Nanocomposites with biodegradable polymers: synthesis, properties, and future perspectives
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Oxford [u.a.]
Oxford Univ. Press
2011
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| Ausgabe: | 1. publ. |
| Schriftenreihe: | Monographs on the physics and chemistry of materials
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVII, 426 S. Ill., graph. Darst. |
| ISBN: | 9780199581924 |
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| 245 | 1 | 0 | |a Nanocomposites with biodegradable polymers |b synthesis, properties, and future perspectives |c ed. by Vikas Mittal |
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Datensatz im Suchindex
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| adam_text | Titel: Nanocomposites with biodegradable polymers
Autor: Mittal, Vikas
Jahr: 2011
Contents
List of contributors xv
1 Bio-nanocomposites: future high-value materials 1
Vikas MITTAL
1.1 Introduction to polymer nanocomposites 1
1.2 Biopolymers or biodegradable polymers 6
1.3 Bio-nanocomposites 7
1.4 References 23
2 Biodegradation of polymeric systems 28
In-Joo CHIN and Shogo UEMATSU
2.1 Biodegradable polymers and their composites 29
2.1.1 Mechanisms of biodegradation 29
2.1.2 Biodegradation of PLA and its nanocomposites 30
2.1.3 Biodegradation of PBS and its composites 34
2.1.4 Biodegradation of PCL 37
2.1.5 Biodegradation of PHB 38
2.2 Biodegradation tests under controlled composting conditions 40
2.2.1 Introduction 40
2.2.2 Test method for biodegradation of plastics under controlled
composting conditions 41
2.2.3 Specifications of ISO 14855-1 and ISO 14855-2 42
2.2.4 Preparation of mature compost 44
2.2.5 pH of compost 45
2.2.6 Water activity (Aw) 46
2.2.7 Test equipment 48
2.2.8 Biodegradation of test materials 49
2.2.9 Conclusion 51
2.3 Acknowledgements 51
2.4 References 51
3 Biodegradable thermoplastic starch/poly(vinyl alcohol) nanocomposites
with layered silicates 58
Katherine M. DEAN, Eustathios PETINAKIS and Long YU
3.1 Introduction 58
3.2 Materials and processing of thermoplastic starch/PVOH nanocomposites 60
3.3 Microstructure and chemistry of the thermoplastic starch/PVOH
nanocomposites 62
3.3.1 XRD analysis of the structures 62
viii Contents
3.3.2 TEM analysis of the structures 65
3.3.3 Fourier transform infrared spectroscopy (FTIR) analysis
of the structures 65
3.4 Mechanical properties of the thermoplastic starch/PVOH nanocomposites 67
3.5 Conclusions 68
3.6 Acknowledgements 69
3.7 References 69
4 Bio-nanocomposites with non-cellulosic biofillers 71
Peter R. CHANG, Jin HUANG and Ning LIN
4.1 Introduction 71
4.2 Manufacture of non-cellulosic nano-sized biofiller 72
4.2.1 Extraction of starch nanocrystal 72
4.2.2 Extraction of chitin nanowhisker 74
4.2.3 Organization of supramolecular lignin complex 75
4.2.4 Artificial nano-sized filler from biomass 75
4.3 Chemical modification of non-cellulosic biofiller 76
4.3.1 Chemical derivation of non-cellulosic biofiller 76
4.3.2 Graft to modification of non-cellulosic biofiller 78
4.3.3 Graft from modification of non-cellulosic biofiller 79
4.4 Processing of bio-nanocomposites with non-cellulosic biofiller 80
4.4.1 Solution blending and subsequent moulding of bio-nanocomposites 80
4.4.2 Compounding of nano-sized biofiller with reactive polymer matrix 81
4.4.3 Post-treatment of moulded bio-nanocomposites 82
4.4.4 Manufacturing of structural bio-nanocomposite materials 83
4.4.5 Thermoforming of polymer-grafted polysaccharide nanocrystals 85
4.4.6 Direct nanoscaffold formation from chitin whiskers 85
4.5 Mechanical properties of bio-nanocomposites with non-cellulosic biofiller 86
4.5.1 Effects of structure and loading level of biofiller 86
4.5.2 Effects of chemical modification of biofillers 87
4.5.3 Effects of processing conditions 89
4.5.4 Reinforcement mechanism of biofiller 89
4.6 Other properties of bio-nanocomposites with non-cellulosic biofiller 90
4.6.1 Thermal properties of bio-nanocomposites 90
4.6.2 Swelling behaviour of bio-nanocomposites 93
4.6.3 Barrier properties of bio-nanocomposites 94
4.7 Conclusion and prospects 95
4.8 References 96
5 Biodegradable poly(butylene succinate)/multi-walled carbon
nanotube nanocomposites 101
Y. F. SHIH and R. J. JENG
5.1 Introduction 101
5.1.1 Biodegradable poly(butylene succinate) 101
5.1.2 Carbon nanotubes 102
5.1.3 Modifications of carbon nanotubes 102
Contents ix
5.1.4 Biodegradable polymer/CNTs composites 104
5.1.5 Thermal degradation kinetics of PBS/CNTs composites 105
5.2 Experimental 105
5.2.1 Materials 105
5.2.2 Instruments 106
5.3 Results and discussion 106
5.3.1 Characterization of the organically grafted CNTs 106
5.3.2 DSC analysis of the PBS/CNTs nanocomposites 107
5.3.3 Mechanical properties of the PBS/CNTs nanocomposites 107
5.3.4 Electrical properties of the PBS/CNTs nanocomposites 111
5.3.5 Morphology of PBS/CNTs nanocomposites 112
5.3.6 Thermal degradation kinetics of PBS/CNTs nanocomposites 113
5.4 Conclusion 118
5.5 References 118
6 Biodegradable nanocomposites from cellulosic plastics and
cellulosic fibre 123
Manju MISRA, Ozgur SEYDIBEYOGLU, Dipa RAY, Kunal DAS and
Amar MOHANTY
6.1 Introduction to nanocomposites and biodegradable materials 123
6.2 Biobased and biodegradable materials 124
6.3 The importance of plant materials 126
6.4 Cellulosic plastics 127
6.4.1 Cellulose esters 127
6.4.2 Chitin 132
6.4.3 Chitosan 133
6.5 Cellulosic fibres (micron and nanoscale) 137
6.5.1 Cellulose nanowhiskers 140
6.5.2 Microfibrillated cellulose 145
6.5.3 Bacterial cellulose 149
6.6 Processing cellulose nanocomposites 155
6.7 Characterization of cellulose nanocomposites 157
6.8 Future perspectives 158
6.9 Concluding remarks 159
6.10 Acknowledgements 159
6.11 References 159
7 Silica/alginate bio-nanocomposites 166
Thibaud CORADIN
7.1 Introduction 166
7.2 Alginate-based materials 167
7.3 Design of silica/alginate biocomposites 169
7.3.1 The composite approach 170
7.3.2 The hybrid approach 171
7.3.3 The IPN approach 173
7.3.4 Scaling down of the procedures 173
Contents
7.4 Physical and chemical properties of silica/alginate nanocomposites 174
7.4.1 Mechanical and thermal stability 174
7.4.2 Chemical stability 175
7.5 Applications 177
7.5.1 Enzymatic biocatalysts 177
7.5.2 Cell-based bioreactors 178
7.5.3 Artificial organs 179
7.5.4 Drug delivery systems 181
7.6 Extensions and perspectives 182
7.6.1 Other alginate-based bio-nanocomposites 182
7.6.2 Bases for further partnership 183
7.7 References 184
Bio-based elastomers from soy oil and nanoclay 189
Lin ZHU and Richard P. WOOL
8.1 Introduction 189
8.2 Experimental 192
8.2.1 Preparation of clay/elastomer elastomer hybrid 192
8.2.2 Characterization 193
8.3 Results and discussion 193
8.3.1 Organic modifier selection 193
8.3.2 Morphology 194
8.3.3 Mechanical properties 196
8.3.4 Crosslink density and network perfection 198
8.3.5 Thermal stability and glass transition temperature 201
8.3.6 Biodegradability 203
8.3.7 Biocompatibility 204
8.4 Conclusions 206
8.5 References 206
Gelatine-based bio-nanocomposites 209
Francisco M. FERNANDES, Margarita DARDER, Ana I. RUIZ, Pilar ARANDA
and Eduardo RUIZ-HITZKY
9.1 Introduction 209
9.2 Gelatine composite materials 210
9.2.1 Gelatine, from the kitchen to the operating table 210
9.2.2 Gelatine, between collagen and synthetic polymers 211
9.2.3 Structural gelatine composites 213
9.2.4 Functional gelatine composites 214
9.3 Silica and silicate-based gelatine nanocomposites 216
9.3.1 Silica-based gelatine nanocomposites 216
9.3.2 Layered silicate-based nanocomposites 218
9.3.3 Fibrous silicate-based nanocomposites 220
9.4 Gelatine nanocomposites based on other inorganic solids 221
9.5 Gelatine in three-component nanocomposite systems 224
9.6 Future perspectives 226
Contents xi
9.7 Acknowledgements 226
9.8 References 226
10 Bio-nanocomposites based on starch 234
Fengwei XIE, Peter J. HALLEY and Luc AVEROUS
10.1 Introduction 234
10.2 Processing techniques 235
10.2.1 Solution intercalation 235
10.2.2 Melt intercalation 236
10.3 Starch-based bio-nanocomposites 236
10.3.1 Starch bio-nanocomposites filled by layered clays 236
10.3.2 Starch bio-nanocomposites filled by whiskers 248
10.3.3 Starch bio-nanocomposites filled by starch nanocrystals 250
10.3.4 Starch bio-nanocomposites filled by other types of nanofillers 250
10.4 Bio-nanocomposites based on other starch-based matrices 252
10.5 Applications 253
10.6 Summary 253
10.7 References 253
11 Soy protein-based polymer nanocomposites 261
Jin HUANG, Ning LIN, Yun CHEN, Peter R. CHANG and Jiahui YU
11.1 Introduction 261
11.2 Soy protein-based nanocomposites filled with inorganic nanofillers 262
11.2.1 Soy protein nanocomposites filled with layered silicates 262
11.2.2 Soy protein nanocomposites filled with spherical Si02
nanoparticles 264
11.2.3 Soy protein nanocomposites filled with carbon nanotube 265
11.2.4 In situ synthesis of soy protein/inorganic nanocrystal
nanocomposites 266
11.3 Soy protein-based composites filled with organic nanofillers 267
11.3.1 Soy protein filled with polysaccharide nanocrystals 267
11.3.2 Soy protein filled with artificial nanoparticles 268
11.3.3 Soy protein filled with self-assembled nanoparticles 270
11.3.4 Soy protein filled with lignin nanophase 271
11.4 Structure-property relationship of soy protein-based
nanocomposites 273
11.4.1 Interfacial interaction between nanofillers and soy protein
matrix 273
11.4.2 Entanglement and penetration of polymer matrix with hollow
nanoparticles 274
11.4.3 Self-organization organization of nanofillers in soy protein
matrix 275
11.4.4 Co-continuous phase mediated with polymer
chains on nanoparticles 277
11.4.5 In situ formed nanostrucrure in soy protein matrix 278
xii Contents
11.5 Conclusion and prospects 278
11.6 References 279
12 Biodegradable nanocomposites based on poly(hydroxyalkanoates) 283
Narendra K. SINGH and Pralay MAITI
12.1 Introduction 283
12.2 Preparation of poly(hydroxyalkanoate) nanocomposites 286
12.2.1 Solution casting method 286
12.2.2 Melt extrusion technique 286
12.2.3 In situ polymerization 286
12.3 Characterization of poly(hydroxyalkanoate) nanocomposites 287
12.3.1 Nanostructure 287
12.3.2 Microstructure 290
12.4 Properties 292
12.4.1 Mechanical properties 292
12.4.2 Thermal properties 301
12.4.3 Gas barrier properties 312
12.4.4 Biodegradation 314
12.5 Processing 320
12.5.1 Melt rheology and structure-property relationship 320
12.6 Uses 321
12.7 Conclusion 321
12.8 Acknowledgements 322
12.9 References 322
13 Bio-nanocomposites using bio-based epoxy resins 329
Mitsuhiro SHIBATA
13.1 Introduction 329
13.2 Bio-based epoxy resin/montmorillonite nanocomposites 332
13.2.1 Layered silicates as fillers of bio-nanocomposites 332
13.2.2 Preparation and morphology of PGPE-PL/MMT nanocomposites 332
13.2.3 Properties of PGPE-PL/MMT composites 333
13.3 Bio-based epoxy resin/microfibrillated cellulose nanocomposites 336
13.3.1 Microfibrillated cellulose as reinforcing fibres of
bio-nanocomposites 336
13.3.2 Preparation of GPE/TA/MFC and SPE/TA/MFC 337
13.3.3 Properties of GPE-TA/MFC and SPE-TA/MFC 337
13.4 Bio-based epoxy resin/self-assembled hydroxystearic acid
nanocomposites 341
13.4.1 Self-assembled suplamolecular fibres as reinforcing fibres
of bio-nanocomposites 341
13.4.2 Preparation and characterization of photo-cured ESO/HSA
nanocomposites 341
13.4.3 Mechanical properties of photo-cured ESO/HSA nanocomposites 344
13.5 References 345
Contents xiii
14 Bio-nanocomposites for food packaging applications 348
Caisa JOHANSSON
14.1 Background 348
14.2 Food packaging requirements 348
14.2.1 Paper-based packaging laminates 349
14.2.2 Self-supporting packaging material 350
14.3 Industrial manufacture of bio-nanocomposite food packaging 351
14.4 Bio-nanocomposites 352
14.4.1 Nanosized components in bio-nanocomposites 352
14.4.2 PolyQactic acid)-based nanocomposites 354
14.4.3 Polycaprolactone-based nanocomposites 355
14.4.4 Polyhydroxyalkanoate-based nanocomposites 356
14.4.5 Starch-based nanocomposites 356
14.4.6 Chitosan-based nanocomposites 357
14.4.7 Other classes of bio-nanocomposites 358
14.5 Costs and commercial availability of bio-nanocomposite components 359
14.6 Potential risks related to bio-nanocomposites in food packaging 360
14.6.1 Contamination and migration 360
14.7 Antimicrobial functionality in bio-nanocomposites 361
14.8 Environmental aspects of bio-nanocomposites 362
14.9 References 364
15 Conductive biopolymer nanocomposites for sensors 368
Jean-Francois FELLER, Bijandra KUMAR and Mickael CASTRO
15.1 Introduction 368
15.2 Conductive biopolymer nanocomposite (CPC) transducer development 369
15.2.1 Choice and association of materials for conductive biopolymer
composite development 369
15.2.2 Conductive biopolymer nanocomposite architecture design 371
15.2.3 Conductive biopolymer nanocomposite transducer characterization 376
15.2.4 Instrumentation and tests 378
15.2.5 Principle of conductive biopolymer nanocomposite resistive sensors 379
15.2.6 Properties of conductive biopolymer nanocomposite resistive
transducers 382
15.2.7 Principle of conductive biopolymer nanocomposite
electrochemical biosensors 390
15.2.8 Applications 391
15.3 Conclusion 391
15.4 References 391
16 Commercial aspects associated with bio-nanocomposites 400
SunU P. LONKAR, A. Pratheep KUMAR and R. P SINGH
16.1 Introduction 400
16.2 Classification of bio-nanocomposites 401
16.2.1 Nanocomposites of biodegradable polymers 401
16.3 Commercial preparation, processing and challenges 407
xiv Contents
16.3.1 Method of preparation 407
16.3.2 Compounding of bio-nanocomposites 408
16.3.3 Thermosetting methods 409
16.3.4 Scale-up/challenges 409
16.3.5 Methods for improving the properties 410
16.4 Energy consumption 410
16.5 Commercial aspects of bio-nanocomposites: the importance 411
16.6 Future perspectives 414
16.7 Summary/conclusions 415
16.8 References 415
Index 421
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| spelling | Nanocomposites with biodegradable polymers synthesis, properties, and future perspectives ed. by Vikas Mittal 1. publ. Oxford [u.a.] Oxford Univ. Press 2011 XVII, 426 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Monographs on the physics and chemistry of materials Nanocomposites (Materials) Polymers Biodegradation Nanokomposit (DE-588)4768127-5 gnd rswk-swf Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd rswk-swf Biologisch abbaubarer Kunststoff (DE-588)4634464-0 s Nanokomposit (DE-588)4768127-5 s DE-604 Mittal, Vikas (DE-588)140061096 edt HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024669956&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nanocomposites with biodegradable polymers synthesis, properties, and future perspectives Nanocomposites (Materials) Polymers Biodegradation Nanokomposit (DE-588)4768127-5 gnd Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd |
| subject_GND | (DE-588)4768127-5 (DE-588)4634464-0 |
| title | Nanocomposites with biodegradable polymers synthesis, properties, and future perspectives |
| title_auth | Nanocomposites with biodegradable polymers synthesis, properties, and future perspectives |
| title_exact_search | Nanocomposites with biodegradable polymers synthesis, properties, and future perspectives |
| title_full | Nanocomposites with biodegradable polymers synthesis, properties, and future perspectives ed. by Vikas Mittal |
| title_fullStr | Nanocomposites with biodegradable polymers synthesis, properties, and future perspectives ed. by Vikas Mittal |
| title_full_unstemmed | Nanocomposites with biodegradable polymers synthesis, properties, and future perspectives ed. by Vikas Mittal |
| title_short | Nanocomposites with biodegradable polymers |
| title_sort | nanocomposites with biodegradable polymers synthesis properties and future perspectives |
| title_sub | synthesis, properties, and future perspectives |
| topic | Nanocomposites (Materials) Polymers Biodegradation Nanokomposit (DE-588)4768127-5 gnd Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd |
| topic_facet | Nanocomposites (Materials) Polymers Biodegradation Nanokomposit Biologisch abbaubarer Kunststoff |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024669956&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mittalvikas nanocompositeswithbiodegradablepolymerssynthesispropertiesandfutureperspectives |