Colloidal suspension rheology:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge [u.a.]
Cambridge Univ. Press
2012
|
| Ausgabe: | 1. publ. |
| Schriftenreihe: | Cambridge series in chemical engineering
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XXI, 393 S. Ill., graph. Darst. |
| ISBN: | 9781107622807 9780521515993 0521515998 |
Internformat
MARC
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| 100 | 1 | |a Mewis, Jan |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Colloidal suspension rheology |c Jan Mewis ; Norman J. Wagner |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a Cambridge [u.a.] |b Cambridge Univ. Press |c 2012 | |
| 300 | |a XXI, 393 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Cambridge series in chemical engineering | |
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| 700 | 1 | |a Wagner, Norman Joseph |d 1962- |e Verfasser |0 (DE-588)136262392 |4 aut | |
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Datensatz im Suchindex
| _version_ | 1804148546500296704 |
|---|---|
| adam_text | Contents
Preface
page
xiii
General list of symbols
xvi
Useful physical constants and values
xx
1
Introduction to colloid science and rheology
................... 1
1.1
Colloidal phenomena
1
1.1.1
Forces acting on individual colloids
2
1.1.2
Colloidal interactions
6
1.1.3
Phase behavior and colloidal stability
15
1.2
Principles of rheology
18
1.2.1
Basic concepts
18
1.2.2
Generalized Newtonian fluids
24
1.2.3
Viscoelasticity
25
1.2.4
Application to colloidal dispersions
30
A look ahead
32
Appendix: Second virial coefficients
32
Chapter notation
33
References
34
2
Hydrodynamic effects: Non-colloidal particles
................. 36
2.1
Introduction
36
2.2
Landmark observations
37
2.2.1
Summary
40
2.3
Dilute systems
41
2.3.1
Flow around and motion of single particles
41
2.3.2
Viscosity of dilute suspensions
43
2.3.3
Summary
46
2.4
Semi-dilute suspensions
46
2.4.1
Summary
51
2.5
Concentrated suspensions
51
2.5.1
Microstructure
52
2.5.2
Viscosity
54
2.5.3
Other stress components
60
vii
viii Contents
2.5.4
Summary
62
2.6
Other flow phenomena
63
2.6.1
Diffusion or migration
63
2.6.2
Inerţial
effects
67
2.6.3
Sedimentation
68
2.6.4
Summary
69
Appendix A: Derivation of Einstein expression for intrinsic
viscosity
70
Appendix B: Derivation of phenomenological equations for
suspension viscosity
71
Chapter notation
72
References
73
Brownian hard spheres
...................................80
3.1
Introduction
80
3.2
Landmark observations
81
3.3
Structure and thermodynamic properties of the hard
sphere fluid
85
3.3.1
Pressure in a hard sphere fluid
86
3.3.2
Brownian forces in concentrated dispersions
87
3.4
Rheology of dilute and semi-dilute dispersions
90
3.5
Concentrated dispersions
95
3.5.1
Zero shear viscosity
95
3.5.2
Linear viscoelasticity
101
3.5.3
Steady shear rheology
105
3.5.4
Hard sphere colloidal glass transition and
mode-coupling theory
109
Summary
112
Appendix A: Principles of the Smoluchowski equation for
dispersion micromechanics
113
Appendix B: The role of hydrodynamic interactions
114
Appendix C: Osmotic pressure for a hard sphere solid
115
Chapter notation
116
References
116
Stable systems
........................................ 122
4.1
Introduction
122
4.2
Landmark observations
123
4.3
Electrostatically stabilized systems
127
4.3.1
Dilute and semi-dilute suspensions
127
4.3.2
Concentrated suspensions
131
4.4
Sterically stabilized systems
137
4.4.1
Mechanism
137
4.4.2
Dilute systems
138
4.4.3
Non-dilute systems
139
4.5
Electrosterically stabilized systems
147
Contents ix
Summary
149
Chapter notation
149
References
150
5
Non-spherical particles
.................................. 155
5.1
Introduction
155
5.2
Landmark observations
155
5.3
Particle motion
160
5.4
Rheology of dilute suspensions of non-spherical particles
163
5.5
Semi-dilute suspensions of non-spherical particles
167
5.6
Concentrated suspensions of non-spherical particles
168
5.7
Charged non-spherical particles
172
Summary
173
Appendix: Structural description of the stresses in fiber suspensions
173
Chapter notation
175
References
176
6
Colloidal attractions and flocculated dispersions
.............. 180
6.1
Introduction
180
6.1.1
Methods to induce interparticle attraction and
flocculation
181
6.2
Landmark observations
183
6.3
Phase behavior,
microstructure,
and state diagrams
187
6.3.1
Equilibrium phase behavior
187
6.3.2
Floes and fractals
188
6.3.3
Effect of flow on floe structure
190
6.3.4
Stable clusters
193
6.3.5
Percolation, gelation, jamming, and vitrification
193
6.4
Rheology at low volume fractions
201
6.5
Concentrated dispersions
203
6.6
Rheology of gelled systems
206
6.6.1
Moduli and yield stress of gels
207
6.7
Kinetics of aggregating systems
214
6.8
Polymer bridge flocculation
214
Summary
215
Appendix: Influence of weak attractions on near hard sphere
dispersion rheology
216
Chapter notation
217
References
218
7
Thixotropy
........................................... 228
7.1
Introduction
228
7.2
The concept of thixotropy
228
7.2.1
Definition
228
7.2.2
Thixotropy versus viscoelasticity
230
7.3
Landmark observations
231
Contents
7.4 Rheological
phenomena
232
7.4.1
Start-up and intermittent flows
232
7.4.2
Hysteresis loops
234
7.4.3
Stepwise changes in shear
235
7.4.4
Creep tests
236
7.4.5
Oscillatory flow
237
7.5
Constitutive equations
239
7.5.1
Structure kinetics models
239
7.5.2
Integral models
244
Summary
245
Appendix: Parameter estimation and model assessment
245
Chapter notation
248
References
248
Shear thickening
.......................................252
8.1
Introduction
252
8.2
Landmark observations
253
8.3
Shear thickening colloidal dispersions
261
8.3.1
Dilute dispersions
261
8.3.2
Concentrated dispersions
265
8.3.3
Non-spherical particle dispersions
274
8.3.4
Extensional thickening, confinement, and field effects
275
8.3.5
Elastohydrodynamic limit of shear thickening
277
8.3.6
Models for predicting the onset of shear thickening
278
8.4
Dilatancy and shear thickening in suspensions
281
Summary
283
Chapter notation
284
References
284
Rheometry of suspensions
............................... 291
9.1
Introduction
291
9.2
Basic measurement geometries
291
9.2.1
Cone and plate
292
9.2.2
Parallel disks
292
9.2.3
Coaxial cylinders
293
9.2.4
Capillary flow
294
9.3
Measurement problems and basic procedures
295
9.3.1
Measurement problems
295
9.3.2
Selection of measurement geometry
297
9.3.3
General measurement procedures
299
9.4
Specific measurement procedures
300
9.4.1
Wall slip
300
9.4.2
Yield stress (shear)
305
9.4.3
Compressive
yield stress
313
9.4.4
Thixotropy
315
9.4.5
Large amplitude oscillatory shear flow (LAOS)
316
Contents xi
Appendix: Characterization
of wall slip
318
Chapter notation
319
References
320
10
Suspensions in viscoelastic media
..........................325
10.1
Introduction
325
10.2
Landmark observations
326
10.3
Particle motion
329
10.4
Rheological behaviour of dilute suspensions
335
10.5
Rheological behavior of concentrated suspensions
336
10.5.1
Steady state shear flow
337
10.5.2
Dynamic moduli
340
10.5.3
Relaxation function
341
10.5.4
Uniaxial extensional
flow
341
10.5.5
Fiber suspensions
341
10.5.6
Filled polymer melts and nanocomposites
343
Summary
346
Chapter notation
347
References
347
11
Advanced topics
.......................................354
11.1
Special methods for bulk rheometry
354
11.1.1
Stress jumps
354
11.1.2
Superposition moduli
355
11.2
Microrheology
357
11.2.1
Passive microrheology
359
11.2.2
Active microrheology
360
11.2.3
Nonlinear microrheology
361
11.2.4
Concluding remarks
364
11.3
Field-response systems:
Electr
orheological and
magnetorheological suspensions
365
11.3.1
Electrorheological fluids
365
11.3.2
Magnetorheological fluids
371
11.4
Two-dimensional colloidal suspensions
373
11.4.1
Interactions and structure in 2D suspensions
374
11.4.2
Interfacial
rheometry
376
11.4.3
Rheological properties of 2D suspensions
378
11.4.4
Flow visualization using 2D suspensions
380
Chapter notation
381
References
382
Index
388
|
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| discipline | Physik Chemie |
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| physical | XXI, 393 S. Ill., graph. Darst. |
| publishDate | 2012 |
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| series2 | Cambridge series in chemical engineering |
| spelling | Mewis, Jan Verfasser aut Colloidal suspension rheology Jan Mewis ; Norman J. Wagner 1. publ. Cambridge [u.a.] Cambridge Univ. Press 2012 XXI, 393 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Cambridge series in chemical engineering Rheologie (DE-588)4049828-1 gnd rswk-swf Kolloidphysik (DE-588)4713763-0 gnd rswk-swf Rheologie (DE-588)4049828-1 s Kolloidphysik (DE-588)4713763-0 s DE-604 Wagner, Norman Joseph 1962- Verfasser (DE-588)136262392 aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024530520&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Mewis, Jan Wagner, Norman Joseph 1962- Colloidal suspension rheology Rheologie (DE-588)4049828-1 gnd Kolloidphysik (DE-588)4713763-0 gnd |
| subject_GND | (DE-588)4049828-1 (DE-588)4713763-0 |
| title | Colloidal suspension rheology |
| title_auth | Colloidal suspension rheology |
| title_exact_search | Colloidal suspension rheology |
| title_full | Colloidal suspension rheology Jan Mewis ; Norman J. Wagner |
| title_fullStr | Colloidal suspension rheology Jan Mewis ; Norman J. Wagner |
| title_full_unstemmed | Colloidal suspension rheology Jan Mewis ; Norman J. Wagner |
| title_short | Colloidal suspension rheology |
| title_sort | colloidal suspension rheology |
| topic | Rheologie (DE-588)4049828-1 gnd Kolloidphysik (DE-588)4713763-0 gnd |
| topic_facet | Rheologie Kolloidphysik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024530520&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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