Solidification and crystallization processing in metals and alloys:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Chichester
Wiley
2012
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | X, 816 S. Ill., graph. Darst. |
| ISBN: | 9781119993056 |
Internformat
MARC
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Datensatz im Suchindex
| _version_ | 1804148723363610624 |
|---|---|
| adam_text | Contents
Preface
ix
1 Thermodynamic
Concepts
and Relationships
1
1.1
Introduction
2
1.2
Thermodynamic Concepts and Relationships
2
1.3
Thermody
namies
of Single-Component Systems
10
1.4
Thermodynamics of Multiple-Component Sy stems
16
1.5
Thermodynamics of Allovs
21
1.6
Thermodynamics of Ideal Binary Solutions
25
1.7
Thermodynamics of Non-Ideal Binary Solutions
26
1.8
Experimental Determination of Thermodynamic Quantities of Binary Alloys
34
Summary
36
Further Reading
41
2
Thermodynamic Analysis of Solidification Processes in Metals and Alloys
42
2.1
Introduction
42
2.2
Thermodynamics of Pure Metals
43
2.3
Thermodynamics of Binary Alloys
44
2.4
Equilibrium Between Phases in Binary Solutions. Phase Diagrams of
Binary Alloys
50
2.5
Driving Force of Solidification in Binary Alloys
76
2.6
Thermodynamics of Ternary Alloys
78
2.7
Thermodynamics of Vacancies in Pure Metals and Alloys
83
Summary
90
Exercises
94
References
98
Further Reading
98
3
Properties of Interfaces
99
3.1
Introduction
99
3.2
Classical Theory of Interface Energy and Surface Tension
100
3.3
Thermodynamics of
Interphases
114
3.4
Structures of Interfaces
123
3.5
Equilibrium Shapes of Crystals
145
Summary
155
Exercises
161
References
165
4
Nucleation
166
4.1
Introduction
166
4.2
Homogeneous Nucleation
167
4.3
Heterogeneous Nucleation. Inoculation
179
4.4
Nucleation of Bubbles
190
4.5
Crystal Multiplication
193
Summary
194
Exercises
197
References
200
ví
Contents
5
Crystal Growth in Vapours
201
5.1
Introduction
202
5.2
Crystal Morphologies
202
5.3
Chemical Vapour Deposition
203
5.4
Crystal Growth
206
5.5
Normal Crystal Growth of Rough Surfaces in Vapours
210
5.6
Layer Crystal Growth of Smooth Surfaces in Vapours
214
5.7
Influence of Impurities on Crystal Growth in Vapours
238
5.8
Epitaxial Growth
244
5.9
Whisker Growth
249
5.10
Mechanical Restrictions on Thin Films
251
Summary
256
Exercises
263
References
266
6
Crystal Growth in Liquids and Melts
267
6.1
Introduction
268
6.2
Structures of Crystals and Melts
268
6.3
Growth Methods
275
6.4
Crystal Growth
278
6.5
Volume Changes and Relaxation Processes during Anelastic Crystal Growth
in Metal Melts
279
6.6
Normal Crystal Growth in Pure Metal Melts
289
6.7
Layer Crystal Growth of Smooth Surfaces in Liquids
297
6.8
Normal Crystal Growth in Binary Alloys
310
6.9
Diffusion-Controlled Growth of Planar Crystals in Binary Alloys
318
6.10
Diffusion-Controlled Growth of Spherical Crystals in Alloys
324
6.11
Impingement
338
6.12
Precipitation of Pores
340
Summary
343
Exercises
355
References
360
7
Heat Transport during Solidification Processes. Thermal Analysis
361
7.1
Introduction
362
7.2
Basic Concepts and Laws of Heat Transport
362
7.3
Convection
366
7.4
Theory of Heat Transport at Unidirectional Solidification
378
7.5
Production of Single Crystals by Unidirectional Solidification
385
7.6
Thermal Analysis
395
7.7
Variable Heat of Fusion of Metals and Alloys
408
7.8
Variable Heat Capacitivity of Metals and Alloys
416
Summary
422
Exercises
429
References
432
8
Crystal Growth Controlled by Heat and Mass Transport
433
8.1
Introduction
433
8.2
Heat and Mass Transports in Alloys during Unidirectional Solidification
434
8.3
Zone Refining
443
8.4
Single Crystal Production by Czochralski Technique
450
8.5
Cellular Growth. Constitutional Undercooling. Interface Stability
454
Summary
465
Exercises
469
References
474
Contents
vii
9
Faceted and Dendritic Solidification Structures
475
9.1
Introduction
476
9.2
Formation of Faceted Crystals
476
9.3
Growth of Faceted Crystals in Pure Metal Melts
476
9.4
Growth of Faceted Crystals in Alloy Melts
485
9.5
Growth of
Dendrite
Crystals
503
9.6
Development of
Dendrites
529
9.7
Transitions between Structure Types in Alloys
565
Summary
573
Exercises
580
References
585
10
Eutectic Solidification Structures
587
10.1
Introduction
588
10.2
Classification of Eutectic Structures
588
10.3
Normal Eutectic Growth
589
10.4
Degenerate and Coupled Eutectic Growth
620
10.5
Structures of Ternary Alloys
635
10.6
Solidification of
Fe
-С
Eutectics
646
10.7
Solidification of
ΑΙ
-Si
Eutectics
658
10.8
Transition between Normal Lamellar and Rod Eutectic Growth
665
Summary
669
Exercises
675
References
680
11
Peritectic Solidification Structures
681
11.1
Introduction
681
1
1
.2
Peritectic Reactions and Transformations
682
11.3
Peritectic Reactions and Transformations in Iron-Base Alloys
693
11.4
Metastable Reactions in Iron-Base Alloys
702
11.5
Metatectic Reactions and Transformations
704
11.6
Microsegregation in Iron-Base Alloys
708
11.7
Transitions between Peritectic and
Eutecîic
Reactions in Iron-Base Alloys
716
Summary
719
Exercises
724
References
727
12
Metallic Glasses and Amorphous Alloy Melts
729
12.1
Introduction
730
12.2
Basic Concepts and Definitions
731
12.3
Production of Metallic Glasses
735
12.4
Experimental Methods for Structure Determination of Metallic
Glasses and Amorphous Alloy Melts
741
12.5
Structures of Metallic Glasses
744
12.6
Comparison of the Structures of Metallic Glasses and Amorphous Alloy
Melts. Rough Models of Metallic Glasses and Amorphous Alloy Melts
753
12.7
Casting of Metallic Glasses. Crystallization Processes in Amorphous Alloy Melts
759
12.8
Classification of Metallic Glasses
763
12.9
Properties and Applications of Metallic Glasses
764
Summary
771
Exercises
775
References
779
Answers to Exercises
781
Index
803
Solidification
and Crystallization Processing
in Metals and Alloys
Hasse Fredriksson, KTH,
Royal Institute of
Technology,
Stockholm, Sweden
Ulla Åkerlind,
University of Stockholm, Stockholm, Sweden
Solidification or crystallization occurs when atoms are transformed from the disordered liquid state to the more ordered solid
state, and is fundamental to metals processing. Conceived as a companion volume to the earlier works. Materials Processing
during Casting
(2006)
and Physics of Functional Materials
(2008),
this book analyzes solidification and crystallization
processes in depth.
Starting from the thermodynamic point of view, it gives a complete description, taking into account kinetics and mass transfer,
down to the final structure. Importantly, the book shows the relationship between the theory and the experimental results.
Topics covered include:
■
Fundamentals of thermodynamics
■
Properties of interfaces
■
Nucleation
■
Crystal growth
-
in vapours, liquids and melts
■
Heat transport during
solidification
processes
■
Solidification structures
-
faceted, dendritic, eutectic and peritectic
■
Metallic glasses and amorphous alloy melts
Solidification and Crystallization Processing in Metals and Alloys features many solved examples in the text, and exercises
(with answers) for students. Full worked solutions to the exercises are available from www.wiley.com/go/fredrikssonS
Intended for Masters and PhD students as well as researchers in Materials Science, Engineering, Chemistry and Metallurgy,
it is also a valuable resource for engineers in industry.
Enjoyed this book?
Why not tell others about it
and write a review on your
favourite online bookseller.
Cover design by Dan Jubb
WILEY
ISBN
978-1-119-99305-6
9 78 1 1
19 9930
56
|
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| indexdate | 2024-07-10T00:11:40Z |
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| isbn | 9781119993056 |
| language | English |
| lccn | 2011014030 |
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| spelling | Fredriksson, Hasse Verfasser aut Solidification and crystallization processing in metals and alloys Hasse Fredriksson and Ulla Åkerlind 1. publ. Chichester Wiley 2012 X, 816 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Metal crystals Growth Legierung (DE-588)4035035-6 gnd rswk-swf Kristallisation (DE-588)4033215-9 gnd rswk-swf Erstarrung (DE-588)4140191-8 gnd rswk-swf Metall (DE-588)4038860-8 gnd rswk-swf Metall (DE-588)4038860-8 s Kristallisation (DE-588)4033215-9 s Erstarrung (DE-588)4140191-8 s DE-604 Legierung (DE-588)4035035-6 s Åkerlind, Ulla Verfasser aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024657632&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024657632&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Fredriksson, Hasse Åkerlind, Ulla Solidification and crystallization processing in metals and alloys Metal crystals Growth Legierung (DE-588)4035035-6 gnd Kristallisation (DE-588)4033215-9 gnd Erstarrung (DE-588)4140191-8 gnd Metall (DE-588)4038860-8 gnd |
| subject_GND | (DE-588)4035035-6 (DE-588)4033215-9 (DE-588)4140191-8 (DE-588)4038860-8 |
| title | Solidification and crystallization processing in metals and alloys |
| title_auth | Solidification and crystallization processing in metals and alloys |
| title_exact_search | Solidification and crystallization processing in metals and alloys |
| title_full | Solidification and crystallization processing in metals and alloys Hasse Fredriksson and Ulla Åkerlind |
| title_fullStr | Solidification and crystallization processing in metals and alloys Hasse Fredriksson and Ulla Åkerlind |
| title_full_unstemmed | Solidification and crystallization processing in metals and alloys Hasse Fredriksson and Ulla Åkerlind |
| title_short | Solidification and crystallization processing in metals and alloys |
| title_sort | solidification and crystallization processing in metals and alloys |
| topic | Metal crystals Growth Legierung (DE-588)4035035-6 gnd Kristallisation (DE-588)4033215-9 gnd Erstarrung (DE-588)4140191-8 gnd Metall (DE-588)4038860-8 gnd |
| topic_facet | Metal crystals Growth Legierung Kristallisation Erstarrung Metall |
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