4306141-2 gnd |
| topic_facet | Fullerene Kohlenstoff-Nanoröhre Supramolekulare Chemie |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3902515&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024832789&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT martinnazario supramolecularchemistryoffullerenesandcarbonnanotubes |